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By Akira Miura, Katsuyuki Sato, Yuken Fukano

JX Nippon Mining and Metals Corporation has developed the JX Iodine Process, which is an innovative and patented copper-leaching process for low-grade primary sulfide ores. This process consists of the irrigation of ferric iron and a low concentration of iodide solutions. One-meter column leaching tests were conducted on ore samples from two different mines. At the end of experiments, the total copper recovery exceeded 70% for Sample A and 50% for Sample B with the iodine method, which was significantly higher than that with conventional ferric leaching of 14% for Sample A and 20% for Sample B. To elucidate the reason for the JX Iodine Process effectiveness, cross sections of leached residues were studied. Reaction products were confirmed around chalcopyrite even in the central area of particles in Sample A, however, reaction products were recognized at a depth of only 1 mm from the ore rim in Sample The resistance of Sample A to the leachate appeared to be lower than that of Sample B because Sample A had a high permeability and porosity, whereas Sample B had been affected strongly by a potassium alteration. No reaction products were visible on conventional leaching samples, even at the ore surfaces. INTRODUCTION Hydrometallurgical copper leaching (heap leaching or dump leaching) has been used extensively for copper recovery from oxide and secondary-sulfide ores, but not for primary copper sulfides, which contain mainly chalcopyrite as copper minerals. Although they are major resources of copper, primary copper sulfides are difficult to process because of their refractory nature. Extensive leaching studies have been carried out to leach primary copper sulfides (chalcopyrite), including biological and chemical, using a variety of oxidants and additives to enhance copper recovery. Watling (2013) reviewed acid-chloride-oxidizing agents with chalcopyrite. Abdollahi et al. (2015) tested silver as a catalyst for bioleaching with a chalcopyrite-bearing molybdenite concentrate. Hiroyoshi, Miki, Hirajima and Tsunekawa (2000) found a specific redox-potential zone for high-speed chalcopyrite leaching by controlling the ratio of ferric and ferrous iron. However, no ambient-temperature economic process has been developed for leaching primary copper sulfide, which usually has a low copper grade.

Jan 1, 2019

By F. Cheuk, E. Krause, V. G. Papangelakis, G. A. Moldoveanu, S. Abendschein

Systematic studies have been conducted at the University of Toronto in order to evaluate lanthanide extraction from clay minerals from different geographical regions. It was found that rare earth elements (REE) are easily recovered into an aqueous solution via an ion exchange mechanism by leaching with electrolyte solutions containing monovalent cations under ambient conditions. In this study we assessed extraction levels of individual REEs as a function of initial clay composition and leaching conditions. It was found that, in spite of variations in clay origin, all clays consistently reached peak REE extraction levels with fast kinetics. However, terminal extractions were clay-specific. The feasibility of using seawater as a leaching solution and potential synergies with ammonium sulphate as a lixiviant was also investigated. Seawater was found to be inferior to using ammonium sulphate, and provided no observable synergy in leaching performance when used together. The aqueous phase trapped in leached clays was shown to contain significant amounts of REE, as demonstrated in clay washing tests. Techniques to improve the REE concentration in leachate through process variations were investigated. However, it was found that most techniques capable of increasing REE concentrations in the resultant leachate also resulted in reduced REE extraction.

Jan 1, 2014

By Chri Rule

"This paper tells the story of the rapid commercial application of stirred milling technology at Anglo American Platinum’s many Concentrators. The first stirred mill – a 10 000 litre IsaMillTM; the largest at the time, was commissioned in late 2003. The project development work was presented at SAG 2001. This operation was “proof of concept” and vindicated the decision to scale up the technology; allowing a rapid and extensive roll-out of mainstream regrind mills as well as several further flotation concentrate regrind mills, over the next six years.Currently 23 stirred mills are in operation with 64 MW of installed drive capacity – this paper describes the projects’ roll-out and the significant results achieved to date. Many operational problems have been solved along the way, some of these will be described. The introduction of the technology has seen a step change in metallurgical results and progressively decreasing operating costs."

Jan 1, 2012

Presentation Outline Introduction Deposit Characteristics Geology Grade, Value and Tonnage Estimates 2006 Advanced Program Drilling Bulk Sampling DMS Test Facility 2006 Exploration Summary

May 1, 2006

By Zhanyou Huang

The logic and capabilities of a short-term planning tool are presented. It was developed using mixed integer linear programming (MILP) techniques to solve the open-pit and underground mine planning problems that include multiple mining areas, multiple processes, multiple destinations and blending requirements. It finds the optimum schedule that achieves the objective while satisfying comprehensive product quality and quantity requirements, equipment utilizations, as well as physical and technical constraints. A case study is given to demonstrate its applications.

Oct 1, 2009

By Zhanyou Huang

The logic and capabilities of a short-term planning tool are presented. It was developed using mixed integer linear programming (MILP) techniques to solve the open-pit and underground mine planning problems that include multiple mining areas, multiple processes, multiple destinations and blending requirements. It finds the optimum schedule that achieves the objective while satisfying comprehensive product quality and quantity requirements, equipment utilizations, as well as physical and technical constraints. A case study is given to demonstrate its applications.

Oct 1, 2009

Some Statistics ? Feasibilitystudiescostbetween2% & 3% of capital andrequire8% to15% of total engineering effort ? Feasibilitystudiesusuallytakebetween8 and16 months ? Historically more than80% of projects fail to achieve all their objectives, usually blame the feasibility study ? What is bankable? Means that your promises will long be remembered. ? Poorly executed feasibility studies ? Driven by inexperience, unrealistic expectations, time constraints, financial constraints, lack of objectivity, front end loading activities incomplete or poorly done ? lack of minimum standard to provide a consistent approach Trend to improve???

May 1, 2010

By M. Moats

World copper refining tankhouse practices have been surveyed. This survey is a supplement to previous surveys that have been carried out in the 1987, 1991, 1995, 1999, 2001 and 2003. On a world basis, process technology trends include the further installation of automated electrode handling systems including permanent cathode systems, automatic anode preparation and cathode handling machines, section switches, fully automatic cranes and polymer concrete cells. General plant process control has increased with more automation of material handling in the copper refining tankhouse. The general trend for most greenfield copper refining projects remains in eastern Asia.

Jan 1, 2007

By Kai Bartram

The successful application of color sorting machines has established sensor-based sorting in the mineral industry in recent years and is considered today as a significant innovation in processing technology. However, we are only at the beginning of (market) introduction. New sensor systems have been developed, which exploit material properties such as electrical conductivity, magnetization, molecular structure, thermal conductivity etc. This opens up new exciting preconcentration and upgrading possibilities for many applications such as nickel, gold, copper and other ores as well as for industrial minerals, diamonds and other gem stones.

May 1, 2009

By I. H. Redeker

North Carolina is the leading state in the USA in feldspar, mica, and spodumene production. Mixed feldspar, spodumene, mica and quartz are mined from hard rock, open pit deposits and recovered by flotation from the fresh pegmatite type ores. Potash feldspar, mica, clay and quartz are recovered from weathered decomposed pegmatites. The North Carolina State University has a Minerals Research Laboratory in Asheville with trained personnel and flexible pilot plant equipment. The flowsheets for the feldspar, spodumene and mica producing companies and for large phosphate and glass sand flotation plants were developed and tested in Asheville. Examples and problems of pegmatite flotation are demonstrated with flowsheets and slides.

Jan 1, 1981

By Paul Johnston

or is it? Mining Automated Loader Technology Application ? Intelligent software mounted in hardware on a remotely controlled scoop. ? Led by INCO, Sudbury, with ? C-CORE, St. John?s ? Automated Mining Systems, Aurora ? Bell Canada, Sudbury ? Laurentian University, Sudbury ? University of Western Ontario, London Completed: March 2000

May 1, 2008

By R. Farhat

Coating systems that yield a thermally grown oxide (TGO) protective layer have been proposed as a potential method for extending the lifecycle of components exposed to high temperature corrosion. This is particularly relevant to the petrochemical industry, where any reduction in corrosion rates can yield substantial cost reductions. The primary goal of this project is to develop a coating repair procedure and to investigate the oxidation performance of the repaired location. Electrospark deposition (ESD) was used to repair spalled segments of TGO grown on MCrA1Y substrates using various electrodes possessing mixed crystal structures. Specifically, electrodes of NiCoCrA1Y (BCC-FCC mixtures) and CoNiCrA1Y (FCCBCC mixtures), were deposited and oxidized to develop the TGO using a heat treatment of 24 hours at 1000°C in air. This presentation will focus on the microstructural evolution of the base metal and ESD repair on damaged area, in both as- deposited and oxidized forms. Results of SEM and XRD analysis will be presented.

Jan 1, 2011

By Robert S. G. Chapman, Kieran M. J. Downes

The Sulphide-Preview Lakes area is located 45 km northeast of La Ronge in northern Saskatchewan. It lies within the southern portion of the Proterozoic La Ronge Volcanic-Sedimentary Belt. Two styles of gold mineralization are present in the Sulphide Lake area , stratabound gold mineralization is intimately associated with a pyrite-pyrrhotite-arsenopyrite-bearing graphitic argillite unit within a sequence of intermediate to felsic volcaniclastics. Past operators established three mineralized zones along this horizon with combined reserves for two of the zones, of about 175,000 tons at 0.22 oz/ton Au. In the Preview Lake area , gold mineralization occurs in variably sheared gabbro/quartz diorite sills within a mixed sedimentary-felsic volcaniclastic sequence. Gold occurs with arsenopyrite, pyrite and minor chalcopyrite associated with quartz veins and stringers. A sulphidebearing graphitic argillite unit occurs in close proximity to the mineralized shears. Past operators delineated seven mineralized shear zones, two of which were drilltested. Average gold grades reported are in the 0.1 to 0.2 oz/ton range with erratic values up to 5.0 oz/ton.

Jan 1, 1986

By M. Eikerling

The full competition between mass transport and reaction in PEMFC unfolds in cathode catalyst layers (CCLs). Recently developed models provide vital insights into effects of thickness and composition on effectiveness of catalyst utilization and performance. However, the CCL's key function in liquid water removal is rather unexplored. Studies of water balance in PEMFCs focus mostly on other cell components. Notwithstanding this prioritization, a simple calculation shows that the CCL is the PEMFC's favourite medium for conversion of liquid water into vapor. Porous structure and wetting properties steer the interplay of evaporation, transport and reaction. A model will be presented, that links pore space morphology, composition, distributed properties (concentrations, pressures, reaction rates, potential) with global performance (critical phenomena). It reveals how problems of flooding in the fuel cell could be mitigated by properly adjusting catalyst layer structure and operation conditions and under which conditions all liquid water arriving in the CCL would leave it as water vapour through the CCL/GDL interface. Results for a simple variant of the model emphasize the role of the CCL as a watershed for the whole cell.

Jan 1, 2005

By Nirmal Weerasekara, Jochen Franke, Malcolm Powell, John Favier

Mill liners serve the dual purpose of protecting the shell from wear and transferring the rotary motion of the mill to an effective grinding action. As the liners wear, the efficiency of energy transfer changes, so there is balance between liner profile for wear and for milling efficiency. A tool that can simultaneously predict the evolution of the liner profile and the associated change in milling efficiency should prove most useful in optimal liner design. This paper presents such an approach, based on measured 3D liner profile data informing 3D DEM simulations of charge motion and liner wear modelling.

Jan 1, 2012

By J. W. Stickney

"On July 1, 1977 Hudson Bay Mining and Smelting Company Limited announced the commencement of construction of a 3800 ton per day concentrator at Snow Lake, Manitoba. Snow Lake, a community of 2200 people, is located 130 road miles from the main metallurgical plants at Flin Flon.The design, detailed engineering and equipment selection for the project was awarded to Wright Engineers Limited of Vancouver, B.C., who would be working in close liason with Hudson Bay Mining personnel throughout the project.The feasibility of constructing a metallurgical plant in the Snow Lake area, in addition to the concentrator at Flin Flon, had been under study since 1964 with plants of varying capacities and designs being considered. Each successive study recommended a plant of increased capacity and sophistication and finally upon an in-depth study in 1976 of ore reserves, freight rates and operational benefits, the construction of a 3800 ton per day copper-lead-zinc concentrator appeared highly benificial."

Jan 1, 1981

By H. Stillman

The International Copper Association, Ltd. (ICA) is responsible for guiding strategy and policy, and funding international initiatives that help deliver the benefits of copper around the world. ICA's technology initiative supports this mission by funding pre-competitive technology development and accelerating the commercialization of new copper-related technologies. The R&D portfolio includes some projects that defend existing applications such as plumbing tube and data cabling, but the majority of projects are designed to enable new applications for copper. The current technology portfolio is focused on leveraging copper's unique electrical, thermal, mechanical and antimicrobial properties to define and expand the role of copper in areas poised for future technological growth: reducing disease transmission, sustainable energy generation, reducing the environmental impact of production processes, and in increasing energy efficiency. Projects related to these areas are conducted at qualified external organizations including universities, early-stage firms, and large OEMs worldwide. This talk will provide an overview of ICA's technology initiative's principles, projects and partnerships to stimulate the audience to think about copper-related innovations.

Jan 1, 2007

By M. C. Bluteau, G. P. Demopoulos

Arsenic reports in the effluents of many non-ferrous metallurgical operations. The production of scorodite, a crystalline ferric arsenate, is considered as an attractive option for the fixation of arsenic from aqueous effluents. However, scorodite solubility and long-term stability in the pH region of interest for tailings disposal have not been thoroughly investigated. In this study the long-term stability of scorodite in the pH 5 to 9 region and the mechanism of scorodite dissolution were studied. Construction of eh-pH diagrams indicated that scorodite stability is highly dependant on the nature (stability) of co-existing iron-hydroxide/oxyhydroxide. It was also found that when scorodite dissolves, a ferrihydrite phase having very small particles size (nano-scale) forms and that the growth and crystallization of this material are delayed by the presence of arsenate even under accelerated (75°C) ageing conditions. Around neutral pH and ambiant temperature (22°C) scorodite seems to reach an equilibrium with ferrihydrite after 48 weeks yielding soluble arsenic concentrations < 5 ppm.

Jan 1, 2004

By James R. Yeager, Eric L. Hoffman, John R. Clark

"Abstract -This paper describes fire assaying and ‘high tech’ alternatives for gold analysis, including advantages and disadvantages of each method. These ‘high tech’ methods include INAA (instrumental neutron activation), aqua regia digestion/AA (atomic absorption), GFAA (graphite furnaceatomic absorption) or ICP/MS (inductively coupled plasma emission mass spectrometry) and a combination of cyanidation with AA, GFAA or ICP/MS methods.Fire assay remains the stalwart among analytical methods for gold but, even with its multiple analytical finishes, is not fool-proof for recovering 100% of the gold present. Consumers of assays should not blindly trust the assay results without consideration of quality control data. Laboratories can and do make mistakes. Some of these can be easily discovered if you do your own due diligence. All these measures should ensure that gold analysis values from successive campaigns and from different laboratories meet acceptable levels of accuracy and precision, and can be correlated together, particularly when they occur in neighboring holes. This is essential just as much for prospect evaluation as for project feasibility."

Jan 1, 1998

By K. L. Eastwood

The ISA PROCESSTM cathode plate is characterised by its copper coated suspension bar, coupled with a blade employing austenitic stainless steel alloy 316L. The blade material has become the mainstay of the technology and has been closely copied by competing cathode designs. Improvement to the cathode plate design remains a key area for research, and ongoing developments by Xstrata Technology&apos;s ISA PROCESSTM have recently been commercialised. Two such developments are the ISA Cathode BRTM and ISA 2000 AB Cathode. The ISA BR cathode is a lower resistance cathode that has proven to enhance operating efficiencies. The AB cathode was designed to improve stripping inefficiencies in the ISA 2000 technology. These developments have now had time to mature and their long term performance will be discussed. Rising material costs and the desire to extend the operating boundaries of the standard 316L cathode plate has triggered a number of significant advances. These involve the use of different stainless steels as alternatives in some operational situations. The technical aspects and results of commercial trials on this development will also be discussed in this paper.

Jan 1, 2007