Search Documents

By J. M. Bowen, P. Wemyss

"Gold losses to natural carbonaceous matter during cyanide leaching have been investigated for over a century. The variation in the severity of the problem from one ore to another has led to a range of different processes being implemented at different mine sites. Most commercial options utilise one or more of the following processes: roasting, carbon pre-flotation, organic blinding, CIL, chlorine passivation, pressure oxidation, biological passivation, elevated temperature CIL, RIL and thiosulfate. This paper provides a background to identify the most appropriate process or combination of processes for a particular ore. It also presents information on how these processes may be implemented, drawing on information in the literature and from current or recent applications at operations such as the following: Stawell, Kumtor, Penjom, Twin Creeks, Macraes Flat, Kittilä, Fosterville, Inata, Carlin, Goldstrike, and Jerritt Canyon. Various process options have been dismissed, or deemed unsuccessful due to limited knowledge available on the strengths and weaknesses of the different options and their implementation. The authors have collectively been involved in flowsheet development and project implementation in four commercial plants that have treated preg-robbing ores.INTRODUCTION Cyanide processing has been the mainstay of gold recovery for well over a century. It is generally a very effective process with over 90% recovery on free milling ores, but complex and refractory ores may only give 0–50% recovery with conventional processing (La Brooy et al., 1994). People have written about gold losses to natural carbonaceous matter during cyanidation for over a century e.g. Feldtmann, (1915). The earliest reports related to African operations, but the issue has since been reported in Canada, North and South America, Australia, Russia and China. The phenomenon is usually referred to as ‘preg-robbing’ dating from the times before the use of granular activated carbon for gold recovery, when gold was lost from the pregnant solution before it could be separated from the leach solids and recovered by cementation. Many excellent reviews have been published e.g. Dunn et al. (2013), summarising the options considered and where they have been applied commercially."

Jan 1, 2017

By J. A. Hudson

"The paper begins with a brief summary of Professor Müller’s formation of the ISRM and the contents of the previous six Müller lectures with their emphases on rock fractures. The geological origin of fractures is described via a deformational spectrum diagram and a matrix characterising the consequences of a sequence of superimposed deformational events. The different fracture frequencies encountered along lines in all directions through a fractured rock mass are explained. The value of computer modelling and simulation is demonstrated through an example of the effects of fracture zones on the distribution of the in situ stress field. The need to establish the validity of computer programs, i.e., that the modelling/simulation, does actually represent the rock reality, is discussed with reference to the work of the DECOVALEX project. Finally, examples are given of the effects of rock fractures on engineering design and construction, from pre-split blasting to caverns.INTRODUCTIONIt is a great honour to have been chosen as the recipient of the ISRM 7th Müller Award and I am grateful to the representatives of the International Society for Rock Mechanics (ISRM) National Groups who voted for me. In addition, I am especially pleased because my working life in rock mechanics and rock engineering has been devoted to understanding the geometry and mechanical properties of rock fractures and rock masses—which were the key subjects that Professor Müller promoted. In the ISRM 50th Anniversary Commemorative Book, Hudson and Lamas (2012), Professor Charles Fairhurst notes that on 24 May 1962, i.e., the day before the constitutional meeting of the ISRM took place in Salzburg, a reporter asked Professor Müller, “Do we know the strength of rock?”, to which Professor Müller replied, “For rock tested in the laboratory, yes. For a rock mass, no. This is what we need to determine. This is why we need an International Society for Rock Mechanics”. Also, in his Opening Address at the 1st ISRM Congress in Lisbon, Professor Müller, as the then ISRM President stated,“Many experts agree with me that discontinuity and anisotropy are the most characteristic properties of the material rock and that the properties of jointed media depend much more upon the fabrics bond of the unit rock block system than upon the rock material. Therefore any theoretical investigation of that material has to go its own ways, in the same way as the construction material of soils years ago suggested to soil mechanics its own methods, which differ greatly from the way of thinking of technical mechanics”."

Jan 1, 2015

By George F. Crocker

Introduction The Helen mine and the Victoria mine of Algoma Ore Properties, Limited, in the Michipicoten district, Ontario, are 120 miles north of Sault Ste. Marie, on the north shore of lake Superior. They are on the Algoma Central railway between Hawk Junction and Michipicoten Harbour. Between them, these mines have produced 10,757,113 tons of iron ore. From 1900 to 1918, 2,823,369 gross tons of brown ore was shipped, and from 1939 to the end of 1949, 7,933,744 tons of siderite was produced from the open-pit operations and underground development. The finished product, known as 'Algoma sinter', is shipped to blast furnaces both in Canada and the United States. The iron-ore bodies are a part of a tabular shaped area of iron formation that extends over a length of more than 10,000 feet and has maximum width of 1,000 feet. The two siderite orebodies, known as the Helen and Victoria, are separated by two diabase dykes. The Helen orebody is 1,600 feet long with a maximum width of 250 feet and the Victoria is 1,200 feet long with a width comparable to the Helen. These orebodies are considered to be a replacement of the original rock by iron carbonate. The introduction of the iron-1bearing material probably occurred after the development of the major folded structures. The open-pit mining of siderite started in the Helen ore body in 1939 and continued until 1945. During this period, 3,853,395 tons of ore was mined. Open-pit mining started in the Victoria body in 1946 and is still being carried on. Underground development commenced in September, 1947. Diamond drilling and surface sampling had shown the Helen deposit to average 35.61 per cent Fe and 7.28 per cent SiO2, and the Vi.otoria deposit 33.73 per cent Fe and 10347 per cent SiO2?

Jan 1, 1950

By I. B. Lambert

The guide has been developed by officials from resources and environment agencies in the Australian Government and the South Australian and Northern Territory Governments. It elaborates on the Australian Government?s policy that new uranium mines are to be approved subject to world best practice environmental and safety standards. The guide outlines the best practice principles and approaches that apply generally to mining in Australia, before giving more detailed consideration to best practice environmental protection and regulation for ISR mining.

Aug 1, 2010

By V. G. Papangelakis, S. Peters

Pressure oxidation of refractory gold ores can be conducted on ores with high carbonate content using just water or water with alkaline reagents to promote fast kinetics, and suppress the formation of elemental sulphur and CO2. In this work, a fundamental study was conducted to explore the silica-pyrite interaction in the presence of calcium and sodium carbonate. It was found that an alkaline environment increases the pyrite decomposition kinetics on one hand, but on the other dissolves silica, which encapsulates the dissolving pyrite thus hindering ultimately its complete decomposition.

Jan 1, 2011

By C. Piribauer, E. Feichtenhofer, A. McEneaney

"As part of a major diversification project, RHI AG, through its plant in Drogheda Ireland, has developed a Caustic Calcined Magnesium Oxide (CCM) for use in the Cobalt (Co) & Nickel (Ni) hydrometallurgical extraction industry. In the course of the project, the company investigated the chemical and physical properties of a number of different Magnesia’s used in Co & Ni hydrometallurgy applications and has been able to determine the important parameters for a successful Magnesia for this application. A number of live plant trials have confirmed the results of this testwork and the company is now proceeding to produce this product in commercial quantities at Premier Periclase Ltd., the RHI AG plant in Drogheda, Ireland. This paper will outline the development work conducted by the company and highlight the important chemical and physical properties that make a successful CCM. Much of the research was conducted at the RHI Technology Centre in Leoben, Austria. In addition, a number of external laboratory studies were conducted on behalf of RHI AG. The result of this work has allowed the company to develop a Magnesia product with optimised properties for use in the Cobalt and Nickel hydrometallurgical extraction process.INTRODUCTION Premier Periclase is part of RHI AG, a globally operating supplier of refractory products, systems and services, headquartered in Vienna, Austria. The company produces Magnesia from seawater at its plant in Drogheda, Ireland. While the main focus is on production of refractory grade Dead Burned Magnesia for the steel industry, the plant also produces a number of different grades of Caustic Calcined Magnesia as well as Magnesium Hydroxide products. As part of a major project to diversify the company’s product base, the use of CCM in the Cobalt (Co) & Nickel (Ni) hydrometallurgical extraction industry was investigated. One of the company’s highly reactive grades of Caustic Calcined Magnesia was found to be particularly suitable for this application. In an effort to understand what makes a successful Magnesia for hydrometallurgy the chemical and physical properties of different Magnesia’s used in Co & Ni hydrometallurgy were investigated. This paper and conference presentation outlines the findings of this process."

Jan 1, 2017

By Robert Yobou, Jacques Naho, Benjamin A. Allou, Jacques Carignan, Huan-Zhang Lu, Jayanta Guha, Koffi Pothin

"Résumé - Les seules productions de columbo-tantalite en Côte d'Ivoire sont effectuées dans les éluvions, colluvions et alluvions d'Issia, au Centre-Ouest de la Côte d'Ivoire. Même si un lien direct avec les roches granitiques est suspecté, aucune attention particulière n'a été accordée à l'étude de la minéralisation primaire en relation avec l'évolution de ces granites et des pegmatites associées. Ces granites, qui sont en intrusion dans les roches sédimentaires du Protérozoïque inférieur, comprennent: le granite orienté à deux micas (type Lobo), le granite orienté à muscovite dominante (type Bitapia) et le granite porphyroïde non orienté à muscovite dominante (type Issia). Les résultats de cette étude indiquent que les pegmatites à Nb-Ta-Be-Li sont liées au granite de type Issia. Les observations de terrain et les analyses sur roche totale montrent que: (1) les trois principaux granites de la région sont de type-S et peralumineux dans leur composition, (2) ils ont été formés pendant la période tardi- à post-Éburnéenne, (3) le granite de type Issia fut le dernier à se former.Les pegmatites liées au granite de type Issia ont été classées en quatre types : A- pegmatites stériles; B- pegmatites à Be; C- pegmatites zonées à Nb-Ta-Be; et D- pegmatites zonées à Be-Nb-Ta-Li. Les pegmatites zonées comprennent les zones suivantes: I- zone à aplite; II- zone graphique; III- zone à albite, microcline, béryl et columbo-tantalite; IV- zone à microcline massive; V- zone à quartztourmaline. Ces pegmatites présentent une zone d'altération métasomatique externe.La minéralisation de Ta, Nb, et Be est liée à la zone III des pegmatites de types C et D, la minéralisation de Li est associée aux greisens qui peuvent être observés n'importe où dans les pegmatites de type D. Les données de terrain et de laboratoire indiquent que le granite de type Issia est la roche parentale des pegmatites à éléments rares de la région. Les pegmatites minéralisées sont distribuées seulement autour du granite de type Issia et les patrons des terres rares des granites et ceux des pegmatites à éléments rares sont très similaires. Les analyses de la composition totale montrent un lien génétique entre le granite de type Issia et les pegmatites à éléments rares. Il est suggéré que les pegmatites ont été formées durant le transport et la cristallisation fractionnée du magma. Les éléments rares sont restés dans le liquide résiduel jusqu'à ce que les conditions favorables à leur précipitation soient atteintes.L'établissement de ce lien génétique ouvre des voies pour des nouvelles stratégies d'exploration."

Jan 1, 2005

By S. E. Jackson, L. J. Cabri

Quantitative determination of gold at sub-ppm concentrations in sulphide minerals is an important component of deportment studies for sulphide-gold deposits. Laser Ablation Inductively Coupled Mass Spectrometry (LA-ICP-MS) analysis is preferred for this application because it rapidly and cost-effectively provides spatially resolved (<20 pm), low ppb concentration data for gold and other elements in mineral grains. Recent advances in LA-ICP-MS analysis include the development and application of elemental mapping. Raw signals from multiple line scans or lines-of-spots are deconvoluted and calibrated to generate elemental maps which provide detailed information on spatial variations of gold and other elements within and between grains.

Jan 1, 2011

By J. Palarski

In the Polish coal mining industry, the use of mine waste in underground backfill has been the most common means of providing ground support to minimize surface subsidence, increasing extraction ratios, and reducing the quantity of waste for surface disposal. Over the last decade attention has been focused on the use of different waste as filling material of underground workings and grouting of roof fall rocks in caving area. In the paper, a brief history of the development of fill technology in Polish coal mining industry is presented. Next, the paper discusses various criteria that should be taken under consideration in the preparation process of a fill slurry and grout, fill distribution systems, mining geometry and placement methods. Moreover, in the paper evaluation of the potential of utilizing coarse and fine waste as a resource material in the production of a backfill slurry and grout for filling and injection in abandoned mines is presented.

May 1, 2007

By R. D. Hossack

"The selection of a site for plant facilities is a function of several factors and has as its objective the maximization of profits, given fixed markets and sources of raw material locations. In practice there are several sites, any one of which or a combination of two or more would be suitable to meet the basic requirements of source of supply of raw material and labour and still fulfill market demands. The model used to select the optimum profit combination utilizes both computer programs and traditional financial analysis techniques. Of the three computer programs used in the mode), one is a linear program and another is a transportation simulator. Basic cost and price data are required. In examining costs, three levels are used: (a) distribution costs of raw material to the plant and finished goods to the market; (b) direct production costs at the plant, such as labour and locally supplied material; and (c) capital and overhead costs at the plant, such as construction costs, taxes, insurance, and federal and provincial cost allowances. The direct costs generally depend on the scale of operations, so that a large plant in one location may have a lower unit cost than two smaller plants. This, of course, must be balanced against distribution costs. In examining profit, it is necessary to think in terms of the price and volume of sales at each of the market locations. Given basic data and relationships, the model can be used to optimally locate production facilities or, alter-natively, optimally structure a transportation network given existing locations of plants and markets. It is dynamic to the extent that it can react to changes in volume, price and cost to optimally locate an additional plant, the expansion of existing plants, the shutting down or cutting back of plants, or the restructuring of distribution networks."

Jan 1, 1970

By T. F. Pugsley, D. Gignac

"The historical background to the project dates back to the mid-30s with the discovery of surface sulphide showings in the Cape Smith-Wakeham Bay ultramafic belt. In the mid1950s, orderly exploration commenced with an extensive work program by Asarco, INCO, Lemoine, Falconbridge and Raglan Nickel Mines Ltd. on exploration permits. In 1966, Falconbridge and Raglan Nickel Mines interests merged. Extensive exploration, drilling, under- ground delineation of the Donaldson orebody and the construction of basic infrastructure such as camps, airfield, road links from Douglas Harbour to Donaldson and Katinniq, a distance of 60 km, were completed.Production project design at that time consisted of plans for a 50 000 mt per year nickel mining and concentrating operation, including a 2000 person community and smelter at Douglas Harbour. These plans unravelled in the mid-70s due to high capital costs, poor nickel market conditions and the realization that the Raglan orebodies were not large enough to economically support the construction of green field smelter and refinery facilities for processing Raglan production. Nickel market conditions in the late 70s and early 80swere generally poor, resulting in further delays on production plans.While recognizing the very high potential to discover increased tonnages of high grade(3% Ni) in excess of 20 million tonnes, the project was deferred into the late 80s when a serious re-evaluation of exploration potential occurred and the requirement to prove up additional reserves resulted in an underground exploration program at Katinniq covering the period 1990-1992."

Jan 1, 1996

By K. L. Azinger

Successful relationships between mining companies and local stakeholders are now an essential part of the social contract of “doing business” (Prescott, 1995). The methodology presented in this paper is designed to assist mining companies in understanding and building relationships with diverse stakeholder groups. The methodology starts by recognizing that mining projects have a natural life cycle which can be used to identify when new external affairs strategies are required. In designing an external affairs strategy, the first step is to set objectives that are compatible with the overall objectives of the mining project. The management team then identifies the main stakeholder groups and seeks to understand the priorities and inter-relationships of the individual stakeholders. The result of this stakeholder analysis is an understanding of the Degrees of Influence of each of the stakeholder groups along with a relationship map which illustrates the strong interactions between stakeholders. The company is then prepared to take a proactive approach to building relationships with the primary stakeholders. This methodology was developed by BHP to assist with the federal government environmental approval process for the development of Canada’s first diamond mine. BHP has successfully used the methodology in three different phases of the NWT Diamonds Project and is now applying the methodology to mining and development projects around the world.

Jan 1, 1998

By Marko Lampi, Ross Andrews, Jouni Pihlasalo, Robert Matusewicz

With widespread discussion on reducing carbon, sulphur and other emissions, use of sustainable energy sources and the pivotal circular economy theme, consideration needs to be given to pyrometallurgical operations broadly and more specifically, non-ferrous metallurgy. These themes present a number of challenges in terms of current operations and the view of processing the metals which are largely taken for granted in day to day living. This paper considers how these themes will impact pyrometallurgical flowsheets using the non-ferrous base metals as an example. It will examine the flowsheet chain to offer views on the boundaries of flowsheet optimization and the application of available tools to meet these future goals and challenges. INTRODUCTION The themes of reducing footprint through lowered CO2, S and other emissions, together with process sustainability (e.g. lowered energy) and links to the circular economy are well known to everyone in the metals industries. Whether it is reducing greenhouse gas emissions or analysing the importance of metals recycling in the circular economy, all these themes carry with them the fundamental premise of any change being considered; how can you best optimize a system to meet your aims? Of course, this depends on the available tools and the approach used for optimisation.

Jan 1, 2019

By A. O. Orumwense

Mill circumferential speed, the number of passes of pulp through the grinding chamber, media type, size and filling ratio were investigated in an attempt to determine how to effectively grind copper concentrates in a stirred mill. The stirred mill product fineness was enhanced to some extent by decreasing media size, high media filling, and an increased number of passes of the pulp through the grinding chamber. Shape also plays a major role in grinding media effectiveness, with spherically shaped media producing a finer size. The fineness of the product increases with increasing power consumption but the method of energy transfer is very important in energy utilization. The effect of the mill parameters on copper flotation was evaluated. Copper recovery was influenced by grinding media size, mill speed and the number of pulp passes through the grinding chamber.

Jan 1, 2006

By P. C. Lightfoot, J. M. Duke, A. J. Naldrett

"The segregation of magmatic sulphides from mafic and ultramafic silicate magmas, in many circumstances, leaves the magma with a lower-than-normal Ni/MgO ratio, which is characteristic of both lavas erupted from the magma chamber and olivine crystallizing within it. Two end members of the segregation process are discussed; i) batch segregation and ii) fractional segregation.In the former, the critical factor is the magma/sulphide ratio. Computer modelling suggests that where this ratio has been less than 1000, the magma will be recognizable as anomalously low in Ni, due to sulphide segregation, and thus a good target for exploration. In fractional segregation, the critical factors are the proportion of sulphide to silicate being segregated and the degree of fractionation.Samples believed to represent the liquid portion of komatiitic lava f lows from a series of unmineralized sequences in the Abitibi greenstone belt, Canada. Belingwe belt, Zimbabwe, and Barberton Mountainland, South Africa coincide with the sulphide-free fractionation model. They are in marked contrast to samples from the ore-bearing districts of Kambalda and Scotia. Western Australia in which distinct Ni depletion, corresponding to fractionation of olivine plus sulphide in a ratio of between 100 and 200:1 is recognizable. Ni-depleted olivines also mark the sulphide-bearing Dumont intrusion of the Abitibi belt.The Moxie intrusion of northern Maine has distinctly Nidepleted olivines, as does the nearby and petrologically related Katahdin body. In both of these intrusions, the composition of the olivine allows reasonable predictions to be made of the Ni tenors of sulphide showings within them. At Katahdin, the Ni depletion is so widespread that little hope is help out for the presence of economic concentrations of sulphide. At Moxie. the olivine compositions suggest that the best chance of economic sulphides lies in the southern lobe of the intrusion.Ni-depleted olivines also characterize certain rock units within intrusions of the Insizwa complex, Transkei, Southern Africa. Many millions of tonnes of Ni have apparently been removed by sulphides from these rock units, many more than are contained within the single mineralized occurrence so far identified at Waterfall Gorge."

Jan 1, 1984

By L. Tong, D. Robinson

"The stirred milling of nickel laterites offers possibilities for improving liberation and selective size reduction of soft nickel-bearing minerals in laterites. Batch grinding tests were performed in a netzsch™ lME4 stirred mill on siliceous goethitic, goethitic, and saprolitic nickel laterites. Tests on the -2,000 µm sample displayed the effects of selective comminution. The -38 µm product of grinding the -2,000/+38 µm feed confirmed the effects of selective grinding and nickel upgrading. Size classification followed by stirred milling is recommended for nickel upgrading. The energy requirement in the stirred milling was also investigated.RÉSUMÉ le broyage par billes de latérites comportant du nickel offre des possibilités d’amélioration de la libération et de la réduction sélective de la taille des minéraux nickélifères tendres dans les latérites. Des essais de broyage en vrac ont été effectués dans un broyeur à billes netzschMD lME4 sur des latérites nickélifères à goethite siliceuse, à goethite et saprolitiques. Des essais sur l’échantillon -2000 µm présentaient des effets d’une comminution sélective. le produit -38 µm de l’alimentation -2000/+38 µm confirme les effets d’un broyage sélectif et du rehaussement de la teneur en nickel. Pour améliorer la teneur en nickel, il est recommandé de classifier le minerai en fonction de sa granulométrie, puis d’effectuer un broyage à billes. l’énergie requise pour le broyage à billes a aussi été étudié."

Jan 1, 2015

By G. P. Demopoulos

The solubilities of calcium sulfate in HCl-CaC1z-H20 solutions up to 100°C were successfully modelled with the aid of OLI software after bringing proper modification to it. Modelling, more specifically, was carried out with the help of the Environmental Simulation Program, V-6.6.0.4 (www.olisystems.com). New model parameters were obtained by regressing the solubility data. A private databank was established by adding the newly defined model parameters and the calcium sulfate hemihydrate phase that is not included in the original OLI database. The McGill-modified OLI software was successfully applied not only to modelling solubilities but also the transformation of the various CaS04 phases, namely dihydrate, hemihydrate and anhydrite. In this paper, the modelling methodology will be discussed along with a comparison of the capabilities of the newly developed model vs the original OLI model.

Jan 1, 2005

By T. Lamb

There are many honor stories about aluminum in the marine environment and many are not based on facts, so they are myths. Myths must be addressed before progress can be made. This paper attempts to dispel the myths and state the facts. A common perception is that aluminum ships cost significantly more than steel ships. This paper illustrates that even though the cost of the aluminum structure is over 50% more than the steel structure, an "equivalent" aluminum naval ship can be built within 7% of the acquisition price of a steel ship. This is possible because of the cascading benefits of the aluminum ship&apos;s significantly lighter weight. Aluminum ships also have a life-cycle cost advantage over steel ships because of reduced maintenance and fuel cost savings.

Jan 1, 2011

Stellite-6 coatings were formulated on two Ni-base superalloys, namely Superni 75 and Superni 600, by a shrouded plasma-spray process, and the oxidation behaviour of these coatings has been investigated in air and in an aggressive environment of Na2SO4- 60%V2O5. Accelerated oxidation tests were conducted in a silicon-carbide tube furnace under cyclic conditions at an elevated temperature of 900°C for 50 cycles. Each cycle consisted of 1 h heating and 20 min cooling in air. A thermogravimetric technique was used to approximate the oxidation kinetics. The corrosion scales were characterised by XRD, SEM/EDAX and EPMA analysis. It has been observed that the coatings nearly followed the parabolic rate law of oxidation. Overall weight gain conceived in air was just 51% of that in the aggressive environment in the case of coated Superni 75, whereas in case of coated Superni 600, the cumulative weight gain in air was found to be one-third of that in the Na2SO4-60% V2O5 atmosphere. Furthermore, the coating showed very good adherence to both of the substrates during the course of air oxidation, whereas some superficial cracks were observed near the edges of the specimens during the molten salt induced oxidation. XRD analysis revealed the presence of phase-like CoO, CoCr2O4 and Cr2O3 in the oxide scales, which are reported be protective against high-temperature oxidation. The XRD results were further supported by SEM/EDAX and EPMA.

Jan 1, 2005

By S. Pauly, U. Kühn, J. Eckert, I. Kaban, G. Wiehl, F. Silze

In the present work, the effect of Ga on the wetting behavior of the Cu-rich braze filler CuGa10 (wt.%) on the steel 304L was investigated. For this, the macroscopic and microscopic effects governing the wetting of pure Ga, pure Cu and CuGa10 alloy (wt.%) on the austenitic steel were analyzed and compared. Contact angle and surface tension measurements were carried out by means of the sessile drop technique and, in addition, the phase formation at the interface was determined. Pure liquid Ga spreads on 304L, which supposedly is related to the formation of intermetallic Fe-Ga phases growing into the liquid Ga. Depending on the annealing time, FeGa3 and Fe14.5Ga12 were identified. In contrast, CuGa10 as well as pure Cu show secondary wetting on the steel surface. Especially, liquid Cu prefers to spread laterally and vertically along the grain boundaries of the steel substrate. In spite of rather similar mechanisms, CuGa10 wets 304L steel at lower rate than pure Cu above the liquidus temperature.

Jan 1, 2014