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By J. Dubinski

Poland is the ninth largest coal producer in the world and Coal Company is the largest Polish producer of this deposit yielding 51% of national production. Coal Company mines are located in the Upper Silesian Coal Basin. These are underground mines which operate in difficult geological conditions at great depths of up to 1200 m. One of the most common natural hazards in Polish mines are rockburst and seismic hazard impacting on surface infrastructure and habitants. In the assessment of the rockburst and seismic hazard methods of mining seismology play a leading role. This paper presents progress that was achieved in the last few years in the implementation of new seismic monitoring systems and seismic interpretation methods for the prevention of hazard deriving from seismicity induced by mining. This progress in assessment of rockburst hazard and impact of seismic activity on the surface infrastructure was achieved through close cooperation between the Coal Company and Central Mining Institute ? the country?s leading scientific institute in the field of mining seismology. New theoretical solutions are in the process of testing in mines of Coal Company where seismic monitoring systems are installed and controlled by well-qualified personnel. Some directions of further joint actions to increase the effectiveness of rockburst and seismic hazard assessment are presented as well.

Aug 1, 2013

By M. K. Jain, Z. T. Xu, M. Bruhis, V. Hegedekatte

"Strain rate and temperature dependent deformation conditions are present during elevated temperature forming of aluminum and other metallic materials. While many constitutive laws have been proposed to represent such deformation conditions, a closer investigation often reveals their limited applicability in terms of fit to the experimental data, and interpolation within and extrapolation outside of the range of experimental stress-strain curves. This is often because material-specific primary deformation mechanisms of temperature-dependent strain and strain rate hardening are poorly captured. In the present work, the Voce-Kocks constitutive model based on mechanics of dislocations storage and annihilation has been found to be suitable for many metallic materials. The model was modified to include the effect of temperature dependent shear modulus. The modified model is then employed to represent the experimental data obtained from uniaxial tensile tests on AA7075-O sheet at elevated temperatures and strain rates. Also, hot gas bulging tests were conducted to verify the applicability of this model. Further, finite element simulation of the hot gas bulge test was performed by incorporating the model as a user material subroutine. Good general agreement was observed between the experimental and FE model predicted results. Some sources of discrepancy in the prediction are also discussed.INTRODUCTION There has been much interest in light-weighting of automobiles from automotive related industries to reduce overall carbon footprint and increase energy efficiency of the vehicles. Aluminum alloys, and especially the medium-strength 5xxx and 6xxx series alloys, have been the primary focus in the last 3 decades to reach the above environmental goals (Huo, Hou, Zhang, & Zhang, 2016) whereas aerospace industry has traditionally focused on high strength 7xxx series aluminum (Al-Zn-Mg-Cu) alloys for structural components (Deng, Yin, & Huang, 2011). Recently, there has been much interest in high strength 7xxx series aluminum as a replacement for heavier steel automotive structural parts such as A-pillar, B-pillar, side impact beams etc. (Harrison & Luckey, 2014). This is both interesting and challenging since the above aluminum structural parts will need to not only meet impact safety standards but also possess sufficient formability for manufacturing such complex parts. Since the formability of high strength 7xxx series materials is quite poor at room temperature, much interest has focused on improving both formability and final part strength via high rate hot stamping, in-die quenching, and subsequent artificial ageing process steps (Kumar & Ross, 2016)."

Jan 1, 2018

By D. M. MacLean

THE property of Howey Gold Mines, Limited, is situated at Red Lake, Ontario, one hundred and seventy-five miles east of Winnipeg and eighty miles north of the Canadian National railway. The mine has been a continuous producer since April, 1930, and, at present writing, a total of 3,042,690 tons has been hoisted, giving a production of $6,422,858.55, for a grade of $2.32 per ton. From 1,064,477 tons mined during the past two years, however, the yield has been only $1,389,607.03, or $1.41 per ton (gold at $20.67). Present output is at the rate of about 1,470 tons. per day. THE ORE-BODY AND WALL-ROCK: The Howey ore-body is part of a quartz porphyry dyke, which has. intruded an area of greenstone. The dyke strikes north 65° east, and its dip varies from 85° to the south at the surface to practically vertical below the. 1,000-foot horizon. Both along the strike and on the dip, the width of the dyke varies from 25 to 200 feet, the widest portion occurring below the 1,000-foot level. To the east of the ore-body, the dyke increases in width and finally splits into tongues of porphyry enclosed in greenstone, diorite, and congloJ11erate. To the west, it passes into the adjoining property, its width at the boundary being 100 feet. The rock in the ore-body is hard to drill, but, because of numerous horizontal slip-planes, it breaks well when blasted. This characteristic makes it possible to break large breasts or benches with a relatively small number of holes. The ore broken in this manner is consequently quite coarse, a large part of it requiring secondary breaking.

Jan 1, 1938

By J. Lapointe, S. Leger, D. Proulx

"Une méthode non-électrolytique est utilisée pour plaquer au cuivre la fibre d'amiante chrysotite. En variant les paramètres de placage du bain, on détermine les conditions optimales du taux de deposition du cuivre . Une analyse par diffraction aux rayons-X permet une comp araison relative des résultats de placage et de précipitation d'oxyde cuivreux dans Ie bain. Le traitement de placage a pour but d'assurer une adhésion suffisante de la fibre dans une matrice métallique Iors de la fabrication éventuelle de materiaux composites.IntroductionCette communication se veut un compte-rendu de nos travaux sur Ie placage au cuivre de la fibre d'amiante chrysotile, en vue de I'incorporer éventuellernent dans une matrice métallique. La fibre d'amiante est constituée de fib rilles élementaires d'un diamètre d'environ 0.02 um qui ont une résistance en tension de I'ordre de celie de la fibre de verre ou de carbone(1). Pour être efficace, la fibre de renf'ort d'un matériau composite doit d'une part, avo ir des propriétés mécaniques intrinsèques élevées, et d'autre part, adhérer solidement â la matrice pour que Ie transfert de charge s'effectue sans qu'il y ait décohésion entre les composantes du matériau.La fibre d'amiante étant naturellement soyeuse, il faut la traiter superficiellement pour que l'adhésion avec la matrice soit suffisante. Ainsi, on recouvre la fibre de phénol-formaldéhyde(2) ou de silane(3) lorsqu'elle est employée avec une matrice polymere. Dans Ie cas d'une matrice métallique, ces dépôts organiques ne peuvent resister aux températures de mise en oeuvre, d'où l'intérêt de plaquer les fibres par un dépôt métallique.Dans cette étude, nous rapportons les résultats relatifs à la methode utilisée pour plaquer au cuivre la fibre d'amiante chrysotile. Une analyse par diffraction aux rayons-X permet de comparer les différentes conditions de placage non-électrolytique."

Jan 1, 1985

By J. L. Llanca

The New Level Mine project (NLMP), the planned underground expansion of the El Teniente mine in Rancagua, Chile, is expected to reach a daily extraction rate of 137 to 180 ktpd upon achieving full capacity. Production is planned to start in the year 2017 and the current plan is to meet that target through two development phases, from the year 2012 to 2014 and from the year 2015 to 2017. To achieve the 2012 to 2014 underground development schedule, the ventilation requirements have been estimated in the range of 189 m3/s (400 kcfm), and cannot be made available without significant modifications to the current system of El Teniente. As a result, a certain number of alternatives were explored to find a solution to this shortfall, for example, adding raises to generate parallel airways and installing fans to reinforce the current ventilation system. From the alternatives studied, the installation of a second main fan (system) in parallel to an existing one was identified as the best solution, and selected for implementation, however the location was not ideal and there were concerns as to the operation of both fans once the second fan was installed. This paper presents the study used to estimate the operational points of both the current and the new fan, and to justify the parallel installation of the additional main fan. An additional computational fluid dynamics study was undertaken to validate the operational point, given the particular geometry of the fan?s location and placement, to guarantee a stable operation of the fans. Finally, the protocols arising out of this work for starting the fans, and operating them in parallel to avoid generating a stall condition and damaging the investment are discussed.

Aug 1, 2013

By P. Coursol

The Noranda Reactor Process (NRP) has been in operation now for more than 30 years and this mature process has attained a high level of performance. The NRP at the Home Smelter of Xstrata Copper treats a wide range of feed materials and a thorough knowledge of both process control and smelting physico-chemistry has been beneficial to help meet the required plant flexibility. In this regard, some level of predictive knowledge related to slag chemistry, in particular, the liquid and solid phases such as spinels or olivines, has been found to be beneficial. In the last decade or so, the availability of commercial thermodynamic modeling packages, such as Factsage1m have been utilized with advantage to help the plant optimize slag chemistry and minimize problems from difficult slags, for example, those the could arise from undue feed variability. This paper illustrates the application of this software in examining a range of operating parameters such as: %Fe in product matte, the %Fe/%Si02 ratio in the slag, the levels of minor slag components including CaO, Ah03, ZnO, and MgO, and the level of oxygen enrichment on the operating conditions of the NRP. The slag composition boundaries at the conditions affecting magnetite control and solid magnetite/other precipitated solid phases, as well the conditions influencing the slag liquidus ranges of NRP slags are also discussed with respect to the overall process chemistry.

Jan 1, 2007

By R. Burns, A. I. A. Salama, M. W. Mikhail

"Large amounts of oil sand tailings are produced in the Fort McMurray area, including sand, clays, and misplaced bitumen. The objective of the present study (as part of the overall engineered tailings program) is to select and evaluate the role of hydrocyclones in removing most of the solids from the tailings slurry and producing an underflow product containing about 75% solids.Multistage cyclones were evaluated in pilot plant tests. Slurry feeds with different percents solids and increasing ratios of superfines (–44 µm) were used in testing multistage cyclone circuits. A two-stage Linatex separator circuit gave high recovery to the underflow of 98.8% to 99.6% by mass with the desired high solids content in the underflow of 73% to 75% by mass. Changes in feed solids content (20% to 50%) had little or no influence on cyclone underflow recovery and solids content. The keys to achieving such results were the apex control mechanism and operation at relatively low feed pressure (<60 kPa for 23 cm F cyclone) when the feed solids content was high. Increasing superfines above 7% by mass in the feed resulted in a significant reduction in the recovery to the underflow, probably due to the heavy medium generated by excessive amounts of clays in the cyclone. Pilot plant results were better than those predicted by available cyclone simulation models in terms of recovery and solids concentration in the underflow.Increasing cyclone diameter from 23 cm for the Linatex separator to 51 cm for the Krebs cyclone appears to have little or no effect on size cutpoint."

Jan 1, 1997

By L. M. Oshinowo

The incorporation of advanced analysis tools, such as CFD, into the process plant design process has become possible through advances in commercially available computational fluid dynamics software and faster computers. Multiphase modeling is now typically employed in the design phase of process plant design at Hatch. The multiphase models include Lagrange-Euler and Euler-Euler treatment of the multiple phases. Additionally, mixture models with interface-sharpening algorithms are applied to the prediction of free-surface flows in complex geometry. CFD is applied to applications where traditional design rules are not applicable. The additional rigor of CFD modeling in 2D and 3D allows process engineers to come closer to realizing true virtual plant design. The objective of this paper is to outline the benefits and pitfalls in the application of multiphase modeling for rigorous design. Several application examples in the hydrometallurgical field will be presented.

Jan 1, 2005

By N. N. Rulyov

"Starting from fundamental principles of colloid-hydrodynamic theory of disperse systems we have shown that application of strongly non-uniform hydrodynamic fields allows to achieve not only faster rates of flocculation of suspension, but also supports significant improvements in the quality of clarified water and separation characteristics of solid phase. Specifically, it has been experimentally proven that the new treatment method based on these principles (then termed as ""ultra-flocculation"") allows:•,Increase the output of thickeners and pressure filters by 1,5-1,7 times;•,Decrease solids fall through into the filtrate in the process of vacuum filtration by 2¬3,5 times;•,Improve the rate of purification of water phase in the upright thickener by 1,5-1,9 times;•,Decrease flocculant consumption by 1,5-3 times;•,Increase the effective operational life time of cloth filters by 3-4 times;•,Ensure sustainable operation of separation equipment, i.e. decrease the sensitivity of process to variation in suspension concentration, as well as to variations of suspension composition and dispersion characteristics;•,Apply flocculant solutions of concentration 2-3 times higher, thus increasing the capacity of equipment used for solutions preparation."

Jan 1, 2004

By R. A. Hemstock

"Simple classification systems are now being used which will describe adequately the surface vegetation, the topography and the peat for any muskeg condition. Good progress is being made in determining some of the mechanical properties of muskeg and it is apparent that the science of soil mechanics will apply largely to these studies. Correlation is also indicated between shear strength as determined by the shear vane tester and vehicle performance. Several tracked vehicles are now available which perform well in muskeg and advances in this field have come rapidly in the past few years. Testing is under way on the largest of all muskeg vehicles -the thirty-five ton Musk Ox. This vehicle will fill the last gap for the oil industry and will make possible the movement of large drilling rigs at any season of the year."

Jan 1, 1960

By R. Roufail

Mineral exploration is in a race to employ drilling technology that can perform the exploration and drilling investigation in a fast and inexpensive manner. After an extensive study of the available drilling technologies in the market, coiled tubing was chosen as a tool to be employed for mineral exploration due to its flexible mobility and ease of operation with a minimum number of personnel. Since coiled tubing technology is primarily used in the oil and gas industry, it was important to re-design the coiled tube rig to drill hard rocks in a fast and feasible manner. The main requirements were to drill the smallest feasible hole diameter and go as deep in the ground as possible, in the shortest reasonable time. The drilled rock particles, cuttings, are to be collected and analysed at the surface for their metal mineral contents. The process also needs to be repeated multiple times at different locations for mapping, without the need to change the tube on the rig due to failure or potential failure. The focus of the new designed coiled tube, for drilling and mineral exploration, is three fold. First is to increase the rate of penetration in drilling by designing a small high speed turbo motor. Second is to determine the controlling parameters of cuttings transport to effectively lift the cuttings to the surface for analysis and third is to minimize the overall weight of the rig for manoeuvring and prolong the life span of the coiled tube string. In this paper, a small downhole turbo motor, 5cm outer diameter, is designed to achieve a rotation speed of up to 10,000 rpm to fit on a small bit, coiled tube drilling assembly. The motor design utilised multiple finite volume and finite element analysis softwares for fluid flow study and fluid structural interaction analysis. The paper is also introducing the concept of a flow slurry loop that is designed to lift the cutting particles to the surface for mineralisation analysis. The controlling parameters of the cuttings transportation are the particle?s physical properties such as size, density, concentration and shape, as well as the rheological properties of the carrying fluid, drilled hole angle, as well as the fluid flow rate and flow dynamics within the annulus gap between the coiled tube and drilled hole. Such parameters are addressed via experimental work as well as numerical analysis. The paper is also presenting the selection and testing procedure of the material type for the coiled tube string. The tube needs to be light in weight for overall rig weight and its transportability. The tube is also required to drill several dozens of investigation holes before failing due to fatigue. A fatigue bending machine is designed to test the endurance limit of candidate materials for coiled tube strings and a performance index methodology is followed for material selection of the optimum material. The coiled tube rig is designed to be light in weight for transportation and relocation. It is also required to speed the drilling operation with the minimum footprint and reclaim the drilled rock particles for mineral composition analysis at the surface.

Aug 1, 2013

By C. A. Morais, L. V. Resende

"The technological development observed in recent years has stimulated the application of rare earth (RE) elements. Amongst their various applications it is well worth mentioning their use in electronics, superconductors, nuclear medicine, as well as in special inks - as those used in radar invisible airplanes. TV and computer monitor screens present as coating a powder containing some rare earth elements, mainly Europium and Yttrium. The recovery of the RE elements from electronic scrap is extremely important as the economic and environmental issues are concerned. This paper describes the study of the Eu and Y recovery from e-scraps. The first step of the process was the leaching of the powder obtained by manually scraping the inside surface of the screen. After the optimization of the leaching, the dissolution of Eu and Y was higher than 98 w/t% and a pregnant sulfuric liquor containing 11.9 g L-1 Y and 0.72 g L-1 Eu was obtained. The second step was the separation of the metals found in the liquor by the solvent extraction technique. The separation of Eu and Y was carried out in a counter current circuit compound of 3 extraction stages, 7 scrubbing stages and 15 stripping stages. DEHPA was used as the extractant, whereas a diluted sulfuric acid solution was applied as scrubbing agent and a hydrochloric acid solution at high concentration was used as the stripping agent.INTRODUCTIONThe rare earths (RE) are a moderately abundant group of 17 elements composed of lanthanides, scandium and yttrium. Amongst the RE, promethium (Pm) is extremely rare, however several of the RE elements are not very rare and occur dispersed in a variety of forms (Greenwood & Earnshaw, 1984; Tyler, 2004).The innumerable applications of the RE elements are based on their particular properties, mainly their spectroscopic and magnetic properties (Martins & Isolani, 2005). The technological development observed in recent years has stimulated the application of rare earth (RE) elements. They have been used in agriculture, electronics, superconductors, nuclear medicine, automobile industry, special inks – as those used in radar invisible airplanes, X-ray screens, high intensity mercury vapour light bulbs, neutron scintilators, charged-particle detectors and optical memory reading systems (Maestro & Huguenin, 1995; Nagaosa & Binghua, 1997; Sánchez et al., 1999)."

Jan 1, 2012

By A. S. Nortjé

At South Deep Gold Mine longhole stopes are backfilled using a cemented Cyclone Classified Tailings in its hydraulic state. The need to contain the hydraulic fill until cured requires a barricade. Due to the massive size of the stopes, the tailings can exert enormous forces on any such barricade. Barricades have long been in use, but recent failures in Australia and the large rate of filling required at South Deep solicited a robust design. A robust design must examine all foreseeable failures and the barricade must be able to resist all expected and, within limits, unexpected loads. The design should also be simple to construct and cost effective, limiting the impact of construction errors and unnecessary delays to production.

May 1, 2007

By Fatemeh Saeidi, Luis Marcelo Tavares, Malcolm Powell, Mohsen Yahyaei

"Understanding a single breakage mechanism is fundamental to the development of breakage testing techniques appropriate for mechanistic modelling of any breakage equipment. In the light of this insight, it is also possible to compare any two breakage events in a mechanistic manner. This paper presents a new method to compare breakage mechanisms of two-point impact with compression, different in their applied strain rates. This approach regards a single breakage event as a process affected by three sub-processes; first fracture, capture and spatial distribution of fragments. Spatial distribution is influenced by the kinetic energy of fragments and their brittleness. Using this methodology allows us to examine how each sub-process is influenced by applied strain rate and its impacts on progeny size distribution. For this purpose, two rock types of widely different strength, magnetite and silicate, were tested at various energy levels using the impact and compression mechanisms. To isolate the effect of spatial distribution of fragments, particles were forced to remain in the breakage zone. In this condition, similar progenies were generated from compression and impact mechanisms at similar energy levels. However, allowing natural distribution of fragments, coarser progeny was produced from compression of silicate. Additionally, using this approach provides a physical meaning and explanation for rock strength parameters such as A×b in the t10-Ecs relationship. INTRODUCTIONComminution models are rapidly progressing toward a destination that enables us to explain the complete physics of a breakage process as well as the properties of the ores. Eventually, they will be able to take into consideration the micro-events that take place during the comminution process (Bourgeois and Banini, 2002). Thus, considerable efforts have been made in the last few years in the area of ore breakage characterisation to comprehend and unlock a single breakage process that has been treated as a black box event in the majority of conventional methods. In this paper, an attempt is made to explain the effect of applied strain rate on the breakage properties of rock by using the knowledge that has been gained by understanding a breakage event. This is particularly important due to its application for various comminution devices that operate within a relatively broad range of speed."

Jan 1, 2016

By John C. Leighton, C. O. Brawner, Doug Stewart

"Despite the availability of established, sophisticated methods for planning and designing stable slopes in rock, comparatively little attention is usually paid to the problems of carrying out the excavation. Blasting should be carefully planned to obtain optimum fragmentation as well as steep, stable working and final pit walls. The principal difficulty facing a blast designer is the lack of prior information about the many critical blasting characteristics of the rock mass. The common practise of trial-and-error lasting will eventually lead to a suitable program, but must be repeated time after time in variable geology. This frequently results in many blast-damaged slopes. Recent research indicates that monitoring drill performance will yield a Rock Quality Index which correlates to a Powder Factor value. The drilling can provide a continual supply of data, reflecting changes in the rock mass which enables the selection of an economical powder factor.IntroductionWhen planning to excavate a large-scale rock slope, engineer s will generally spend considerable effort to produce a safe, feasible and economical design. Much time will usually be spent on the field map ping, &apos;structural geologic studies, surface and subsurface hydrology, determination of strengths and effective friction angles of discontinuities, and finally checking stability with the aid of mathematical and analytical models. If the rock cut is to be along a transportation corridor, the prime justification for this time and effort is to produce a clean, stable slope which will be safe for those travelling or working beneath it. For the walls of an open-pit mine, there is the additional economic incentive to maintain the steepest stable slope angle for the minimum stripping ratio (Stewart and Kennedy)."

Jan 1, 1982

By J. R. Rodda

Stainless steels are widely used to handle concentrated sulphuric acid (H2SO4) solutions produced in the manufacturing process, The majority of corrosion rate data published for stainless steel in product acid conditions is typically complied in tables or in iso-corrosion diagrams (iso-corrosion rates plotted as a function of temperature and H2SO4 concentration), without any reported consideration as to the accuracy and relevance of the method used to obtain the data, Given the characteristic potential cycling associated with the active-passive corrosion behaviour exhibited by stainless steel in hot, concentrated H2SO4, weight loss is considered to be a more reliable method than electrochemical measurements to measure corrosion rates, Consequently, an effort is made herein to demonstrate the accuracy and relevance of weight loss to determine laboratory corrosion rates in product acid conditions.

Jan 1, 2010

By Martin Lebeuf

The phenomena occurring in the cathode and at the cathode surface of aluminum electrolysis cells are very important in regards to cathode voltage drop and cathode wear. In the current study, laboratory-scale aluminum electrolysis cell cathodes were analyzed by X-ray microtomography. This technique allows an excellent visualization of the distribution of different substances, if their respective X-ray attenuation coefficients are different enough. In the current case, the important difference in the mean atomic number between cryolitic bath and graphitic carbon results in good contrasts. The volumetric bath penetration profile, porosity and impurities distribution in the cathode were thus obtained. Furthermore, metallic impurities and bath heterogeneities were observed at the cathode surface. Observations were also made with Scanning Electron Microscopy - Energy Dispersive Spectroscopy (SEM-EDS).

Jan 1, 2011

By Magnus Evertsson, Johannes Quist

HPGRs have since introduced in the 1980s (Kellerwessel, 1993; Schönert, 1988), now become integral comminution units at several minerals processing plants around the world. Even though a lot of the initial issues concerning performance, availability and wear have been addressed and solved there are still phenomena and aspects which can be improved and understood further. Schönert and Sander (2002) presented experimental results and a mechanistic model including the internal force dynamics between the rollers and the compacted bed. They derived expressions for the pressure distribution involving most of the influencing terms and effects. However, in order to solve the differential equations several of the terms vanish by assumptions. The Schönert and Sander model reflects the experimental data in many aspects but the predicted shear force distinctly deviates from the experimental results at the angular position of the peak pressure level. This finding suggests that the particle to particle interaction and breakage process in the different zones seen in Figure 1 are complex and difficult to model using analytical models. A numerical modelling approach using DEM does not require the same amount of assumptions and simplifications of boundary conditions. Hence such modelling may provide further knowledge and vital understanding. In this paper the breakage process is simulated in order to investigate the shear slip behaviour and how it relates to different operating variables. A laboratory scale HPGR corresponding to the experimental setup used by Schönert (2002) have been modelled in EDEM (DEM-Solutions). The bonded particle model (BPM) is used for modelling quartz particles (Potyondy, 2004). The breakage model strength parameters are calibrated against interparticle breakage experiments in an Instron 400RD compression device. The contact model parameters are calibrated using calibration methods developed by Quist (2015). The floating roller dynamics are modelled using a spring-damper system. Results present insights regarding the interparticle slip behaviour as well as the frictional tangential force distribution on the rollers. The simulated roller pressure distribution shows good correspondence with previously reported findings in the literature.

Jan 1, 2016

By I. Lackey

In 2004, Zinifex Budel Zink commenced testing with the objective to increase the precipitation of aluminium in the iron purification stage of its hydrometallurgical zinc circuit, without the use of expensive reagents. Findings from the literature applied to the leach circuit at Zinifex Budel Zink demonstrated that aluminium removal from the leach circuit could be increased by lowering the ferric concentration and acidity in the vessels where jarosite precipitation occurs. An associated increase in copper precipitation was mitigated by limiting the extent to which the ferric concentration was lowered in the vessels where jarosite forms and lowering the ratio of copper to aluminium in the solutions entering these vessels.

Jan 1, 2006

By Kirsten Corin, Margreth Tadie, Cyril O’Connor, Jenny Wiese, Wonder Chimonyo

"Relating flotation performance to the electrochemical characteristics of a pulp remains a complex issue both in fundamental research and in practice. For example, in the case of thiol collectors different Eh values can result in the formation of the dimer or the metal thiolate which may or may not enhance the hydrophobicity of the mineral. Reducing or oxidizing conditions in a flotation system, viz. changing the Eh value, are usually manipulated to achieve an optimum flotation response by the control of pH and dissolved oxygen levels in the system. It is also possible to vary the potential by the addition of modifiers such as sodium hydrosulphide (NaHS), sodium hypochlorite (NaClO) or hydrogen peroxide (H2O2). The objective of the present study was to investigate the effect of the addition of the oxidising agents, NaClO and H2O2, on valuable mineral recoveries and grades in the flotation of sulphides from a PGM bearing Merensky ore. Batch flotation tests were conducted at pH 9.2, the natural pH of the system, in the absence and presence of a xanthate collector and Eh modifiers, viz. NaClO or H2O2. Most importantly in this way it was possible to vary Eh at constant pH and DO levels. The results indicate that in the absence or presence of xanthate the addition of H2O2 reduced both the recovery and grade of copper and nickel. In the absence of xanthate, the addition of NaClO improved the recovery of copper slightly and both the recovery and grade of nickel significantly, but in the presence of xanthate NaClO addition resulted in unchanged copper recovery and grade, but those of nickel were reduced. Based on anecdotal evidence that the addition of trace amounts of a potential modifier could improve flotation performance further tests were conducted the results of which suggest improved flotation performance.INTRODUCTIONIn the Merensky Reef, platinum group minerals (PGM) are commonly associated with base metal sulphides (BMS) and this has an effect on the way in which these minerals can be concentrated by flotation (Vermaak, Venter & Pistorius, 2004; Wiese, Harris & Bradshaw, 2005; Schouwstra, Kinloch & Lee., 2000). A major problem stemming from this association has been reported to be the loss of valuable minerals (PGM) associated with the loss of BMS (Wiese et al., 2005) during flotation. Shackleton (2007) suggested that PGMs behave in a similar manner to sulphides during flotation. Therefore, in order to recover the PGM, base metals are targeted. There is thus a need to investigate ways to improve the flotation performance of the sulphide minerals. The electrochemistry of the flotation of sulphide minerals has been studied for over half a century and there is consensus that sulphide minerals float only under a suitable redox environment (Heyes & Trahar 1979). This implies that reducing and oxidizing conditions during flotation of ores such as Merensky can be manipulated/varied to achieve an optimum flotation response.During flotation, sulphide minerals interact with thiol collectors in an electrochemical reaction to form hydrophobic species at the mineral surface (Finkelstein & Goold 1972; Rand & Woods 1984). The sulphide minerals are semiconductors and their interaction with collectors involves transfer of electrons. As such, a potential difference results which is responsible for driving electrons between reacting species (Fuerstenau, Jameson & Yoon, 2007). The magnitude of the potential difference affects the relative energies of charge carriers (electrons) at the mineral/solution interface hence controlling the direction and rate of charge transfer or rate of reaction (Bard & Faulkner, 2001). In a mixed mineral system the mineral/solution interface potentials account for the mixed potential which is critical to the process of flotation (Chander, 2003; Woods, 2003)."

Jan 1, 2016