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By B. Dimitriades

Experimental work has been done to refine and to confirm an analytical procedure by which gas-liquid chromatographic (GLC) spectra are interpreted from retention time data alone. The rationale of this spectra interpretation technique involves whether or not a given peak invariably represents the same component or component mixture; if not, what factors influence changes in peak identifications. To answer these questions, peak-identification procedures, based mainly on the use of subtractive columns, were developed and applied to interpret GLC spectra of several exhaust (and fuel) samples.

Jan 1, 1972

By C. D. Litton

Submicrometer particle concentrations and average particle sizes were monitored for four full-scale sealed coal fires in the multiple-entry section of the Bruceton Experimental Mine. The data from these tests indicate that there exists a very good correlation between the submicrometer particle concentrations and the maximum temperatures measured within the coalbed. As the maximum coalbed temperature decreases with time after sealing, the submicrometer particle concentrations show a corresponding reduction. This particle-temperature correlation is in sharp contrast to the gas concentration data obtained, for which essentially no correlation exists with the measured coal-bed temperatures. The results of these full-scale tests indicate that the measurement of submicrometer particle concentrations may be a more realistic approach to determining the status of underground sealed fire areas.

Jan 1, 1981

By D. B. Dow

This report on methods employed for dehydrating oil-field emulsions, is the second of a series prepared as a result of a study of oil-field emulsions recently completed by the writer. The first paper2 dealt with the factors responsible for the formation of emulsions. A third paper will discuss the physical chemistry involved in the formation and resolution of such emulsions. In the early development of the oil fields of Pennsylvania, no emulsion troubles of any consequence were encountered, nor to any serious extent in the oil fields of other Eastern States: However, with the development of fields west of the Mississippi in Oklahoma, Kansas, Texas and California, where heavier oils of different characteristics were found, the problem of dealing with cut oil soon became of great importance.

Jan 1, 1925

By F. D. Osgood, H. M. Cooper, A. C. Fieldner

The analyses in the tables are arranged geographically with respect to county and towns, and are grouped as follows: l The proximate analysis--moisture, volatile matter, fixed car bon, and ash; 2 The ultimate analysis-carbon, hydrogen, nitrogen, oxygen, sulphur, and ash; 3 The calorific value of heat of combustion; 4 The softening temperature of ash, when such determinations were made. Ultimate analyses are given in three conditions-namely, (1) as received, (2) moisture free, and (3) moisture and ash free Proximate analyses and heating values are given generally in one condition -namely, as received, some are in two conditions, as received and moisture free.

Jan 1, 1928

By E. W. Dean

The Bureau of Mines is engaged in the work of obtaining data regarding the physical and chemical properties of typical crude oils from the various producing fields of the, United" States. Preliminary reports have been published that cover the eastern fields* and the' Rocky Mountain districts.** Since the appearance of these, reports: it has been suggested that certain additional data. I regarding the samples would be of practical value. It was believed that a knowledge of the viscosity of crude oil was desirable, particularly in connection with the design and operation of pipe lines. In accordance with this suggestion, the authors have made viscosity tests upon as many of the samples of the two series as wore still available for examination. Determinations were made at temperatures of 70° and 100°F., and in addition the oils were Subjected to the A. S. T M, pour-test*** to as certain the lowest temperatures at which they remain in a fluid condition.

Jan 1, 1921

By D. Z. Hobbs

Because an economic method for preparing pure boron has not been developed, a program was started by the Bureau of Mines to evaluate existing techniques or to develop new methods for preparing the pure element. This report describes investigations directed toward the development of techniques for the preparation of pure boron by fused-salt electrolysis. Only two of the several fused-salt baths tested were satisfactory for the preparation of boron. These baths contained (1) potassium fluoride, lithium fluoride, potassium fluoborate and boron trioxide; and (2) potassium fluoride, potassium chloride, and boron trioxide. Of these two mixtures, the latter was more satisfactory. Elemental boron of from 90- to 95-percent purity and, in isolated cases, as high as 98-percent purity, was prepared from these two types of fused-salt baths. There appeared to be no distinct differences either in the yields or the purity of boron prepared at current densities ranging from 795 to 1,000 amperes per square foot. Current efficiencies were as high as 85 percent.

Jan 1, 1961

By Joseph S. Coffman

The Bureau of Mines investigated the availability of barite (BaSO4) from 35 U.S. and 41 non-U.S. mines and deposits in 17 market economy countries (MEC's). This evaluation assesses the availability of mud-grade barite, and concentrates consumed by the chemicals and fillers industries. The demonstrated resources defined in this analysis totaled 130 million metric tons (Mmt) of barite (contained BaSO4), yielding a potential 115 Mmt of recoverable barite concentrates. At the 1984 MEC production rate, the evaluated resources would last about 30 yr; however, this would include production costs of up to $100/mt concentrate. An average price needed to cover all costs of production over the life of each operation was determined for both mud-grade and chemical- and filler-grade barite products. Including a 0-pct discounted-cash-flow rate of return (DCFROR), regional weighted- average total production cost ranged from $38/mt for barite concentrates in Asia to $71/mt for U.S. operations. Transportation costs have the greatest impact, contributing up to 60 pct of the total cost of production. Rail transportation costs from the mines to U.S. markets are generally significantly higher than ocean shipping rates on imports.

Jan 1, 1986

By Dennis R. Dolinar

Screen material in the form of welded wire mesh and geogrids are used in underground coal mines to prevent the fall of small pieces of rock from the roof between roof bolts. Further, if the screen is installed during the production cycle, roof fall injuries can be reduced significantly. Therefore, the National Institute for Occupational Safety and Health (NIOSH), because of the safety implications, conducted an evaluation of screen materials commonly used in U.S. coal mines to determine their support characteristics and identify the parameters that could affect their performance with respect to controlling the fall of rock from the roof surface. To evaluate the load and stiffness characteristics of the screen, a test frame was designed and installed in the Mine Roof Simulator (MRS) at the NIOSH Pittsburgh Research Laboratory (PRL). With this test set up, the screen is bolted at four corners of the frame and a center load is applied. The test set up allows for up to 20 in of screen deflection while the load and screen defection are continuously recorded. A series of tests were conducted to evaluate the effects of various parameters such as bolt tension, the type of load bearing surface and the size of bearing plates on welded screen performance. The most common screen material used in U. S. coal mines is an 8-gauge wire welded in a 4-by-4-in spacing or aperture. The peak screen load was normally limited by wire breakage. The conditions at the bearing plate influence the nature of the wire breakage. However, the screen stiffness was controlled by slippage at the bearing plates, and by weld and wire failure. The size of the bearing plate had a significant effect on the performance of the welded screen. Therefore, the design capacity of the 8-gauge screen is evaluated based on plate size. For a 6-by-6-in bearing plate the average peak load is 2,900 lb with a stiffness of 250 lb/in. For an 8-by-8-in bearing plate, the average peak load is 4,500 lb with a stiffness of 430 lb/in. These test results are based on a 4-by-4-ft bolt spacing. A geogrid mesh was also tested.

By John P. Gooch

Data for the ternary phase diagram for the system 1,1,2,2-tetrabromoethane/water/2-propanol at 25° C have been measured. Experimental methods used are described, and the complete ternary phase diagram is presented. A simple example is given to review the use of the ternary diagram.

Jan 1, 1972

By Carla A. Kertis, Alan A. Campoli, Claude A. Goode

This Bureau of Mines study was conducted to obtain a better understanding of the coal mine bump problem and its effect on underground coal mining in the Eastern United States. To accomplish this, information was collected on the geologic conditions, mining techniques, and engineering parameters at five bump-prone mines. Two geologic conditions have been found to cause the occurrence of bumps in the Eastern United States: (1) relatively thick overburden and (2) extremely rigid strata occurring immediately above and below the mine coalbed. Additionally, the probability of bump occurrence is increased by certain mining practices that concentrate stresses during retreat mining, in areas where geologic conditions are conducive to bumps. Mining plans that permit the development of pillar line points or long roof spans that project over gob areas should be avoided because these features may contribute to the occurrence of bumps.

Jan 1, 1987

By William C. McBee

Prompted by forecasts of a sulfur oversupply, the Bureau of Mines, U.S. Department of the Interior, is conducting research on potentially large-scale uses of this commodity to extend or replace such construction materials as asphalt, cement, and mineral aggregates. Through these efforts, paving materials have been developed in which sulfur replaces up to 50 pct of the asphalt normally present and which can be prepared and placed with existing mixing and paving equipment. Laboratory properties and design methods for this direct mixing process are described along with properties obtained on small-and large-scale field demonstration projects. These properties are compared with those obtained from control materials prepared without sulfur additions. Monitoring for toxic gases during laboratory and commercial mixing and paving operations is discussed also.

Jan 1, 1978

By Stephen C. Brown

THE expansion of the world economy which has been in process since 1958 continued in 1963 and both production and consumption of minerals rose. Gross national product (GNP) rose sharply in the United Kingdom and Japan, continued to expand in the United States and Canada, and maintained a high though slightly declining rate of growth in the European Economic Community (EEC) despite the appearance of excess capacity in certain lines and inflationary pressures in Italy and France. The steel and motor vehicle industries both increased output in North America, Western Europe, and Japan. The less developed areas benefited substantially from an improvement in their terms of trade, and their export earnings increased some 8 percent in 1963; although estimates of GNP for the majority of them are 110t yet available, it is probable that this increase was partly reflected in a substantial rise of GNP.2 In the United States the expansion was steady and extended through all sectors of the economy producing no distortions likely to disturb its continuing growth; at yearend with unemployment still at about 5.5 percent of the labor force and operating rates of industry estimated at about 87 percent of capacity, there was a substantial margin for further expansion. Though the balance of payments was still in heavy deficit for the year, in the last half it was moving rapidly toward equalibrium as net exports rose and capital outflows declined; prices were relatively stable, inventories increased only slightly and the activity of mineral-consuming industries remained high, steel output rising by 11 percent to highest level since 1957 and the auto industry output equalling the 1955 record.3

Jan 1, 1964

By J. H. Jansky, P. W. Jeran, G. L. Hassett, M. C. Irani

This Bureau of Mines report tabulates methane emissions from U.S. bituminous coal mines with daily emission rates of at least 100,000 cfd according to States, counties, and coalbeds. Most of the methane emitted is from mines in the Appalachian States. Total daily emissionin 1975 was 216.3 MMcfd, compared with 227.0 MMcfd in 1971 and 214.5 MMcfd in 1973. Thirty counties in nine States had daily methane emissions of 1 MMcfd or more, These emitted 93 percent of the total methane. The highest emissions were from Monongalia County, W. Va,, which accounted for 18.9 percent of the total. This was followed by Marion County, W. Va., 9.6 percent; Buchanan County, Va., 8.5 percent; Jefferson County, Ala., 6.1 percent; and Washington County, Pa., 5.9 percent. The Pittsburgh coalbed emitted 45.7 percent of the total methane, followed by the Pocahontas No. 3 coalbed with 12.9 percent. The report lists 196 mines, of which 60 had daily methane emissions of 1 MMcfd or more. Included in this compilation are the identification and thickness of the coalbed, methane emission, coal production and ventilation rates, number of drifts, shafts, and slopes used for ventilation purposes, shaft depth, age of mine, and gas-to-coal ratio.

Jan 1, 1975

By Charles L. Kimbell

Bulk carriers, freighters, and tankers are the three classes of marine vessels engaged in transporting mineral commodities. However, vessels in each of these categories are not devoted wholly to mineral commodity transport. Bulk carriers move agricultural products as well as crude minerals and mineral fertilizers, as ore/bulk/oil carriers also do. Freighters, owing to their great variety, can be devoted wholly to hauling mineral products or wholly to moving nonmineral goods, as well as carrying mixed mineral and nonmineral cargoes. They include general cargo carriers, full containerships, partial containerships, roll-on/roll-off ships, and barge carriers. Tankers, although largely engaged in moving crude oil and refinery products, also transport liquid chemicals, molasses, wine, liquefied natural gas, and other fluids. Although physical characteristics of vessels, such as sue, draft, crew requirements, and type of propulsion system, as well as fuel costs, have an undeniable influence on shipping industry performance, problems of and changes in the quantity and quality and types of material moved also significantly affect the shipping sector of the world economy. Unfortunately, comprehensive data in this regard are not available.

Jan 1, 1992

By A. G. Kim

Coal formation begins in peat swamps or bogs, in which microorganisms alter plant material and initiate the formation of carbonaceous sediments. Methane, which constitutes about 98 percent of the hydrocarbon gas in coalbeds, is known to be a product of anaerobic microbial metabolism. To determine if other hydrocarbon gases could be produced in an environment similar to that of a swamp, samples of wood cellulose and lignin were inoculated with soil micro-organisms and incubated anaerobically. The resultant gases included methane, ethylene, propane, propylene, butanes, pentanes, and carbon dioxide. Hydrogen was also produced from the wood samples during the first month of incubation. Over 90 percent of the produced gas was methane; C02 was the other predominant component. Concentrations of all other hydrocarbon gases ranged from l to 20 parts per million, approximately 0.1 percent of the total hydrocarbons, which was less than the concentration in coalbeds. Therefore, although higher hydrocarbons could be produced in a swamp environment, subsequent mechanisms, either concentration by adsorption or formation during geochemical reactions, must affect the final concentration of higher hydrocarbons in coalbeds.

Jan 1, 1972

The U.S. Department of Labor?s Mine Safety and Health Administration (MSHA),through its winter alert program, warns U.S. mine operators and miners at underground coal mines of workplace hazards that can arise when the weather turns colder. MSHA records indicate that, historically, most explosions in underground coal mines occur during winter months. ?The changes in weather can increase the risk of fatal accidents,? says David G. Dye, Acting Assistant Secretary of Labor for Mine Safety and Health. ?Each miner and mine operator must take individual responsibility to eliminate the kinds of hazards that can cause fatal accidents in the workplace. Safety is not the other guy?s job?safety begins with you.? In fact, MSHA?s slogan for this year?s campaign is ?Winter Alert Starts Now and Safety Begins with YOU.? This message reminds miners and mine operators of the risks of colder weather and educates them about helping to reduce risks and hazards. ?Safety requires the joint effort of both management and labor,? Dye says. ?Everyone at the mine site must see safety as an individual value and act to ensure a safe working environment.?

Jan 1, 2006

By Gregory J. Chekan

In order to reduce waste and improve resource conservation, mine planning, and development, the U.S. Bureau of Mines is investigating multiple seam interactions associated with longwall mining. Longwall gate entry and panel stability have been influenced by previous mining in coalbeds above and below a mine in Virginia that operates in the Lower Banner Coalbed. Directly superjacent, approximately 115 ft, the Upper Banner Coalbed has been partially worked by room-and-pillar mining. Directly subjacent, approximately 730 ft, the Tiller Coalbed has been worked by partial room-and-pillar retreat mining. The study mine has experienced problems during development of gate entries in areas of overmining and undermining. It is anticipated that stress fields associated with adjacent mining may further affect gate entry stability and face advancement during the extraction of the longwall panel. To assess overmining and undermining effects on ground stability, the Bureau gathered geotechnical information at the site. Headgate entries and pillars were instrumented and monitored to study loading behavior as the longwall face approached and passed potential problem areas. Measurements indicate that although increases in average pillar pressure were greater than predicted values, previous mining in adjacent coalbeds had little effect on headgate stability.

Jan 1, 1989

By B. J. Scheiner

As part of its mission to reduce pollution associated with mineral production, the Bureau of Mines is developing a dewatering technique for phosphatic clay waste that uses a flocculant, polyethylene oxide (PEO). This flocculant forms strong, stable flocs, which can be partially dewatered on a static screen and dewatered further on a rotary screen. Using this technique, a field test unit (FTU) was operated at a nominal 100 gal/min. Consolidated phosphatic clay material containing 20 percent solids was produced when feed slurries of 3 percent solids were treated with 0.69 pound of PEO per ton of feed solids. Pit and column tests indicated that the PEO-treated material continued to dewater; compacted products containing 40 percent solids were obtained after 45 days.

Jan 1, 1981

By R. T. Stull, L. E. Geyer

"Previous Work:As outlined in previous papers* ond clays for graphite crucibles have been tested at the plants of the Detroit Lubricator Co., and the Detroit Copper and Brass Rolling Mills, Detroit, Mich.These tests indicated that there were two American clays (Missouri pot clay and Illinois kaolin) that tested better than the Klingenberg (German) clay. Dorset (English) ball clay was tenth in the list.Making the Crucibles:After it had been determined that American clays can be used successfully in graphite crucible manufacture and service, the next step in the investigation was to determine the value of American graphites as compared to the foreign, These final tests were carried out at the plant of the Detroit Lubricator Co., through the courtesy of Mr. G. B. Duffield. The crucibles, as previously. were made at the plant of the Vesuvius Crucible Co., Swissvale, Penna., from a formula compiled by the Bureau of Mines and under the supervision of Bureau engineers.The graphites to be tested were given an initial to indicate their source. The number of crucibles made and shipped are set forth in Table 1."

Nov 1, 1923

By Sean Gallagher, Thomas G. Bobick, Diane M. Doyle-Coombs, Richard L. Unger

The U.S. Bureau of Mines has developed an in-house facility to evaluate selected effects of whole-body vibration (WBV) levels experienced by underground mobile equipment operators, Vertical vibration data were collected from a coal haulage vehicle via a uniaxial accelerometer attached to the machine frame under the operator&apos;s seat. Data were analyzed and processed so a computer-controlled platform could approximate the vibration signals. Eight men (35.5 yr 2 6.5 SD) participated in a pilot study to evaluate the effects of shock and kBV on heart rate (HR), blood pressure (BP), and subjective discomfort. Subjects were exposed to vibration for 30-min periods while seated in a typical seat (backrest angle at 90° or 130°) &apos;that was plain steel or modified with 2 in foam padding. Subjects repeated the same protocol on a separate day, without the vibration. Results indicated the vibration significantly increased the HR (Q< 0.01), systolic BP, mean BP, the number of times subjects reported discomfort, and overall subjective discomfort rating (pc 0.85). When seated in the steel seat, the overall discomfort rating (E< 0,081) ad the number of times discomfort was reported (p< 0.05) increased significantly. Seatback angle had no significant effect on any of the dependent measures.