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By K Baskaran, T McKenzie

Sustainability is becoming increasingly important in the mining and mineral processing industries and must incorporate the associated waste products. Acid mine drainage (AMD) is one such by-product and is one of the most serious environmental problems facing the minerals industry today. The oxidation of sulphidic mine wastes often continues for a substantial period of time after mine closure, resulting in difficult and costly remediation and rehabilitation works. Mining companies are often reluctant to spend increasing amounts of money on waste treatment when the mine life is limited or even finished. Hence a simple, low maintenance and low-cost method of treating AMD is required. Whilst this paper does not address the issue of AMD, it does propose methods for removal of individual species from AMD with potential benefits, including raising AMD pH. A novel concept of using biosolids as a biological adsorbent, or æbiosorbentÆ, of metals from AMD is being investigated at a laboratory/pilot scale level. Biosolids are a by-product resulting from the biological treatment of wastewater, and have been previously shown to adsorb metals from aqueous solutions. This could lead to an environmentally sustainable or ægreenÆ method for treating both AMD discharges and disposing/reusing the biosolids. The result of a laboratory-scale study of the biosorption of Zn(II) is presented in this paper. Physical parameters including reaction kinetics, mixing speed and solution pH were investigated. Solution pH also rose an average of 2 pH units over the 24 hour equilibrium time û a valuable side effect when treating acid mine drainage. The outcome of the study highlights the usefulness of biosolids as a biosorbent for the removal/recovery of metal ions from acid mine drainage. A simple, low-cost treatment technology requiring low maintenance would be beneficial to the mining industry to address some issues relating to AMD and would help integrate environmental and economic considerations into sustainable environmental management.

Jan 1, 2002

In the early ages man contented himself with the use of such tools and appliances as would assist him in the enlightenment of his labours. With the advancement of science, numerous motives, with modifications and adaptations, have been introduced to enlighten labours, and in many cases have taken the place of man, but it can hardly be said that this applies to shovels, although one of the oldest implements of labour; certainly, with the introduction of the steam shovel the labours of man have been considerably reduced, but the hand shovel of today is used similarly to that of years ago.If the principle of the hand shovel has not been improved upon, it must not be suggested that the manufacturers of this article are not endeavouring to improve its quality, and the main point with which the manufacturers have to contend is the production of an article which will give a maximum of durability combined with a minimum of lightness. In order to accomplish this they must select suitable material, and subject it to such heat treatment process that will produce a shovel having a maximum of hardness and toughness without being unduly brittle, and which will withstand the excessive wear to which it is subjected.In this article an endeavour will be made to explain (a) the manufacture of shovels; (b) the defects commonly met with-the cause of same and measures which are necessary to remedy them.Before doing so a brief description will be given of the class of steel used for shovels; this is an important factor, and a steel which is admirably suitable is a plain carbon one containing approximately 55 - 70% C., and closely resembles that used for the manufacture of railway rails. This plain carbon steel is very extensively used, although at present alloy steels are being utilised to a certain extent for shovel manufacture, and with suitable heat-treatment.

Jan 1, 1926

By Laajalehto K

The basic condition necessary for flotation is hydrophobicity of the surface of the mineral to be floated. For sulphides, this condition usually requires treatment with a collector solution. The conditions for this treatment have until recently usually been chosen by the trial and error principle which has indeed been working relatively well under favourable conditions; ie for simple homogeneous ores. However, the present tendency to increasing use of complex and often relatively lean ores sets increasing requirements for the control of the flotation process. This development is the reason for the present rapid development of process control methods in flotation. In addition to the already well-established practices of pH and reagent feed controls, the importance of measuring and controlling the electrochemical potential of the ore particles to be floated is recognised in the case of sufficiently conductive minerals. In fact, the electrochemical potential seems to be the basic quantity determining the flotation behaviour of such relatively well-conducting minerals as sulphides. Since the hydrophobicity of the mineral and, hence, its flotation properties are ultimately determined by the composition and structure of its surface, information on these under different process conditions is important for design and operation of efficient flotation processes. The basic requirement set for the methods used for obtaining this information is high surface sensitivity of the method. The recent rapid development of surface characterisation has produced several methods which fulfil this requirement. Their application to the problem of characterising surfaces of mineral samples in contact with collector solution is, however, often complicated. The main reason for this is the vacuum environment necessary for the measurement. In the case of flotation experiments this means that in most of these methods the measurement cannot be made in situ, but the sample must be extracted from the liquid and subsequently evacuated in the vacuum chamber of the instrument. It is essential to carry out these steps so as to avoid to the extent possible changes in the sample surface. For the purpose of establishing whether this has been accomplished it is important to compare the results of methods operating in vacuum with some available in situ method. An optimal choice of methods seems therefore to be a combination of the available powerful vacuum methods with in situ measurements. The most usual combination seems to be X-ray photoelectron spectroscopy (XPS or ESCA), Fourier transform infrared spectroscopy (FTIR) and electrochemical measurements. This choice combines the unique possibilities for direct elemental and chemical characterisation offered by XPS (Cecile, 1985) with the in situ capability of FTIR and electrochemistry. In the XPS measurements, it is essential to apply a special sample handling technique to avoid loss or damage of some sensitive species of the collector-based layer on the mineral surface. In the following will be given some examples of the application of the XPS technique in combination with electrochemical methods of sample treatment to studies of the layer formed on sulphide substrates in ethyl xanthate (EX)

Jan 1, 1993

By R M. Hough, G Duclaux, M A. Pearce, M F. Gazley

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Microcharacterisation, such as that described in this paper, provides understanding of a mineral system at multiple scales, and understanding microscale variations is the key to understanding the large-scale variations in a mineral system. More than 50 high-grade lode samples from across Plutonic Gold Mine (Plutonic), Marymia Inlier, Western Australia were analysed by a variety of techniques, including micro X-ray fluorescence (µXRF) mapping, micro X-ray computed tomography (µCT), scanning electron microscopy (SEM), field emission gun SEM, electron back-scatter detector (EBSD), proton-induced X-ray emission microprobe and synchrotron XRF mapping. These data demonstrate that competency contrasts are the key to governing the location of Au mineralisation at Plutonic. Micro CT imaging of high-grade samples shows the Au filling in voids and pore-space in the rock, after having travelled along more permeable layers and already existing or reaction-induced pores formed during hydrothermal circulation. Using 3D visualisation, the Au is seen to form a connected network that appears undisturbed at the scale of the samples, and a high-grade Au deposition event was one of the last events to affect the rock. This interpretation is supported by SEM analyses on high-grade samples that reveal calc-silicate (epidote-clinozoisite) alteration that is not present in lower Au grade samples, which are typically dominated by potassic alteration, and that sulfides are typically less abundant close to the Au. The replacement of biotite by chlorite is an alteration associated with the high-grade Au-mineralising fluid. Gold is coarsest where Au particles are located on the margins of minerals, typically sulfide and quartz grains, suggesting the importance of rheological contrast at the microscale. Furthermore, EBSD data reveals that Au is undeformed and overprints peak metamorphic and retrograde minerals. Data confirm recent deposit-scale observations, suggesting that deposition of high-grade, visible Au was related to a hydrothermal fluid circulation event late in the geological history of Plutonic.CITATION:Gazley, M F, Duclaux, G, Fisher, L A, Hough, R M and Pearce, M A, 2015. High-resolution characterisation of gold mineralisation at Plutonic Gold Mine, Western Australia – evidence for the late-stage deposition of high-grade gold , in Proceedings PACRIM 2015 Congress, pp 51–58 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By M DellÆAmico, K Vining

The iron blast furnace is the most widely used and efficient producer of liquid iron; however, emissions from sintering and coking cause environmental pressure for the integrated steel works. The combustion of coke fines (breeze) during sintering contributes to greenhouse gases (GHG) (eg carbon dioxide) and is a source of SOx and NOx emissions. Coking capacity is also constrained by environmental concerns and economic factors, such as increased coke consumption, and short supply is leading to high prices. Improved coking practices, which result in reduced production of fines, are also contributing to the tight availability of breeze for sintering. This combination of factors presents an opportunity to consider alternatives to coke as a fuel for sintering. CSIRO Minerals has been investigating the use of wood biomass/char as a substitute for coke during sintering. Wood biomass, or char produced from it, is an attractive carbon source as carbon dioxide liberated during combustion can be sequestered back into growing biomass. It has great potential to reduce the emissions from integrated steelworks and improve their environmental acceptability. Harvested biomass/char is also a renewable and sustainable resource and can be integrated with good land management practices such as remediation of salinity affected land. Weeds, especially woody weeds, can also be used as a source of biomass for charcoal, and integrating char production with weed management can help address a pressing environmental issue in Australia. Previous reported preliminary testwork indicated that the use of Red Gum char as a replacement for coke resulted in a product sinter of comparable quality, improvements in productivity and significant reductions in SOx and NOx emissions. In the latest testwork, CSIRO has examined the properties of a range of potential charcoals, and has conducted a further series of granulation and small-scale sintering trials with them in simulated Japanese Steel Mill iron ore blends. Sinter fuels characterised and evaluated include industry sourced coke breeze, commercially available wood char and a charcoal from prickly acacia (acacia nilotica). Prickly acacia has been declared a noxious weed, is widespread in Australia, and is classified as a æWeed of National SignificanceÆ. The results presented in this paper support the notion that charcoal outperforms coke in many aspects of iron ore sintering and factoring in environmental considerations makes the switch to charcoal even more favourable.

Jan 1, 2005

By H Holmstr÷m, A Widerlund, M Lindvall

At the Kristineberg mine in northern Sweden sulfide-rich, poorly buffered tailings have been deposited in five impoundments located along a valley. The tailings area has been remediated by applying a combination of till cover and flooding. A new method that has been applied to parts of the tailings area is to raise the groundwater table to saturate the tailings. By increasing pH by liming, thereby reducing metal mobility, a water-covered downstream impoundment is functioning as a trap for metals released from the till-covered impoundments upstream. In this paper the efficiency of the system approach used at Kristineberg is evaluated. Progressive changes of water quality from groundwater in the upstream till-covered impoundments via surface streams within the pond system to the water in the flooded downstream pond and its outlet are described. The results show that the system approach used in the design of the remediation programme of the tailings works as planned. The sulfide oxidation rate has decreased in the till-covered impoundments, and, as predicted, there is an out-flush of old weathering products which will continue for at least five years before equilibrium is reached. The groundwater in the till-covered impoundments has high concentrations of Fe, S, Mg and Zn, but the concentrations of metals such as Cu, Cd and Pb are much lower than before the till cover was applied. The limed pond is an efficient metal trap, with concentrations as high as 2.76 per cent Zn and 0.28 per cent Cu in the calcite-gypsum sludge developed on the tailings. The outlet from the flooded pond, and thus from the whole mining area, releases small amounts of metals to the recipient in comparison to the amounts that are in movement within the mining area. During the period May to November, 13 kg dissolved Zn and 111 kg particulate Zn was released to the recipient, whereas a total of 27 000 kg was transported by surface water within the impoundment system during the same period. The results from Kristineberg show that when planning remediation of complex mining areas, it is useful to adopt a system approach in which different methods are used on different parts of the area along the flow path of the drainage water, whereas flooding of the downstream pond is the key to the performance of the entire system.

Jan 1, 2003

By P Commander

Western Australia is a major exporter of minerals, which places significant economic and environmental responsibility on Government and the stateÆs mining industry. Moving into the 21st century, mineral production in Western Australia is $14 billion accounting for 50 per cent of the stateÆs export income. There are over 60 large-scale mining operations distributed throughout the arid regions of the state (less than 300 mm/year rainfall). There are four key mineral provinces in arid Western Australia including the Pilbara (iron ore), Murchison (gold), Northern and Southern Goldfields (gold and nickel). These provinces have significant differences, particularly in respect to groundwater demand from mining and mineral processing, aquifer systems that are utilised, and approaches to groundwater management. The arid nature of the stateÆs interior and subsequent lack of surface water resources has required substantial groundwater resource development by the mining industry. A variety of aquifers have been explored and utilised ranging from shallow alluvium and calcrete, discrete fractured zones in bedrock, concealed palaeochannels and inland sedimentary basins. Groundwater usage by the mining industry is about 150 GL/year with most abstraction related to mine dewatering, mineral processing and dust suppression. Groundwater abstraction in Western Australia is regulated by the Water and Rivers Commission. In the Goldfields, the depletion of brackish (>2000 mg/L) and saline groundwater from storage is permissible, as mining is considered the beneficial use for groundwater which may be as much as 200 000 mg/L. In contrast, the low salinity groundwater of the Murchison and Pilbara is allocated on a sustainable basis. The role of monitoring and ongoing aquifer reassessment is crucial in water management, in evaluating the condition and performance of stressed aquifer systems. Mining operations face a variety of water resource issues ranging from insufficient availability for processing to excessive mine dewatering. These issues also change as a mine operation proceeds through its development, commonly starting with a deficiency and moving into surplus as deeper pits require more dewatering. Operating mines have to contend with three main issues: water supply, wastewater disposal and contamination of local water resources. In contrast, post closure issues are related to aquifer recovery or re-establishment of groundwater equilibrium, development of pit lakes in mine voids and isolation of waste products and associated seepage or run-off.

Jan 1, 2003

By Bogar D. V

Often dewatering of coal tailings is inhibited by the presence of clays, making it difficult to obtain a high concentration, handleable coal tailings. The net result can be a low concentration, chocolate mousse-like tailings which poses significant sedimentation problems in a tailings dam and represents a significant environmental problem. This paper examines the coal tailings from a Hunter Valley colliery where the tailings properties are influenced significantly by the presence of montmorillonite clay. The influence of the calcium ion on the rheology and sedimentation/compression behaviour of coal tailings . containing montmorillonite already dispersed in water was investigated and revealed that very little improvement in the properties is achieved through the coagulation. The preliminary investigations also indicated that the properties of the tailings were dominated by the presence of the montmorillonite clay. Thus investigations were carried out on the clay alone in water. Investigations into the effect of dispersing samples of the clay alone in water and then coagulating with calcium compared with dispersing the clay directly into calcium ion solutions at the same calcium concentration showed huge improvements in the rheology, compressibility, sedimentation rates and sediment solids concentrations for the second dispersion method, which can be called controlled dispersion. The sediment volume fraction solids improved by more than a factor of two by controlling the dispersion of the clay. The reason for the improved properties lies in the suppression of the initial swelling of the clay, which is initially in the sodium form, thus maintaining the parallel orientation of the platelets that is present before wetting. While swelling is being suppressed, ion exchange occurs with the calcium which results in permanent swelling suppression. In the uncontrolled dispersion case where swelling is uninhibited, the clay is allowed to break up and despite the powerful coagulating nature of the calcium ion, the random orientation of the high aspect ratio clay platelets inhibits effective coagulation. Results indicate that the initial electrolyte concentration of the washwater in a coal washery is the critical factor controlling the dewaterability of clay tailings and the handleability of the dewatered product rather than the actual act of coagulating with the calcium ion. The results presented are of clear practical significance and indicate how coal tailings problems where clay dominates the rheology can be improved considerably by knowledge of the surface chemistry.

Jan 1, 1995

Preparing for automated sample preparation has two facets; the need for better procedures as seen by the laboratory Manager and the approach to be adopted as envisaged by the equipment manufacturer. Both have many options and during the 1990s some at least of these options will be tried. As automation of sample preparation is only just beginning, can it be said that there is a real need for better procedures. What does automated sample preparation have to offer? Does it have real advantages or is it just a marketing tool to sell equipment?

Jan 1, 1976

The excavator selection process is quite complex due to the large number of influencing factors, many of these are variable and difficult to accurately define. The majority of mining companies prepare a tender of general specifications and suppliers will then match a product to those specifications. The mining company will then evaluate the tenders on the basis of the best available deal. In this paper, the importance of open pit excavator selection in terms of its impact on operating costs is analysed and discussed. A rigorous process for selection is then outlined.

Jan 1, 2003

The last 40 years has seen a dramatic reduction in the prevalence of pneumoconiosis through improved mining engineering associated with continuing medical surveillance of those at risk. Presently the dust particle count standard is being correlated with gravimetric dust standards. Chronic Bronchitis and Emphysema are also coal mining related diseases. Methane is the commonest of a number of coal mine gases. Oxygen deficiency symptoms may result from high gas content of mine air. The explosive nature of methane-air mixtures is well known. Mine gases will always present a potential threat to safety.

Jan 1, 1983

By Morrison R

Optimisation has two distinct applications in the concentrator ò the first is in the area of the flowsheet and the operating parameters of the various unit operations ò the second is associated with the higher levels of process control. The Plant Metallurgist is faced with a library of complex theories relating to optimisation. The practical reality of optimisation lies in a combination of steady state simulation to ensure that the process route will permit maximum productivity and an appropriate process control system which will permit achievement of the production and quality objectives.

Jan 1, 1991

In the pursuit of commercial solutions for environmental issues, individual problems are often identified, considered and resolved in isolation from other environmental matters and always at the end of the cycle û after the problem has been created. Inter-relationships are neglected if they are not seen to obviously impact on a specific problem and the issue at hand is plucked from the environmental landscape and dealt with in total isolation to all else. In a Zero Waste approach to environmental matters, all outputs are pursued as potential inputs. Industrial processes are viewed as a variation on natureÆs theme and opportunity pursued above all else. When viewed from this perspective, industry appears to have forgotten its origins. It has forgotten that it is principally about people. The juggernaut of global trade has forgotten that it is a small part of a big landscape and that its principal participants, people, cannot exist without healthy soil. Commercial activity in all parts of the world relies heavily on the ability of agriculture to produce the necessary inputs for industrial production. The care and nurturing of our soils is fundamental, not only to the survival of humanity, but also to the economic systems that support that humanity and to the industry which profits by it. Actual levels of domestic recycling in many countries around the world seldom reflect the 90 plus per cent desire to recycle recorded in surveys conducted by local authorities in almost every country. If the desire to recycle is far removed from the end result, why is it that the systems provided are so ineffective? It is obvious that what we do need is a recycling system that both engages and rewards the participant and stimulates the innate desire to support the environment. A recent trial in New South Wales, Australia, demonstrated that by giving individual households credits for recycling organic wastes, not only will contamination levels fall dramatically, but increased yields, improved soil structure, improved land values, reduced fertiliser costs and increased water use efficiency give the farmer good economic reasons for purchasing and applying quality composted product. By underpinning and securing the agricultural community, we secure the future of industry. The æCity to SoilÆ project linked the economic on-farm benefits of compost use with reduced contamination through the provision of rewards paid for by the purchase of product by the farmer.

Jan 1, 2006

Explosives have been an important tool for unlocking minearl wealth from the earth's crust for several countries. In'the past, innovation in explosives technology, spurred on by industry needs has assisted the Mining Industry to improve productivity and reduce costs. A symbolic relationship exists between Explosives and Mining. Australia has vast mineral wealth. Our Mining Industry is of major importance to the Economy., The value of mineral produc- tion in 1987 was $25 million or 10% of GDP. Australian Mining is a business depending on international markets. The Mining Industry is our leading export earner, generating 44% of all export income. 60% of mineral production is exported. About half of these minerals are extracted using explosives. Explosives rank as one of the top three consumable expenditures for a mine. For example: A major open-cut iron or coal mine can spend $6 million dollar per annum on explosives.

Jan 1, 1988

Gentlemen, you heard the good Doctor has commissioned me to make a'summary of the proceedings to date and also to close the said proceedings. It seems that over the years the business of making a summary alternates between'Mr. Pearce and myself, also I,think that w~oever is around onthe day in question 'obtains the task and apparently I drew it this, year. It is hoped you will be patient as previous experience in this capacity'indicates that the best way to proceed is to have a brief summary on each paper and then do a summary of summa~ies. This makes the approacha little cumbersome but it is felt to be fair to each author and it brings'back to the audience some recollections of what transpired at the time and they can make their own decisions, which may not necessarily agree with those of the 'sum'marisor.

Jan 1, 1983

To grow a mining company today is seen to be challenged by the reduced interest in resources companies by the financial markets, the complexity of native title and a somewhat depressed commodity cycle. However, the opportunity to grow production and sales in a mining company are as numerous as they have ever been. It is the challenge of growing significant shareholder value that is difficult. The distinction between growth in æcompany sizeÆ and growth in æshareholder valueÆ is an important distinction upon which some resource companies are now firmly focussed. The equity market/commodity market cycle can provide windows of opportunity to consolidate and expand a company for the benefit of shareholders. These benefits may not be reflected until more buoyant equity markets return but, as the cycle turns, as it surely will, those with the foresight to position themselves may be richly rewarded.

Jan 1, 2000

By W Lu, D Wang

Study of coal oxidation at low temperatures forms the basis of investigating the inherent properties of spontaneous combustion of coal. In general, the process of coal oxidation at low temperatures is very complex, involving many factors. Experiments examining the properties of oxidation and ignition of coal have been carried out. Based upon the results of these experiments, the catastrophe properties in the process of coal oxidation are analysed and the mechanism of catastrophe is proved for the ignition of coal. A folding catastrophe model is also established for the process of coal oxidation. Results obtained show that the process of coal oxidation to ignition is discontinuous, where the coal-environment system yields structure destabilisation. The system can jump from one stable attractor to another. The research results presented in this paper help to show the irregularities of coal oxidation at low temperatures and how to pursue effective control measures.

Jan 1, 2005

Mining is a global industry. The conference is a good example of this, as itÆs jointly organised by professional associations from Canada, Australia and South Africa, and has attracted speakers and delegates from around the world. I commend the organisers for their initiative. I am pleased to be asked to participate in this panel û although I would hasten to add I see myself as perhaps an informed observer rather than an expert. It wonÆt be news to most in this room that AustraliaÆs mining sector is booming. As one of the most productive and diversified mineral regions in the world, this activity is also something that has not escaped the attention of CanadaÆs largest mining companies! This means that I follow what is happening in the industry and more specifically what might be occurring here. Two-way investment between Canada and Australia stood at $9.8 billion in 2005 with Canada as the seventh largest overall investor in Australia with $8.22 billion in investments. The majority of this investment is by Canadian minerals and metals companies. In recognition of the importance of Canadian investment in this sector in Australia, I maintain close contact with our companies. By way of example, in the past two months I spent a week in Western Australia visiting Perth and meeting with companies for example, like Teck Cominco and LionOre as well as seeing various Barrick Gold operations in Kalgoorlie. I attended the opening of AlcanÆs new Asia Pacific Headquarters in Brisbane in August and just two weeks ago was in Cowal, NSW for the opening of BarrickÆs new mine there. Having met with BHP Billiton in Vancouver, IÆm equally aware of active Australian mining interests in Canada. This is not designed to indicate how active I am but rather to demonstrate the dynamism in the mining industry and the diversity of Canadian mining interests in this country and Australian interests in Canada.

Jan 1, 2006

By Takagi T, Seetharam R, Sie SH, Naito K

Tin-polymetallic vein type deposits are one of the major source of metal producers in the Circum Pacific Belt. This type of deposit is of great importance for the modem electronics and medical industries because of their high content of rare metals (especially indium and bismuth). We have studied two representatives, Tosham of India (Cu-In-Bi-Sn-W-Ag-Au), and Mount Pleasant of Canada (Zn-Cu-In-Bi-Sn-W), using proton and electron microprobes in order to delineate the distribution of medical/high-tech rare metals. The electron microprobe study showed that major indium carrier in such type of deposit are roquesite (CulnSZ), sphalerite, stannite and a Cu-Zn-Fe-In-Sn-S mineral; and that indium is incorporated in sulfides by coupled substitution like Cu + In = 2(Zn + Fe). The proton microprobe showed that indium at trace levels is also present in chalcopyrite and pyrite. In addition, zinc, copper, arsenic, antimony, selenium, tin, and bismuth are common in chalcopyrite and pyrite. Arsenopyrite contains nickel, copper, zinc, silver, tin, antimony and bismuth. In chalcopyrite and pyrite, zinc, arsenic, indium, bismuth and lead are higher in Mount Pleasant ore, but silver is higher at Tosham. Also thallium and gold were found only in Tosham pyrite. The Tosham deposit is genetically related to S-type magma, while the Mount Pleasant deposit is related to A-type granite. Tosham ore contains zinc-bearing biotites that coexist with chalcopyrite in ore bodies but Mount Pleasant ore lacks such biotite. We propose that the difference in elemental abundance between the two deposits are caused by the different character of source magma and different mineral associations of the ore body.

Jan 1, 1995

By S Brunt

A new elution process has been developed for the recovery of gold thiosulfate from ion exchange resins. This is a synergistic system which utilises a base eluent, such as nitrate or trithionate, along with an additive that improves the elution of gold. The use of the additive enables lower eluent concentrations to be adopted, as well as weaker eluents such as chloride. With the chloride + additive system, complete gold elution can be achieved within 12 BV when utilising an eluent flow of 5 BV/h. When the eluent flow is reduced to 2 BV/h, complete elution is achieved within 8 BV. Similar results are obtained when using nitrate or trithionate as the base eluent. A copper pre-elution process has also been developed, whereby the majority of copper can be stripped within 5 BV prior to gold elution. This method is a significant improvement on the ammonia + oxygen pre-elution previously suggested. The development of a new analytical procedure based on ion chromatography with UV detection is also described for the quantification of polythionates in leach solutions and loaded on resins. This enables analysis to be carried out for resin-in- leach type processes where the polythionates are being formed in solution and simultaneously adsorbed onto the resin.

Jan 1, 2007