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By C. Gu

Flow field design is critical for PEM fuel cells. The flow field design can affect reactant distribution to the catalyst surface, water management, thermal management and current collection. Therefore, it has tremendous impacts on the fuel cell performance and durability as well as reliability and operational flexibility. In this paper, an optical method is used to study the reactant distribution in the flow field channels of two commonly used flow field designs, straight channel design and serpentine channel design. Images of the flow patterns are shown followed by discussions of the flow patterns.

Jan 1, 2005

By O. Lashkari

Swirled Enthalpy Equilibration Device (SEED) is a new patented Slurry-on-Demand, SoD, processing route. The semi-solid slug preparation is carried out by off-center swirling of aluminum melt in a metallic mould. As part of the current research program on the semi¬solid processing of aluminum alloys, the morphological evolution of 356 aluminum foundry alloy microstructure is reported here. Semi-solid slugs were prepared using two different pouring temperatures of 645°C and 695°C respectively. Morphological evolution of the semi-solid microstructure was characterized using image analysis through measuring of primary a-Al particle size, number density, aspect ratio and sphericity. The possible relationships between microstructural features and process parameters were also investigated. The current report covers the effect of pouring temperature on the morphology of primary a-Al dendrites and attempts are made to explain the differences between the predicted percentage primary a-Al phase and those of the actual values in the as-cast slugs.

Jan 1, 2004

By J. Sadaki, G. Dodbiba, S. Murakami, T. Fujita, S. Matsuo, H. Ono, K. Okaya

Printed circuit boards (PCBs) from discarded personal computer (PC) and household appliances were crushed by mechanical crushing or water explosion to remove mounted parts. More parts were stripped from PCB for PC composed of epoxy resin than from PCB for household appliance composed of phenol resin. In an attempt to raise the copper grade of PCB by removing other components, a carbonization treatment was investigated. The crushed PCB without surface-mounted parts was carbonized under a nitrogen atmosphere at 1073K. After screening, the char was classified by size into oversized pieces, undersized pieces and powder. The copper foil and glass fiber pieces were liberated and collected in undersized fraction. The copper foil was liberated easily from glass fiber by stamping treatment. On the other hand, tantalum capacitors were collected from mounted parts. The tantalum-sintered bodies were separated from molded resins by heat treatment at 723 to 773K in air atmosphere and screening of 0.5mm. Silica was removed and 70% of tantalum grade was obtained after more than 823K heating and separation.

Jan 1, 2011

By Mayumi Ito

Mineral processing of rare-earth ore from the Dong Pao deposit, Vietnam, was investigated. The ore contained bastnaesite, (REE (rare earth element)) CO3F, as the valuable mineral and barite, quartz, and fluorite as gangue. To establish a mineral processing flowchart, selective comminution, size classification, and magnetic separation were tested. Bastnaesite shows brittle properties and selective comminution was applied to improve the purity of products. The crushed products were classified by decantation, and the overflow product showed high purity of bastnaesite indicating that bastnaesite becomes fines by crushing and that selective crushing can be used to concentrate the bastnaesite. Magnetic separation for the sink product was carried out and the mag-product showed high recovery rates of bastnaesite, indicating that the combination of size classification and magnetic separation is effective.

Aug 1, 2013

By S. I. Saif

The Key Anacon deposit lies about 6 miles northeast of the Brunswick NO.6 mine of Brunswick Mining and Smelting Corporation. Geological mapping, especially in the well-exposed Nepisiguit River section, geophysical data, and information from extensive underground and some surface drilling show that the rocks at Key Anacon are similar in many aspects of stratigraphy and structure to those of the Brunswick Mine area. They include narrow beds of fine acid volcanic material interpreted to be metatuff and volcanogenic metasediments. The massive sulphide ore body at Key Anacon lies immediately above these acidic rocks, in association with other chloritic, sideritic or magnetic iron-rich metasediments. The iron formation, which is similar to that associated with other orebodies in the district, is overlain by massive andesitic material. Four phases of structural deformation have been recognized in the Key Anacon area; they are similar in intensity and style to those of the Brunswick No. 6 mine area. The orebody lies in a zone of complex isoclinal folding along the flank of a major F2 fold (Key Anacon Syncline) and in general appears to be stratiform. The ore occurs in probable F2 parasitic folds, and this suggests a complicated structural geometry superimposed on the original beds. The general similarity of the mineralization at Key Anacon, together with its occurrence with other iron-rich metasediments between a footwall of acid volcanic material and overlying andesitic rocks, is suggestive of stratigraphic time-equivalence with the Brunswick zone . If so, the metavolcanics at Key Anacon might have been derived either from a center within the main volcanic pile to the west or from a smaller local center active at the same time. Alternatively, the Key Anacon ore could have been formed during a much older volcanic cycle. The solution to this aspect of the problem is the subject of a continuing study.

Jan 1, 1978

By K. N. Subramanian, H. Kanduth

"It is well known that chalcopyrite can be dissociated into simple sulphides by heating with elemental sulphur at about 475°C:CuFeS2 + S -> CuS + FeS2Experimental work was undertaken to determine whether this ""activation"" could be used to advantage in the selective leaching of copper from chalcopyrite concentrate.A method of treating copper concentrate with molten sulphur was developed and the activated product was leached in dilute sulphuric acid using oxygen, ferric iron or manganese dioxide as the oxidant. The object was to obtain a solution suitable for electrowinning with minimal purification, but it was impossible to obtain rapid extraction of copper without simultaneously dissolving a large proportion of iron. This was attributed to the fact that some of the copper was present as a low iron-copper sulphide (idaite) and that the pyrite formed during the ""activation"" step was more easily oxidized than natural pyrite."

Jan 1, 1973

Strips of AA6111 automotive alloy were cast on a horizontal single belt strip casting simulator, Pure copper and carbon steels substrates plasma sprayed with different coatings for improving the strip surface quality, were used as chill moulds, Experimental studies revealed that a graphite coating provided the greatest benefit in achieving good surface quality. The interfacial heat fluxes during solidification of AA6111 strip were calculated by the IHCP method (Inverse Heat Conduction Problem). Temperature variations and cooling rates within the strips were then calculated through numerical simulations based on the time-dependent heat fluxes obtained by IHCP, The effects of casting parameters, including casting temperature and strip thickness, on interfacial heat fluxes, cooling rates and microstructures, were investigated, Although the maximum interfacial heat fluxes on the chill copper substrate were much higher than the results obtained from the steel substrates, the solidification times of the melts were mainly determined by strip thickness. Very fine equi-axed grains were obtained for both 1.2mm and 2.5mm thick strips thanks to the rapid extraction of heat, and effective grain refinement.

Jan 1, 2005

By M. Potesser

In the past, different furnace types have been developed for use within the copper industry, with two common anode furnace designs typically used in copper smelting plants worldwide: the tiltable reverberatory furnace (KPO) generally used for the secondary copper industry and the cylindrical or drum type anode furnace (TRO) for handling a liquid blister charge generated in primary copper production. The disadvantage of the KPO is its design related to the longer refining period, because of the low bath depth, however it provides good conditions in the melting period due to its large bath surface. On the other hand, small amounts of scrap charged into the TRO increase the melting and dissolution period, but it provides good conditions for the refining period. The newly-developed elliptical furnace concept (TRE) offers the advantages of each of these furnace types. The special design allows melting of the scrap more efficiently than in the KPO and refining the liquid copper more efficiently than the TRO. This paper shows a metallurgical comparison of the three furnace types in regard to the melting period by heat technological considerations (optimized arch design) and of the refining period done by CFD with concentration on current, recirculation and dwell time of the gas in the melt. The paper outlines the possibilities for a reduction of the tap-to-tap time and energy consumption as well as for an increase of the production capacity, which can be achieved by applying the TRE instead of the conventional furnace designs.

Jan 1, 2007

By Z. Zhang, X. -G. Chen, F. Breton, A. Arici

"The microstructure of Al-10Si-0.3Mg-0.5Mn alloy with 0.27% Zr and 0.19% V addition was quantitatively analysed and compared to the base material. The addition of Zr and V in the AlSi10Mg alloy exhibit a beneficial effect on the Si modification, resulting in the reduction of the size of eutectic Si particles on both as-cast and T6 conditions. The quantitative image analysis results show that the Zr and V addition and T6 treatment can reduce the size of the intermetallic phases. In addition, the presence of Zr and V is favour to the partial dissolution of the intermetallic phases during the T6 treatment. Different heat treatment procedures were tested to optimize treatment parameters. The mechanical properties of the alloys were evaluated using hardness measurements and tensile tests. The results show that the addition of Zr and V can remarkably improve the mechanical properties on as-cast and T6-treated conditions. The correlation between the microstructure and mechanical properties of the alloys is discussed.INTRODUCTION Al-Si-Mg foundry alloys have been widely used in automotive and aerospace industries due to their high strength-to-weight ratio, heat-treatable capability and excellent castability. The alloying elements such as Cu, Mn, Fe are traditionally added into Al-Si-Mg alloys to improve their mechanical properties (Mohamed, Samuel, Samuel & Doty, 2009). In recent years, the attention has been paid to the effect of the transition elements such as Zr, V, Ti, etc, as minor alloying additives, on the properties of aluminum alloys (Elhadari, Patel, Chen, & Kasprzak, 2011; Kasprzak, Amirkhiz & Niewczas, 2014; Shaha, Czerwinski, Kasprzak, Friedman & Chen, 2015; Shaha, Czerwinski, Kasprzak & Chen, 2014; Mahmudi, Sepehrband, Ghasemi & 2006; Meng, Cui, Zhao & Zuo, 2013). Kasprzak et al., (2014) and Shaha et al., (2015) reported that additions of Zr, V, and Ti in Al-Si-Cu-Mg cast alloys can improve the alloy mechanical properties at high temperature by forming stable intermetallics and precipitates on as-cast and heat treatment conditions. On the other hand, the mechanical properties of near-eutectic and eutectic Al–Si cast alloys depend not only on the chemical composition but also, even more importantly, on microstructural features such as the morphology and size of eutectic silicon and intermetallic particles, which are present on both as-cast and heat treatment conditions (Mohamed et al., 2009). However, there is rather limited information on the effect of Zr and V on the microstructure features and mechanical properties of near-eutectic Al-Si-Mg cast alloys."

Jan 1, 2018

By J. Salazar

This paper presents a dynamic simulator of the semi-autogenous grinding operation deduced from first principles (non-stationary population balances) coupled to a Model-Based Real-Time Optimization (MBRTO) system to study optimizing strategies for an industrial semi-autogenous mill using genetic algorithms. For the design of the MBRTO both a validated first-principle steady-state model adapted on-line and a dynamic model were used to study the transient effect. The objective function considered is to maximize the ore throughput or the fine-product rate by changing the power-draw. For these purposes, these two performance indexes were introduced as fitness functions in the genetic algorithms. The three decision variables used were the ore feed rate, the water feed rate and the mill rotating velocity. The optimization problem was solved using a classical genetic algorithm with constant population. Constraints in the power draw and the filling level were handled by assigning a penalty function to the fitness function. Simulation results using industrial data for a large 1800 t/h copper-ore mill show the effectiveness of the system in finding the optimum controller set-points as a function of the process-operating constraints; mainly maximum ore feed rate, power draw and filling level. Starting from non- optimum conditions, the optimizer is able to improve the global performance index by 50% relative to a base case.

Jan 1, 2007

By Q. J. Xu

In blasting sensitive areas, the use of traditional blasting for rock fracture is restricted. Soundless cracking technology has been presented to achieve rock fracture instead of blasting. However, when the diameter of a borehole is larger than 50 mm, it is very dangerous that the soundless cracking agent (SCA) will have a tendency to gush from the borehole, which also leads to cracking failure. In this paper, a new large scale borehole soundless cracking technology is presented, using a new enlarged drill bit and mechanical plugging, which could solve the hole gush problem. Experiments were made to measure the expansive pressure of the SCA working in boreholes of F40 mm and F100 mm. The difference between two sizes of cracking phenomenon was compared and analyzed to show that large scale borehole soundless cracking has larger expansion pressure and faster reaction speed than traditional soundless cracking. Based on the experimental data, finite element analysis was utilized to study the stress concentration and stress distribution between two neighboring large boreholes in several media during the cracking process. Using the data from experiments with finite element numerical simulation, the brittle material fracture condition was analyzed to design the parameters of the borehole mesh. With the theoretical analysis, the technological process and reference parameters of large scale borehole soundless cracking were proposed, including the borehole spacing, burden distance, depth of the borehole and so on. Then a single rock was cracked with the new enlarged drill bit and new plugging, and the results proved the feasibility of the new large scale borehole soundless cracking technology, which achieved the expected goal of improving the cracking ability and reducing the cracking time. This paper presents a new efficient rock cracking method for blasting sensitive areas, and which could apply to mining engineering, demolition engineering, excavation engineering and other engineering applications where there is a demand soundless and non-vibration fracturing of rock.

Aug 1, 2013

By P. Chollet, A Constant

THE RESULTS of a previous investigation ( 1) on the work-softening of some heat-treated steels have led to the conclusion that the occurrence and intensity of the phenomenon is possibly governed by the work-hardening capacity of the material, and the relative amount of retained austenite. The first assumption is compatible with Polakowski's theory (2) that the absence of work-softening, in steels quenched and tempered at relatively low temperatures, may be attributed to the high rate of work-hardening which compensates for, and even out-weighs, the loss of internal energy associated with the simultaneous rearrangement of the original system of internal stresses. Indeed, Polakowski first considered the work-softening as a manifestation of a partial release (by cold-working) of the latent strain energy stored in

Jan 1, 1962

Gold recovery from refractory ores can be very difficult and complicated depending on the causes of the refractoriness. Typically, a fine wind and/or the oxidation of the gold-bearing sulfide minerals are required to liberate gold from the host rock matrix. Mineral separation techniques, particularly surface¬wettability based separation (i.e., flotation) and magnetic separation, can be used to pre-concentrate the gold and sulfide minerals, or to remove mineral species that are harmful either to the oxidation of the gold-bearing sulfides or to the cyanidation following the oxidation. In this paper, several processes are described, including oil-agglomeration flotation recovery of fine-grained gold and sulfide, reverse flotation of carbonate minerals prior to pressure or bio oxidation, reverse flotation of elemental sulfur after pressure or bio oxidation but prior to cyanide leaching, and magnetic concentration of gold-bearing iron oxides. The integration of these techniques with gold hydrometallurgical processes may make the economic recovery of gold from an otherwise uneconomic refractory ore possible.

Jan 1, 2011

By Hyumng Sup Choi

The role of the interfacial electrical 'Condition on the adsorption of col-lectors on mineral surfaces has been studied by electrophoretic mobility and adsorption measurements made on zircon. From the investigation of the electrokinetic properties of zircon, H+ and OH-are seen to act as potential determining ions, thus controlling the electrical nature of this mineral. The isoelectric point of zircon occurs at a pH of approximately 5.0, and it is evident, therefore, that the zircon surface would be positively charged below a pH of 5.0 and negatively charged above this pH. The adsorption of collectors therefore de-pends strongly on the pH of the solution; anionic collectors are adsorbed on positively charged surfaces and cationic collectors on negatively charged surfaces. This, in turn, de-fines the effective flotation condition, with respective collectors, for this mineral. The above results have been correlated with the flotation behaviour obtained by the simplified flotation test using a modified Hallimond tube.

Jan 1, 1963

By E. Ghali, B. Arsenault

Aluminum alloys play an important role in the manufacturing of air and ground vehicles. However, with such alloys, corrosion damage is often found on structural components subjected to fatigue loading. The alloying provides large benefit in terms of the high specific tensile strength (ultimate strength/density ratio) to the aluminum alloy but causes the aluminum alloy to be more sensitive to localized corrosion due to complex microscopic heterogeneities such as secondary phases. This paper investigates thermal spray coating namely arc spraying to evaluate the protection against environmentally assisted cracking (EAC) and localized corrosion on Aircraft structural 7075 T651 aluminum alloys. In particular, EAC and pitting corrosion at the interface coating-substrate are a challenge for thermal spray protective coatings on aluminum alloys under cyclic load and immersion. To address these issues, different surface preparation techniques prior to arc spraying were considered such as chemical de-oxidation, laser ablation, shot peening and grit blasting. Results indicate that surface preparation and improved coating process parameters play an important role to provide a coating conferring a protection against both localized corrosion and EAC.

Jan 1, 2006

By A. Hosseini

Full-scale rupture tests were conducted on 508 mm (20 in) diameter API X-60 5.7 mm wall thickness pipes containing either axial semi-elliptical cracks or simulated corrosion defects with equivalent depths ranging from 20 to 60 percent thickness. In the case of the cracks, the failure pressures were predicted with reasonable accuracy when considering a level 3 failure assessment diagram (FAD) procedure based on API 579, as compared to level 2 FAD, since the mechanical properties were known. In both cases, the accuracy improved for shallower cracks. Considering simulated corrosion defects, the RSTRENG approach provided more reliable results on predicting the collapse pressure. For a similar depth and profile, the cracked pipes failed at a lower pressure than those containing simulated corrosion defects of equivalent depth.

Jan 1, 2010

"In flotation research, relatively little attention has been paid to understanding particle-bubble detachment phenomena compared with attachment processes. With CFD models now incorporating attachment/detachment kinetics, it is important to obtain more accurate formulations for detachment probability. The formula most often used is due to Bloom and Heindel (2002) who proposed that the rate of detachment would equal the product of detachment frequency, as previously estimated by other authors, and probability of destabilization, as estimated previously by Schulze. These two factors both account for the balance between stabilization and destabilization forces, so the product accounts for this effect twice. An integrated procedure has been followed to estimate the overall detachment rate by re-analysing the process. In this analysis, detachment rate is calculated as the frequency of eddy-aggregate interactions (or “collisions”) sufficiently energetic to cause detachment. The Bond number analysis of Schulze has been incorporated into the turbulence frequency analysis of previous authors in an integrated way. The new formulation has essentially the same type of dependencies as the previous model, but gives a lower detachment frequency. Detachment frequency has been calculated using the new formula for conditions relevant to an industrial flotation cell. INTRODUCTIONIt is well known that the effectiveness of froth flotation for separating different minerals is limited to the particle size range of approximately 10–100 mm (Trahar & Warren, 1976; Trahar, 1981). Fine particles tend to follow fluid streamlines around bubbles limiting the likelihood of bubble–particle collision, while coarse particles can be more easily detached from bubbles before collection can be achieved.Phenomenological models have been developed to quantify the physico-chemical aspects of flotation in order to better understand factors affecting these limitations, and to suggest ways of broadening the window of feasible flotation. Koh and Schwarz (2008) have incorporated these models into computational fluid dynamics (CFD) models of flotation cells, which have then been used for design and scale-up purposes (Schwarz et al., 2015). The models are based on dividing the process of bubble–particle interaction into three subprocesses: collision, adhesion and detachment. Of these, the hydrodynamics of bubble–particle collision and the probability of adhesion have been studied most extensively, while the dynamics of detachment have received relatively little attention from investigators."

Jan 1, 2016

By Jr. Wilkinson

Suncor Energy currently mines approximately nine hundred thousand tonnes of ore and waste per day at its open pit operations in the Athabasca Oilsands near Fort McMurray, Alberta. Modeling these deposits for planning purposes is particularly challenging given the characteristics associated with the deposit - stratigraphic deposition coupled with gradational grade distribution. The identification of ore and waste is a combination of bitumen cutoff grade, minimum mining thickness and separable waste thickness subject to criteria established by provincial regulatory agencies. Suncor along with Mincom Inc. have collaborated on this project to derive a methodology, automated by computer software, to streamline the ore and waste identification process. This paper explains the methodology and programs created to identify ore and waste in use at Suncor Energy and how this identification is used to categorize reserves and to generate mine design surfaces.

Apr 1, 2005

By Si Qin

Unknown goafs and roadways of abandoned coalmines can be a great water inrush hazard for coalmine workers. Consequently, advance detection of such hazards is of great importance. By detonating seismic charges in underground coal seams, we can collect seismic data using a surface survey line, which is located across the ground projection of the underground shot point. This experiment was conducted in a coalmine in Shaanxi Province, China. After surface elevation compensation and travel time adjustments, we accurately determined the position of the goaf boundary along the survey line based on the wave velocity anomaly on the seismic record. Then we used a scattered wave imaging technique to enhance the energy of the scattered waves that are generated when the coal seam roof slide wave (refracted wave when the incident angle bigger than the critical angle) hits the roadway, thus confirming location of a geological discontinuity (roadway). This experiment shows that the coalmine ground seismic method, employing an underground explosive charge and a surface seismic array, has the ability to detect an abandoned roadway and goaf in advance of coal mining, thus can improve worker safety.

Aug 1, 2013

By Bruce Regensburg

As trucks become larger and larger, haul roads take on a more significant role in mining costs and economics. The School of Mining at the University of Alberta has compiled a design manual for haul roads using both empirical and theoretical information. One section of this manual deals with the economics of haul road construction. While many mines look only at the construction costs of haul roads, this paper looks at all associated parameters including construction costs, removal costs, timing, truck productivity and width implications. The authors demonstrate the method to determine the most appropriate quality of road for different road conditions and life spans.

May 1, 2001