Search Documents

By W. Zhang

"The adsorption of collector on bornite has been studied in situ in aqueous solutions by applying an atomic force microscopy (AFM). The AFM images show that xanthate, such as potassium ethyl xanthate (KEX) and potassium amyl xanthate (PAX), adsorbs strongly on bornite mainly in the form of insoluble metal xanthate, which binds strongly with the mineral surface without being removed by flushing with ethanol alcohol. This adsorption mechanism is very similar to the one obtained with chalcocite/xanthate system. However, the result also clearly shows that the adsorption of xanthate on bornite is totally different from its adsorption on chalcopyrite, during which oily dixanthogen is the main adsorption product on chalcopyrite surface. The obtained AFM images also showed that the adsorption increases with increasing the collector’s concentration. When Cytec Aerofloat 238, a dialkyl dithiophosphate collector, is used, it adsorb on bornite mainly in the form of an oily substance, which can be rinsed off mineral surface by flushing with ethanol alcohol. AFM images also show that the adsorption of Cytec Aerofloat 238 increases with increasing the adsorption time. INTRODUCTION The adsorption of collector on mineral surface is vital for a successful flotation process to achieve a satisfying recovery. Historically, many works have been carried out to clarify the adsorption mechanism of collectors on sulfides. (Gaudin and Schuhmann, 1936, Poling and Leja, 1963; Allison et al., 1972, Fuerstenau, 1982; Leja, 1982; Woods, 1984) Compared to other copper minerals such as chalcopyrite and chalcocite, much less work has been done to study the adsorption collector on bornite. Allison et al. (1972) studied the reaction products of various sulfide minerals with xanthate solutions and reported that the measured rest potential of bornite in 6.25×10-4 M KEX solution at pH 7 was +60 mV and the reaction product of PAX on bornite was cuprous alkyl xanthate. Mielczarski and Suoninen (1984a, 1984b) applied the XPS and studied the adsorption of potassium ethyl xanthate on cuprous sulfide. It was reported that there was a relatively rapid formation of a well-oriented monolayer of xanthate ions followed by a slow growth of disordered cuprous xanthate molecules on top of this layer. Buckley et al. (1984) investigated the surface oxidation of bornite by linear potential sweep voltammetry and X-ray Photoelectron Spectroscopy and proposed the adsorption products on bornite depended on the solution potential. Zachwieja et al. (1987) studied the electrochemical flotation of the bornite-ethylxanthate system and reported that KEX reacted with bornite through an electrochemical oxidation reaction forming cuprous xanthate between -0.4 and -0.2v (SCE). Hangone et al. (2005) studied the flotation of a bornite-rich copper sulfide ore using thio collectors and their mixtures and reported that the highest copper recoveries were obtained with the diethyl dithiophosphate (di C2-DTP)."

Jan 1, 2016

By Arthur E. Lewis

A contained nuclear explosion is proposed to produce a chimney of broken ore well below the water table. After the chimney is filled with water and reaches hydrostatic equilibrium, oxygen, under pressure, is introduced near the bottom of the mass of broken rock. The increase in solubility of oxygen at high hydrostatic pressure is sufficient to initiate the oxidation of the primary sulfides: chalcopyrite and pyrite. The oxidation and dissolution of these sulfides produces enough heat to increase the temperature of the ore and water in the chimney as much as 1000 to 150°C. The rate of dissolution of chalcopyrite becomes so rapid under these conditions that the rate of recovery is no longer limited by the rate of chalcopyrite dissolution, but by the degree of exposure and other factors. Means of solution control and distribution of oxygen in the chimney have been examined in some detail. A calculational model utilizing experimentally determined solubility rates is utilized to estimate the temperature rise in the chimney and the rate of copper recovery as a function of initial temperature, sulfide content of ore, size of sulfide particles, and fraction of sulfide exposed to solution.

Jan 1, 1972

By M. D. Ross

Complex combinations of technical, economical, safety and environmental factors are causing mining engineers everywhere to review their operations. Naturally, some of the traditional methods still have a large role to play because they are, in certain circumstances still adequate and are well understood. But, as circumstances change, a new approach is required. The combination of technical and economical reasons for introducing Long- wall mining in some seams in the United States is associated with strata control. Other reasons include simplifications and improvement of ventilation, reduced coal dust, more output from each unit and crew, increased percentage of recovery from each area of the coal deposit, and reduction of rock dusting. The innovations which transformed Longwall mining from a cyclic to a continuous mining system were the armored conveyor and power loading machines, but the crucial breakthrough for application to high production was the development of the powered roof support, which at once gave the system the advantages of mastery of strata control, increased rate of advance, significant reduction of manpower, and increased safety.

Jan 1, 1974

By F. W. Bond

Predictive ground-water modeling is currently being applied to a wide range of engineering applications. In recent years models have been used to evaluate the effect of large ground-water withdrawals on regional water supplies; subsidence associated with overpumping; siting and design studies for chemical dumps; siting and safety aspects of nuclear waste storage; and heavy metal migration from disposal sites. Similar modeling techniques could be used to analyze water-related problems in the minerals industry such as mine dewatering (both open pit and underground), environmental and pollution control, and process water supply and disposal The objective of this discussion is to describe how ground-water models are being used to assist in the solution of water-related problems outside the industry and to extrapolate that use to mining problems.

Jan 1, 1980

By Donna Wallace

Past EPA groundwater monitoring programs required that contamination not leave the boundaries of a disposal facility. New regulations under the Resource Conservation and Recovery Act (RCRA) require that once hazardous waste constituents are detected beyond the limits of the disposal area, a program to define the rate and extent of contaminant migration must be instituted. Future regulations are likely to include even more stringent groundwater protection criteria. The implications of both the existing and probable future groundwater protection and monitoring requirements in terms of using geologic containment as a means of disposing of hazardous waste are explored in this paper.

Jan 1, 1981

By Stanley Kesler

The first of two initial 650-mw units of the Paradise Steam Station, located on the banks of the Green River in the south-central portion of the western Kentucky coal basin, is scheduled for operation in late fall of 1962. Location of the site is shown on the map of figure 1. This plant will be the eighth, large-capacity,, modern station built by TVA in a series starting with Johnsonville, operated first in 1951. During that period of 10 years,, unit sizes have increased from a capability of 125 mw to 500 mw at the recently completed Widows Creek Unit 7 addition and at Paradise to 650 mw. This new unit will take its place in a power system that serves an area of some 80,000; square miles with a present installed capacity of over 12,000 mw. Upon completion of the Paradise units and other additional hydro and steam units presently under construction, the system capacity will have reached over 15,000 mw. Projected load estimates indicate that this system will provide a margin' of slightly under 10 percent of dependable capacity above peak demand at that tire. One Paradise 650-mw unit at that time will represent approximately 4 percent of the total system installed capacity.

Jan 1, 1962

By R. L. Clayton

The Bagdad district is 67 kilometers west of Prescott, Arizona, (Figure 1). The area north of the Old Dick and Bruce Mines was originally mapped by Anderson, Scholz and Strobell between 1943 and 1945, (1). The region is perhaps better known for the Bagdad porphyry copper deposit of tertiary age. However, 2 to 5 kilometers south of this deposit are several small massive sulfide occurrences in a eugeosynclinal Precambrian greenschist environment. More specifically, in. the Bridle formation of the Yavapai schist series. Three of these mines - Old Dick, Bruce and Copper Queen - were mined by Cyprus Mines Corporation between 1957 and 1977, and produced nearly 2mm tons of 3.6% copper and 12% zinc. These deposits occur at the interface between andesite and rhyolite and are stratiform in character. Certain structural and textural properties of the Bruce orebody suggest that remobilization of the massive sulfides occurred at some period during the metamorphic history of the area.

Jan 1, 1978

By Benjamin Grunauer, Anthony Iannacchione, Taylor DaCanal

"In Pennsylvania’s rich mining history, various forms of room-and-pillar mining have been in use for over 150 years. Longwall mining, introduced in the late 1960s, occupies only the last 60 of those 150 years and now represents the dominant method of extracting coal in the Pittsburgh coalbed. The introduction of longwall mining allowed larger quantities of coal to be extracted in safer and more efficient manners than room-and-pillar mining. However, the associated formation of subsidence basins have elevated both the number and intensity of watersource and surface structure impacts. When these first longwall panels were mined the factors responsible for these impacts were poorly understood and regulations were focused only on surface structures. Today, with over 600 panels mined under a wide range of conditions, these factors are known and regulations have developed to help mitigate water supply and surface structure impacts.The cause and severity of surface effects are thought to be dependent on multiple factors, including the location within the subsidence basin, overburden, panel width, and orientation of the panel. The changing characteristics of over 600 longwall panels mined in the last 60 years are analyzed to determine factors important in subsidence related surface impacts. This study compares the location of the surface impacts with the longwall panel size, overburden, and maximum predicted vertical subsidence. The data shows that changing these characteristics are impacting surface features in a significant manner as measured by the number of company liable reported effects.INTRODUCTIONLongwall mining has occurred in Pennsylvania for over 60 years, and at the current mining rates, longwall mining is expected to continue in the Pennsylvania Pittsburgh Coalbed until the reserves are exhausted. Figure 1 shows all mining that has occurred in the Pittsburgh Coalbed, as well as the area that is left to mine. It is predicted that there are 40 years left of longwall mining on the Pittsburgh Coalbed, under the assumption that 50% of the total 280,000 acres will be mined at the current rate of 3500 acres/year."

Jan 1, 2019

By C. W. Armbrust

At FHC Gold Company's Paradise Peak Mine gold and silver are produced. Precious metals recovery rates are very satisfactory along with the recovery and production of a relative high volume of mercury. At Paradise Peak precious metals are recovered via the Merrill-Crowe process and delivered to the refinery area as a mercury-bearing precipitate cake. The recovery of mercury is then obtained through a vacuum retort system. The balance of the material is mixed with fluxes and then melted and cast into dore' bars for shipping. Issues of retort capacity and concerns over efficiency led to research into the retort process itself.

Jan 1, 1990

By Samuel S. Adams

The Permian Salado Formation of west Texas and southeastern New Mexico is composed of halite and subordinate amounts of anhydrite, clay and potassium and magnesium-bearing evaporite minerals. Aspects of the geochemistry of the Salado Formation have been investigated through studies of the stratigraphy, mineral assemblages, textures and minor element content of the salts. These studies provide information on the origin of the evaporites when combined with data on equilibria in saturated salt solutions. The principal potash ore zone in the district is composed essentially of halite (NaC1) and sylvite (KC1). Data on the color, bromide content, and proportions of halite and sylvite suggest that this simple assemblage is the product of a series of replacements rather than primary precipitation. The bromide content of the salts also indicates that the brine which precipitated the Salado Formation was derived from the dissolution of older evaporites rather than the simple evaporation of sea water.

Jan 1, 1966

By Liliana Rybarska-Rusinek, Aleksandr M. Linkov, Ewa Rejwer-Kosińska

Joined modeling of stressed state and induced seismicity is a means to join geomechanics with seismic observations. When applied to quantifying rockburst hazard, it provides, on one hand, estimations in terms of mechanics, such as stress concentration, and, on the other hand, in statistical terms of the risk analysis developed in mining seismology. The modeling became possible due to progress in computers and numerical methods. However, despite tremendous increase of computational abilities, the joined modeling is still quite time expensive. To make it available for wide use and real time simulations, there is need to reduce the time cost of its key stages: calculation of stresses, caused by mining, and simulation of seismic events, induced by these stresses. The present work aims to decrease the time cost. The stages are time costly because of the same reason, which is a very large number N (up to millions) of elements, representing rock structure, openings and flaws. This leads to immense computational complexity (roughly of order N2) of conventional accounting for pairwise interactions between the elements. The complexity may be notably reduced, when employing the fact that interactions decrease with growing distance between elements. Specifically, the fast multipole methods (FMM) avoid the complexity N2, by employing translations of far-fields from whole collections of sources. This reduces the complexity to the order 22, where p is the number of terms involved in a single translation, is the number of translations, and is the dimension of the quantity translated. Still, for conventional FMM, the complexity remains too high to routinely perform joined modeling of stresses and seismicity.

Apr 26, 2022

"Longwall shearers are widely employed in underground coal mines. The reliability of such machine has significant importance for successful mining operations. This paper aims at studying reliability of a longwall shearer using failure data recorded for a year. Data was pre-processed, sorted and selected for analysis. Selected data is then examined using statistical models. Distribution fitting of time-between-failure (TBF) and time-to-repair (TTR) are accomplished using three different models. Goodness-of-fit criteria is used to ascertain the best fitting model. Reliability in terms of mean-time-between-failure (MTBF), and mean-time-to-repair (MTTR) are calculated using the model which best represents the failure data. Exponential distribution best represents the time between failure and lognormal distribution the time to repair data. A well-known risk management technique Failure Mode Effect and Criticality Analysis is used to evaluate the critical breakdowns. Critical system/parts, experiencing regular failures is delineated based on this analysis. INTRODUCTION Mining is a capital intensive process, and huge monetary investment is required to develop and operate a mining project. Heavy and expensive equipment’s are employed in development and operation of these projects. In order to ensure timely completion of set milestones, it is mandatory that equipment’s perform their required task productively. Delays are not unusual owing to breakdown of these equipment’s. Breakdown or failure experienced by any of the equipment pose heavy financial burden. Moreover, frequent times, companies have to employ and dedicate additional resources to make up for such delays. Delays in project is not only detrimental to company’s image in market, but it also interrupts customer commitments. Mines having history of not fulfilling their promise usually get lower commodity price. Penalties are also imposed on the companies defaulting its obligations. Especially, in today’s world where competition among the companies are growing, success means keeping up the commitments in a timely manner. Heavy machinery and equipment are instrumental in success of any project. These machinery and equipment’s have to reliable in a sense that they can perform the set task in given time period. Reliability of these equipment plays a pivotal role in success of any project. The reliability analysis of mining equipment has long history. Many researchers have applied different statistical models for analyzing the reliability of mining machines (Samanta, Sarkar [1]. Kumar and Klefsjö [2] demonstrated the use of the power law process model for reliability assessments of repairable mining machines. Barabady and Kumar [3] performed the reliability analysis from failure data of the crushing plants."

Jan 1, 2018

By D. R. Spears

The U.S. Bureau of Mines has developed a Fast Air-injected hydrocyclone-Shallow Tank (FAST) flotation system. Conventional flotation cell kinetics are a compromise between two conflicting requirements, the need for an agitated zone for rapid bubble-particle collision, and a quiescent zone for bubble-pulp separation. The Bureau of Mines has designed a flotation system in which bubble-particle collision and bubble separation are carried out in two discreet unit operations. A bubble slurry was mixed with an ore slurry at a high rate in a modified air-injected hydrocyclone for rapid bubble-particle collision. The mixture was then fed into a unit specially designed for rapid separation of the bubbles from the pulp. A conventional flotation cell required 2.8 min to obtain 90 pet recovery at a 7-pct Cu rougher concentrate grade, whereas the FAST flotation system can obtain 85 pet recovery with a 13-pct Cu rougher concentrate grade in 0.28 min, and 92 pet recovery with a 7-pet Cu grade in 0.56 min. The Bureau's FAST flotation system is adaptable to a wider variety of flow sheets and could potentially allow for replacement of conventional flotation cells with smaller and faster units.

Jan 1, 1991

By P. Munjal

"Usage of Supercritical CO2 in place of high pressure freshwater has proven to be a potential breakthrough in the technique of fracturing. Tapping of carbon footprints from feasible sources like industries can be used to manufacture Supercritical CO2 required for fracking. Supercritical CO2, being less viscous than water, creates complex and coherent micro-fractures which can connect many more natural fractures greatly, increasing maximally the fractures’ conductivity leading to an increment in production. The better clean-up property of Supercritical CO2 provides auxiliary benefits of immediate evaluation of fracture zones, usage of an optimized quantity of mesh proppant and elimination of the need of swabbing. Also, Coal has a stronger affinity for CO2 than for CH4. When CO2 is present, CH4 on coal is replaced by CO2. This also ensures rigorous recovery of gas from the coal beds. Use of Supercritical CO2 will obliterate many problems as the CO2 used for fracturing is either sequestered beneath the crust or is recovered at the surface and reused. Therefore, injecting CO2 into coalbeds achieves not only enhanced CBM recovery, but also greenhouse sequestration underground. INTRODUCTION Coalbed Methane At various times in the geologic past, earth had dense forests in low-lying wetland areas. Due to natural processes such as flooding, these forests were buried underneath the soil. As more and more soil deposited over them, these dead plant remains were compressed. As the process continued the plant matter was protected from biodegradation and oxidation, usually by mud or acidic water. Under high pressure and high temperature, dead vegetation was slowly converted to coal. The omnibus process of formation of coal, thus, comprises of conversion of dead plant matter into peat, followed by its conversion to lignite, then sub-bituminous coal, after that bituminous coal, and lastly anthracite. This process of enrichment of coal as it is progressively forced deeper into an ambience with higher temperature and pressure involves biological and geological processes that take place over a long period and is called coalification. During coalification, large amounts of methane-rich gas are generated and stored within the coal on internal surfaces; hence comes coalbed methane. Coalbed methane (CBM), a gas formed as part of the geological processes that are responsible for the generation of coal, is adsorbed into the solid matrix of the coal during its formation process. Coalbed methane is distinct from a typical sandstone or other conventional gas reservoirs, as the methane is adsorbed and not absorbed. The methane is in a near-liquid state, lining the inside of pores within the coal. The open fractures in the coal that result from the liberation of volatile materials (and subsequent contraction due to the liberation) from the coal due to the high temperature and pressure conditions encountered, called cleats, may also contain free gas or can be saturated with water."

Jan 1, 2015

By R. C. Emmett

The industrial practice of concentration of solids and production of clear solution by gravity sedimentation is an old technology. Through the years, many devices have been designed and built to aid this process. One of the more significant developments was a revolving rake mechanism to convey settled material to a central discharge point of a circular tank, patented in 1907(1). In recent years, clarification systems employing parallel inclined plates have appeared on the market; the original device utilizing this principle was patented in 1886(2). Numerous other methods have been invented, tested, discarded and sometimes re-invented, all with the specific intention of improving the capacity of a particular settling area. Sedimentation theory, as expressed in Stokes' Law, shows that the rate of settling of a particle is directly proportional to the difference in density between the particle and the surrounding liquid and, more significantly, proportional to the square of the particle diameter. Anything that can increase the latter will greatly assist sedimentation and, as a result, flocculation always has been an integral part of sedimentation. Most materials suspended in aqueous media are naturally flocculent to some degree and, hence, are readily concentrated by sedimentation, although sometimes very slowly.

Jan 1, 1978

By R. K. Singhal

This new tool can be used for the proper assessment of the potential economic wealth of any risky capital project. It does provide an unambiguous recommendation of the type "go or no go" to the decision-maker simply by comparing two different ratios profit/investment. One ratio determines the minimum value required to at least break-even while the other measures a probable value based on the asymptotic theory of statistical extremes (weakest link concept). Its application is briefly illustrated by means of an underground gold mine project, an oil sands mine project and a poly-metallic open pit project.

Jan 1, 1993

By R. Venkataramani

Crushed stone operations have become more difficult due to rising costs of labor and equipment, with the consequent reduction in profit margins. Competition from other operators and the encroachment of vertically integrated companies place severe restrictions on available markets. The seasonal demand for stone precludes any definite production level, and changes in productivity have to be accommodated. These influence profitability, and therefore production plans must be continuously adjusted to keep pace with rapidly changing conditions. The basic problem of stone companies seeking to maximize profits is one of balancing stone production costs, costs of inventory holding and stock-piling, marketing costs and any other charges accruing over time against the selling price of stone. Because of high peak demands, slack period production must be stored and then distributed to supplement peak period production. For a multi-plant operation, there is a need to evaluate at the same time the interaction between the plants and the various marketing sectors. In a multi-plant operation with different production capacities and production costs, stone producers are interested in the answers to the following questions: 1. How much stone should be produced at each plant in each time period? 2. What should be the optimum stone shipment from each plant to each market? 3. What are the effects on net returns and shipping plans, if production capacities are altered at the plants? These questions have many different answers that, will satisfy demands. From the point of production scheduling, the minimum production cost may be the objective. From the inventory standpoint, the best solution will be to synchronize production with sales. However, when the transportation of stone is also considered, the desired end is to achieve that delivered cost which maximizes the company f s net return. Besides, only an extremely naive analysis ,wouId attempt to

Jan 1, 1971

By J. C. Motz

During the past five years, Rexnord has developed, tested and introduced the Nordberg Omnicone Crusher to the industry. When the Symons brothers invented the cone crusher over 60 years ago, they employed the principle wherein the length of the crushing stroke was related to the free fall of material by gravity. This permitted the material being crushed to fall vertically in the crushing chamber; and in effect, caused the particles to be crushed in a series of steps or stages as the particles got smaller due to the crushing action. This also helps to reduce the rate of wear of the liners since the sliding motion of the particles is minimized.

Jan 1, 1986

By M. J. Hrebar

Surface coal mine design has traditionally relied on graphic and analytic approaches for pit layout and equipment selection. A number of interactive graphic microcomputer programs have been written which aid in the design process in the academic arena and should also have industrial applications. The programs described include a dragline cut diagram and production index calculation program, a downslope load scraper cut diagram and volume program and an overburden volume and coal tonnage sequencing program.

Jan 1, 1985

By John L. Shafer

A process for the conversion of stibnite (Sb2Sj) concentrates, crude antimony oxide, or metal to a pure cubic antimonous oxide (senarmontite) has been developed on a laboratory scale. The conversion of stibnite to senarmontite has been piloted. The high purity of the final product is the result of forming antimony trichloride as a low temperature distillable intermediate. To obtain the antimony trichloride the stibnite, or crude oxide is slurried in molten antimony trichloride and reacted with gaseous hydrogen chloride. Antimony metal is oxidized to the trichloride with chlorine. The hydrogen sulfide produced from the hydro- chlorination of stibnite can be upgraded to a strength of 95% or greater for further treatment. The crude antimony trichloride is separated from the gangue by a preliminary evaporation and then is fractionally distilled and the trichloride distillate has less than 50ppm of arsenic and lead combined (the most troublesome impurities in antimony processing). The purified antimony trichloride is then hydrolyzed with sodium or ammonium hydroxide to produce the cubic form of antimonous oxide (senarmontite) to the exclusion of the rhombic form (valentinite) which is photosensitive. The advantage of this process is the ability to treat a wide range of antimony ores, concentrates, and metal to yield a high purity oxide in a controllable range of particle sizes.

Jan 1, 1975