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By M. Lundström, J. Aromaa, S. Seisko

"Gold dissolution was investigated in ferric chloride media, promoted as one of the most promising alternatives for cyanide-free gold leaching. The characteristics of gold open circuit potential (OCP) and its relation to gold dissolution rate was investigated. Furthermore, the reaction mechanism of gold dissolution in ferric chloride leaching was discussed. The effect of solution variables, [Fe3+] = 0.02–1.0 M, [Cl–] = 2–5 M, T = 25–95 °C and pH = 0–1.0, on OCP and dissolution rate were studied electrochemically using rotating disk electrode (RDE) and linear polarization resistance (LPR) method with ?cyc = 1000 RPM. The investigated gold OCPs in ferric chloride solutions were found to vary between 597 and 688 mV vs. saturated calomel electrode (SCE) and gold dissolution rates between 1.2·10–5–5.0·10–4 mol s–1 m–2. Increase in temperature (25–55 °C) and ferric concentration (0.02–1.0 M) changed OCP into more positive values, while increase in chloride concentration (2–5 M) decreased it. The logarithm of gold dissolution rate was shown to increase linearly with increasing OCP at the temperature range 25–95 °C, ferric concentration range 0.02–0.5 M and chloride concentration range 2–4 M. A notable increase in the gold dissolution reaction rate was evident at T > 55 °C. INTRODUCTION Currently cyanide leaching is the predominant method used in gold production from primary raw materials (Marsden and House, 2006). However, since the Baia Mare disaster in Romania in 2000, the use of cyanide has been the subject of international concern due to the toxic nature of the chemical posing a significant health threat if exposed to the ecological entities (Hilson and Monhenius, 2006; UNEP/OCHA, 2000). Therefore, several countries e.g., Costa Rica, Czech Republic, Germany, Hungary, Turkey, many states of the USA and provinces of Argentina, have started to ban or limit cyanidation via legislation (Laitos, 2012). Thus, alternative solutions, such as thiourea, thiosulphate, oil-coal agglomerates as well as halides have been investigated in order to replace cyanide as lixiviant (Adams, 2016; Aromaa et al., 2014; Aylmore, 2005; Hilson and Monhemius, 2006; Lampinen et al., 2015). Ferric and cupric chloride leaching have been reported to have advantage over cyanidation being capable to dissolve refractory gold minerals, without pre-treatment such as pressure oxidation or roasting (Angelidis et al., 1993; Lundström et al., 2014; Marsden and House, 2006; van Meersbergen et al., 1993). According to Aylmore (2005), 4% of publications for alternative lixiviants to cyanide in gold leaching were within category oxidative chloride processes including aqua regia and acid ferric chloride leaching. Further, some patents have been granted for ferric chloride leaching of gold (Abe and Hosaka, 2010; Lundström et al., 2016)"

Jan 1, 2018

By Glasswell K. Nkonde, Fredrick Chileshe, Steven Simukanga

Improving food security by increasing crop output is a primary objective for most countries in the sub- Saharan region. Most soils in the region are deficient in phosphorus an important nutrient after nitrogen in plant growth. Phosphates are therefore used together with nitrogen and potassium based fertilizers in improving crop production. Zambia like many other countries in the sub-Saharan region imports phosphate fertilizers for use by its farmers. However, indigenous phosphate deposits of igneous origin exist in Zambia of which the main ones are Chilembwe in Petauke district, Mumbwa sugarloaf in Mumbwa district, and Nkombwa Hill in Isoka district. If commercially exploited, these deposits could become a ready source of inexpensive phosphate for the local farming communities in the country. Previous research has shown that partially acidulated phosphate rock (PAPR) produced using Chilembwe phosphate rock is just as agronomically effective as the imported superphosphate fertilizers on food crops in most of the Zambian soils. PAPR is produced by reacting finely ground phosphate rock with only a fraction (usually 50%) of the stoichiometric quantity of the sulphuric acid required to fully convert the apatite in the rock to monocalcium phosphate thus making the process cheaper in terms of acid consumption than the poduction of single superphosphate where the apatite in the rock has to be fully converted to monocalcium phophate. The factors that affect the percentage of available P2O5 in the PAPR produced include particle size of phosphate rock, degree of acidulation, concentration of acid, process temperature profile, residence time and drying temperature. These factors were studied in a 25kg/hr PAPR pilot-plant in the School of Mines at the University of Zambia using Chilembwe phosphate rock. The PAPR pilot-plant consisted of a rotary drum granulator as the main reactor, a rotary drum dryer and a triple deck vibrating screen. Ground phosphate rock was reacted with sulphuric acid and water in the granulator to form a granular product which entered the drier. The dry product was screened into three size fractions. The 1 – 4 mm size fraction was the final product whilst the –1mm size fraction was recycled. The +4mm size fraction was sent to a crusher while the crushed PAPR was sent back to the screens.

Jan 1, 2003

By L. S. Gertsch

The production of minerals for human use at locations other than the Earth is expected to ?advance ? human prosperity in ? ways that [do] not compromise the potential prosperity and quality of life of future generations? (Brundtland, 1987); in other words, sustainably. This paper examines the interaction of extra-terrestrial mineral production (ETMP) with the following sustainability imperatives: ? The sustainability of human activities on Earth; ? The sustainability of human activities elsewhere; ? Human survival in general, the ultimate sustainability goal. Some of the consequences of mineral production on Earth are widely considered to decrease the future prosperity and quality of human life. Examples include noxious by-products or wastes and unsettling economic up- and downswings. Moving mineral production activities to extra-terrestrial locations, where appropriate, will decrease many of its deleterious effects. Terrestrial mineral production presently is decreasing in some countries and increasing in others, moving from the cheaper and easier ores to more expensive, difficult materials. When the full costs of maintaining the terrestrial environment in a sustainable manner are included, total mineral pro-duction costs must increase. The cost of extracting mineral products from extra-terrestrial sources will be substantially higher, especially in the initial phases, but as the full costs of terrestrial production increase, at some point in the future (different points for different minerals), the curves will cross (Fig.1). This will occur at different points for different materials, a process whose prediction will be complicated by substitution of cheaper materials for some uses as prices of the original material rise. In summary, mineral products from extra-terrestrial sources will tend to increase the sustainability of human civilization, once steady state has been reached.

Jan 1, 2014

By Wei Sun, Xue-feng Cao, Lei Sun, Run-qing Liu

The flotation performance of kaolinite in laboratory micro-flotation was investigated with 3- (dodecyloxy) propan-1-amine (ON12) as the collector. Compared with dode cylamine (DDA), which is commonly used as the bauxite reverse flotation collector, ON12 shows stronger collecting ability for kaolinite than using the same amounts of DDA, when experimental pH value reaches more than 6. With the addition of ON12, the isoelectric point of kaolinite shifts to 6.1 from 3.6, which suggests a strong adsorption between kaolinite and ON12. Infrared spectra analysis indicates that the type of ON12 adsorbed on the kaolinite surface is mainly of electrostatic adsorption. Molecular dynamics simulation further indicate that electrostatic adsorption of ON12 cation on kaolinite (001) surface based on electrostatic interaction between NH4+ and O atoms. ON12 will be suitable for bauxite reverse flotation with the efficiency depressors of the diaspora.

Jan 1, 2014

By Gurubasayya Swamy

This paper presents the performance study of sag mill in the processing of gold ore. Deterioting ore grade and high demand of metals has tremendously influenced the SAG mills. Today?s high capacity Semi-autogenous grinding (SAG) mills expand vast amounts of energy and in doing so consume tons of shell liners and steel balls, while processing ore. Semi-autogenous (SAG) mill performance is influenced by ball charge, feed properties, shell, grate, and pulp lifter design. In the performance study of SAG mill, based on the results obtained it can be observed that SAG mill performed better at feed size +4 inch and grinding media consumption 0.90kg/mt. In the present study the effect of crusher bypass on SAG mill performance, an immediate drop of throughput ranging from 10-20tph is observed. Keywords: sag mill, pulp lifters, grinding media, energy, consumption, throughput

Sep 1, 2012

By Z. B. Pan

The innovative point of this new technology can be described that under normal pressure and 70°C, using a new combined activating and oxidizing agent, the minerals bearing arsenic and organic carbon are oxidized effectively. This technology can be applied in commercial scale. The high carbon and arsenic bearing gold ore is taken from Gansu, where hundreds of tons gold deposit. The ore has 0.51% of arsenic and 1.75% of carbon (1.07% of organic carbon). The gold occurs mainly in native with particle size 0.02~0.6 mm and a few are enwrapped by pyrite and arsenopyrite. The traditional cyanide leaching process gains a very low gold leaching rate with only 5%. Through systemic experimental study, the technological flowsheet of flotation process for concentrating gold, then pre-treating the gold concentrate followed by cyanide leaching the gold concentrate are used. With 4.92 g/t gold of head sample, the gold concentrate with 46.52g/t gold grade and 96.53% gold recovery is gained by flotation process. Followed by pre-treatment for 6 hours, the gold concentrate is leached with cyanide after filtration and washing. The total gold leaching rate is up to 95.44%.

Jan 1, 2014

By Z. Y. Ma, M. D. Liu, Z. Z. Liu, J. K. Zhou

"An optimization method of microwave assisted leaching of copper anode slime was proposed based on Taguchi method. The results showed that the solid-liquid ratio was the most important factor affecting SNR(signal noise ratio) of the copper, tellurium and selenium leaching efficiencies, and its contributions to the copper, tellurium and selenium leaching efficiencies were 58.34%, 55.54% and 60.74%, respectively. Solid-liquid ratio was a significant factor to SNR(copper, tellurium and selenium). Reaction period was a less significant factor to SNR(copper and tellurium) and concentration of sulphuric acid was a less significant factor to SNR(selenium) while microwave power was an non-significant factor, its contributions to the copper, tellurium and selenium efficiencies were 3.22%, 11.73% and 12.73%, respectively. The optimized parameters of the microwave assisted leaching of copper were as follow: microwave power of 500 W, reaction period of 10 min, solid-liquid ratio of 0.10 g·mL-1 and H2SO4 concentration of 1.0 mol·L-1. The optimized parameters of the microwave assisted leaching of tellurium and selenium were as follow: microwave power of 800 W, reaction period of 15 min, solid-liquid ratio of 0.10 g·mL-1 and H2SO4 concentration of 1.0 mol·L-1. The validation experiments under the optimized conditions has been carried out, the copper, tellurium and selenium leaching efficiencies were 98.66%, 84.32% and 64.54%, respectively. INTRODUCTION As important valuable by-products, copper anode slimes are collected from the bottom of the electrolytic bath in the electrolytic copper refining process(Kilic, 2013). The value of the anode slime is determined by the content of rare metals and precious metals(Liu, 2014). Generally, pretreatment of copper anode slime is the first stage of the whole process. The aim of the pretreatment process is to remove Cu, Te and Se etc and enrich the valuable metals. The methods of pretreatment process can be differentiated into: pyrometallurgical processing and hydrometallurgical processing(Amer, 2003). The hydrometallurgical processes are more promising compared to pyrometallurgical processes in terms of cost effectiveness, low energy consumption and environmental concerns(Ranjbar, 2014). However, the disadvantages of the hydrometallurgy process are evident, such as lengthy processing times and low efficiency. Therefore, it is necessary to develop a highly efficient and environmentally friendly pretreatment method."

Jan 1, 2018

By Z. H. Li

In connection with the features of characteristic waste water (containing cyanogen, arsenic and heavy metal) pollutants discharged by gold industry as well as the environmental features at the location of gold production enterprises, this paper briefly described the traditional method of treatment, and focused on the argument for technologies of clean production, advanced treatment and process control technology. Moreover, it clarified the future policies and development trend for treatment on characteristic waste water from gold industry.

Jan 1, 2014

By X. L. Song

A large amount of tailings in concentrators bring a series of problems to the environment and society. It is significant to reclaim the huge tailings and reuse them in industries in order to utilize mineral resources adequately. Primarily Lead-Zinc tailings with a certain quality of clay and feldspar were used to produce ceramic tiles by sintering method under specific technical conditions. By testing the properties of the ceramic tiles, it was shown that the amount of Lead-Zinc tailing used in the tiles was 60%~70%, and the mechanics properties were good. The optimum proportion parameters were Lead-Zinc tailing 60%, clay 35%, feldspar 5%, and the maximum flexural strength of tiles was up to 38.2MPa when it was sintered at 1090? for 30min. Its flexural strength, water absorption and thermal shock resistance reached the State Standard of GB/T4100.4. The product is suitable to be used in pavements and paths of parks.

Jan 1, 2014

By Atul Kumar Bhatnagar

TATA STEEL is the pioneer in coal beneficiation in India. The first coal beneficiation plant was set up in 1951 at West Bokaro and subsequently in 1953 in Jharia. Over the years more beneficiation capacity was added by setting up new coal washeries in both West Bokaro and Jharia, the coal divisions of Tata Steel. currently the beneficiation capacity available is 8.5 mtp aappx Being a captive supplier supplying the coking coal as per demands of our steel works is challenging in the sense that the intent is to leverage the captive raw material advantage and select the best strategy for maximizing value up to steel making. The beneficiation plants were designed to produce clean coal up to 17% ash. With the demand of increasing productivity at the blast furnace the clean coal ash was lowered. subsequently the processes were audited and efficiency improved. The next challenge was to improve the throughputs in the existing plants to maximize the clean coal production. The upgradation was designed in house and implemented to upgrade the plant from nameplate capacity of 2.1 mtpa to 4.5 mtpa while the yearly production targets were also achieved. The presentation will detail the different phases of improvements, process followed, challenges faced, and the results as achieved in the process. Keywords: coal beneficiation, India, coal washeries, beneficiation plants XXVI INTERNATIONAL

Sep 1, 2012

By G. J. Feng

Based on detailed theoretical analysis of coarse floatation and three-phase froth, a laboratory system which contains a new type of froth floatation equipment is established. Through water experiment, the relationship among floatation dynamics parameters of the equipment is studied and the best work parameters are educed too. Based on all of above, Slurry test is carried out in a copper concentration plant. Granule between 0.28~0.45mm can be reclaimed successfully. The slurry test proves that to separate coarse minerals in froth floatation equipment is a kind of effective method, it is well worth to make a further study.

Jan 1, 2014

By W. X. Yin

Electrowinning of lead from aqueous solution of PbCl2 and electrowinning of manganese dioxide from aqueous solution of MnCl2 are two research focuses in hydrometallurgy. This paper investigated a new process of simultaneous electrowinning of lead and manganese dioxide in chloride medium. The simultaneous electrowinning process in chloride solution not only can prevent chloride from liberating at anodes but also obtain two electrolysis products and decrease electric energy consumption. Diaphragm cell is used in the simultaneous electrowinning process to form separate anode and cathode compartment. The effects of temperature, HCl concentration in anolyte, NaCl concentration in catholyte and electrolysis time on current efficiency and cell voltage are studied. The results indicate that current efficiency of anode and cathode for 5 hours is 99% and 96% respectively, average cell voltage is 1. 701V, the weight ratio of lead and manganese dioxide produced at electrodes is 2. 39:1 under the optimum conditions. As anode products, manganese dioxide is ??MnO2, content of which in the products is more than 92%.

Jan 1, 2014

By Q. W. Jiang

This paper presents a new process for producing industrial magnesium sulphate using waste water from titanium white plant and magnesium oxide from calcinations of magnesite ore as raw materials. With the laboratory experimental equipment, the waste liquid and magnesium dioxide react effectively at ambient temperature and under atmosphere pressure. Via the press filter, a clear liquid predominately containing magnesium sulphate is obtained. It is further evaporated and crystallized by cooling, separated by centrifuge and dried. Consequently a high quality of industrial magnesium sulphate is achieved as the final product. In the course of process, as the majority of valuable component (SO42-) is recovered in the final product, most of impurities from waste acid is being removed into the by- product. With the simple operational process, it is possible for titanium dioxide plant to resolve the environmental problem completely and benefit from the industrial magnesium sulphate product as well. The filter cakes containing valuable elements such as Mg, S, Fe, Mn, V, Ti are by-product proposed to be used for manufacture of agriculture fertilizer particularly for peanut planting.

Jan 1, 2014

By M. I. Panayotova

Some of effluents released by copper smelting plants are highly acidic (pH = 0~1) and contain arsenic and copper in relatively high concentrations (10~20 g/L). Usually arsenic is removed by precipitation with different reagents, such as lime, iron salts, calcium salts, aluminium salts, etc. Precipitates (often voluminous) that require further handling are formed and copper and other valuable components are lost. A method is presented for copper and arsenic extraction from acidic effluents. Effluents are treated in specially designed closed electrochemical cell without chemicals? addition. Gases formed are collected and treated for decomposing the eventual traces of As-bearing compounds and ensuring the environment protection. Initially copper of grade of 85 % is electro-won. Further about half of the initially available arsenic is separated as low-soluble, low volume mixture of intermetallic compounds, oxides and some elemental arsenic. At the next stage the main part of the left arsenic is immobilized as low soluble stable compound. Arsenic content in the treated acid is in the range 0.20~0.25 g/L. Acidity of treated effluent after first two stages remains practically unchanged and the solution can be re-used. Physicochemical and electrochemical processes, governing copper and arsenic removal, are discussed.

Jan 1, 2014

By M. Paymardi, A. Foroutan, T. P. Oladele, M. Abbaszadeh

"Reducing the amount of zinc and iron in lead concentrate is one of the important aspects of processing in lead and zinc flotation plants which results in improvement of lead concentrate quality and prevents zinc loss. In mineral flotation industries, lignin sulfonates are known for their depressant properties for both non-metallic and sulfide minerals such as pyrite and pyrrhotite.This paper investigates the effect of lignin sulfonate on flotation of galena, sphalerite and pyrite in sulfidic lead and zinc bearing ores. Batch flotation tests were carried out on a high pre-activated zinc samples. The feed contains 0.9% lead, 2.3% zinc and 7.5% iron. The dosage of all reagents such as sodium cyanide, zinc sulfate, ethyl xanthate and methyl isobutyl carbinol (MIBC) were kept constant for lead flotation step except calcium lignin sulfonate (CLS) that was varied between 0 and 80 gr/ton.Results for lead rougher concentrate showed that the grade of lead increased by 2.7% while the recovery decreased around 4 % at the highest dosage of CLS. Furthermore, zinc recovery decreased by 6.3% with no significant change in grade. Iron recovery in lead rougher concentrate decreased by 2.3 % while the grade changed around 1%. In sphalerite flotation step, CLS dosage was changed in the range of 0 to 80 gr/ton while the dosage of other reagents such as copper sulfate, lime, amil xanthate and MIBC were kept constant. In this step, no decreasing in grade and recovery of zinc was observed, while iron recovery decreased. It was suggested that CLS has a depression effect on sphalerite in conjunction with other zinc depressants such as zinc sulfate and sodium cyanide. CLS was further used in plant with non-pre-activated zinc minerals. Similar trends were observed in plant.INTRODUCTIONlead-zinc sulfide minerals play an important role in the production of lead and zinc metals in the mineral processing industry (Luo, Feng et al. 2016). Due to complexity of the lead-zinc ores mineralogy, in some situations, their flotation properties vary significantly from one deposit to another one even in itself (Bulatovic 2007)."

Jan 1, 2018

By József Faitli, Imre Gombköto, Barnabás Csoke, Tamás Magyar, Beáta Oláh, Sándor Nagy

"Raw materials are among the main building blocks of a growing economy. Without raw materials, no matter whether it is primary or secondary, production is not possible. Products with high added value require special materials. Recently, worldwide production of some important raw materials mainly comes from a handful of countries, for example: China (Rare Earths Elements (REE)), Russia, South Africa (Platinum Group Elements (PGE)), Democratic Republic of Congo (Cobalt), etc. In the EU as well as in Hungary, the importance of the so called 14 critical raw materials has been recognized. Within the frame of the TÁMOP-4.2.2.A-11/1/KONV-2012-0005 - CriticEL project, the Institute of Raw Materials Preparation and Environmental Processing in cooperation with the Institute of Mineralogy and Geology of the University of Miskolc are working on the exploration of the primary and secondary sources and developing innovative preparation technologies of critical raw materials in Hungary. The research work showed in this article, focused on the recovery of critical materials from LCD TVs and monitors. There are high deviations in different literatures regarding to concentrations of critical elements in displays (e.g.: indium), probably because of the differences in production year, producers and recovery technologies. During the research - described in this study - a well specified sample of quite large amount of displays had been used. The exact place and shape of the ITO (indium-tin oxide) layer were determined by SEM analysis. The applied preparation technology was developed based on the results of our investigations and by technologies found in the literature. The developed process accomplishes two main parts: the mechanical preparation (mainly the liberation of different display layers, removal of liquid crystal) and the acidic dissolution of indium."

Jan 1, 2014

By S. V. Petrov

In recent years, heap leaching of gold is becoming wide spread due to low capital and operational costs that allows economically feasible processing of low-grade and cut-off grade ores. Currently, over 30 heap leach projects are operated in Russia. Some of the deposits treated by heap leach methods are almost depleted. Therefore, they will soon require spent heaps detoxification and reclamation. Traditionally, spent heaps are detoxified by chemical treatment. This process is characterized by relatively high kinetics and requires expensive reagents and additional equipment. The main disadvantage of this process is secondary contamination of the solutions by products of detoxification reactions and impurities contained in reagents. If there is enough time, spent heaps can be detoxified by natural degradation. The advantages of the proposed method are low operational costs due to use of existing heap leaching facilities and eliminating the need for chemicals for spent heaps detoxification. Residual concentrations of cyanides and thyocyanates in liquid phase (wet ore) of spent gold ore heaps after detoxification were 0.2~0.3 mg/L. Heavy metals were almost completely removed. The method was successfully used for detoxification of spent heaps at two gold mines.

Jan 1, 2014

By L. Y. Zhang

The metallic sulphides in Jinchuan Mine are relative friable and the gangue minerals suffer of wide secondary change, the overgrinding of metallic sulphides and sliming of gangue minerals are the main cause that makes the mineral separation indexes difficult to improve. So changing the process of grinding, and classification, and optimizing the particle size distribution of grinding product is the key improving the separation performance of Jinchuan nickel and copper ore.

Jan 1, 2014

By X. M. Yu

A large amount of polluted sludge is produced by a nonferrous metal factory after treating waste water with lime/ferrous salt. The concentration of arsenic in the dried sludge is high to 5.84%, a toxicity test is taken on the sludge according to GB5085.3-2007 and the extraction content is 15.75mg/L, which surpasses the arsenic extraction standard [As]=5mg/L, the sludge is categorized as hazardous waste. If put outside without disposal, it would be very harmful to environments. Here we report an optimum protocol to extract arsenic; S2- alkaline liquor is utilized to treat the arsenic sludge. At 85?, 10L 7% S2- liquor is added into 1kg dried sludge and the resulting mixture is stirred for 120min at 250r/min, then separated by centrifugation and the compressed waste residue dried naturally. The average arsenic content is 1.40mg/L, lower than GB5085.3-2007 Standard and arsenic-free residue is consistent with GB18598-2001 Standard, which can be bury safely. The extracted arsenic is transferred into copper arsensite for use as addictive in copper electrolysis and the waste water can be recycle after calcium is removed.

Jan 1, 2014

By Yuhe Tang

High Gradient Magnetic Separator with Horizontal Magnetic Line is a new type High Gradient Magnetic Separator product. It has many specific advantages, such as water-air joint discharging technique, double pulses pulp dispersion technique, multi-magnetic gradient for collecting matrix with different diameter rods, better discharging rate with the especial matrix dispose, high separating accuracy and wide applicability. In this paper, the author makes a description of High Gradient Magnetic Separator with Horizontal Magnetic Line, and puts its emphasis on analyzing industrial production data using high gradient magnetic separator with Horizontal Magnetic Line to separate weakly magnetic minerals. It is found that as the rougher for weakly magnetic minerals separation, High Gradient Magnetic Separator with Horizontal Magnetic Line has more stable metallurgical performance and cheaper running costs than other types of High Gradient Magnetic Separator when the properties of the ore change greatly and there is in the case of embedded fine particle size distribution. Keywords: high gradient magnetic separator, self cleaning technology, horizontal magnetic line, water air discharging technique

Sep 1, 2012