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By A. S. Malicsi, M. D. Baker, I. Iwasaki

Fine grinding may he required for- some coals to remove sulfur and ash or to prepare coal-water slurry. Fine grinding leads to increased hall wear and its effect on the surface properties of the ground coal becomes of concern. Marked hall wear - tests were performed to study the effects of oxygen, pH, the soluble species of coal, and the addition of pyrrhotite on hall wear. The synergistic action of coal and oxygen greatly enhanced the corrosion of mild steel halls during grinding. Elec.trochemica1 measurements on a mild steel electrode in coal slurries and SEM observations of grinding hall surfaces were carried out to explore the corrosive wear mechanism.

Jan 1, 1991

By W. Lin, E. Heuze

This paper focuses on tests performed on sandstones and shales from four gas wells in the Mesaverde formation. A previous document showed a comparison of the static and dynamic laboratory moduli. This publication describes how field velocity logs were used to derive field dynamic moduli. A 3-way comparison was then performed for these stiffness properties; the results show no agreement between the three sets of values. Differences between dynamic stiffness coefficients from the field and the laboratory exceed 200%; differences between static and dynamic coefficients range up to 600%. In turn, this indicates that a reliable method of estimating mechanical rock properties for hydraulic fracturing design has not been established, and that such a task should be pursued.

Jan 1, 1986

By O. Olajide, E. H. Cho

A laboratory study of the jigging process with Pittsburgh seam coal has been conducted. The laboratory-scale Baum jig used in this study was a McNally-Norton LO30X Right Hand Model Baum jig with an effective screen area of 0.186 m2 Feed material was prepared by selecting a size range from 6 mesh to 1.91 cm. Solid feed rates were 27.2 kg/min and 32.7 kg/min. Water flow rates were varied from 37.9 to 94.6 L/min. It has been found that smaller particles give higher values of density of separation and lower efficiency of separation. Increasing water flow rate increases the discharge rate of clean coal at a constant solid feed rate. It appears that the efficiency of separation increases by increasing water flow rate up to a certain value, and then levels off upon increasing the flow rate further.

Jan 1, 1988

By H. K. Lin

Cyclic voltammetric and potential step chronoamperometric techniques were used to study gold dissolution in cyanide solution. Three distinct anodic peaks and one cathodic peak appear on the voltammogram between -0.50 and 0.80 V vs. SCE. The corresponding reactions were proposed to explain the peaks and the passivations. The proposed reactions were in agreement with the effect of pH and cyanide on the magnitude of the peak currents. Cyclic voltammetric tests, with various vertex potentials, were also conducted to examine the proposed reactions. Steady-state currents at various potentials were obtained by potential step chronoamperometric technique and were compared with transient currents obtained by the cyclic voltammetric technique.

Jan 1, 2002

By Richard D. Doepker, Cathy A. Summers

Part 1: Physical Characteristics The physical and mineralogical characteristics of samples from five sources in the Western United States were determined using size analyses, microscopic studies, and point counts. These results were combined with leachability assays and the chemistry of leachates obtained during slurry tests to predict sample dissolution characteristics during column leaching tests. Part 2: Dissolution Characteristics Two columns of each sample were leached over a period of 3 years with synthetic rain. Residence times were between 2 and 11 weeks. The samples were subjected to daily and seasonal temperature fluctuations and wet-dry and freeze-thaw cycles. During the latter part of this study, a biocide leachant (sodium benzoate) was substituted for synthetic rain to assess the degree of dissolution caused by biological oxidation. It was found that the presence or absence of barite or carbonate minerals can be used to predict the leaching behavior of the column material.

Jan 1, 1995

By Fred N. Kissell, Robert J. Timko

Safe escape from coal mine fires continues to be a concern of the mining industry. The most life-threatening fires occur outby the working sections. Because stoppings always leak some air, an outby fire may in time cause intake escapeways to become contaminated with smoke and toxic gases. Smoke and gas infiltration into intake escapeways can be minimized by raising their air pressure over that of adjacent airways. This can be done by checking off the intake escapeway near the working face. The Bureau of Mines has investigated the use of a parachute stopping as a quick-erect check curtain during mine fires, and the concept has been tested in several mines. In every instance, when a parachute stopping was erected on the section, the intake pressure went up substantially. The pressure-raising effect of the parachute persisted for up to 1200 m (4000 ft) outby. Results indicate that checking off the intake escapeway may serve as a viable way to improve safety during mine fires.

Jan 1, 1991

By Peter J. Suardini

Over the last few years, researcher have been working on improving procedures for fine-coal (minus 150 microns) washability analyses. The effort was stimulated by past difficulties in obtaining accurate and reproducible results from the various commercial laboratories providing fined washability services. This paper contains the results from fine-coal washability testing, performed by Process Technology, Inc. (PTI), as part of a U.S. Department of Energy (DOE)-sponsored project. The testing focused on comparing the performance of a number of media options (i.e., aqueous solutions and organic solvents), as well as evaluating the impact of a number of procedural steps on separation performance. The paper summarizes PTI's recommended washability procedures for various size fractions and ranks of coal, and makes recommendations for future studies of certain phenomenon, such as void penetration and particle density changes, which are not well understood.

Jan 1, 1995

By L. G. Austin, R. C. Klimpel

Batch breakage kinetic tests were performed in a mill of 0.3 m diameter for a range of mill conditions. Accurate simulation required the measurement and use of factors which accelerated the specific rates of breakage of the top sizes as finer material accumulated in the slurry. These factors depended on the size distribution expressed relative to the top size, not the absolute size, suggesting that they are due to a packing effect not a rheological effect. The data simulated correctly a series of steady-state continuous tests in a mill of the same diameter providing values were corrected to the hold-up, ball load, slurry density, and size distribution measured in the continuous mill tests.

Jan 1, 1990

By Mark J. Schultz, William J. Francart, Gary J. Wirth

Atmospheric Monitoring Systems (AMS) utilizing carbon monoxide sensors have demonstrated their superiority over thermal type fire sensors for early fire detection in underground coal mines. After proving their capability and dependability throughout the 1980's, systems are now evolving and applying new technologies to enhance their effectiveness and reliability. The use of AMS in coal mines which utilize diesel equipment presents unique obstacles. Exhaust gases from diesel equipment not only raise mine ambient CO readings, but also cause numerous nuisance alarms. Both of these conditions reduce the effectiveness of the AMS. New technologies, such as discriminating devices, smoke detectors, and time delays, as well as administrative controls, have been developed and are being utilized to help reduce nuisance alarms produced by the diesel exhaust. This paper will discuss these technologies and administrative controls which are being utilized in coal mines to enhance the effectiveness of the Atmospheric Monitoring Systems. Reference to specific products does not imply endorsement by the Mine Safety and Health Administration.

Jan 1, 1995

By P. V. Avotins, D. R. Nagaraj, S. S. Wang

Xanthates and dithiophosphates are the most commonly used collectors in the flotation of sulfide minerals. Other reagents such as thionocarbamates, mercaptobenzothiazoles (MBT), mercaptans and xanthogen formates occupy niche positions in industrial collector use. Over the last ten years there has been much activity by chemical companies to develop new collector compositions. The new collectors are aimed at meeting specific process needs such as recovering an increment of valuable metals, improved sulfide separations, increased flotation kinetics, and reducing reagents costs. A review of the patent literature shows that American Cyanamid (Cytec), Dow Chemical, Phillips Petroleum, Sentrachem Ltd., Henkel, Montan Chemicals and Elf Aquitaine, among others, have been active in sulfide collector research. Several companies have achieved considerable success in laboratory and plant tests of the new collectors; however, commercial acceptance for plant usage has been slow. Those most advanced have been plant tested extensively and some are in day-to-day use. The new collector types in this category are: Modified thionocarbamates, dithiophosphinates, organic sulfides, trithiocarbonates, monothiophosphates, and modified thioureas. Others such as substituted mercaptobenzothiazoles and monothiophosphinates have been tested in the laboratory. The chemistry of collectors developed in the last 10 years, their preparation, physical properties and their potential for commercial use are reviewed in this paper.

Jan 1, 1994

By Talaat A. B. Lawendy, Guerry H. McClellan

Batch laboratory-scale flotation tests were conducted on some carbonate-containing sedimentary phosphate ores to obtain concentrates suitable for chemical processing. The phosphate samples tested contained both calcite and dolomite. The calcitic phosphate ore was from Israel and the dolomitic ores were from China, India, Egypt, and Pakistan. The phosphate sample from Pakistan also contained a significant amount of silica. Several flotation techniques that have been proposed for upgrading carbonate -containing phosphate ores and concentrates were tested. Two processes gave better results compared with the other processes tested: a modified IMC anionic process and a. phosphoric acid depression process. At the best flotation conditions tested, phosphate concentrates assaying 32.5%-36.5% P205, 44.0%-51.0% CaO, and 0.6%-1.0% MgO were obtained at 69%-76% overall P205 recoveries from run-of-mine (ROM) ores containing 16.0%-25.0% P205, 40.0%-52.0% CaO, and 1.0%-11.6% MgO.

Jan 1, 1993

By Y. M. Jiang

From underground instrumentation data and from direct observation of longwall panels, it was demonstrated that growth of the main-roof overhang causes an extremely high roof weighting on the face supports. This can result in catastrophic effects on the supports when the roof-weighting intensity far exceeds the support capacity. In this paper, a comprehensive study was conducted on the characteristics of main-roof breakage and its effects on shields at different locations along the face. The study was based on monitored shield data, theoretical analysis and finite element analysis. With the help of theoretical analysis and numerical modeling, stress distribution and redistribution in the main roof were analyzed to define the main-roof failure modes and to understand the maximum roof-weighting intensity imposed on the shields. From this study, it was found that the effects of main-roof breakage on shields are chiefly related to the shield's initial-setting condition and to the final failure mode of the main roof.

Jan 1, 1996

By H. E. M. N. Moursy, Hassan El-Shall, M. N. Ahmad, Ponisseril Somasundaran, C. R. Holland, D. Chandler, G. Walker, Regis Stana, Patrick Zhang

The reaction kinetics of the acidulation of Moroccan phosphate rock (32% P?05) using 45% nitric acid were investigated using the Shrinking Core Model (SCM) , a newly developed Diffusion Model (DM) and a newly developed Combined Reaction and Diffusion Model (CRDM). This was achieved buy conducting a number of experiments in a controlled batch reactor system at different temperatures. The conversion and the reaction rate were calculated at different time intervals. The SCM based on reaction time and the CRDM characterize the acidulation process of phosphate rock. Diffusion of nitric acid and the products of acidulation at the early stages of reaction through the phosphate rock were found to be the rate-controlling step, resulting in a dif- fusion coefficient, which controls the mass transfer process. The reaction kinetics were found to fit first-order kinetics especially during early stages of reaction time. The deviation of the kinetics from first-order at later stages was due to the fact that the overall reaction was mass transfer controlled with respect to nitric acid and products diffusion.

Jan 1, 2002

By D. Elsworth, M. Bai

The influence of mining on the hydro-geo-mechanical environment can be greatly modified by alternating mining geometries. The limiting magnitudes of surface subsidence and groundwater flow over the mining area, as a result of mine geometric changes, can be reasonably predicted through the coupled finite-element model introduced in this paper. The model has been verified using real and conceptual case studies which reveal that changes in strata conductivities are strongly related to the strata deformation induced by mining. The greatest modification of hydraulic conductivities occurs within the caving or severely fractured zones. The study indicates that narrowing the panel face width will substantially reduce both the intensity and extent of mining damage to the overlying strata, limit surface subsidence and constrain the change in hydraulic conductivity to a reduced scale and smaller extent, particularly as mining depth increases.

Jan 1, 1995

By N. Choi, W. D. Cho

Distribution coefficients of gold and silver between matte and slag during the pyrometallurgical treatment of nickel-copper sulfide concentrates were evaluated as a function of matte and slag compositions in the temperature range of 1,250oC to 1,300oC. It was observed that the composition of the matte phase, including matte grade and copper content in the matte, significantly affected the distribution behavior of gold and silver in the matte-slag system. Both gold and silver preferentially concentrated in the matte phase as the matte grade increased With increasing temperature and copper content in the matte, the distribution coefficients of silver increased, while the gold distribution coefficients decreased. It was also, found that slag additives such as CaO, MgO, and A12O3 caused a significant decrease in the solubility of both gold and silver in silica-saturated iron silicate slag. An activity coefficient of gold in matte was derived from the experimenta1 results.

Jan 1, 1999

By M. W. Rutland, E. Manev, R. J. Pugh

Data collected from several different fundamental surface chemical techniques were compared to study the interfacial interactions in the dodecylaminelmica flotation system. In the present study, the method used was the microinterferometric free foam film technique of Scheludko (1967) in which the stability, thickness and interfacial potentials at the air/dodecylamine solution interface were determined. These results were compared to previously published data, obtained from surface force measurements (Rutland et al. 1992), in which the interaction and hydrophobic adhesion (pull-off force) between molecularly smooth mica sheets in the amine solution had been reported. Also equilibrium contact angle measurements were used for comparison. The data was collected over a range of pH values and related to the batch flotation response of mica in dodecylamine solution. It was found that maximum flotation occurred at pH 8, but this did not correlate with the minimum in double layer interaction potential. However, it appeared to correspond with a tightly packed collector monolayer giving maximum hydrophobicity to the mica surface. Finally, from the extended DLVO theory, it was shown that heterocoagulation between the bubble and the mica could only occur, providing there was a very long range hydrophobic interaction force to counterbalance the repulsive van der Waals and electrostatic forces.

Jan 1, 1995

By J. W. Craven, M. Katom, K. M. McCaffery

At Ok Tedi, ore type and SAG feed size distribution vary widely and frequently. This makes control of the SAG mills by application of the power/pressure relationship difficult. Power logic has traditionally been conservative due to power spikes associated with rapid size-distribution changes. A new expert system was installed in early 2000. The system incorporates multiple state fuzzy logic to deal with frequent and radical ore type and size variations, along with monitoring of motor temperatures. A short-term power spike no longer warrants immediate radical action. This has resulted in increased mill throughput and improved circuit stability. Key words: SAG mills, Mill control, Fuzzy logic

Jan 1, 2003

By Gregg Sherry, Bob Gordan

INTRODUCTION This paper report presents the general case history for the construction of the North Outfall Replacement Sewer (NORS) project. A 1982 City of Los Angeles Wastewater Facilities Plan recognized that a 19.3 km (12¬mile) section of the North Outfall Sewer (NOS), from Culver City to the Hyperion Treatment Plant, was deteriorating and had insufficient capacity. Built in the 1920s of unreinforced concrete and lined with vitreous clay tiles, the originally unventilated NOS suffered considerable corrosion by H2S gas. This caused roof tile and concrete to fall to the bottom of the pipe, which, over the years, reduced the 11.9 M3/S (420 cubic feet per second (cfs)) design capacity of the NOS to a current level of approximately 8.5 M3/S (300 cfs). This worsening condition, thereby contributing to the polluting of Santa Monica Bay. This situation culminated in the State of California Regional Water Quality Control Board, Los Angeles Region, issuing a Cease and Desist Order on January 27, 1986, which required the City of Los Angeles to eliminate such dry weather overflows through a number of prescribed actions. One of these was to construct the North Outfall Replacement Sewer (NORS) by April 1, 1993. PROJECT DESCRIPTION The NORS Project involved the construction of over eight miles of tunnel and related structures. It consisted of a main tunnel conduit to convey sewage to the Hyperion Treatment Plant and four diversion lines connecting the main tunnel to major existing

Jan 1, 1993

[Costs may be classified according to their source and behavior: Scale of aggregation - Total costs - Unit costs Time period for which the costs are charged - Product costs - Period costs Controllability and relevance for decision-making and control - Controllable costs - Noncontrollable costs - Sunkcosts - Opportunity costs Their basic source - Production costs (also termed manufacturing costs) - Nonproduction costs How the costs change with changes in activity - Fixed costs - Variable costs - Semivariable costs Traceability to individual units of production - Direct costs - Indirect costs Use in planning (budgeting) and subsequent control - Standard costs - Normal costs ]

Jan 1, 1999

By Leslie S. Halasz

This paper describes the techniques implemented at Randfontein Estates to develop twin-haulages at 'high speed'. An operation which culminated in the world record advance for twin-end multiblast cyclic development in hard abrasive quartzites. A major expansion project was planned for the mine, with the sinking of a third twin-shaft system (to be known as Cooke No. 3), to raise the level of ore production from 3 500 000 to 5 000 000 tonnes per alumm. Subsequent redesign of the proposed shaft system as a single 9 m brattice wall shaft took place, reducing the planned shaft sinking period by 12 months and saving an estimated R 250 000 (U.S. $ 330 000) in sinking costs. The advancement of the Cooke No. 3 Shaft sinking and development programme necessitated a rapid excavation schedule for two interconnecting twin-haulages from the existing Cooke No. 2 twin shaft complex to provide a second means of egress. An early holing between the two shafts would provide significant financial and technical benefits. Pre-development and equipping of shaft pillar excavations would enable a rapid shaft production build up and blocking out of at least one year's ore-reserves.

Jan 1, 1983