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By Z. Mubarok

An overview of the problems encountered the electrorefining of copper anodes containing high levels of nickel and antimony is presented. Our investigations have been focusing on the passivation behaviour of the anodes with high contents of Ni, Sb, Sn, and Pb, the formations of kupferglimmer and floating slimes. The results of linear voltammetry, chronopotentiometry and electrolysis test revealed a noticeable lower resistance of the anodes to passivation in comparison to those with lower contents of Ni, Sb, Sn, and Pb. Anode containing kupferglimmer exhibited oxygen gas evolution during the passivation state. Scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) indicated that tin can replace and/or join antimony in the kupferglimmer structure. Under specified experimental conditions, floating slimes precipitations took place with high Ni, Sb, Sn, and Pb anodes prior to the end of one anode period.

Jan 1, 2007

By F. Golestani-Fard, A. A. Nourbakhsh

In this paper microstructural development of nitride-Bonded SIC refractories is reported in presence of Al203, Mg() and Urea additives .The samples were prepared by mixing, shaping and firing at 1400-1500°c in a controlled atmosphere furnace. Phase analysis, microscopic observation and mechanical evaluation were taken for microstructural investigations. The strength of samples doped with Al203 was first increased and then decreased at higher amount of Al2O3 additions. The addition of MgO decreased the strength while the urea showed an improving effect on strength. These phenomena could be attributed to microstructural evolution and mainly to liquid phase formation and grain morphology. It was found that the additives such as Al203, MO and urea could modify the microstructure in terms of phase formation and texture modification, which in terms influences the mechanical behavior.

Jan 1, 2004

By T. Maruyama

Tamano Refinery started its operation in 1972 with the cathode production capacity of 84,000 tons per year. After several expansions, the production capacity increased to 228,000 tons per year in 2001. In this paper, we are introducing our next expansion projects starting October 2006. The project expands the production capacity of cathode from 228,000 tons to 260,000 tons per year. The main modification of this project is the conversion to the ISA process and the installation of additional seventy-two cells in the No.2 Tankhouse. The No.1 Tankhouse remains the same, using the conventional process. Half of our starting sheet cells are converted to commercial cells. The other expansions are to enlarge our purification plant. And the incidental facilities are enlarged, for example, circulation tanks, heat exchangers, filtration system, etc. Finally, this paper describes those improvements to our refinery performance and preparing for future expansions.

Jan 1, 2007

By Y. Vermeulen, J. Simoes, P. Guillo, A. Di Donate

New design techniques have been developed to optimize continuous casting (CC) refractory components. The overall objective is to increase CC productivity as well as steel quality by using optimized refractory from tundish-to-mold. These techniques allow the prediction of steel and refractory chemical interactions and, thus, steel chemistry evolution as well as build up and corrosion occurrence. Specific fluido-dynamic models (CFD) have also been developed to better take into account the physical parameters at the steel/refractory interface and to optimize steel flow control. The CFD model can be coupled with refractory chemical interactions to simulate steel chemical evolution. These two different approaches result in shape and material modifications. They are completed by dedicated thermal stress analysis in order to improve thermal shock resistance. The mechanical FEA evaluations take into account specific mechanical behavior of refractory components as well as high temperature evolution of their properties.

Jan 1, 2004

By Michel Aubertin

Mining activities can produce large volumes of waste rock, which are typically deposited in piles on the soil surface, above the water table. Such piles can cover areas of several tens of hectares and can reach over a hundred meters in height. For hard rock mines, the waste rock grain size can vary from silty particles to metre-scale blocks. The internal structure of a pile constructed on a relatively flat surface typically includes two main zones. The first zone corresponds to the heart of the pile, and is formed by several sub-horizontal stratifications (with dense and loose layers) due to the heavy mine equipment traffic which induces local compaction and degradation of the waste rock. The second zone corresponds to regions where waste rocks are deposited by push-dumping or end-dumping close to the external flank of the pile, inducing grain size segregation along the slope. Depending on the deposition sequence, grain size distribution and bench height, a gradation may then be observed, with coarser particles (with cobbles and blocks) near the base and finer particles near the crest, together with inclined stratifications due to the advance of the deposition face. These internal features affect the distribution and flow of water (and air) in the pile. To assess the internal distribution of material properties within the pile, a combination of several tools is usually required which can provide information on the hydrogeological and geochemical characteristics of the waste rock. In this regard, geophysical tools are very interesting because they can lead to a threedimensional mapping of property variations. The information gathered from a combination of appropriately selected techniques can be used to construct numerical models to further study unsaturated water flow and reactive transport. Such simulations help better understand the pile response in its actual and future states, which in turn provides input to adjust the deposition sequence, to plan for closure, and to select an in situ groundwater monitoring strategy. The presentation will give an overview of techniques that have been developed to characterise material properties in the laboratory and in the field, and to obtain a general picture of a pile?s internal structure. Additional results on unsaturated reactive transport modelling will also be shown to illustrate how the internal pile structure may influence its hydro-geochemical and environmental response.

Nov 1, 2008

By G. C. Laurence

"This paper discusses the hazards and extensive precautions taken in Canadian uranium mines, concentrating plants and processing plants. It also outlines Canadian policy regarding the control of the sale and distribution of uranium and other nuclear materials.OVER THIRTY YEARS AGO, I spoke to The Canadian Institute of Mining and Metallurgy here in Montreal about radioactivity and its dangers. I must have made quite an impression thirty odd years ago, because now you have asked me to do it again. Of course, the picture has changed. Then they were mining uranium ore, recovering the radium from it and throwing away the uranium. Now they are still mining uranium ore, but are throwing the radium out on the tailings dumps. Thirty years ago, most people did not know what ""radioactivity"" meant. Nowadays, they have beard that it is dangerous, and some of them, recently, be-came worried about the radium in the tailings dumps and what becomes of it."

Jan 1, 1969

By F. King, R. Sutherby, J. Been

With thousands of kilometers of buried oil and gas pipelines throughout the country, carrying flammable, high-energy hydrocarbons, the integrity and safety of this transportation and distribution network are paramount. The pipeline industry has the primary responsibility for pipeline safety and has in many ways taken the lead in dealing with safety issues. Over recent years, regulatory demands have increased, requiring operators to comprehensively evaluate their pipelines through indirect and direct inspections and to manage risk through integrity programs. Mechanistic and correlative models have been developed that assist in the prediction of pipeline integrity and the determination of reassessment intervals. These lifetime prediction models are based on decades of laboratory research as well as pipeline operating data, material data, and field monitoring data pertaining to soil conditions and CP. An overview is presented of an integrated approach towards the development of such models for the evaluation of external cracking and corrosion of transmission lines.

Jan 1, 2005

By Dina Aloi

The need to be seen as responsible neighbours and good corporate citizens is a critical success criteria for mining companies. To be seen as responsible requires both achieving responsible performance, and making that good performance visible to the community, legislators, investors, and other stakeholders. This has broadened the skills required for the successful operation of a mining company to include social sciences, public affairs, communications, and environmental sciences. Mining companies still look to technical specialists to achieve the core of that good performance - broadly characterized as a sustainable operation. However, the degree of understanding that those specialists have of the requirements for sustainability and overall Corporate Social Responsibility has a tremendous impact on the overall performance of the project and company. In her keynote address to the Sustainability for Profit session, Dina will outline some of the key areas in which technical employees and consultants can contribute to achieving successful sustainable mining operations.

Jan 1, 2010

By Michael Nicol

A quantitative description of hydrometallurgical operations depends primarily on an understanding of the kinetics of the chemical and physical processes that take place in such operations. This paper will review the current status of kinetics in hydrometallurgy in terms primarily of the author’s experience in diverse unit operations. A distinction will be made between the popular use of models based on limited kinetic data and mechanisms which reflect the actual elementary chemical or physical steps involved in an overall process. Several examples will be used to illustrate this distinction. The proliferation of published papers of declining quality has resulted in the bequest to later researchers of outdated and often incorrect conclusions by a process that is often difficult to reverse. Some examples of these mysterious concepts will be examined and hopefully reversed. Finally, several examples will be given that identify significant gaps in our understanding of the kinetics of important processes that remain unresolved.

Jan 1, 2014

By J. E. Nesset

The past 50 years have been a golden era, not just for the CMP but also for the development and success of Canadian technologies in the field of mineral processing. The CMP has played a critical role of technology transfer agent, and the success of these technologies is also linked to the success of the CMP itself. The presentation will cover, in brief, the growth of the CMP from its origins as the Canadian Gold Metallurgists in 1964, with some 39 attendees, to the present day when the annual meeting sees 500 and more from a dozen countries. Also covered will be selected technology success stories from the 50th anniversary volume to be given to all delegates ‘Canadian Contributions to Mineral Processing Technology 1968-2018’. The volume itself highlights some 40 technologies that have been divided into five categories; process water treatment and minesite environment, technology innovations, innovations in operations, technology providers and university contributions. Some international perspectives will also be shared.

Jan 1, 2018

By G. Kordosky

Leaching aids that result in an increase in leaching rates and overall copper recovery have the potential to be beneficial to copper leach/solvent extraction/electrowinning operations. It is generally accepted that effective leaching aids facilitate the penetration of leach solution into ore by lowering the surface tension of the leach solution. Surfactants are designed to do this, and a leaching aid containing the widely used surfactant class, alkyl phenol ethoxylates, has been suggested. Alkyl phenol ethoxylates were tested to determine how they may affect phase separation, entrainment and degradation in a copper solvent extraction plant. The test results suggest the use of leaching aids at a regular rate, or even for a short time period, may have a long term impact on copper solvent extraction. Several scenarios are evaluated regarding existing operations and future solvent extraction projects and cautionary suggestions related to the use of surfactants as leaching aids are given.

Jan 1, 2007

By R. Ramirez

Atlantic Copper Refinery (Huelva, Spain) has operated the ISA permanent cathode technology since 1995. The current production rates are 260,000 t/y cathodes and 730 t/y anode slimes. These slimes undergo an atmospheric leaching in which their copper content is reduced from an average value of 24 % to 16 %. In June 2005 an optimization study of the leaching conditions was carried out aimed at lowering the copper content in the slimes to less than 8%. At the same time, a new mixer (Outukumpu Technology GLS-mixer) was installed in one of the three leaching reactors. As a result of the improvement of the leaching performance and to prevent the return of tellurium to the tankhouse, a cementation plant was commissioned in July 2005 to ensure a Te content below 50 ppm in the Cu-rich leachate. This paper describes the results of the improvement of the leaching conditions and the operation of the new tellurium removal plant.

Jan 1, 2007

By R. S. Rogers

Abstract - Forensic geology in a mineral exploration context is concerned with geology and related technical matters as they pertain to legal cases involving exploration and evaluation of mineral properties. Such cases involve the possibility of outright scams that include falsification of data and information, as well as inappropriate application of various technical procedures. Experience in forensic geology in such cases emphasizes the need for systematic quality control procedures during routine exploration/appraisal and indicates the need for more attention to ‘target hardening’ (improving security in the chain of custody of samples and assay results). A number of ‘early warning signs’ that might suggest some form of tampering or falsification of information are listed. These measures will support the work of the "Qualified Persons" (geologists and engineers) entrusted with the scientific and technical aspects of mineral exploration, and facilitate the increased attention to regulatory oversight and enforcement of securities laws recommended in the report "Setting New Standards."

Jan 1, 1998

By Q. Dong, S. A. Nightingale

An investigation has been carried out to assess the effects of an applied voltage on the dissolution rate of MgO refractory in a steelmaking like slag. In this study corrosion results obtained from dip tests using a dense direct bonded MgO refractory in a CaO-SiO2-Fe2O3-FeO-MgO slag are presented. These results demonstrate that the application of a voltage across a dense MgO refractory-slag interface can change the rate of refractory dissolution. For the slag composition used and the voltage range tested, it was found that a maximum corrosion rate was obtained at a voltage setting of -0.45V. The results of this investigation have been explained in terms of voltage affects on Marangoni (interfacial tension induced) stirring and its effect on the MgO dissolution reaction that is at least partly controlled by mass transfer in the slag.

Jan 1, 2004

By S. Afshar, C. Allaire

Several studied have recently shown that the use of non-wetting additives is not always a sufficient solution to improve the corrosion resistance of refractories against molten aluminum. Once in contact with liquid aluminum, the coarse aluminosilicate aggregates, which do not benefit from the protective effect of non-wetting additives in the matrix, may be corroded. In some cases, the corrosion of aggregates, especially those containing a significant amount of free silica and/or alkalis, promotes corrosion in the surrounding matrix. The present work explores the possibility to protect the poor corrosion resistant aggregates via a lining procedure. A slip casting method, using either alumina or celsian-like composition based slurries, has been applied for lining of a series of aggregates. The results from this study show that such linings may prevent efficiently the corrosion of aluminosilicate aggregates. This work also analyzes the effects of firing temperature and lining quality on the corrosion behavior of aggregates

Jan 1, 2004

By B. T. Lu, J. L. Luo, T. Yu, C. W. Chen

In this paper, the synergism in erosion-corrosion process occurring in oil sand wastewater transportation caused by the interaction of mechanical and electrochemical factors was experimentally investigated. The erosion-corrosion tests were conducted with A1045 steel in synthetic slurries comprising tap water and silica sand. The material loss due to corrosion-enhanced erosion was assessed with the chemo-mechanical model developed by the authors recently. The results indicate that the material loss produced by corrosion-enhanced erosion at the open circuit potential can be formulated as a linear function of logarithm of corrosion current density. The wastage caused by the erosion-enhanced corrosion was analyzed based on the concept of non-equilibrium thermodynamics. The material loss induced by the erosion-enhanced corrosion is approximately a linear function of overall erosion rate measured in synthetic slurries, indicating that erosion-enhanced corrosion could be reduced by adopting surface strengthening techniques to improve the resistance to the plastic deformation in surface layer.

Jan 1, 2004

By Steven Aiken

The East Boulder Mine located in Montana, U.S.A. utilizes snowmaking to assist with mine water treatment for nitrogen removal. Nitrogen species, including ammonia, are common contaminants in mine water from underground mining operations. Snowmaking provides secondary treatment of nitrogen during the winter due to the chemical and physical processes that occur during snowmaking, in the snow pack and in the snowmelt. The primary processes include atomization, evaporation, sublimation and volatilization. The snowmakers also provide secondary treatment for nitrogen removal when used as evaporators and/or land application units during the summer. In 2002, the snowmaking process was successful at reducing total nitrogen in the mine water by up to 87%. If additional losses due to soil and root zone processes are included, total nitrogen reduction would increase to between 87 and 97%. Snowmaking is an effective nitrogen reducing treatment method during the winter when other treatment methods such as land application cannot be used.

May 1, 2004

By D. D. Rodier

The mining and metals indusrty's approach to Sustainable Development has dramatically evolved in response to growing concerns for the future ability of the industry to continue as a vital contributor to the sustainability of society. This paper will review recent trends,including the overriding global issues impacting the sustainability of society and what the Global responses to these issues have been. This will be followed by the response of the mining and metals industry to better contribute to sustainable development, starting with the landmark independent study the MMSD Study and the creation of a global policy voice for the industry, the Intrenational Council for Mining and Metals (ICMM). The tenants of the ICMM's Sustainability Framework guide this organization's work with the overall themes of performance improvement, leadership and leverage through partnerships. The paper will then conclude with a brief description of an example of what, an individual company, a service provider to the industry, is doing to assist in the industry's efforts.

Jan 1, 2007

By W. D. Gould, F. Goodazi, W. F. A. Duncan, A. G. Mattes

A biological treatment system designed to passively remove high concentrations of metals from leachate collected from a landfill near a large integrated zinc lead smelter has been in operation intermittently for the past five years including winter time operations. High metal removal efficiencies in the system were achieved. After 729 days of operation and treating over 8 million L of water the original anaerobic bioreactor constructed in 1997 was taken apart and rebuilt. The deconstruction of the bioreactor allowed systematic sampling at all depths of the biological matrix. Samples were analyzed for metal, S and TOC concentrations; as well bacterial populations were determined. Results of this sampling procedure are examined and compared at various depths within layers and between layers using one-way ANOVA and linear regressions. Metal concentrations were positively correlated with sulphur and negatively with total organic carbon. This is in concurrence with a model of biogenic precipitation of metal sulphides.

Jan 1, 2004

By G. Dörsam, M. Spreij, S. J. Van der Wal, A. P. Schmidt

The transfer of hot metal desulphurising from the torpedo cars to the hot metal ladles at the IJmuiden BOS plant no.2 caused a decrease in ladle lining life from 680 to 470 heats. Changing the desulphurising agent CaC2 for CaO during a trial period, for environmental reasons, led to a further decrease in refractory life. Availability of the ladles became critical and the major reasons for the low life were identified. Solving one of them, temperature, quickly resulted in restoration of the original lives. However, re- introduction of the new desulphurising agent on 50% of the heats again resulted in a decrease, this time from 700 to 550 heats. In order to be prepared for the full introduction of the new agent, thorough investigation of worn linings was conducted, revealing the major (chemical) wear mechanisms. With these findings, a new design for the hot metal ladle is proposed.

Jan 1, 2004