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By Hajime Miki, Michael J. Nicol

Relatively simple techniques have been developed which enable the electrochemistry of sulfide minerals to be studied with particles varying in size from above 100 pm to less than 1 pm. Both oxidative and reductive processes have been studied wing the minerals pyrite, arsenopyrite and chalcopyrite. It has been shown that it is possible to completely oxidise or reduce the minerals during a single voltammetic sweep. The resulting voltammogram produces peaks which are characteristic of each mineral and can be used to qualitatively identify the minerals. In the case of chalcopyrite, it has been demonstrated that the charge involved in the anodic oxidation can be quantitatively related to the amount of copper dissolved. Quantitative information can be obtained using peak fitting techniques. Interesting differences in the behaviour of the minerals in sulfuric and hydrochloric acids have been observed, particularly in the case of pyrite for which a second major peak is obtained which has been attributed to the oxidation of elemental sulfur in the presence of chloride ions. The technique offers the possibility of providing mineralogical information of individual particles based on an electrochemical voltammetic finger print.

Jan 1, 2005

By J. K. Ahlness

The US Bureau of Mines investigated technologies for determining the integrity of in situ leach mining wells. A self-contained trailer-mounted well integrity testing system (WITS) was designed and built to enable rapid testing of well casings for leaks as required by environmental regulations. The WITS utilizes two inflatable packers to seal off the entire casing length or any portion thereof. Water pressure is built between the packers to the desired test pressure, and the presence or absence of casing leaks is determined by monitoring the pressure drop between the packers. A winch and steel cable are used to run the packers in and out of the well. The WITS underwent an industry field test at the Irigaray in situ uranium leaching mine near Buffalo, WY. A total of 37 wells with an average depth of 69 m (225 ft) were tested at an average rate of four wells per eight-hour shift with a two-person operating crew. This represents a 75% time savings and an 83% labor savings compared to the rigid-pipe method previously used at the mine, with which a three-person crew tested an average of one well per shift.

Jan 1, 1988

By H. Bernatowicz

The Nucoalyzer (On-Line Nuclear Analyzer) is a new method recently made comercially available for monitoring the elemental composition of a process stream. Applications for the Nucoalyzer include grading ore on a conveyor belt before or after it has gone through primary crushing, monitoring the slurry being transported in a pipe to the concentrator, and monitoring the stream of concentrate or the tailings from the concentrator. The Nucoalyzer may also be used at the smelter to monitor elements in the feed that include copper, sulfur, iron and silicon where a uniform feed is desired. The advantage of the Nucoalyzer over most other techniques are (a) it performs the measurement directly on the process with no sampling necessary, (b) the analysis can be performed on streams of particulate and slurries, and (c) the system does not have to make contact with the material it measures. These Nucoalyzers are operating at coal fired power plants and several more are about to be placed in service. This paper discusses the principles of operation of the Nucoalyzer, our experience in the field, application of minicomputers to data reduction, and potential applications in the ferrous and non-ferrous industries.

Jan 1, 1982

By Bernardo Portillo, Alejandro Perez, Daniel Norrgran, Joseph Wernham

High gradient permanent magnetic separators (termed "Ferrous Wheel") are described as used to recover the iron bearing minerals from mill tailings at the Grupo Acerero del Norte's Hercules iron mines in Coahuila, Mexico. The pilot scale test work as well as the "in-plant" test work provided the basis for a 385 MTPH plant expansion to be commissioned late in 1995. Approximately 6 million metric tons of flotation tailings averaging 50 percent iron, mostly as hematite, are contained in two separate ponds. The tailings are relatively fine at 93 percent -200 mesh and 72 percent -500 mesh. After testing various recovery methods, a high gradient permanent magnetic separator was selected to produce a preconcentrate prior to flotation. The separator uses a flux converging matrix to generate high gradient magnetic fields and capture the hematite. The advantage of the Ferrous Wheel high gradient permanent magnetic separator is the use of permanent magnets as opposed to electro-magnets. Further the vertical rotating ring is much more conducive to matrix cleaning as opposed to the conventional horizontal ring separators. This feature also allows the use of a wide range of matrix materials to achieve the optimum metallurgical response

Jan 1, 1995

By T. Leftwich, G. Faison, K. Pavlich, R. Borden, S. Pavlou

Recent regulatory and policy initiatives under the Resource Conservation and Recovery Act (RCRA), and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), will have a significant effect in risk reduction requirements for the mining and minerals processing industry. For example, Congress is considering regulating 20 special wastes from the processing of ore and minerals through RCRA Subtitle D and TSCA. The performance of risk analyses and environmental planning at mining projects is often driven by Federal and state regulatory standards. Recent regulatory and policy initiatives by the Environmental Protection Agency under the Resource Conservation and Recovery Act (RCRA), and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), will have a significant effect on environmental planning and risk reduction programs for mining and minerals processing. Regulatory programs implemented under other Federal laws including the Safe Drinking Water Act, Clean Water Act, and Clean Air Act will also impact industry practices. This paper provides: 1) a brief overview of mining waste and mining waste management, and 2) a description of these regulatory initiatives and a discussion on the impacts of new requirements on environmental and risk reduction programs in the mining industry.

Jan 1, 1992

By R. E. Greuer

The design of mine fire emergency plans requires that the contamination of mines by fumes, and the mutual interaction of fires and ventilation systems be pre-calculated. Several computer models were developed by the Bureau of Mines for this purpose during the last decade. The models advanced in sophistication from the transient-state simulation of fume concentrations for the early stages of a fire to the steady-state simulation of airflow rates, concentrations, and temperatures for fully developed fires, and finally to the complete transient-state simulation of fires and ventilation systems. The principal features of these models are described.

Jan 1, 1989

By Paul M. Keyser, Donald G. Foot, Jeffrey D. Mckay

In the past 30 years, there have been tremendous advancements in the uses and applications of column flotation. From their first use as final cleaners that could produce excellent grades at the cost of recoveries, columns are now being used in every stage of the flotation circuit as well as is SX-EW. Columns as roughers, final scavengers and even at the end of CIL circuits, are finding their way into the marketplace. Operational results of these new uses are presented. INTRODUCTION Flotation columns have been in use since the early 1950's in the U.S. (Hollingsworth, 1952) and the early 1960's in Canada (Trembley, Boutin, Wheeler, 1963). Application of column flotation has been somewhat diverse. In the early years, columns were used predominately for molybdenum cleaning in Canada and for phosphate flotation in the United States. Unfortunately, results met with skepticism and disdain as the columns were hard to operate, temperamental and although producing high grades, could not achieve acceptable recoveries. Since the inception of column flotation technology, the degree of knowledge for design and operation of columns has vastly improved. Despite improvements in the technology, there is still some reluctance by mineral producers to investigate the use of column flotation cells for processing stages other than cleaner flotation. This characterization is in part due to the proven advantage of flotation columns in reducing gangue entrainment in the froth product which results in higher grade products and/or fewer processing stages. Also, during the development of column technology, different types of spargers have been used with varying degrees of success. Furthermore, the general knowledge base of parameters affecting column flotation design and operation have advanced tremendously. Inefficient, or primitive, sparger design, coupled with the lack of column design and operating knowledge and experience, resulted in poor metallurgical and mechanical performance in many cases. Unfortunately, this lack of knowledge caused many column installations to be characterized as failures. The industry felt that columns could not achieve high recoveries, especially when dealing with coarse particles. Therefore, columns were characterized as cleaners, where low recoveries could be tolerated as recirculating loads rather than direct losses and froth cleaning advantages of the quiescent column flotation regime could be realized. Fortunately for the minerals industry, some producers have stood at the forefront of technology and allowed the column to be utilized for new applications. In the last decade, column flotation applications have expanded to virtually every mineral system and plant location throughout the world. The expanded application of columns has generated a new wave of interest for processing various streams. One of the most notable is in the use of columns as rougher cells. This is of particular interest to "green-field" plants and plants where expansions are taking place. Here, metallurgical superiority can be combined with maximum capital and operating cost advantages for a rapid return on investment. The superior results experienced to date, have generated a cohesive vision of the future in mineral processing where flotation columns function as single stage primary separation devices (roughers) with a single stage cleaner, if necessary. The advantages of column flotation go far beyond their original uses. We now have seen columns used as final tail scavengers, in SX-EW plants and even at the end of CIL circuits. Some of these cases will be reviewed. CASE STUDIES In an attempt to show the diversification of column flotation to many facets of the mineral processing plant, a variety of case studies will be discussed. Some of these were designed by the authors while others have been provided by plant sources. It is important to note that in each successful case, the columns were designed using the author's design and scale-up approach. This method assures that the columns are designed correctly for their particular application. For successful

Jan 1, 1993

By Louise H. Michaud

An interactive mine planning system that employs recent advances in 3D computer graphics capabilities and 3D geologic modelling to aid with the tasks involved in producing dragline mine plans was developed. As well as offering large potential saving in the time required to carry out the planning tasks, the system offers immediate visual feedback to the planning engineer. This can greatly aid in the conceptual understanding of complex geology and mine plans. The package incorporates the generation of a three dimensional Gridded Seam Model (GSM) as the basis for the development of the geologic database. This modelling method is capable of accurately representing rugged topography and multiple coal seams, including folding and faulting. The GSM is then integrated with an interactive graphics mine planning system in order to develop one model and one database for the generation of the mine design, the depletion of the coal resources and the movement of spoil material. The gridded structure of the model also provides the foundation on which all mine and spoil pile volumes are calculated.

Jan 1, 1992

By R. V. Ramani, R. Srikanth, R. Zhao

A two-part study was conducted to understand the factors affecting respirable dust generation potential or dustiness of coal seams. In the first part, the data from three prior comprehensive laboratory studies was analyzed to establish quantitative relationships between respirable dust generation potential and coal characteristics. This analysis indicates that respirable dust generation rate is positively correlated with Hardgrove Grindability Index (HGI), fuel ratio (fixed carbodvolatile matter), Vitrinke Reflectance (VR), and Level of Organic Metamorphism (LOM). In the second part, specially-designed single breakage experiments were conducted to determine the primary dust generation potential of 17 coal samples obtained from four continuous miner sections, three longwall sections, and the Penn State Coal Data Bank. The single breakage study indicates that primary dust generation rate is positively correlated with fixed carbon content, fuel ratio (fixed carbon/volatile matter), VR, and LOM. Since VR and LOM are strongly influenced by the process of coalification, differences in respirable dust generation rates in different coal seams may be explained by the thermal metamorphism of sedimentary organic matter during subsurface burial.

Jan 1, 1995

By Mark A. Alspaugh, E. A. “Bud” Viren

The driving force behind most advances in technology is need. In the early 1980s, underground coal miners in the USA wanted to build longer conveyors to handle larger capacities but continue to use fabric reinforced belting with mechanical fasteners. Conveyors with intermediate drives were certainly the answer but achieving reliable designs required a significant learning curve. Basic design methodologies had to evolve including advanced simulation of starting and stopping along with complex control techniques and logic. Some components also evolved as specific performance requirements changed Today, in addition to underground mining, the technology has been used extensively in the tunneling industry where the need is for control of belt tensions to negotiate tight horizontal curves. Even though intermediate drives are not used extensively on the surface yet, the lessons learned will find their way to long overland surface conveyance where smaller components are more available and reliable, and often with less capital cost. This paper will document the evolution of intermediate drive technology over the last 30 years and will show examples of its current use.

Jan 1, 2004

By S. Chander

A comparison of gold, platinum and sulfide ion selective electrodes was made for determination of Eh in solutions containing hydrosulfide ions as a model system. The comparison was made in terms of the accuracy of the measured response, response time, pH dependence, and reproducibility of measurement. The sensitivity of each electrode towards changes in hydrosulfide ion concentration was measured in terms of the change in measured Eh per decade change in concentration. On the basis of a detailed investigation of the electrode processes occurring at the surface of gold and platinum electrodes, it was postulated that within the pH range investigated these electrodes respond to changes in the hydrosulfide ion concentration in solution. In comparison, the sulfide ion selective electrode is known to respond to changes in the sulfide ion activity in solution. Although the potentials measured with gold and platinum electrodes were mixed potentials, pretreatment procedures can be used to obtain a signal suitable for process control. For control of hydrosulfide ions in flotation pulps, the use of a gold electrode pretreated at 1.0 V with respect to a standard hydrogen electrode is recommended.

Jan 1, 1992

By Haydn H. Murray

The three major catalyst markets that utilize industrial minerals as raw materials are petroleum refining, chemical processing, and emission control. Because of economic, competitive, and regulatory pressures, catalyst producers are pushed to develop products with improved performance to meet changing environmental standards. Also, refiners are demanding new families of cracking catalysts that will crack residual fuels. In 1987, worldwide cracking catalyst sales amounted to $457 million (Occelli, 1988a). Recently enacted federal and state laws to improve air quality have prompted strong growth for environmental catalysts, which in 1989 accounted for more than a third of the $1.9 billion catalyst market in the United States (Farrauto, Heck, and Speronello, 1992). A catalyst is a material that promotes or enhances a chemical reaction but does not itself enter into the reaction. One of the more important mineral groups used as catalysts is clays. The first recorded use of clay as a catalyst was its use in the dehydration of alcohol (Bondt et al., 1797). Clay minerals that are used as catalysts are kaolinite, halloysite, smectite, palygorskite, and sepiolite. Minerals used as catalysts, catalyst supports, or as a raw material to make zeolites are kaolinite, halloysite, sodium montmorillonite, calcium montmorillonite, hectorite, palygorskite, sepiolite, talc, calcined kaolinite, gibbsite, chlorite, and titanium dioxide.

Jan 1, 1994

By Erich U. Petersen

Discussion by Erich U. Petersen Harbuck et al. (1990) present results of research on sulfuric acid leaching of a germanium-gallium ore and shed considerable insight on possible extraction methods for gallium and germanium. However, the presentation does not give sufficient details to evaluate the research, so some of the conclusions may not be as applicable as stated. The objective of this communication is to indicate that relevant and easily obtainable geological and technical information was omitted. Consequently, on this basis, alternative explanations for some of the data are possible. Discussed below are the omission of: • pertinent geological, mineralogical and geochemical literature; • details regarding the determination of germanium concentration in quartz by electron microprobe; and • details on the calculation of the amount of germanium locked in quartz. "These topics are important since the determination of the amount and locus of "unrecoverable, locked germanium" may have an important impact on the economics and methods of germanium extraction and the directions of future research. Harbuck et al. state that "A key to increasing germanium extraction is understanding the mineralogy of the ore." However, only two studies are cited that in some manner describe the mineralogy of the ores. In addition, both of these studies were very preliminary, of limited scope and examined very few

Jan 1, 1993

By Stephen J. Reynolds

Arizona's geologic history is complex, resulting in a diversity of rock types and earth materials, including those of commercial interest. Regional variations in geologic history gave rise to three geologic provinces and an inequitable distribution of both metallic and nonmetallic mineral wealth. The Colorado Plateau is largely composed of flat-lying Paleozoic and Mesozoic sedimentary rocks and late Cenozoic volcanic fields and sedimentary deposits. Associated resources include gypsum, halite, sylvite, clays, specialty sand, flagstone, volcanic products, and aggregate. The adjacent Transition Zone features a large expanse of Proterozoic rocks, economically important Devonian and Mississippian carbonate rocks, and Tertiary volcanic and sedimentary materials. Nonmetallic resources in this province include facing and dimension stone, aggregate, decomposed granite, chrysotile asbestos, gypsum, clay, barite, fluorspar, zeolites, and limestone used for lime, cement, and railroad ballast. The Basin and Range Province has the most complex geologic history and, therefore, the most diverse assemblage of industrial mineral occurrences. These include halite, gypsum, clay, aggregate, decomposed granite, diatomite, zeolites, perlite, pumice, kyanite, limestone, marble, stone, and others. In addition, young stream deposits yield vast quantities of sand and gravel, Arizona's most economically important nonmetallic mineral commodity.

Jan 1, 1987

By Bruce W. Cavender, Brian L. Granger

The leaching characteristics of non-homogeneous ores have traditionally been difficult to assess in laboratory tests. A result of the large sample size necessary to ensure representativity, this difficulty is most acute for ores containing nuggets or other irregular occurrences of precious minerals. Consequently, small-scale leaching tests are often regarded as indicative rather than conclusive. The predictive nature of leaching tests can be improved by applying the experimental design concepts of blocking and randomization. In the case of column leaching, experimental 'blocks" are constructed with the same number of columns as there are separate test conditions. These blocks are treated identically throughout the test, with differences between columns within each block being the variables of interest. To maximize the uniformity of the blocks, randomization procedures are employed in the preparation of the sample and conduct of the test. The initial ore sample is screened and individual column charges composited from randomly selected increments from each size fraction. The leaching order, daily solution analyses, and processing of leach residues are similarly randomized. The observed differences in leaching performance between the columns in each block are compared to determine the over-all outcome of the test. A statistical analysis using t distributions gives a quantitative measure of the reproducibility of the outcome.

Jan 1, 1995

By Kot F. v. Unrug

In spite of extensive research and accumulated experience from mining operations, appropriate coal strength values for pillar design remain debatable. Coal strengths determined in the laboratory on standardized samples vary widely among various coal seams with poor repeatability. Penetrometric in situ strength testing obtains multiple measurements at multiple horizons within the coal seam to provide a strength profile. Alliance Coal has used that method in many of its mines for pillar design. Pillars in these mines perform well. This paper presents a series of case studies and discussion of issues related to coal pillar design. The analysis demonstrates that the proposed default in situ strength of 900 psi is appropriate when no other data exist. However, in the case of appropriate strength measurements combined with analysis of pillar structural composition, differing values can be used successfully. In areas where the penetrometric derived in situ strength is greater than the standard 900 psi in situ strength, reserve recovery has been optimized as required by law without compromising safety.

Jan 1, 2009

By Victor F. Hollister

This section on case histories of discoveries of volcanic-associated and volcanogenic massive sulfide deposits is divided into a preliminary discussion of models and then into three parts: Kuroko- type, Anyox-type, and shale-hosted. The separation is made to accommodate the use of exploration models, and these may not coincide with genetic models discussed in the literature. The exploration models grew as knowledge was gained concerning ore guides and ore controls in the volcanic-related deposits. The evolution of the genesis of massive sulfide deposits in volcanic terranes from a replacement to a syngenetic hypothesis in the 1950s and 1960s necessitated changes in exploration approaches in ore search. The acceptance of a syngenetic origin for conformable or concordant sulfide masses led to more widespread adoption of stratigraphic ore guides. 'The occurrence of epigenetic stringer ore with and stratigraphically below many conformable massive sulfide deposits did not diminish the importance of stratigraphic ore controls. Proximal conformable sulfide masses were formed near their seafloor hot spring source and normally are underlain by epigenetic sulfides: whereas. distal conformable sulfide masses were deposited away from the hot spring and may have no associated feede; zone. Industry groups that early recognized the syngenetic nature of volcanogenic massive sulfides were responsible for discovery of some of the large and economically significant deposits. Ultimately, the rest of the geological profession accepted the leadership of the early iconoclasts.

Jan 1, 1991

By Thomas M. Hanna, John W. Anthony, Lee C. Atkinson

Ground water can pose major engineering and environmental problems to the new generation of large, deep gold mines currently being developed throughout the world. It is important that the potential magnitude of these problems be assessed early in the planning of such projects and that any necessary dewatering and environmental remediation programs be designed at least preliminarily in the feasibility stage. The assessment should begin with acquisition of hydrogeologic data during exploration drilling and be followed by carefully designed and analyzed aquifer tests. Once a sufficiently detailed conceptual hydrogeologic model has been defined, state-of-the-art numerical models should be used to estimate ground-water inflows to proposed pits and underground openings, to design and evaluate the potential effects of various dewatering schemes, to define specific environmental impacts, and to predict pore pressures in highwalls relative to slope stability. The modeling results will indicate which method(s) of dewatering will be most effective both technically and economically. If wells are used, it is imperative that they be as hydraulically efficient as possible. There are new methods of drilling and completing dewatering wells that can help assure maximum efficiency.

Jan 1, 1989

By A. C. Noble, D. E. Ranta, J. W. Mustard

Skarn deposits present many unique problems in estimating ore reserves, including difficulties arising from the complex character of the mineralization and intricate ore body shapes resulting from structural complexity. Mineralization within skarns occurs in metasomatically altered carbonate horizons produced by magmatic hydrothermal fluids emanating from intrusive stocks. Deposit formation is controlled by both the presence of favorable host rocks and by proximity of these host rocks to a mineralizing intrusion. Ore controls must be defined to account for abrupt changes in grade that occur between miner- alized and unmineralized horizons. Gradational grade changes within the mineralized zones must also be defined in terms of skarn type and included barren rock to assist in reserve estimation. Defining mineralized limits can be further complicated by faulted, rotated, or folded strata affecting the morphology of an ore body. The MacTung copper-tungsten exoskarn deposit, located along the Yukon-Northwest Territories border in Northwestern Canada exhibits a number of unique properties that preclude a simple mathematical approach to ore re- serve estimation. This deposit is used to demonstrate methods for modeling geologic controls and geostatistical properties for a skarn deposit.

Jan 1, 1992

By K. Biswas, H. C. Lee, S. J. Jung

Ore passes are circular openings excavated in rock for in-mine gravity-transportation of ore. It is a very important component of the overall load-haul system of an underground mine. The function of an ore pass is two-fold: first, gravity-transportation of ore from the extraction level to the haulage level and second, the loading operation at the haulage level utilizing the gate assembly. In reality, like any other system component, an ore pass breaks down either due to a hang-up within the ore pass or due to a failure in the gate structure. The failure of the gate assembly may be attributed to a greater extent to the impact load as experienced by the components of a gate structure as a result of the direct impacts of the rock fragments and to a lesser extent to the static or 'dead weight' loads of the accumulated materials in the ore pass. This paper uses simulations in Working Model® as an aid to investigate the effect of both the impact and static loading on the gate assembly and on the inner-walls of the ore pass. The paper also investigates the impact of ore pass inclination and the presence or absence of dogleg on the static and impact loading of the same.

Jan 1, 2002