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By O. Laitinen, M. Rudolph, J. A. Sirviö, H. Liimatainen, R. Hartmann, University of Oulu

The increasing complexity of the ores composition worldwide calls for suitable collectors with specific properties, such as selectivity, wettability, and in regard to current regulations, environmental sustainability. Therefore, collectors have to satisfy many features to improve the efficiency of flotation processes. Cellulose nanocrystals gain more and more interest due to the versatile synthesis routes which enable the integration of specific functional groups and components with different degrees of hydrophobicity within the molecular structure. Consequently, cellulose nanocrystals can be employed in flotation processes as depressant or collector molecules, respectively. Nonetheless, the usage of cellulose nanocrystals is still limited due to a lack of the characterization of nanocrystal-mineral interactions and the change of the surface wetting properties of minerals after adsorption phenomena between nanocrystals and minerals. In these studies, butyl-amine cellulose nanocrystal (BAC) and quartz are used as model system to investigate physicochemical properties of both, BAC and quartz, and examine the applicability of BAC in flotation processes. Therefore, the surface charge distribution and electrophoretic mobility of BAC and quartz are investigated and compared to understand the effect of electrostatic interactions between BACs, and BAC and quartz. Based on this, the adsorption of BAC on quartz is examined. Finally, microflotation experiments test the efficiency of BAC to be used in flotation processes. The flotation response is correlated to the specific surface charge of BAC revealing the dominant effect of surface charges on effective particle-bubble adhesions.

Jan 1, 2016

By Kwang-Hyun Jeon

Recently, 3D printing technology in the manufacturing field is in the spotlight. In the construction industry, similar rapid prototyping technology that does not use conventional form can be applied to meet the demand on free formed structure that can provide aesthetic value and functionality. Conventional formwork can increase construction cost and period for various structure with complex shapes while it has numerous advantages such as high strength, convenience, accuracy and good quality of surface roughness. To meet the demand on free formed structure, automated freeform construction systems such as Contour Crafting and Concrete Printing have been developed with active collaboration between university and industry in USA and England. However, details on the system have not been fully released in public, so the possibility of its fusion and spin-off technology cannot be expected. In this paper, cost-effective solution for mechanical and control system for constructing a free curved structure without mold are described. As an appropriate material for the system, fiber reinforced mortar was selected by experiments on compressive strength, setting time and fluidity. After performing G-code simulation, transfer and extrusion experiments with the selected mortar mix were performed and the possibility of the development of automated freeform construction system was demonstrated. Based on this research results, it is required to keep the automated freeform construction system improve and extend it into the new application area in construction industry.

Aug 1, 2013

By Karim Ramji

The extractive sector today faces growing social, legal and political risks (SLPs) from so many different stakeholders including national and local governments, name and shame groups, civil society and environmental groups, and the ?Occupy? movement. Beyond these stakeholders, there are the indigenous peoples who have growing legal, social, political and economic influence which can often determine the outcome of the Project. The development curve in the extractive sector from initial exploration to mine start-up has become longer, steeper and more risky and expensive as these SLPs have grown in scope and complexity. Even if a project is permitted or starts commercial production, its ongoing development and operations are also facing these SLPs. The continuous assessment of these SLPs and the strategy to mitigate for them has now become critical for every project in the extractive sector. A project will only be successful if it is able to obtain the legal permits to operate, then withstand any judicial reviews, and then also to be able to gain and maintain the Social License to Operate (SLO). Stakeholder identification, management and engagement are key risk-mitigation tools. This paper focuses on the growing influence that indigenous peoples are now enjoying and the impacts on the extractive sector. Indigenous peoples are a unique stakeholder group because their legal rights and interests to lands and resources, their aboriginal title and rights, are gaining more recognition. When indigenous peoples form alliances with other stakeholders, this simply adds to their growing momentum and leverage, and this can become a daunting challenge for the extractive sector. More due diligence is required by companies to understand and assess the challenges posed by operating in areas claimed by indigenous peoples. There is a real need for mining companies to develop an effective indigenous engagement strategy to address these challenges in order to successfully convert risks into opportunities. Early identification and engagement with the indigenous peoples is required and the goal should be to conclude an Impact Benefits Agreement (IBA) with the affected indigenous peoples. The real objective must be to develop a real and transparent relationship between the company and the indigenous peoples so as to gain and maintain the SLO.

Aug 1, 2013

By Erica J. Wanless, Ghislain Bournival, Seher Ata, Jose Hamilton Tavares

In froth flotation valuable particles are captured by bubbles and transferred to a froth layer where bubbles are in close proximity. Bubble coalescence frequently occurs in flotation, especially in the froth layer. The coalescence of two bubbles causes a release of energy, which may expel particles from the bubble surface. A series of experiments were carried out to determine the effect of bubble interfacial properties on the detachment of particles upon the coalescence of capillary-held bubbles of 2 mm in size. The interfacial properties of the bubbles were changed by the addition of low molecular weight alcohols, namely 1-pentanol or methyl isobutyl carbinol (MIBC). Using esterified glass particles (? = 43 °) with a 10 % and 90 % cumulative passing diameter of 47.2 and 92.5 µm, respectively, as model particles, it was found a certain concentration of frother, different for each additive, is needed in order to observe a reduction in the detachment of particles. In the presence of frother, the detachment was evaluated at approximately 65 % which was a considerable reduction in the detachment compared with the value of approximately 85 % found in the absence of frother. Frother molecules changed the properties of the airwater interface. Upon the coalescence of two bubbles, the release of energy caused the merged bubble to oscillate; effectively resulting in the detachment of particles. The addition of frothing agents augmented the elasticity of the bubbles, which appeared to be related to the detachment of particles. Whereas frothing agents are generally used to prevent bubble coalescence and stabilise the froth phase, only transient stability is imparted. The results suggested that an additional role of frothers in flotation is to decrease the detachment of particles from bubble surfaces. The type and concentration of frother can be strategically selected to improve metallurgical recovery as an economic incentive.

Jan 1, 2016

By Jan Rosenkranz, Anders Sand, Lisa Malm, Nils-Johan Bolin

Within flotation technology the general trend is towards very large cells. Scale-up is usually done by postulating geometrical similarity, which implies keeping the aspect ratio constant when increasing cell volume. Consequently, the design of flotation circuits typically involves several cells of identical geometry within a bank. Using a few standard sizes in a flotation plant simplifies design, manufacturing and maintenance of the cells, but does not necessarily guarantee optimal performance and selectivity of the flotation process. Geometry parameters for a given cell volume that influence flotation cell performance include cell height, which causes changes in the hydrostatic pressure and suspension hydrodynamics, and also influences the travel distance of particle-bubble agglomerates as well as the homogeneity of the mixing. Also the thickness of the froth layer depends on the aspect ratio of the cell. The objective of this work is to gain a better understanding of material distribution and properties within a flotation cell and, based on this information, elucidate how alterations of the cell geometry can influence separation efficiency. For this purpose systematic measurements and analyses of the spatial distribution of the different phases within a 160 m3 flotation cell have been carried out with a particular focus on an industrial, low-grade copper ore beneficiation process. The concepts for sampling at different vertical and lateral positions of the flotation cell are introduced. The results from the experimental work give an understanding of internal material distribution within flotation cells. Based on the measured phase distribution and concentrations as well as particle properties at various positions within the cell, the implications for an optimized scaling and design of individual flotation cells within a flotation circuit are discussed.

Jan 1, 2016

By David Penswick

Despite anecdotal evidence to the contrary, the mining industry is not in decline. Rather, the world?s largest mining companies are among the most consistently profitable companies in any industry. In many cases, profitable mining companies have been built around a few large scale, long life mines. These criteria for success ? size and long life ? have led to the current preference for deposits that can be exploited using open pit methods. However, developments in the science of block caving have resulted in this mining method achieving costs and productivities that are competitive with the largest open pits, while achieving widespread applicability. One implication of the low costs and widespread applicability of block caving is that some current open pits are possibly too deep.

May 1, 2003

By Bonnie Cooper

3D printing by fused deposition can be used on lunar soil. The soil can be precisely size-separated to make the 3D printing process work efficiently. Using a MASER instead of a LASER would allow us to use the finest fraction of lunar soil, AS-IS, to manufacture things on the Moon.

May 1, 2013

By A. F. Robertson

FOR several years, the rock-burst question has been given serious consideration by the operating staff at Wright-Hargreaves mine and, as a result of observations and experiences, several different methods of mining have been developed which are now in use in various parts of the mine. These are described in the following pages. It should be emphasized, how-ever, that these methods, and the views expressed in this paper, are based solely on conditions at Wright-Hargreaves mine. Such conditions may or may not be similar to those obtaining in other mines in the Kirkland Lake area, where ore occurrences, veins, wall-rock, faulting, intrusives, etc., may be entirely different. Size and shape of ore-bodies, composition of the ore-bodies and their surrounding rocks, locations of intrusives and sedimentary rocks, and direction, dip, and strength of faults, all introduce problems that are peculiar to each individual mine. Ground failure' in coal and metal mines is not at all unusual. A variety of systems of mining have been developed to delay movement of large or small blocks of ground, or, in some instances, to take advantage of the fact that ground movement, due to mining operations, is unavoidable. Ground failure may be either slow collapse or it may take place with explosive violence. It is principally with the latter condition that we are concerned in the mines of the Kirkland Lake district.

Jan 1, 1939

By P. Latostenmaa, T. Veneranta, J. Järvi, E. J. Peuraniemi

Boliden Harjavalta has operated a copper flash smelter since 1949 thus the smelter celebrates 70th anniversary of flash smelting in 2019. This paper shortly describes the historical perspective of the smelter and gives an update of the current operational issues and process modifications made during the recent years. The plant has carried out several major investments lately providing a firm view on the future. A new landfill area for the final slag was commissioned in 2018. A modernization of the concentrate storage area, a new acid plant and a debottlenecking project of the smelting line have been recently commissioned. At the same time, the tankhouse capacity will be expanded. This paper focuses on smelter modernizations. INTRODUCTION Boliden is a metal company operating mainly in northern Europe with core competencies in the fields of exploration, mining, smelting and metal recycling. Boliden Harjavalta, located in Finland, is part of the Smelters Business area of the Boliden Group and operates a copper and nickel smelter with related sulphuric acid plant in Harjavalta, and a copper refinery in Pori. As a short historical review, Harjavalta’s history may be dated back to the year 1910 when the Outokumpu ore body in eastern Finland was discovered. By the end of 1913, a copper mine was in operation and a copper plant based on Hybinette process was ready for commissioning. Due to difficulties in metal recoveries and throughput the Hybinette process was permanently shut down in 1929, and 100% of the mining production was sold as concentrate abroad. As the mine production increased steadily, a decision of a new smelter was made in early 30’s. In 1936 Outokumpu’s copper smelter based on electric smelting was commissioned in Imatra. The smelter was dismantled and transferred to Harjavalta during the final stages of the Second World War. The copper refinery started in Pori already in 1941 and the first copper anodes were cast in Harjavalta in 1945. First sulphuric acid plant started operation in 1947. Due to the post-war shortage of electrical energy, the plant metallurgists initiated a major development work to start exploiting the latent heat of concentrates. Thus, the flash smelting method was developed in Harjavalta and commissioned in 1949. Ten years later, flash smelting was also applied for nickel concentrates. Table 1 summarizes major historical and technical milestones of Harjavalta. The history of flash smelting is described in details in another paper of this conference (Jåfs et al., 2019).

Jan 1, 2019

By M. Mirnezami, J. A. Finch

The McGill component of the consortium contributed detailed examination of the electrokinetic properties of the constituent minerals, primarily pentlandite and serpentine. Mineral specimens were derived from an ore sample; mineralogical examination showed the serpentine was predominantly clinochrysotile, a fibrous mineral responsible for much of the flotation separation problem. The study included design of a novel sedimentation potential measuring device to classify the surface charge of the ore and electrophoresis measurements on single and mixed minerals which progressively approached flotation conditions. The sedimentation potential measurements provided a general association between surface charge and the visual state of aggregation as a function of pH. The electrophoresis experiments started with single minerals in a background of indifferent electrolyte and progressed to mixed minerals in a background of supernatant derived from an ore sample. The single mineral tests supported the suspected electrostatic interaction, i.e., hetero-coagulation, at flotation pH 9-10. The mixed mineral tests demonstrated this interaction and also revealed hetero-coagulation with Mg(OH)2 precipitates, derived from the supernatant. This interpretation was confirmed by optical and electron beam imaging. A series of agents, CMC, polyphosphate, soda ash, EDTA, were examined to disperse the system. To accommodate the small mass of single mineral available a novel turbidity measurement using a UV/Vis spectrophotometer was introduced. Selected conditions were used in contact angle and small-scale flotation tests.

Jan 1, 2011

By J. E. Gill, A. R. Byers

The Surf and Pugsley gold-copper mines; owned and operated by Surf Inlet Consolidated Gold Mines; Limited; are about 6 miles inland from; the head of Surf inlet; on Princess Royal island; Skeena mining division; British Columbia. Surf inlet is a fiord 360 miles in an air line northwest of; Vancouver.

Jan 1, 1954

By BARRY BANNATYNE

Non-swelling bentonite has been quarried in Manitoba by Pembina Mountain Clays Limited since 1941. It occurs in several thin layers near the base of the Pembina Member of the Upper Cretaceous Vermilion River Formation, and is quarried from the narrow outcrop belt along the slope of the Manitoba Escarpment. It is marketed both as natural and activated bentonite for a variety of specialized uses. Percolation of acidic water through bentonite has produced a naturally activated bentonite with good absorbent properties; these properties are enhanced by treatment with sulphuric acid to produce an activated bentonitefor decolourizing petroleum and vegetable oil.

Jan 1, 1984

By George B. Saunders

The mines in western Canada producing steam coal will find a better opportunity this year to market their product in Winnipeg - for two reasons: First, the new wage schedules, signed with local unions at each mine, have enabled them to reduce the selling price materially. Second, the duty on slack coal coming in from the United States has been raised to 50 cents, which is equal to the duty on run-of-mine coal. This has had the effect of raising the cost of mine-run to .the importer. Formerly, it was the practice to bring in slack coal under a duty of 14 cents and lump coal under a 53-cent duty and, by judicious mixing of the two, manufacture a mine-run coal at an average duty cost of about 22 cents. Fortunately, through efforts of the Alberta Government, and other friends of the Canadian coal trade, the Federal Government was persuaded to adjust the duty on slack coal as indicated. While it will be found that the Manitoba market, this season, is slightly more easy of access we have still a long way to go before we reach the desired goal. Geographically and economically the Manitoba market should belong to western Canada. However, it has been found a very profitable market for United States mines because large tonnages of coal can be shipped, practically at the convenience of the mines, via the Great Lakes, during seasons of slack business. They will therefore not relinquish this market without a struggle.

Jan 1, 1925

By Xuanxue Mo, Zengqian Hou

"Yidun Island Arc in Sanjiang Region is one of the important Kuroko-type volcanogenic massive sulfide deposits (VMS) districts in southwestern China. Tectonically, the region is situated in the eastern portion of the Tethys orogenic belt, and is a late Triassic extensional island-arc. The island-arc underwent earlier arc construction, intra-arc rifting, later arc construction and backarc spreading during its evolution and formed a complete trench-are-basin system, i.e., the Ganzilitang suture zone, forearc basin, outer are, intra-arc rifting zone, inner arc and back-arc basin from east to west across the island-arc.Kuroko-type VMS deposits and occurrences discovered so far are limited to within the intra-arc rifting zone of the Yidun Island Arc and tend to occur in groups or clusters distributed in separate faultbound basins; e.g., Zengke, Gacun and Xiangcheng basins, in which submarine volcanic rocks, especially bimodal volcanic suites, were extensively developed. The VMS deposits formed in the waning stages of volcanic eruption in the late Triassic and are hosted in the uppermost section of acidic volcanic rocks (rhyolitic-dacitic) within a bimodal suite. The orebodies are associated with these host rocks: rhyolitic-dacitic pyroclastic rocks and exhalites and chemical sedimentary rocks.All VMS deposits in Sanjiang are of the Zn-Pb-Cu type. The architecture of the deposits is twofold, consisting of concordant lenses and layers of massive sulfides and an underlying discordant stockwork. All deposits show metal zoning. The hydrothermal alteration related to mineralization is strong and asymmetrical, and is found dominantly within the stockwork zone and host rocks surrounding the ores. There are two alteration patterns: (1) chloritization - sericitization - silicification from outer sides to core of the alteration pipe; and (2) silicification + sericitization - silicification + carbonate from the lower to upper part of the alteration pipe.The mineralization temperatures of ore-forming fluids vary in the range 200°C to 335°C. Thermal evolution of the fluids displays temperature profiles that first increase and then decrease with progression of mineralization processes. The majority of black-ore minerals (Groups I and informed during intensifying stages of hydrothermal activity, and the majority of semi-yellow-ore minerals (Group III) formed during a thermal maximum. There followed the formation of fine-grained black-ore minerals (Group IV), which interacted with barite layers during decreasing temperature phases.Oxygen and hydrogen isotope studies show that the sources of ore-forming fluids for the Kurokotype VMS deposits are two-fold: seawater and magmatic hydrothermal solutions, represented by the Kuroko deposits in Japan and Kuroko-type VMS deposits in Sanjiang, respectively. In the latter case the hydrothermal solutions reacted with host rocks and mixed with cold seawater percolating downward, and circulated through volcanic rocks resulting in development of alteration zones and formation of ore minerals in Kuroko-type VMS deposits."

Jan 1, 1993

By D. Mark Richards

Highland Valley Copper is a large open pit copper mine in the southern interior of British Columbia. Machine guidance technology using the Global Positioning System (GPS), was first implemented at the mine in late 1996 for blast hole drill navigation. The purchase of a third BE49R drill in 1998 completed the change to GPS navigation for all the mine?s drilling. The acceptance of this technology was almost immediate at both the operator and management levels. With the purchase of a new P&H 2800 shovel in 1997, the opportunity was taken to extend GPS navigation to a shovel. Due to communication restrictions, this was not as successful as envisaged. In late 1999, following a cost benefit analysis, a three-shovel trial of Caterpillar?s Computer Aided Earthmoving System (CAES), was initiated. The trial was successfully concluded in June 2000 and a further two shovels were equipped. Acceptance of this system has been very good at all levels, which has undoubtedly contributed to its success. In September 2000, CAES was extended to the dozer fleet with the purchase of a new track dozer. The CAES equipped dozer is used for pit production and project work. It is planned to extend CAES to the rest of the shovel fleet in 2001, along with a production front-end loader and one or two more track dozers.

May 1, 2001

By G. Chung, W. Petruk, D. Doyle

"A series of tests was conducted on Carol Lake iron ore, which contains about 38 wt % hematite and 19 wt % magnetite, to establish a flowsheet for high weight yield by spirals. A pilot plant was run in parallel with the IOC concentrator to simultaneously test two flowsheets on the same feed material. The IOC concentrator processes the ore by treating it directly in a spiral circuit, whereas the pilot plant used a laconite flowsheet which had a low intensity magnetic separator (LIMS) at the front of the circuit. The LIMS produced a non-magnetic (hematite-rich) product and a magnetic (magnetite-rich) product prior to treating the ore in two separate spiral circuits. The results from about 150 tests were evaluated by chemical assays and materials balancing techniques, and a selected test was evaluated by the image analysis and materials balancing technique.The image analysis and materials balancing evaluation showed that a higher hematite recovery was obtained by the hematite spiral circuit than by the IOC concentrator spiral circuit, and a slightly lower magnetite recovery by the magnetite spiral circuit than by the IOC concentrator spiral circuit. Furthermore the hematite recovery by hematite spirals was higher than the magnetite recovery by magnetite spirals. The better hematite recovery was achieved because a higher liberation is obtained for hematite than for magnetite, and the hematite in the Carol Lake ore has a narrower grain size range than magnetite. Consequently, better spiral control can be maintained when processing a hematite-rich spiral feed, than when processing a magnetite-rich spiral feed. Since the feed to the IOC concentrator spiral is a mixture of hematite and magnetite, an intermediate hematite recovery is obtained by the IOC concentrator. INTRODUCTIONA study of characteristics that affect recoveries of hematite and magnetite from the Carol Lake ores of the Iron Ore Company of Canada (IOC), was carried out in connection with a project on designing a flowsheet for maximum weight yields. A pilot plant using a taconite flowsheet was run in parallel with the existing IOC concentrator which uses a classical iron ore flowsheet. About 150 tests were run to compare iron recoveries and weight yields by the spirals in the two flowsheets. Better iron recoveries were indicated for the taconite flowsheet, but the results were not consistent and the reasons for the observed differences were not apparent. The material from one test (Test 61), which gave better iron recoveries for the taconite flowsheet, was evaluated by the image analysis and materials balancing technique. A suite of samples was taken from 5 points in the IOC concentrator and from 8 points in a pilot plant (taconite flowsheet). The samples were analyzed to compare the behaviours of the Carol Lake hematite and magnetite in the spirals of the two flowsheets. The results provided a sound basis for further tests in designing a high weight yield flow sheet."

Jan 1, 1993

By Charles W. Villiers

AS is well known, there are large and valuable deposits of coal in British Columbia, both on the mainland and on Vancouver island. These deposits are widely distributed over the Province. The chief sources of supply on the mainland are found in the Fernie and Princeton-Nicola districts and on Vancouver island in the Comox and Nanaimo districts. The coals range from a very high quality bituminous coal to lignite. On the Upper Skeena river there is said to be a very large deposit of anthracite or semi-anthracite, but this field has not been developed. Coal was first discovered in British Columbia on the north end of Vancouver island in the year 1835, but it was not until 1852 that coal mining was seriously undertaken by the Hudson's Bay Company at Nanaimo, where mining has been carried on continuously ever since that date. The production of coal in the Province continued to increase until the year 1910, when the annual output reached its peak at 3,100,000 tons and a total of 7,800 men were employed in the industry. Since 1910, the production has dropped steadily until, in 1934, only 1,347,000 tons of coal were produced and less than 3,000 men were employed. This continued decrease in production has in no way been caused by lack of coal reserves. It has been due entirely to curtailment of markets. I do not propose to discuss coal mining practice in British Columbia, where we have all sorts of mining conditions, including submarine mining. There is no lack of coal supplies for either industrial or domestic purposes, nor is there likely to be any shortage of coal in the Province for many generations. We have our mining troubles, which increase the cost of production, but there are no insuperable difficulties to prevent the extraction of a large and increasing supply of coal. Our main difficulty-in fact our only serious difficulty-is to find a market for our output, and we must consider means which can be evolved not only to conserve our existing markets but also to expand them, at any rate within the boundaries of Canada. I will therefore confine my remarks chiefly to the all-important factor of Markets for our coal.

Jan 1, 1936

By I. Kylmakorpi

In non-ferrous metal smelting, when the concentrate entering the furnace contains high levels of moisture, energy requirement for heating and drying increases and large volumes of exhaust are produced. To solve this problem, rotary dryers and flash dryers using direct heating, and also steam dryers using indirect heating have all been used for drying concentrate. The focus of this paper is to present the development and current applications of the Kumera Rotary steam dryer. The advantages of this technology are numerous, including reduced heating requirements, environmental friendliness, operation reliability and minimum maintenance needs; making it a top choice for drying concentrate.

Jan 1, 2008

By J. P. Sims

Abstract - Ultramafic to mafic igneous intrusions of the Las Aguilas district form part of a belt of generally mafic plutonic bodies within medium- and high-grade early Paleozoic metamorphic rocks in the southern Sierras Pampeanas region, Province of San Luis. The intrusions host the largest known nickel sulfide resource in Argentina and contain significant Cu, Co and PGE mineralization (2.2 Mt at 0.5% Ni, 0.5% Cu, 0.035% Co). Sulfides at Las Aguilas Este, one of two principal mineralized zones, are hosted by a body comprising subvertically dipping units of predominantly orthopyroxenite and melanorite cumulate, with lesser dunite, harzburgite, norite, leuconorite, and amphibolite. The units are zoned horizontally from ultramafic to mafic compositions, representing primary magmatic zonation away from an original base or side of the intrusion. Intercumulus nettextured and disseminated aggregates of pyrrhotite-chalcopyrite-pentlandite are concentrated in the peridotitic zones and extend into melanorite. Whole rock major and trace element compositions, and olivine chemistry, indicate that the parent magma was gabbroic/basaltic with 100 (Mg/Mg+Fe) near 59, and resembles tholeiitic magmas generated in subduction-related arc, or back-arc settings. Unusually aluminous Cr-bearing spinel is compositionally similar to those in some synorogenic mafic/ultramafic plutons in magmatic arc settings. Relatively Ni-depleted olivines and low Cu/Pd ratios are indicative of magmatic sulfide segregation early in the crystallization of the magma. Early orthopyroxene saturation and virtual lack of clinopyroxene, in conjunction with sulfur isotope values up to +6.6 ‰, spinel compositions, and presence of graphite, phlogopite and magmatic hornblende, all attest to probable crustal contamination of the parent magma. Assimilation of crustal sulfur may have been crucial in the early attainment of sulfide saturation and resultant formation of magmatic Ni-Cu sulfide mineralization. Fabrics, textures and mineralogy of the intrusions and country rocks and U-Pb zircon dating indicate syntectonic-synmetamorphic emplacement at 478±6 Ma during the Famatinian (Ordovician) orogeny. Minor to locally significant recrystallization and deformation of mafic-ultramafic rocks and redistribution of sulfides and PGE occurred during and following the Famatinian orogeny. The Las Aguilas intrusion is one of several tholeiitic mafic-ultramafic intrusive complexes within an Ordovician arc - back-arc system in the Sierras Pampeanas. Aeromagnetic datasets and regional mapping suggest there is further potential for intrusion-hosted Ni-Cu mineralization along this eroded magmatic arc.

Jan 1, 1999

By So-Yeong Lee, Moosang Lee, Seung Hwan Ahn, Ho-Sang Sohn, Jongshin Chang

It is necessary to understand the characteristics, phase changes and chemical reactions of flue dusts introduced from a furnace to an off-gas line in order to achieve the stable operation and the improvement. This study is to develop the dust reaction model for chemical reactions of dusts in an uptake shaft of smelting furnace and a waste heat boiler. Phase equilibria and reaction paths in this system were determined by thermodynamic calculation with experimental and industrial data. The oxidation reaction rate of dusts was determined by the gas film mass transfer controlling. And the sulfation reaction rate was evaluated by the unreacted shrinking core model. Kinetic parameters were estimated by reference data including industrial ones. The present study with the developed model shows various effects of temperatures, dust particle sizes, and O2 gas partial pressures on dust reactions. INTRODUCTION The flue dusts from a copper smelting furnace move along a furnace off-gas stream into an uptake shaft and a waste heat boiler (WHB) and electrostatic precipitator(s). It is necessary to control the dust quality in order to stabilize the operation because the sticking behaviors differ depending on the phase of dusts. Phase changes of dusts are caused by chemical reactions at given conditions such as temperature and partial pressure of gases. Therefore, it is required to understand the phase changes and chemical reactions of dusts in order to perform the improvement and stable operation. The present study carried out the investigation to understand their fundamental knowledge. Especially, this study was focused on the kinetics of chemical reactions of flue dusts, developed the model. In particular, the scope of development and utilization of the model was defined as the uptake shaft of the Mitsubishi S furnace and the S-WHB radiation section in the Onsan smelter. Information needed for the modeling work referred to data from these processes.

Jan 1, 2019