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By P. M. Shibley

"IntroductionMine drainage, surface. drainage and process liquors are the principal mine and mill effluents. The quantity and quality of these flows varies according to mineralogy, type and scale of mining, the process, tailing disposal, local ground conditions and climate.Typical contaminants remaining after solids sedimentation are colloidal or semi-colloidal particles, acids, alkalis, metals in solution, cyanides and thiosalts. Environmental regulations and guidelines have been issued in detail by the appropriate government agencies and will not be reviewed here. Revisions and additions are being made as our comprehension and abilities increase. Some contaminants of consequence have not been specifically regulated as practical treatment technology has not been identified. Thiosalts fall into that category as do the derivatives of the first stage of cyanide oxidation - cyanates.Most mining activities have present or foreseeable water treatment requirements. Because process economics can be adversely skewed by the environmental factor, the acknowledged objective of every operation must be to identify and anticipate those requirements.The evaluation and selection of water treatment techniques for mine-mill applications is complicated by the fact that most mine-mill effluents are high volume, dilute and chemically complex systems. Treatment processes applicable to most contaminants are: chemical or biological oxidation; neutralization and/or precipitation; liquid/solids separation. Other processes such as ion exchange, electro-deposition, foam fractionation, freeze crystallization and reverse osmosis offer the possibility of selective removal or concentration of contaminents. The latter tediniques, representing a slightly higher level of technology, are less suited to the large, low value flows usually encountered in the mine environment."

Jan 1, 1989

By L Mariani, G. Mendoza-Suarez

In this investigation, TiH2 powders were coated with copper and nickel by electroless plating to delay hydrogen evolution. Copper-coated samples were found to have a mixed acicular (2D growth) and cauliflower (3D growth) morphology whereas the nickel-coated samples had a cauliflower morphology. Examinations of the coated powder cross-sections revealed that the coating thickness ranges from 0.2 µm to 4 µm. Uncoated areas on the powder surface and coating flakes unattached to TiH2 particles suggest poor adhesion between the coating and the substrate. The phase transformation undergone by the TiH2 during dehydrogenation was studied in samples taken at intermediary points in the heating cycles and examined by XRD. The findings reveal that as the powder is heated from room temperature to 800°C, it changes from TiH1.971 to Tiu and to aTi. Differential Thermal Analysis (DTA) was performed to study the effects of the coatings on the temperature of hydrogen release. It was found that increasing the number of plating iterations, and therefore the thickness of the coating, creates a significant shift in the temperature of gas release.

Jan 1, 2006

By Bruce Macdonald

Operational reservoir management activities such as cyclical steam, water or CO2 injections frequently cause surface micro-deformation. InSAR monitoring from space based sensors of this surface deformation has become a valuable approach to confirm and monitor extraction and injection activities. Sequestration of CO2 into deep saline aquifers is discussed as an important long term solution to slow future climate change. This method requires reliable continuous monitoring to assure that captured CO2 is sequestered in the substrate for ?all time? (typical minimum requirement by law is 20-30 years). We have shown that combining flow and deformation modeling with spaceborne synthetic aperture RADAR interferometry (InSAR) measurement of ground uplift caused by the underground release and spreading of the CO2 can be forged into a powerful tool to monitor sequestration. We used a novel InSAR approach to resolve the surface motion over the In Salah, Algeria CO2 sequestration site. Our approach exploits all information contained in an interferometric stack by exploiting both persistent distributed as well as persistent point scatterers. Displacement time series are obtained with a network inversion approach applied after topographic error and preliminary atmospheric correction of the network (dual-scale technique). After inverting the original network data to common master we then use an advanced spatio-temporal filtering scheme to remove the remaining atmospheric phase components down to scales of 1 km or less. By comparing final displacement series from multiple interleaving InSAR stacks we show that the accuracy of our refined solution to detect uplift outside of significant temporal data gaps in the InSAR stack is significantly better than 1 mm per year. We further show that accuracy and robustness to data gaps are both significantly improved by co-inverting multiple datasets with the same and different sensors. This co-inversion method also allows the seamless continuation of the monitoring from one sensor to another.

Jun 1, 2012

By C. Blawert

In spite of various corrosion studies on HPDC AZ91, there is no clear indication which microstructure gives the best corrosion performance. The skin with its fine microstructure is sometimes reported to have the best corrosion resistance, but there is no clear definition of the skin. If the skin is the outermost part of the casting and nothing is removed from it, then it is contaminated and the corrosion resistance is low. If the outermost skin is removed (about 25 µm) then a better corrosion resistance can be obtained. However this does not automatically mean that there is no other region in the bulk of the casting which could have a similar or even better corrosion resistance. Indeed, the corrosion measurements including potentiodynamic polarization and long term electrochemical impedance spectroscopy (EIS) revealed a lower corrosion resistance of the original as-cast skin about 100 pm thick. The thickness of this region is more or less independent from the thickness of the casting section. The surface region is free from any dendritic grain growth which influences the amount and distribution of the 13-phase and therefore the distribution of the most important alloying element Al. This could explain the different corrosion behavior. Further reason can be found in the enrichment of some impurities such as Fe in the near surface.

Jan 1, 2006

By P. Mageau-Béland, È. -M. Proulx, M. -C. Patoine

Over the past six decades, Hatch has helped several industrial processing facilities in debottlenecking their operations, allowing them to produce more with the same equipment, to reduce and even eliminate expenditure investments, or to increase the return value of their expansion projects. These successes result from the application of a proven analysis approach that can be applied to any industrial facility. A five-stage methodology is discussed and demonstrated with a specific example of a nickel concentrator optimization study. The first stage is an observation stage which allows to meet key actors at the plant, develop mutual understanding of problems, understand operating philosophy, and efficiently collect large amounts of operating and maintenance data. Following is a data compilation stage during which data is analyzed over a representative time period to identify parameters that significantly affect the production, to evaluate data reliability and to define the focus of the upcoming analysis. Quantitative metrics are defined using statistical tools such as pivot tables, histograms, percentiles and MDR (Maximum demonstrated production rate during 3 to 7 consecutive days). Then, the production bottlenecks are identified by a thorough analysis of the facility’s control philosophy, process throughput, equipment capacity, availability, downtime causes, and interaction between components of each circuit. Understanding the maintenance practices and frequency of planned shutdown is also critical to this analysis. Opportunities for improvement are identified in collaboration with the operation, maintenance and engineering teams, ranked as a function of their impact on the bottlenecks and prioritized. The final and most critical stage involves engagement with the plant stakeholders, namely the operators and the maintenance staff members, to present the results of the analysis and obtain their participation in the implementation of the solutions. The benefits of the case study translated into: 10% production capacity gain, improved maintenance planning and avoidance of several million dollars of investment.

Jan 1, 2016

An optimized long-term mine planning determines the best order of material extraction, so that the Net Present Value (NPV) becomes maximum. In the case of oil sands surface mining, one of the key constraints in NPV maximization is the volume of tailings slurry that will be generated downstream. Specifications of tailings slurry are also important from environmental perspective. Moreover, most of the material that will be used for the reclamation of tailings ponds in later periods is generated in extraction and processing of oil sands. In this paper, an integrated optimization framework is proposed to maximize the NPV of the produced oil sands, with respect to tailings capacity constraints and reclamation material requirements. A mixed integer linear programming (MILP) model is developed to find the optimal solution for long-term mine planning problem. The proposed model is coded in Matlab and has been run using CPLEX for verification. The results for real-case oil sands dataset show that the optimal production schedule meets material requirements for reclamation, tailings volume is within tailings capacity range in all periods and the production schedule follows the predetermined horizontal direction.

Aug 1, 2013

By C. R. Edwards, D. G. Feasby

"Over the last 50 years disposal of uranium mill tailings has evolved from dumping untreated tailings into the nearest depression to depositing chemically-stabilized tailings into highly engineered management facilities. This paper describes the evolution of disposal methods and the criteria which have determined the development path followed. Remediation techniques to bring older and now unacceptable tailings deposits into satisfactory compliance with today's· regulations are reviewed.With the closure of the uranium mines in Elliot Lake, Ontario, considerable effort is being made on decommissioning the tailings areas by developing long term maintenance of water covers. The innovative methods being used to develop these water covers are detailed. Methods now under development in Saskatchewan for subaqueous deposition of high density or paste tailings for permanent disposal in mined out open pits are described.SummaryThe technology for uranium mill tailings disposal in Canada has evolved considerably over the past 51 years. This evolution has been driven by an improving understanding of how best to safely and permanently store tailings, in conjunction with stricter environmental protection regulations. Old sites are being decommissioned in situ, but may require long term care and maintenance. The use of water covers is an important technique in eastern Canada to prevent intrusion, radon evolution and, for the Elliot Lake tailings, acid generation. The major drawback of water covers in any above ground disposal method is the requirement that a long term maintenance and monitoring plan be put into effect for each site.New higher grade mines in Saskatchewan will increasingly use disposal in mined-out pits using the pervious surround method and/or paste tailings technology as a method to permanently dispose of these wastes and to permit “walkaway” after a few years of monitoring."

Jan 1, 1996

By Michel Noël

This paper presents a partial compilation of adopted measures of waste rock dump closures at mine sites located in Canada and Alaska, where the climate includes cold winters. The paper also presents the selection process that was followed for some of those mine sites. Mining operations usually generate waste rock that can sometimes result in very large quantities. Additionally, the nature of the ore body and the host rock will often introduce environmental impacts. These impacts need to be managed not only during the operations but also in the long term. Mine closure plans consequently have to address the long term issues that sometimes require perpetual treatment. Closure planning often involves the evaluation of risks associated with environmental and financial liabilities. It needs to consider the science, some common definition of objectives, and there will be a need to manage resources and schedules. Closure planning is essentially an exercise in constrained decision making. A performance and risk based ranking matrix is often developed during this selection process to identify the preferred option(s). The case studies presented in this paper provides a few examples. The level of knowledge on acid rock drainage from waste rock dumps has increased considerably over the past decades. It did not necessarily increase the level of complexity of the adopted closure methods, as the selected closure methods are often kept simple. A common approach consists of stabilising the slopes of the waste rock dumps material by resloping and then covering the waste rock with a growth media to support vegetation. Such covers prevent direct contact of animals with the waste rock material, minimise erosion and reduce infiltration to various degrees. The inclusion of water treatment is obviously dependent on the water quality being released.

Nov 1, 2008

By J. L. Huisman, G. Schouten

After pyrometallurgy and hydrometallurgy, bio(hydro)metallurgy is the latest development in the ongoing search for efficient and economic metal winning processes. In addition to bioleaching, other biotechnology-based applications are getting more and more accepted. In this paper a number of proven and commercial processes will be presented that can be applied for nickel and cobalt recovery and refining. These processes are based on the ability of biomass to convert the redox state of sulphur compounds under ambient conditions. They can be applied to recover sulphate from effluents or SOx from off gases and convert it to H2S or dissolved sulphide that can be reused in production or effluent treatment. Not only does this minimize the costs on resources but it also reduces waste production and improves the quality of discharges even to the point where reuse becomes feasible.

Jan 1, 2005

By G. Chi, W. J. Davis, S. Watters, D. Hoy, S. Castonguay

"The Poplar Mountain gold occurrence in western New Brunswick is hosted in the Poplar Mountain volcanic complex (PMVC), which is located along the southern segment of the regional Woodstock fault zone. The PMVC consists of three principal units including, in ascending order, a porphyritic felsic volcanic unit, a volcaniclastic unit, and a mafic volcanic unit. U-Pb dating of zircon indicates that the age of the volcanic rocks is younger than 459 ± 3 Ma, and 40Ar/39Ar dating of mineralization-associated sericite indicates that the age of mineralization is 411 ± 3.7 Ma. Gold-mineralized zones occur in all the lithologic units but mainly in the porphyritic felsic volcanic unit. Gold zones are not controlled by individual faults but are characterized by high-density brittle fracturing, thin carbonate-quartz veining, and intensive ankerite-sericite alteration, superimposed on an earlier chlorite-calcite- quartz alteration. Gold is associated with arsenopyrite, which mostly occurs as disseminations in the host rocks, and to a lesser extent with quartz-carbonate-sericite veins and quartz-cemented breccias.Geochemical data indicate that mineralization-associated alteration is characterized by enrichment of K, Rb, Cs, Ca, Sr, Ba, As, Sb, W, C, and S. Fluid inclusion data indicate that the mineralizing fluids are composed of H2O, salts, and CO2 with variable amounts of N2 and CH4; salinities range from 2.3 to 10.6 eq. wt.% NaCl, but mainly from 2.3 to 5.6 eq. wt.% NaCl, and homogenization temperatures lie mainly between 220° and 270°C. Fluid pressures at the site of mineralization are estimated to have been 770 to 1200 bars, corresponding to a depth of 2.9 to 4.6 km at lithostatic pressure. The d18OSMOW and d13CPDB values of mineralization-related ankerite range from +14.5‰ to +16.5‰, and -6.8‰ to -8.3‰, respectively. The d18O values of the ore-forming fluids are estimated to be 6.4‰ to 8.3‰ at a temperature of 250°C. These carbon and oxygen isotope data fall in the field of magmatic fluids and in part the field of metamorphic fluids.Considering the geological setting of the region, abundant granitic intrusions, the similarity between the age of mineralization (411 ± 3.7 Ma) and the nearby Pokiok batholith (402-415 Ma), and the enrichment of granophile elements in mineralization-related alteration, the ore-forming fluids were probably derived from a granitic intrusion underneath the PMVC. These fluids were focused along structures related to the Woodstock fault. The Poplar Mountain gold occurrence might be compared to some granitic intrusion-related gold systems based on the geochemical data presented herein. L’indice aurifère de Poplar Mountain dans l’ouest du Nouveau Brunswick est contenu dans le complexe volcanique de Poplar Mountain (CVPM), lequel est situé le long du segment sud de la zone de faille régionale de Woodstock. Les trois unités principales du CVPM sont, de la base au sommet, une unité volcanique felsique porphyrique, une unité volcaniclastique et une unité volcanique mafique. La datation U-Pb de zircons indique que les roches volcaniques sont plus jeunes que 459 ± 3 Ma, et la datation par la méthode 40Ar/39Ar de séricite associée à la minéralisation assigne à la minéralisation un age de 411 ± 3.7 Ma. Bien que les zones minéralisées en or soient présentes dans toutes les unités lithologiques, on les retrouve surtout dans l’unité felsique porphyrique. Les zones aurifères ne sont pas contrôlées par des failles individuelles mais sont caractérisées par une grande densité de fractures cassantes, de minces veines de quartz-carbonate, et par une altération en ankérite-séricite intense qui se superpose à une altération antérieure en chlorite-calcite-quartz. L’or est associé à l’arsénopyrite, laquelle est principalement présente à l’état de disséminations dans la roche hôte, et à un moindre degré avec des veines de quartz-carbonate-séricite et des brèches à ciment de quartz.Les données de géochimie indiquent que l’alté"

Jan 1, 2008

By W. G. Robinson

"MINING is one of Canada's most important industries and exploration is the life-blood of this dynamic and exciting business. The health and growth of the mining industry of tomorrow depends on the effort and thought that go into exploration today. The Members of the Geology Division of the C.I.M. are directly concerned with exploration, and it is fitting that this Division should periodically sponsor reviews of the thoughts and practices of the exploration com-munity. Accordingly, we have invited seven leading authorities to contribute papers dealing with specialized aspects of this field.Exploration is a science, or art if you will, that is constantly changing in keeping with our expanding knowledge of geology and technology. It started with the old-time prospectors who searched the wilds for exposures of ore, and made finds that developed into some of our most important mining camps. As more discoveries were made, they were able to relate certain types of deposits with particular geological conditions, laying the foundation for modern concepts of economic geology. The mapping by the early field parties lacked detail and usually served to outline the ""greenstone"" areas considered favourable for prospecting. More de-tailed studies through the years by government and company geologists led to new thoughts on the origin, emplacement and geological control of orebodies. The continuing diversity of opinion on these subjects indicates a need for further research, but each year sees an increase in our reserves of factual information."

Jan 1, 1967

By G. Szilvay, P. Kinnunen, J. Salminen, V. Miettinen, O. Salmi, J. Mäkinen

This paper demonstrates experimental studies on bioprocessing of different waste streams. In Part I of this paper three tailings from mining industry were bioleached with mixed acidophilic culture in order to solubilize valuable metals, like copper, nickel, zinc and manganese to leaching liquor. Bioleaching resulted in > 70 %, > 85 %, 100 % and > 70 % leaching yields for Cu, Ni, Zn and Mn, respectively. However, contaminants like arsenic and chromium were not leached efficiently and they will cause challenges in residual solids and sometimes also in metal recovery from leaching liquor. Bioleaching resulted in 99 % leaching yield for copper. Part II demonstrates mine water treatment and also gold recovery from process liquids with biosorption method. The novelty of biosorption was finding that certain fungal species were able to be cultivated to self-immobilized systems, which are easier to operate than traditional suspended biomass methods. Biosorption resulted in more than 90 % removal for all contaminants, but was also seen to be gold selective.

Jan 1, 2014

By J. Nsasi Bakambu

This paper describes an autonomous platform for exploration and navigation within networks of tunnels, as those typically found in underground mines and caves. In the exploration mode, a remotely located supervisor instructs the platform to move through successive sections of the network, gathering range data that is, then, concatenated into 2D/3D survey maps of the environment. In the navigation mode, the supervisor specifies high-level missions on the previously acquired survey maps. A motion planner, then, translates each mission into a set of consecutive navigation actions, separated by natural landmarks. Mission execution consists of detecting landmarks, self-localizing and performing the planned navigation actions.

May 1, 2003

By T. R. Madhavan

The development of contact angles on highly polished ?uraninite surfaces, using sodium oleate and dodecyl ammonium acetate as collectors, has been studied at different collector and hydrogen ion concentrations. It was found that sodium oleate in acidic media (up to a neutral: PH) and dodecyl ammonium acetate in neutral and alkaline media give good contact angles. It appears that the combined forms of these collectors, viz., oleic acid and free amine, are more important in effecting contact. W ITH the emergence of uranium as a strategic metal in the last fifteen years, considerable effort has been directed toward the commercial recovery of uranium from its ores. This has resulted in the development of a uranium technology. It is only in recent years, However, that fundamental data regarding the floatability and surface properties of uraninite and ?pitchblende have been elucidated by different methods. Contact-angle measurement is one of the important tools for tl1e evaluation of the conditions of floatability

Jan 1, 1964

Particles for heap leaching in conventional circuits are prepared using Cone crushers. Cone crushers are used to crush the ore to the size range between 12-25 mm for heap leaching operations. Leaching from these relatively coarse particles occurs only at the surface and in subsurface regions, which are accessible from the surface by cracks and pores. Since leaching is active in accessible areas, the method of comminution that forms multiple cracks and pores would offer an advantage for heap leach. An investigation was performed in this study to assess if the HPGR forms more cracks and pores than a Cone crusher. X-ray computed tomography (CT) was used to characterize the degree of cracks and pores formed by these two comminution devices that can be used for heap leaching feed preparation. In order to compare the effect of the comminution method on crack network generation, a bulk sample of the zinc ore was crushed by the HPGR at three different pressure settings (45, 95 and 120 bar), the sample ore was also crushed with a Cone crusher for comparison purposes. Products from the Cone crusher and HPGR experiment were then screened into five size fractions ((-25 +19), (-19+16), (-16+9.5), (-9.5+5), (-5+4.75) mm), Subsamples from the ((-25 +19), (-16+9.5), (-5+4.75) mm) size fractions were analysed. The spatial distribution of the crack network of sphalerite particles was characterized using a highresolution industrial X-ray CT system. This paper describes the use of image analysis techniques including image segmentation, which uses a combination of thresholding and other methods to characterize and quantify crack and mineral dissemination in the sphalerite particles after comminution with the HPGR and Cone crusher. The results are validated with those obtained using traditional techniques such as physical gas (with N2) adsorption, mercury intrusion porosimetry, SEM and QEMSCAN.

Jan 1, 2012

By P. Hr?enjak

Two groups of methods are usually used in design procedures of underground excavation of dimension stone: the analytical and numerical methods of analysis. In all of these methods the in situ rock mass strength represents the main problem. This is due to massive rocks in dimension stone deposits, consisting of large blocks of rock separated with particular discontinuities, for which the Hoek-Brown empirical criterion, developed for jointed rock masses, cannot be realistically used to estimate rock mass strength, especially for a particular block of rock mass or a particular pillar. On the basis of the regular underground excavation process of dimension stone by separating blocks with the flat jack application, we developed the in situ flexural strength testing method. We carried out numerical analyses and evaluation of uncertainty of measurement in order to validate the in situ flexural strength testing method. On the basis of very good validation results, as well as results of the in situ flexural strength testing of exploitable layers on the ?Kanfanar? quarry, we introduced a new coefficient of reduction, which can be used for correction of other strength parameters determined by laboratory testing for obtaining a realistic value of rock mass strength.

Aug 1, 2013

By C. Anderson, H. Huang, P. Miranda, E. Dahlgren, I. Chandra, M. Jeffrey

The latter part of the 20th century saw great advances in the treatment of refractory gold ores coupled with increased reliance on the use of cyanide for gold processing. Now, in many parts of the world, there is social pressure to limit or eliminate the use of cyanide. As well, treatment of some refractory ores or concentrates which have excessive cyanide consumption, gold cyanide pregrobbing or significant sulfide content remain difficult. This paper will outline the history of the development of alkaline sulfide leaching as an ancillary process to nitrogen species catalyzed (NSC) pressure leaching. Electrochemical fundamentals and the applicable thermodynamics of the alkaline sulfide hydrometallurgical system will be outlined. As well, examples of refractory gold recovery with alkaline sulfide hydrometallurgy such as an arsenopyrite gold concentrate application, a chalcopyrite gold concentrate application, a pregrobbing gold ore application, and a cyanide consuming gold ore application will be delineated in this paper.

Jan 1, 2005

In-Situ Leaching (ISL) process plants are low cost producers for uranium deposits where the geology is suitable. In the 1970s, a three-year pilot ISL program occurred on gold ore from the Ajax Mine, Cripple Creek District, Colorado, using a chloride and iodide solution [1]. The test was halted due to poor results. With gold and silver the international ISL progress has been slow; however the potential for low capital expenditure (CAPEX) and operating expenditure (OPEX) with large low grade deposits is real. Unless the metallurgy has been demonstrated there are significant risks which could be fatal flaws to an ISL gold or silver project. The metallurgy of gold ISL projects is far from simple and it is early days with project development.

Jan 1, 2011

By F. Hassani, J. Peck, D. J. Lucifora

The performance of a rotary blasthole drill is heavily dependent on the material being drilled. This material is a microcosm of the in-situ geology that makes up the surface mine in which the rotary blasthole drill is deployed. The performance metrics that are influenced by the in-situ geology are penetration rate (distance drilled per unit time), rotary torque and to a lesser extent rotary speed and vibration. For simulation and testing purposes it is useful to have a validated plant model based upon the application of study. Once validated, a plant model can be used to perform simulation based testing as a supplement and possibly in place of more expensive and logistically complex field testing. Previous studies in the field of rock mechanics have supplied proven models that relate the performance of a rotary blasthole drill to the material being drilled for a given rock type with a given drill bit. In this study, field based experiments were conducted in an active surface mine on a working rotary blasthole drill and the corresponding monitoring while drilling (MWD) data was recorded. Data analysis was then performed on the collected field data. The techniques used successfully fit the collected MWD data to the previously proven rock mechanic models. This paper explores the theory relating rotary blasthole drill performance to the material being drilled, illustrates the required data collection and data analysis techniques, and demonstrates the ability of these techniques and the known rock mechanic models to provide a simulated plant model for the drilling process that can then be validated. This validation is also discussed.

Jan 1, 2015

By Fathi Habashi, Ahmet Deniz Bas

"The mechanism of leaching of semiconducting minerals such as PbS, ZnS, UO2, etc., has been the subject of intensive speculation by hydrometallurgy researchers in the early 1950s who assumed the formation of intermediate surface complexes that could be neither separated nor identified by physicochemical techniques. The electrochemical theory of leaching introduced in the late 1960s resolved this problem by comparing the leaching process to a corrosion phenomenon similar to the corrosion of metals. Few years later, experimental evidence showed that anodic and cathodic zones are formed on the dissolving mineral although no electric current is imposed on the mineral during dissolution. A discussion of these findings is outlined.INTRODUCTIONIn the early 1950s researchers realized that kinetic studies for leaching ores are as important as thermodynamic calculations. It was also during this period that the concept of species adsorption on mineral surfaces has dominated the interpretation of the mechanisms of most reactions. This may have been due to the fact that many researchers of this period came from the mineral dressing sector and were influenced by flotation theories. However, when the knowledge of lattice defects and the semiconductivity of minerals became known and their importance in extractive metallurgy was realized, there was a need to explain the leaching reactions in light of these modern theories (Habashi, 1969, 1970). Semiconducting minerals of importance in metallurgy are two categories: the sulfides such as those of copper, lead, zinc, and the oxides such as those of uranium."

Jan 1, 2016