Search Documents

By M E. Trim, J J. Johnson, W Cranston

The Brightwater conveyance system is located near Seattle, Washington in the north-western United States. The East Contract portion of the system consists of a 4.3 km long, 5.9 m diameter tunnel in soft ground and two large shafts constructed in challenging soil conditions. The two shafts are situated side-by-side in an urban valley. One will house an influent structure to direct incoming sewage and outgoing treated effluent, while the other will house a 645 megalitre per day (ML/d) influent pump station. The tunnel contains four pipelines: two force mains to convey untreated wastewater eastward from the new pump station to a new treatment plant, one gravity-pressure pipeline to convey treated effluent westward to a new outfall in Puget Sound, and one high-pressure pipeline to convey reclaimed water from the treatment plant to downstream distribution points. The shafts and the tunnel presented many design challenges. Groundwater is near the surface in the area surrounding the shafts, and compressible peat and clay soils preclude dewatering during construction. These and other challenges were encountered during design of the pump station shaft and multiple-pipe tunnel. The challenges were addressed by a design that includes a dual intersecting circular cell shaft (referred to as æthe peanutÆ) and a single tunnel into which stacked pipes will be æstuffedÆ. This paper discusses the design approach and design details for both elements.

Jan 1, 2008

The sharp deterioration in Au~tralia'S ternn of trade in recent years and the accumulating national debt highlight the need for a restructuring of the economy which is highly dependent upon primary agricultural and mineral commodity exports (figure 1). Table I gives an indication of the value that can be added to raw material by mineral processing. Significantly higher value is added through downstream manufacturing. In 1987, the mining and rural sectors accounted for 47010 and 38010 respectively of total exports valued at $35,782 million (figure 2). The export contribution from minerals comprised $12,266 mil- lion from unprocessed ores and concentrates and $4,668 million from metals and processed minerals including some simple manufactures. Coal accounted for 450/s of total primary mineral exports. Iron ore and alumina are other important mineral exports, while gold and aluminium are major metal exports. (Figure 3) Australia's minerals are now traded in a much more competi- tive and oversupplied market in contrast to the 1960's and 1970's period which was characterised by increasing exports of largely unprocessed ores and concentrates. Since the early 1980's (I cI) resscd )ver~cas nutrkcts and km rununodlity liriccs ha~c hcen the product of excess capacity installed to satisfy a forecast high growth in demand which never eventuated due to the world reces- sion. During this period the emphasis on technology development was focussed on reducing costs through increased production effi- ciencies in order to maintain competitiveness.

Jan 1, 1988

By d&apos, Alton AJ, Rigden DT

Modern petroleum refining offers a complexity of environments, each requiring different metals for the satisfactory performance of-the various sections of the refinery, and this paper first outlines the varied enva.x¦on-ments thus met.It follows that the metal types in use will also vary to suit each particular environment, and the paper' consequently covers the use of ferrous-metals, ranging from plan carbon steels to the high alloy types and the non-ferrous metals, particularly copper and its alloys.The failures of some,of these metals and alloys are then illustrated by experiences it Kwinana. These failures are duo to (a) corrosion, (b) erosion, (c) faulty welding, and (d) mechanical defects,' of which the first is by far the most prevalent. The protective measures taken to prevent subsequent failures are then given under one or other of the following headings :(1) alterations in process conditions, (2) the use of alternative ,alloys,(3) suitable heat treatment, (4) redesign of the failed section, (5) cathodic protection, and (6) use of corrosion inhibitors.Reference is then made to the use of specialised metals and alloys.Metals, generally in the form of oxides or salts, are also used as catalysts in refining processes. Activated alumina is used, combined with silica .forScracking' of heavy oils, and as a support -for platinum, cobalt, molybdenum, nickel and similar metals, which catalyse hydro-genation and dehydrogenation-processes. .In the final formulation of petroleum products metallic compounds may be added. Reference is made to the large quantities of lead used by the petroleum industry and to the use of metallic soaps and detergents in the formulation of lubricating oils and greases.

Jan 1, 1962

A process was developed based on the thermal hydrolysis and precipitation of iron from solutions resulting from the leaching of zinc plant residue. A study was made of the hydrolysis of iron, at temperatures in the range 140-220°C, in both pure solutions of ferrie sulphate and in leach solutions derived from plant spent electrolyte.At 200°C hydrolysis of pure ferric sulphate solutions results in the precipitation of ferric oxide, Fe2O3, at low acid. concentrations, and a basic salt, Fe2O3.2S03.H20, at hIgher acid concentrations. At 180°C ferric oxide is precipitated at low acid concentrations, but at higher acidities. carphosiderite, 3Fe203.4SO.3.9H20, is the stable phase. Frequently a mIxture of ferric oxide and carphosldente IS produced at 180°C, the ratio of phases being dependent on the non-equilibrium experimental conditions.With solutions derived from plant spent electrolyte hydrolysIS at elevated temperatures results in the precipitation of jarosite compounds of the type NaFe3(S04)2(OH)6 The precipitation of natrojarosite jarosite, and ammonio-jarosite was studied in detail. Temperature, free acidity, and the concentration of sodium potassium, and ammonium ions are critical factors which affect the extent of precipitation.A process based on ammonio-jarosite precipitation was tested in a pilot plant.An alternative method of iron removal based on the addition of zinc oxide calcine, to neutralize excess acidity, and the precipitation of ferric oxide was also tested in the pilot plant. Both processes appear economically favourable...

Jan 1, 1967

An Investigation on the Effect of Chrysotile Particle Shape and Anisotropic Properites on the Rheology of Chrysotile Suspensions Chrysotile, a polymorph of serpentine, is a phyllosilicate mineral that occurs as a major gangue mineral in many ores (eg Mt Keith nickel sulfide ore, Western Australia). The rheological behaviour of chrysotile stems from two main factors: its distinctive morphology and its electrical surface charge. It is believed that these factors are central to the problematic rheological behaviour and low solids throughput typically experienced in the processing of such ores. In this work, a study of the effects of chrysotile surface charge properties and particle shape on the rheology of chrysotile suspensions was conducted. It was found that the rheology of suspensions of pure chrysotile is characterised by extremely high yield stress values over a broad pH range (pH 4 to 11).The disparity in the point of zero charge and range of maximum yield stress for chrysotile is consistent with the anisotropic nature of chrysotile particles. A comparison of the rheological behaviour of quartz suspensions (non-fibrous) to that of chrysotile suspensions (fibrous) provides a practical indication of the effects of the fibrous nature of chrysotile relative to non-fibrous minerals. The long, thin fibres are easily entangled to form suspensions with much higher plastic viscosities and Bingham yield stresses than non-fibrous particles. Chrysotile particle shape and surface charge are central to the rheology of chrysotile suspensions, although shape appears to play a more significant role in this regard. This fundamental study would be beneficial to the ongoing research for improved recovery in the Mt Keith nickel sulfide ore as well as other chrysotile bearing ores.

Sep 13, 2010

By Orr T. O H, Hodkinson I. P

The Mount Leyshon breccia complex is located on an east-west trending contact between Cambrian metasediments (Puddler Creek Formation) and the Ordovician Mt. Leyshon granite, within the Lolworth-Ravenswood block. Detailed mapping of basement, breccia and igneous unit geometries, crosscutting relationships and resolution of complex chronological relation- ships indicates that the Mt. Leyshon breccia complex should be reinterpreted as a number of intrusive igneous and breccia phases. This is in contrast to a previously published account of a largely extrusive geological setting. A complex structural history dominated by strike-slip faulting is preserved within the basement units and is responsible for controlling the location and geometry of the breccia complex. The breccia complex has been divided into brecciated "basement", "main pipe breccia" and an "interactive magma/breccia sequence". Main pipe breccia (the most voluminous unit within the complex) has been re-interpreted as an intrusive breccia, rather than an extrusive or vent fill as previously proposed. This is based on the following evidence: 1. the facies characteristics of the main pipe breccia, 2. the presence of a progression from cohesive basement through to mixed breccia, 3. minor basement block rotation during breccia complex formation, and 4. the partial structural control on the main pipe breccia. No unambiguous evidence exists for pyroclastic facies, although the fine breccia variant commonly contains "accretionary structures", very similar in appearance to those formed during pyroclastic processes. In view of 1. above, they are interpreted to be the product of particle accretion during upward movement of fragmental material, although an origin due to altera- tion cannot be completely discounted. heir occurrence in the main pipe breccia indicates that their presence within a rock unit is not necessarily diagnostic of nvroclastic nroeesses.

Jan 1, 1991

By C J. Stanley

Reflected light optical microscopy, or epimicroscopy, is one of the oldest techniques of modern mineralogy. At a relatively low capital cost, it is also very resourceful, and the analytical choice for the identification of most ore minerals. In ore mineralogy, reflected light optical images have the potential to overcome the main limitation of backscattered electron images from scanning electron microscopes, namely contrast of mean atomic number  below the spectral resolution of the backscattered electrons detector. This is the case for relevant ores, like iron (haematite-magnetite) and copper-zinc ores (sphalerite-bornite), but for both cases the pairs of minerals are easily discriminated in reflected light. The improvements in optics and electronics also made microscopy a powerful source of digital images, suitable for automated analysis for minerals processing, as the determination of liberation spectra. The drawback, however, has always been the impossibility to recognise the transparent minerals, which account for most of the gangue phases in ores, from the embedding resin, usually epoxy. In order to determine if there was any possibility to separate quartz from epoxy resins, reflectance spectra have been acquired for quartz and some commercial epoxy resins (Araldite, BuehlerÆs Epothin and Epocolor, Araldite spiked with fluorochrome from Struers), from 380 to 720 nm in 5 nm intervals. Reflectance of quartz and epoxy is very similar over the whole visible light range, and varies from 4.5 to five per cent. Epocolor, a red-dyed epoxy, reflects slightly more above 560 nm, as does Araldite spiked with the fluorochrome from 460 to 570, but for both the reflectance is still very close to that of quartz, under 5.1 per cent. This data set is final, and precludes the application of reflectance in light optical image analysis for assessment of liberation, phase quantification, or any other signal that requires separation of resin from transparent minerals.

Jan 1, 2008

Pan Australian Mining lid installed a milling and gold leaching plant designed to process 2 million tonnes per annum of breccia sulphide ore. This plant was commissioned in January 1989. Since commissioning, increased ore reserves have been established and the plant has been expanded by the addition of one ball mill and several tanks to increase the design capacity to 3 million tonnes per annum. This additional plant was commissioned in May 1990, bringing the total number of mills up to three, each 4.5 m diameter x 7 m long. The paper details how milling rates have been increased at the expense of grind size to increase the capacity of the original plant from 2 million to 3.1 million tonne per year rate before the additional ball mill was Commissioned.

Jan 1, 1991

By Ito H, Noguchi F, Ueda Y

DTA curves of synthesis lead sulfide and commercial. lead concentrates during oxidation were measured to clarify the mechanism of ox- idation of lead sulfide. The oxidation reac tions could be divided to elementary reactions with production of basic lead sulfates such as 2PbO PbSO4. An existance of iron sulfide played an important role of the oxidation of lead concentrates. The oxidation rates of lead sulfide were measured in the wide range of oxygen potenti- als using IR type SO2 gas-meter. The oxidation rates under low Po 2 which corresponds to the direct oxidation smelting were much lower than those obtained under high Pot. The combustion temperatures of lead sulfide were also measured by hot thermocouple method. Those values were extremly low compar- ing the oxidation temperatures obtained by DTA.

Jan 1, 1987

The four major contracts for the construction of Museum Station are: 1) Installation of Soldier Piles, 2) Structural Contract including the temporary support, 3) Architectural Finishes which include Electrical and Mechanical Services and 4) Supply and Installation of lifts and escalators. Specific areas of interest include the fabrication, installation and removal of temporary support steelwork, the monitoring of ground loading, and the interface between the structure and. the temporary support. The information collated during construction confirmed the design assumptions and criteria. No major changes'were required in the design of the construction methods. The open cut excavation and construction of this major structure in an inner city area was significant by any standard and was successfully completed with minimum disruption to the public and without damage to adjoining or surrounding property.

Jan 1, 1981

The Circum-Pacific is defined to include back arcs and continental areas of volcanism. Volcanoes must be regarded as dormant, if the time since their last eruption is less than about ten times the average interval between eruptions, even if they have not erupted for tens of thousands of years or longer. It is important to establish a complete history, over as long a period as possible, for varying volumes of eruptions. In order to assess risk, the average interval between eruptions should be calculated for each range of erupted vo4ume~, in orders of magnitude from about 10 m up to the maximum volume possible at each volcano. Eruptions are considered to consist of individual explosions, and are grouped into eruptive sequences, with the sequences grouped into overall cycles of activity. Frequency of eruption versus volume erupted is a linear relationship for most andesitic and basaltic volcanoes, but is often bimodal at rhyolitic volcanoes, 3 with a slower eruption rate above about 10 km. Worldwide, during the last 7000 years, there have been three known e~uptions with volumes of ejecta of > 100 km , a9d, since 1638 A.D., 7 with volumes > 10 km , and 48 with volumes > 1 km . Average recurrence intervals are about 71 years for eruptions of > 20 km , 39 years for those of > 10 km , and 7 years for those of > 1 km . Rough esti- mates can be made for larger volumes erupted. Mean intervals in the Circum-Pacific are about twice the length of those for the world as a whole. During the last 400 years, about 61% of the world's eruptions of > 1 km3 have taken place in this region.

Jan 1, 1987

By C M. Rebagliati, J G. Payne, K Roberts

The Pebble deposit, located in south-west Alaska, is one of the largest Copper- Gold-Molybdenum (Cu-Au-Mo) porphyry systems in the world, with a current resource of >8 billion tonnes which contain 73.7 billion pounds of copper, 87.1 million ounces of gold and 4.16 billion pounds of molybdenum. The Pebble deposit formed at ~90 Ma, during emplacement of subduction-related hornblende granodiorite porphyry intrusions emplaced into Jurassic-Cretaceous sedimentary, volcanic and subvolcanic intrusive rocks of the Kahiltna Terrane. The Pebble West and Pebble East Zones represent two thermal and fluid centres in a single large magmatic-hydrothermal system. The West Zone extends from surface to about 500 m depth, has thin zones of oxide and supergene mineralisation overlying hypogene chalcopyrite mineralisation, and is amenable to open pit extraction. The East Zone extends to at least 1700 m depth, is higher grade, occurs beneath an eastward-thickening cover of younger sedimentary and volcanic rocks, lacks oxide and supergene mineralisation, and is being evaluated for underground block-cave mining. Most Cu-Au-Mo was introduced with early K-silicate alteration and related quartz-sulfide veins. In the East Zone, a structurally-controlled overprint by advanced argillic alteration significantly increased Au and, to a lesser extent, Cu grades. Exploration potential at Pebble and its surrounding district remains high. Several other porphyry, skarn and epithermal deposits have been discovered in the district, but only limited exploration has been conducted. The eastern, higher grade part of the Pebble deposit remains open in several directions, with significant potential for resource expansion by ongoing, aggressive drill exploration. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

QEMSCAN« technology is a widely accepted automated e-beam technique providing quantitative and statistically robust mineralogical data to the mining industry. It uses X-ray mapping combined with backscattered electron (BSE) brightness to identify minerals in almost any type of geological material (Gottlieb et al, 2000). Besides the modal mineralogy also the liberation, associations, average grain size and other textural information can be obtained. The aim of this study is to test reproducibility of this technique by setting up and running standard tests on different QEMSCAN« systems. Multiple sample blocks were prepared by our standard operating procedure as epoxy-mounted, carbon-coated, polished blocks. The replicates were measured under the same conditions and measurement parameter settings on different QEMSCAN« instruments. The relative standard deviation (RSD) for the set of measurements was calculated. Generally the reproducibility of the systems themselves was found to be excellent, ranging between 0.4 and 1.5 per cent RSD. The more significant change in the reproducibility was found to be caused potentially by the sample preparation and variation in the mineralogy of the replicates. The measurement parameter settings together with these variations can account for almost 15 per cent RSD for minerals of low abundance. For analysed samples good results for the main phases present in quantities higher than 2 - 5 wt per cent of the total mass of the sample were confirmed with RSD generally below six per cent. Following the experiments, the parameters having the biggest influence on the performance of the QEMSCAN« and its precision are discussed in detail. The importance of sample preparation procedures and measurement parameter settings is emphasised. It is shown that experience and excellence is necessary for getting the most from the automatic mineralogical methods like QEMSCAN«.

Jan 1, 2008

Oxy-ACETYLENE system of welding and cutting is at present practised in two forms, which may be described as the high and lowpressure systems. In the high-pressure system the two gases, oxygen and acetylene, are delivered. to the blow-pipe under pressure from properly constructed trade cylinders. Oxygen cylinders are in two sizes, each containing 100 and 200 cub. ft. of gas respectively. These cylinders are charged to a pressure of 120 atmospheres, or 1800 lb. per sq. in. approximately. The acetylene cylinders are made in one size as far as the writer knows, and contain 200 cub. ft. of acetylene gas at a pressure of 10 atmospheres. Each cylinder is provided with a valve and connection for attaching a regulator to "break down" the high pressure in the cylinders to the necessary low working pressure of the blow-pipes, and to deliver the two gases at a constant pressure irrespective of the variable pressures in the cylinders. These regulators can be adjusted down to as low as 1 lb. and are provided with two pressure gaugesone reading the contents of the cylinder in atmospheres, and the other the working pressure in lb. per sq. in. The high-pressure, or "two cylinder" system is compact and can readily be transported from place to place in the works. For this purpose the two cylinders are mounted on an easy-running 4-wheeled truck, which the operator and assistant find no difficulty in manipulating. In the low-pressure system the two gases are delivered to the blow-pipe, one from the oxygen cylinder and the other from the acetylene gas generating plant, which consists of the following:Generating cylinder, half filled with water, into which the cathoide is plunged. The generated gas is passed through a filter to the gasometer, then through a water washer on to the hydraullic seal...

Jan 1, 1922

The total cost of horizontal development can be minimised by optimising the cost of each of the component operations (eg drilling, blasting, etc). Component costs should not be minimised. To optimise blasting results (ie the mean advance per round, muckpile characteristics and overbreak), operators need to optimise the blast design and drilling and blasting procedures. The costs of pulling extremely long (say >6 m) rounds, producing unnecessarily fine fragmentation, and minimising overbreak are excessively high. Operators should continually consider how they can shorten the cycle period by saving time at the face. To enable it to be matched to the pertinent rock properties, the blast design needs to be based on as much relevant experience as possible. To develop the most valid correlation between blasting results and blast design, the latter must be implemented carefully and accurately, but without sacrificing speed excessively. The total cost can often be reduced by using: 1. computer-controlled jumbos (to reduce the period and cost of drilling and to increase drilling accuracy); 2. larger diameter (51 mm to 64 mm) and longer (4.5 m to 6 m) blastholes; 3. at least three large diameter ( ¦89 mm) relief holes that are 0.2 m to 0.3 m longer than the blastholes; 4. explosive products that are selected on the basis of proven reliability and overall cost efficiency rather than price; and5. stemming (to increase the amount of effective work done by each kilogram of explosive and, hence, to reduce the powder factor and possibly the number of blastholes and the costs of drilling and initiation). Non-perimeter blastholes should be charged with ANFO or a bulk emulsion of established performance. Upper perimeter blastholes should be charged with a bulk explosive with a much lower effective density. But where geology varies considerably, greatest control over overbreak could possibly be achieved with the versatile pre-assembled charge shown in Figure 1. This paper presents numerous potential ways in which the total cost of development can be minimised. It concentrates on recommending blast design features and the safe, rapid, cost-effective implementation of designs.

Jan 1, 1998

By Kohra A, Shoji S

The amount of copper production by flash smelting process occupies about 17% (equivalent to 1.4 million t/year) of total free world production. In Japan, 650,000 tons of copper is produced annually by flash smelting. This is 65% of the gross copper production of Japan. To reinforce pollution control, promote energy saving, and enhance production efficiency by increasing the size of furnaces, conventional blast furnaces and reverberatory furnaces are being replaced with the flash smelters worldwide. The Ashio Smelter started copper production in 1884 and developed in association with the Ashio mine. In those days, the Ashio smelter produced copper by using the blast furnace process designed for the high-grade ore from the copper mine. At that time, this process was specialized in Japan. In 1956, for the first time in Japan, the Ashio Smelter introduced the flash smelting process developed by Outokumpu Oy of Finland (it is suitable for treating the copper concentrate, producing sulfuric acid and improving production efficiency). The flash furnace in Ashio, the first ever in Japan, had a capacity of 230 t/day for copper concentrate and was operated up to 1962. During this period, various operational troubles were solved, and further improvements were made; and, in 1962, a Furukawa-type flash smelting furnace was completed in Ashio. This improved version of a flash furnace had a capacity of 450 t/day. There was one flash furnace and one waste heat boiler, which were arranged in a unique pattern for that time. This furnace may be said to be the prototype of the present flash smelting process in the world.

Jan 1, 1987

Solid Energy New Zealand Limited (æSolid EnergyÆ) is a state-owned coal mining company, producing 4.0 Mtpa from a number of opencast and underground mines in the Huntly, West Coast and Southland regions in New Zealand. The company currently exports 2.1 Mtpa of coking coal. Exports are expected to grow strongly over the next five year as the company expands production into new semi-soft and thermal coal reserves. Domestic coal demand is also expected to grow strongly, particularly in the North Island, as the Maui gas field reserves diminish, and thermal coal becomes more important for electricity generation and meeting the energy needs of forest processing and other industries. Solid Energy is expanding and developing its risk management practices across all areas of the business: strategic planning û extensive use of scenario analysis and probabilistic modelling over a 20 year period; investment decisions û development and application of a rigorous six stage æProject Assessment GuidelineÆ process for all new mine developments; geological and geotechnical risk assessment techniques û use of best practice techniques including seismic surveys; financial risk management û a dynamic approach to hedging based on effects based analysis of Cash Flow at Risk analysis against preset risk tolerances; risk financing û the use of a captive insurance subsidiary, and the experiences of a small coal company seeking to obtain insurance cover on a æhardÆ international insurance market; and integrated risk management û the challenges of trying to implement a broad integrated risk management approach across the company, that supports implementation of strategic objectives as well as meeting æcompliance or legislative basedÆ risk management requirements.

Jan 1, 2003

By Dixon D. R, Sparrow G. J

Pressure leach liquors from the pressure oxidation of a bulk flotation concentrate prepared from a complex Cu-Pb-Zn sulphide ore were treated to remove iron, either by pressure oxidation (the Hematite process) or with particles of magnetite (the Magnetite process), followed by cementation of various metals with zinc dust to obtain a purified solution from which zinc was electrowon. Satisfactory iron removal was achieved by both processes after neutralisation to pH 4.5 or 5.5. Pressure oxidation of the liquor at 200¦C and 690 kPa oxygen overpressure, conditions similar to those of the Hematite process used in the zinc industry, resulted in the precipitation of the iron as hematite. With the Magnetite process, an iron hydroxide was precipitated onto magnetite at atmospheric pressure and ambient temperature and removed by a magnetic separation step. The performances of both these processes for the removal of iron are compared. It is concluded that the Magnetite process offers considerable cost savings. Other impurities, in particular arsenic, were also removed with the iron in both processes. Cementation at pH 5.2 and 85-90 ¦C with 3.5 g/L zinc dust reduced the levels of copper, cadmium, and nickel to a satisfactory level and subsequent electrolysis in a laboratory cell gave an acceptable deposit of zinc.

Jan 1, 1989

While, in the past, a great deal of attention has been focussed on technical issues and the performance of explosives in rock, the explosive user, an essential link in the chain, has often been neglected. In the mining industry, too often, the benefits of excellent technical work have been degraded over time due to the lack of definitive and documented control. Using the principles of quality management a quality training system was developed and implemented for management of explosives use at Gunpowder Copper Ltd (GCL). This paper describes the structure of the system, its development and implementation, and contains practical advice and information for managers responsible for blasting and charge crews. The paper is in four parts: I Quality systems. A brief overview of the relevant aspects of total quality management that apply to explosives use. The requirements for documentation, management and auditing are explored. 2. Training for competency. The five essential elements of Competency Board Training (CBT) are examined, including auditing. 3. The Gunpowder Copper system. Implementation of the complete training system. Documentation and its control, auditing, instructions for operators, management responsibility and means of obtaining operator ownership are amongst the issues raised. Reporting requirements are the means to effectively manage change are described. 4. Summary. The paper concludes with the tangible benefits seen by Gunpowder Copper through the adoption of a quality training System.

Jan 1, 1995

By Young D. R, Webb I. D

The hydro-chlorination of Fe2O3 and Fe304 has been investigated in the range 850-950¦C in order to elucidate the role of iron in the segregation process for nickeliferous laterites. The kinetics of Fe203 chlorination using 20% HC1 - 80% N2 gas mixtures is consistent with a single-stage structure control model, whereas Fe3O 4 exhibits a two-stage reaction mechanism. Oxygen potential measurements using a CSZ probe located above the bed and X-ray powder diffraction results confirm the proposed reaction scheme. When a serpentine nickeliferous laterite (1.03% Ni - 11.7% Fe) was chlorinated at 900¦C with a 20% HCl - 80% N2 gas mixture it was found that the iron oxide in the ore was extracted in a similar manner to the synthetic iron oxides. Also, it was found that the nickel extraction from the ore paralleled that of the iron and the tests indicated that for the major part of the extraction, the solid nickel species were in equilibrium with the gas phase. The recovery of nickel from laterite ores by the segregation process has been investigated by a number of workers and several extensive reviews of the literature associated with this field have been published (Iwasaki, 1972; Canterford, 1975; Wright, 1973).

Jan 1, 1987