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By Pierre Roy, Claude Gosselin, Maryam Sadeghi, Michel Bourassa, Christian Rochefort, Claude Bazin, Gautier Mahieu, François Lavoie, Marilène Renaud, David Cataford

"Spirals are gravity concentrators used for the concentration of iron oxide minerals from ores. This paper presents the mineral size recovery curves observed for spirals operating in two Canadian iron ore processing plants. The size recovery curves are presented for rougher, cleaner and re-cleaner spirals. The partition curves observed for the spirals are significantly different than those observed for typical gravity concentration devices such as hydrocyclones or hydraulic classifiers. The size recovery curves show the complex behaviour of the minerals as they flow down a spiral and are analysed with a view toward process modelling and simulation. Initial simulation results show that gains in the iron recovery can be achieved by increasing the recovery of coarse iron oxide particles in the rougher spirals.INTRODUCTION Spiral concentrators are gravity based separation devices used for the preparation of coal, iron and different heavy minerals ores (Wills, 1992). The classification of the particles in spirals is based on the combination of gravity, centrifuge, drag, lift and Bagnold forces (Atasoy and Spottiswood, 1995; Burt, 1984; Bouchard, 2001). Several papers are dedicated to the analysis of the forces acting on the particles flowing down a spiral (Das and al., 2007; Sivamohan and Forssberg, 1985; Holland-Batt and Holtham, 1991; Holtham , 1992). Most of these papers aim at the development of a general model for the simulation of the classification of the particles for coal ore processing. Few papers deal with the operation of spirals for processing iron ores (Hyma and Meech, 1989; Srivastava, 2001; Dallaire et al., 1978) and fewer papers present results for spirals used as cleaners following a rougher stage. Since the classification in spiral classifiers is dependent on the particle size and specific gravity a partition or performance curve commonly applied to classifiers (Mai Manga et al., 2012) is used here to analyse spiral operation. Few papers were found to describe the operation of spirals in terms of partition curves (Atasoy and Spottiswood, 1995; Holland-Batt and Holtham, 1991; Richards et al., 2000). Most of the investigations presented the application of a model to simulate the position of coal particles of various sizes and specific gravities along the trough of a spiral (Kapur et al., 1996; Holland-Batt and Holtham, 1991). In addition most of the available literature on spirals deals with one stage of concentration by spirals (Dallaire et al., 1978; Das and al., 2007; Sivamohan and Forssberg, 1985) while industrial circuits usually consist of rougher and cleaner spirals."

Jan 1, 2014

By P. D. R. Maltby

"With the narrow vein structure of Nova Scotia gold deposits, selective mining is rarely possible and mill heads will be too low (below 0.10 oz per ton of gold) to support a conventional mill of up to 1000 ton per day capacity at present gold prices. The recent operation of a small 100 t.p.d. mill at Cochrane Hill using fine grinding - leaching - filtration supported this assertion. Milling costs exceeded $25.00/ton of feed mainly due to high capital, labour and maintenance costs.Accordingly, since 1981, efforts have been directed towards the development of a cheap gold extraction process in terms of both capital and operating costs. The main criteria is to produce gold below US $200 per oz including all administration, mining and process stages. This paper describes such a process development for Cochrane Hill. LOCATION AND HISTORY OF THE PROPERTYThe Cochrane Hill property is located about 8 miles North of Sherbrooke, N.S. on highway No. 7. Sherbrooke is about 180 miles east of Halifax. Gold was originally discovered at Cochrane Hill in the 1860's. Early work consisted of trenching. In the 1930's a small shaft was sunk to about 80 feet and some tonnage treated using a stamp mill with gravity concentration of gold.Northumberland Mines Ltd. acquired a 70% interest in the property in 1977. Subsequent drilling indicated a potential zone of gold mineralization with a drill-indicated tonnage of one million tons having a grade of 0.07 ounces per ton of gold (all high assays cut to 1 oz) down to a depth of 300 feet recoverable by open pit mining methods. In broad terms, the goldbearing zone is about 50 feet wide and 800 feet long and dips at about 70°."

Jan 1, 1984

By M. Leroux, P. Lacombe, S. R. Rao, J. Y. Kim, J. A. Finch, G. Labonté, N. Macminn, M. Ounpuu

"Laboratory investigations on two complex ores, the A1 zone ore from Les Mines Selbaie and the Lyon Lake ore from Mattabi Mines Ltd. (Division of Noranda Minerals), have been carried out to determine some of the main variables in collectorless flotation. In particular, the effect of pulp potential (controlled by gas composition), conditioning time, pH and grinding media have been studied.Chalcopyrite showed the greatest response to collectorless flotation among the four major sulphide minerals present, followed by galena. Flotation of sphalerite was variable from minimal to important depending on the mineralogy and the pre-treatment performed. Appreciable silver recovery was achieved collectorlessly for the Lyon Lake ore while it could not be achieved for the A1 zone ore of Les Mines Selbaie. It appears that the difference between the two ores is related to silver's predominance as tetrahydrite in the Lyon Lake ore while it is as argentite and native silver in the A1 zone ore.The response of the ores to collectorless flotation is strongly dependent on the pulp potential, Ep, and pH. Using different gas compositions and different conditioning times it was found that collectorless flotation occurs when Ep is +195 to +295 mv (vs SHE). The actual on-set potential for collectorless flotation is dependent on the ore. A too high potential or prolonged oxidation leads to a decrease in selectivity. Some other factors were examined, notably the effect of pH and the type of grinding media on the selectivity achieved in the laboratory.Preliminary results from a plant trial at Mattabi Mines Ltd. confirmed that collectorless flotation occurs and that it is preferential for chalcopyrite and to a lesser extent galena. Collectorless flotation was not attempted at Les Mines Selbaie. However, examination of the distribution of collector between the different addition points in the copper circuit suggests that it may be present."

Jan 1, 1990

By M. Beth McClenaghan

This paper summarizes diamond exploration techniques used in glaciated terrain, focusing on indicator mineral and geochemical methods applied to glacial sediments. Understanding the ice flow history, depositional history, and stratigraphy of glacial sediments are essential to successful sampling, interpretation and follow-up of indicator mineral and geochemical anomalies related to kimberlites. Kimberlite indicator minerals survive glacial transport over long distances and the relative abundance of each mineral in till is a function of the primary mineralogy of individual kimberlites. Indicator mineral distributions observed at a regional scale define the net effect of glacial dispersal, often along different ice flow directions. Local-scale distributions define individual dispersal trains. The medium sand (0.25 to 0.5 mm) fraction of heavy mineral concentrates prepared from glacial sediment samples is best suited for indicator mineral surveys. The application of till geochemistry to diamond exploration is increasing because it is significantly cheaper than indicator mineral analysis and it can be performed quickly. The <0.063 mm (silt+clay) and 0.5 to 2.0 mm (coarse sand) fractions provide the best geochemical contrast between background and kimberlite-rich till. Kimberlite pathfinder elements that provide good contrast include Ni, Cr, Ba, Co, Sr, Rb, Nb, Mg, Ta, Ca, Fe, K, Ti and REE, the relative importance of which will depend on kimberlite composition as well as that of the surrounding bedrock.

May 1, 2002

By W. A. Ahrens, J. H. McNamara, J. G. Franek

"An economical, pollution-free process has been developed for the hydrometallurgical extraction of copper from sulphide ores. The extracted copper, in the form of cuprous chloride (CuC/), is converted by reduction to copper metal. The metal is melted and fire -refined into wire bars which meet the standards of electrolytic tough pitch (ETP) copper wirebars. IntroductionThe successful development of the Cyprus Copper Process has been an evolutionary series of events covering a time span of some nine years. The original process, based on an electrolytic membrane cell principle , was abandoned in 1975 because of technical, economic and pollution problems. During the past four years, the pilot plant has been reconstructed based on a new flowsheet and operated successfully in several campaigns, some for as long as four months. The pilot-plant hydro section operates at a 225-lblhr copper rate. In October 1977, a feasibility study was completed by Jacobs Engineering, Pasadena, California. The study showed favourable economic and technical feasibility. Jacob&apos;s studies in 1978-79 revealed favourable comparative economics with other known pyrohydro processes and favourable economies of scale.The Cyprus Copper Process converts copper concentrates of varying composition into copper metal, which has been proven to be equivalent in every way to electrolytic tough pitch copper, suitable for electrical applications. This is accomplished at capital and operating costs which are estimated to be lower than those associated with any other known currently applicable technology. Also, the total energy requirement is equal to or less than any other known process and the process is essentially pollution free."

Jan 1, 1980

By J. K. Afidenyo, J. Osei-Owusu

"The Obuasi Mine of AngloGold Ashanti Limited has been operating the world’s largest Biooxidation Plant at its Sulfide Treatment Plant (STP) in Ghana, using the Gencor Biox® technology since February 1994. The Biox® technology was preferred to other alternative methods of treating refractory sulfide ores such as roasting, pressure oxidation and nitric acid leaching due to among other reasons, its lower capital and operating costs, reduced technical risk, relatively benign environmental impact and its ease of operation and maintenance in a remote location.STP has since commissioning succeeded in operating this technology successfully but not without some operational problems. The Plant has seen a number of upgrades and modifications in its circuits which were motivated by cost, operational and throughput constraints.The objective of this paper is therefore to highlight the mine’s experience in the treatment of its complex carbonaceous refractory sulfide gold ores with emphasis on plant operations and improvements such as the Biox® reactors expansion, flotation concentrate upgrade project and neutralization circuit modifications. The Biox® Plant operating cost is also discussed.INTRODUCTIONThe Obuasi mine forms part of the AngloGold Ashanti Group of Gold Mines. It is located in the Adansi West District of the Republic of Ghana. The mine is primarily an underground operation, although some surface mining still takes place. Ore is processed by two main treatment plants: the Sulfide Treatment Plant (for underground ore) and the Tailings plant (for tailings reclamation operations). A third plant, the Oxide Plant, is used to batch-treat remnant opencast ore and stockpiles, of which there are adequate tonnages to keep the plant operational until 2008.Though reference is made in this paper to the Tailings and Oxide Treatment Plants, the main focus will be on the Sulfide Treatment Plant."

Jan 1, 2008

By V. I. Lakshmanan

Process Research ORTECH Inc. (PRO), with its in-depth knowledge on cobalt behaviour in nickel matte smelters and its novel mixed chloride hydrometallurgical processing, is developing a hybrid process to enhance cobalt recovery. PRO’s experimental data is compared with plant information on cobalt behaviour in smelters. In final stages of iron rejection in the converters, the thermodynamics of the matte-slag system dictates the undesirable transfer of the cobalt to the final converter slags. This results in much lower cobalt recovery in the product Copper/Nickel matte (<60%) in present copper and nickel smelters. This information is used to transfer cobalt into desired quantity of converter slag. The enriched cobalt slag is subjected to PRO mixed chloride process to recover nickel, and cobalt as high value salts of importance in lithium ion batteries. From a typical converter slag containing 3.5% Ni, 1.5% Co, and 1.0% Cu, PRO leach process extracts 98 % Ni, and 98 % Co, and 99% Cu. Application of this process to enhance cobalt recovery in typical Copper/Nickel smelters is presented. In addition, this will also enhance the Copper and Nickel recovery. Both these aspects are of interest to the Copper, Nickel, and cobalt producers. INTRODUCTION In pyrometallurgical extraction of copper and nickel from sulphide ores cobalt often occurs with copper and nickel. The requirement of cobalt is increasing due to its need in lithium ion cells used in electric vehicles. Therefore its efficient and economical extraction in a form suitable for use in lithium batteries is of great interest at present. In the pyrometallurgical processing of copper and nickel sulphide concentrates the concentrate is smelted to produce a furnace matte, which is then sent for converting to remove the iron to produce iron free (~1% Fe) matte for further processing to copper or nickel matte. The copper/nickel matte is processed for metals recovery by hydrometallurgical or vapo-metallurgical or oxidation – reduction routes to make market products. As shown in Figures 1 and 2 the slags are produced in the smelting step and in the converting steps. The metal losses in smelting are controlled by the oxygen pressure in that step and slag production which is controlled by concentrate grade. The slag produced in the converting step which is carried out at a higher oxygen pressure contains higher level of metals is often returned to the smelting step to increase value metals recovery.

Jan 1, 2019

By N. Hmidi, T. Yalcin, M. Papadakis, B. Hilscher

Mill tailings, containing iron sulphides in particular, pose an environmental concern since they constitute a potential source of acid mine drainage which can damage vegetation, harm soil and living organisms, and contaminate groundwaters. Proper disposal of acid generating tailings is therefore an important issue that must be addressed and resolved in a satisfactory manner. Placer Dome Canada operates a 4000 t/d gold cyanidation facility at Musselwhite mine, in northwestern Ontario, where the mill tailings have been classified as acid generating. This study was conducted to explore the effectiveness of froth flotation in removing the sulphide minerals from these tailings and producing a low-sulphur, non-acid generating material that could serve as a capping material for previously deposited tailings. Laboratory semi-batch flotation tests were carried out in accordance with an experimental design procedure, and a computer simulation program was developed to facilitate the evaluation of flotation performance. In this investigation, pH, collector concentration, and airflow rate were considered as the relevant flotation variables, and their effects were examined both experimentally and by simulation. Results have demonstrated that flotation can successfully desulphurize the Musselwhite mine tailings and render them non-acid generating.

Jan 1, 2004

By Bruce Mennie

PT Freeport Indonesia (PTFI) operates copper and gold mining operations in a mountainous area of the Mimika regency, near Tembagapura, Papua (formerly, Irian Jaya), Indonesia. The mining and concentrating operations typically produce 240,000 metric tonnes per day of Copper and Gold ore from the combined mining of an 80,000 tonne per day (ore) block cave operation (DOZ Mine) and a 160,000 tonne per day (ore) open pit mining operation (Grasberg Open Pit). The Grasberg Open pit mine will be complete in 2016 at which time PTFI?s operations will convert to Underground. Mining operations will transition from today?s mixed surface and underground operation to full underground mining over the next 6 years. This paper reviews the history of Redpath?s relationship with PTFI, beginning with a raiseboring contract in 1981 and evolving into vertical and horizontal development contracts of up to 37,700 equivalent metres of lateral development and 4,000 metres of vertical development in 2011. An overview of the current operations (PTFI?s Grasberg Open Pit and DOZ Underground Mines) and transition period (challenges for the transition from current to future underground mines) is presented with details of development of common underground infrastructure and future mines; Big Gossan Mine, DMLZ Mine, Grasberg Block Cave Mine, and the Kucing Liar Mine.

Oct 1, 2010

By J. E. Sepulveda, R. Morrow

"The Linear Wear Theory provides a reliable framework for the assessment of grinding media performance at full scale. This theory can be applied for analyzing grinding media consumption rates in any given grinding operation as well as the evaluation of alternative grinding media products, based on actual operational data, correcting for conditions like ore hardness, feed and product sizes, mill power and circuit throughput; all of them unrelated to the grinding media intrinsic quality attributes. A series of Moly-Cop Tools 3.0 applications have been developed to facilitate the calculations involved. Moly-Cop Tools 3.0 is available, free of charge, to all interested parties through the corresponding author.INTRODUCTION Mineral grinding circuit operators recognize the significance of grinding media (balls) consumption on the cost structure of any full scale grinding facility. The effective cost associated with this essential consumable depends on two factors: delivered price and durability (quality) of the grinding media. When evaluating alternative grinding media varieties, there is a well accepted evaluation criterion by which a given media type is considered to be “cost-effective” when its unit application cost – normally expressed in $/ton of ore ground – is shown to be lower than that of a nominal reference condition: Grinding Media Cost = Ball Price x Ball Consumption (1) ($ /ton ground) ($/ton balls) (ton balls/ton ground) Under this criterion, an alternative, higher-price grinding media product could be “cost-effective” if its associated consumption rate is sufficiently lower than the reference media, enough to yield a lower grinding cost, as dictated by Equation 1. For the proper application of the above criterion, evaluators must rely on representative indicators of grinding media quality, ideally independent of most mill operating conditions. In each particular case, ball price is always a known component; however, it is not so evident how media performance (quality) differences amongst alternative product types could be assessed with a reasonable degree of accuracy and precision."

Jan 1, 2014

By J. Maheu

Heap leaching is an old technique for the recovery of copper, but a fairly new technique for the recovery of gold.The paper outlines the equipment required for the establishment of heap leaching test facilities and the procedure required to insure meaningful results. Sampling methods, the metal balance, carbon adsorption and stripping and safety procedures are discussed in broad outline.

Jan 1, 1982

"The characterisation of resources and description of variability across different ore domains is key to accurate prediction of probable metallurgical performance. Such characterisation testwork often has limited drill-core from which to work and this immediately confines the characterisation method to smallscale. For flotation feeds, the JKMSI (Mineral Separability Indicator) is being developed as a potential characterisation tool, building on earlier work by Chudacek, (1990), which used shaken test tubes, and was called the EMDEE device. In addition, the consistency of flotation recovery for specified size fractions has shown to be preserved, irrespective of the amount of material in that size fraction obtained by different milling conditions, so that the overall recovery can be estimated from knowing the particle size distribution (McIvor and Finch, 1991; Bazin et al, 1994, Runge, 2007 and Wightman et al, 2010) The JKMSI unit uses less than 10 g of material per test in narrowly sized classes and results to date have demonstrated the value of the test. This paper discusses the potential of the test by demonstrating the link between JKMSI performance and mineralogy of five different ores from Laguna Seca, Escondida Minera Limitada as well as the correlation to plant scale performance obtained in an earlier survey (Coleman et al, 2006). Further work to tie down the proof of representatively of the small sample has been identified and is discussed and included in the paper. INTRODUCTIONSince the uptake of the flotation process at the turn of the twentieth century, small scale, laboratory methods have been sought to characterise flotation response. Although laboratory batch flotation tests are the most widely used method to evaluate reagents, characterise ore variability and obtain suitable model parameters using various scale up factors Runge (2101) other methods using less ore would be useful where ore samples were limited.A method using test tubes for testing ores’s flotation response to reagents was first developed by Ian Walk (Wark & Wark, 1935; Wark; 1938; Sutherland and Wark 1955). In these tests a 50 cc stoppered measuring cylinder served as a means for a qualitative experiment, the aeration being effected through violent shaking by hand. In these experiments about 10 g of mineral was ground by pestle and mortar under water after which the ground material was deslimed and adequately conditioned with the appropriate reagents."

Jan 1, 2013

By T. Belem

The main objective of this study is to better understand the effect of underground CPB placement conditions on its microstructural, hydro-mechanical and geochemical properties. To reach this objective, three PVC columns, each 3 m high, were built, and were filled with CPB material. The columns allow simulating undrained (UD), half-drained (HD) and fully-drained (FD) conditions along with the measurement of resulting self-weight consolidation settlement of the CPB. Bleed and drainage waters were also collected from each column for geochemical analyses (pH, Eh, EC, SO42- content). After 90-days of curing time, a total of sixty CPB samples were cored from the backfill columns and subjected to uniaxial compression tests followed by physical characterization (Gs, void ratio, water content, degree of saturation, specific surface area). The results showed that the total drainage water and the maximum observed settlement occur mainly within the first 72 hours after the columns are filled. The corresponding volumetric strains suggest that in situ backfilled stopes simulated behave in a similar way to the fully-drained (FD) or the half-drained (HD) conditions. The MIP test results show that the pore structure varies between the top and the bottom of each column.

May 1, 2007

By M. P. Hay

"For a model to be successful it must address the concerns and needs of a target audience. Further, the model must demonstrate the same patterns of behaviour as the real system, and need only be complex enough to meet this objective. If the model is too complex it can become unusable to those who need it most.With this in mind, SUPASIM has been developed for the practical metallurgist requiring only laboratory flotation rate data as input. Some 35+ successful plant simulations have been completed since 1985. The approach of SUPASIM is to characterise an ore, organise information in an understandable way and add structure to the complex flotation situation and hence support the metallurgist to interpret the relationship between variables and optimise the flotation process.The paper describes the basis on which the model was developed and sets out to provide an insight into interpreting laboratory flotation kinetics and their physical meaning in a production plant and the influence floatable gangue has on float performance and plant design. A case study illustrates how the ratio of slow floating mineral to gangue can influence circuit design and improve recovery on a plant scale.INTRODUCTIONThere is an enormous amount of useful data in the results of a laboratory scale rate test. Each variable of fraction and rate, for mineral, metal and gangue has a physical meaning in the plant. The link between float kinetics and the plant in respect of recovery, grade, pulp density, pulp flowrate, residence time, number of stages of cleaning and circuit configuration has been established by the author in the process of developing SUPASIM."

Jan 1, 2005

By Ioannis K. Kapageridis

The lignite deposits of the Kozani-Ptolemais-Amyntaio basin in western Macedonia (North-West Greece) present a difficult modelling problem. Each deposit consists of several thin lignite layers ranging from a few centimetres to a few tens of centimeters in thickness, and thin intercalated sterile layers of marly limestones, marls, clays, and sands. These layers are practically impossible to model individually due to fast lateral transition of lignite layers to humus clay and vice versa and the lack of reliable and detailed stratigraphic correlation, leading to compositing methods being applied prior to any interpolation and modelling. The complexity of the deposit is further increased by the presence of a number of faults. This paper presents the modelling and estimation procedures applied during the most recent study of the South Western Field ? a new deposit that is considered for development and lignite production over the next years and will support the operation of a new power station in the area. Special focus is given to drillhole database structuring, fault modelling, stratigraphic correlation, mineable lignite intervals compositing, and resource estimation. The use of specialised mine planning software in all stages of modelling and estimation is thoroughly explained.

Oct 1, 2009

"Geoscan is used for multi-elemental analysis of conveyed bulk materials in the minerals industry with proven performance and demonstrated paybacks of weeks or months in iron ore, manganese, copper, zinc-lead and phosphate industries. Geoscan-M measures continuously through the full bed depth and is unaffected by belt speed, particle size, layering, mineralogy and dust levels. Increments of typically two minutes are accurately measured and provide the plant operators with tonnage weighted results of contained elements. Measurement of the composition in real time enables prompt feedback to the mining operators and also feed forward to the process operators. Crushed ore increments can be diverted based on composition, such as diverting waste for disposal or marginal material to a stockpile for separate processing. Bulk sorting allows material to be placed into relevant stockpiles for subsequent blending to achieve consistency for process feed. Parameters used for decisions may be primary metal content, deleterious component content, other process parameter, or a combination of these. Process parameter may be the elemental ratio between critical components, e.g. Cu:S ratio, basicity, or the content of an “indicator” element (such as Si indicating material hardness). Benefits will be discussed based on case studies in copper and iron ore.IntroductionAs operators of process plants strive to remain competitive as capital and operating costs increase and commodity prices fluctuate, more focus has been directed at incremental performance improvements at incremental cost rather than major expansions to increase output. The philosophy of working smarter allows plants to adopt technologies proven in other industry sectors to minimise risk. This paper discusses one such technology that the minerals sector is adopting and has found to be safe, reliable and accurate with paybacks of weeks in most applications. New applications continue to be found and major benefits realised at various stages in the processing and handling of ores and products."

Jan 1, 2016

By M. Tarvainen, J. Kallioinen

"Depressed metal prices coupled with increasing production costs have presented a great challenge for operators to control and reduce the costs of production to maintain profitability. Depleting ore reserves, added to the above has forced Outokumpu to take a hard look at its operations, to develop new methods to profitably extend the life of its mines. One of the areas investigated and approved for further development has been the use of larger and more energy efficient equipment. As a result, large flotation machines were developed and today 38 and 60m3 flotation machines are in use.Secondly, ore preconcentration has been developed to avoid processing the part of the ore that has little or no mineral values.Another quite recent development and the topic of this paper, has been the use of coarse flotation before conventional flotation. The main idea is that part of the valuable mineral is separated as early as practical by floating it with specially designed flotation equipment, installed in the grinding classification circuit. The new flotation cell is specially designed for this application and differs from the conventional cells in the tank design, feed arrangement and modified mechanisms in some cases."

Jan 1, 1984

By Hua-Zhong Yu

Gold is one of the most widely used substrate materials for self-assembly. Self-assembled monolayers (SAMs) prepared from alkanethiols and their derivatives on gold are the most reliable and well-studied systems to date, which have attracted much attention because of interest in two-dimensional molecular assemblies, and of their potential applications in molecular devices, sensors, and functionalized interfaces. Gold electrodes are also very important in microelectronics and electroanalytical chemistry. This work reports the characterization of a new type of gold substrates for self-assembly. The gold substrates are constructed from recordable compact disks (R-CDs) with simple and straightforward wet-chemical treatment, and can be made at desired sizes and shapes that satisfy different experimental needs. In particular, an easy, inexpensive, and reproducible method to prepare self-assembled monolayers (SAMs) on CD-R gold substrates after removing the protective polymer films with concentrated nitric acid was described.

Oct 1, 2003

By Andy Lemay

Vale (previously known as CVRD) is: ? The second-largest mining company by market capitalization (NYSE:RIO) ? Headquartered in Brazil ? Global workforce of over 100,000 employees including outsourced workers. Vale Inco Limited is a wholly?owned subsidiary of Vale Vale Inco Limited ? is based in Toronto, Ontario Canada: ? Operations and Projects in 20 countries ? Marketing Network extending to 40 countries ? Over 12,000 employees worldwide ? Last years sales of US $8 Billion

May 1, 2008

By Jodi Roberts, Curtis Deredin, Jean-Guy Paulin

"Since the establishment of the Six Sigma quality improvement program in 2001, several projects have been successfully carried out in the copper-lead, zinc, copper separation, lead upgrading and bulk flotation circuits in the Brunswick Concentrator.This paper provides an update on the process improvement initiatives that have taken place since 2004 using the Six Sigma methodology:•,The recirculation of warm water to the flotation circuit (to save on energy costs)•,Installation of a heat recovery tower to recuperate the heat lost from the zinc dryers•,Installation of an extra row of cleaner-scavenger cells for the copper-lead circuit for extra capacity, and a new reagent scheme for the copper separation circuit that have increased copper and lead recoveries.INTRODUCTIONThe Brunswick Mine Concentrator (Xstrata Zinc Canada) is located near Bathurst, New Brunswick and is one of the world’s largest lead/zinc mines. Milling of ore commenced in 1964 from the No. 12 orebody, with an expansion in 1966 to accommodate ore from the No. 6 open pit mine. The concentrator utilizes selective flotation to produce zinc, lead, copper, and bulk lead/zinc concentrates. The ore is a complex massive sulphide, consisting of approximately 20% valuable minerals, 60% pyrite and 20% silicates.Figures 1, 2, and 3 illustrate the historical annual average metallurgical performance and process improvements achieved at Brunswick Mine for the zinc, lead and copper concentrate products. The objective is to continuously direct metallurgical performance towards increasing grades and recoveries while minimizing operating costs."

Jan 1, 2008