Search Documents

The Kyaukpahto gold deposit is located at latitude 23¦ 47Æ 55" N and longitude 95¦ 56Æ 35" E in the Kawlin-Wuntho district, Sagaing Division, Myanmar. Gold mineralisation is hosted in sandstone of the Male Formation (Eocene) and occurs as stockworks and disseminations. The high-grade gold mineralisation is locally concentrated in a breccia zone. The gold deposit is closely associated with a NNE-SSW trending fracture system that forms tensional open fractures. These tensional zones are thought to be directly related to the Sagiang transfer fault system that experienced several hundred kilometres of northward dextral movement during the post-Upper Miocene. Major sulfide minerals are pyrite and arsenopyrite with minor galena, chalcopyrite and sphalerite. Gold mineralisation is associated with intense silicification, sericitisation and argillic alteration. Primary Type I fluid inclusions in the quartz from the mineralised zone are 5 to 15 ¦m across and yield homogenisation temperatures of 239¦ - 310¦C and salinities of 1.2 - 10.9 wt per cent NaCl equivalent. Laser Raman spectroscopic analysis indicates the presence of CO2 and CH4 in Type II fluid inclusions. Sulfur isotope analysis of disseminated pyrite in the ore zone by the laser ablation method indicates d34S values from -5.48ë to +5.53ë. The geology, alteration, ore mineralogy, fluid inclusion microthermometry and sulfur isotope data of the Kyaukpahto deposit are consistent with an epithermal ore deposit model for the deposit. However, the presence of CO2-liquid bearing fluids and the detectable CH4 in the gaseous phase of the fluid inclusions conflict with a typical epithermal origin for the Kyaukpahto deposit. The host siltstone and mudstone sequence, trace element geochemistry, and the disseminated nature of sulfide and gold mineralisation are also common characteristics of a sedimentary rock-hosted gold deposit, and these features may indicate a Carlin-like affinity. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By B J. Monaghan, R J. Longbottom, D J. Pinson, S J. Chew

Recycling steel plant by-products is a critical issue for achieving both environmental and economic sustainability of integrated steel plants. A key steel plant by-product stream is dust from basic oxygen steelmaking (BOS), which can be recycled back to the BOS vessel as iron units and to aid slag formation. The major limitations for its recycling are zinc and the uncertainty in zinc speciation of the dust. This uncertainty affects the amount of dust recycled and how it interacts with the slag during processing. BOS dust in stockpiles can undergo self-sintering reactions that oxidise the iron-bearing components. As this occurs, zinc (or oxide) may combine with iron oxides to form a zinc-iron spinel solid solution phase. Knowing which zinc-bearing species are present in the BOS dust is a key aspect in understanding and developing an efficient recycling process for the dust. To overcome difficulties associated with phase identification in the BOS dust (both fresh and selfsintered), particularly the magnetite-zinc ferrite spinel solid solution using X-ray diffraction (XRD) / scanning electron microscopy (SEM) / energy dispersive spectroscopy (EDS), high end characterisation tools, transmission electron microscopy (TEM) and Mössbauer spectroscopy, were also used. Such an approach allowed improved phase identification of key zinc- and iron-bearing phases that were not previously resolvable. The zinc in fresh BOS dust was mostly present as extremely fine separate particles of zinc oxide, attached to the iron particles. These extremely fine particles were <10 nm in size. Additionally, a small amount of zinc ferrite was also identified within the sample (most likely contained within a magnetite-zinc ferrite spinel solid solution). However, the zinc in the self-sintered BOS dust, was found to be present entirely in a magnetite-zinc ferrite spinel solid solution. While this spinel phase had been previously identified by XRD, it was not clear that it contained zinc. The Mössbauer results provided definitive evidence of zinc within the spinel phase.

Jun 19, 2024

In general the iron ore industry has been slow to adopt the Whittle Pit optimising software in the evaluation of iron ore deposits. The reasons for this are two-fold:the iron ore industry has developed techniques, usually bespoke software residing in the corporate offices of the respective iron ore companies, to establish their final pit limits; and the fact that the Whittle software doesnÆt easily lend itself to estimating a sales product of constant quality without maximising grade (metal content). The Whittle software is based on the work done by Lerch and Grossman (in the early 1970s), which proposed that graph theory be used to establish an optimal surface that maximises the revenue from a deposit. The maximised surface created in the pit optimiser is translated into a proposed optimal final pit shape that can be used by the mine design engineers as a target outline to lay out the final practical pit. By treating a geological and ore resources model that was created for an iron ore deposit as a subset of the recoverable resources estimation (RRE) type of geological models, the evaluation of an iron ore deposit and establishing the final pit is greatly simplified in the Whittle 4-X optimiser. Instead of trying to optimise the iron content of the deposit, the emphasis swings to maximising the extraction of a finished and saleable iron ore product. This is achieved by treating the finished saleable iron ore as an element in the multi-element Whittle optimiser. The quality of the finished sales product is represented, and the material that cannot be used in the blended product is also shown. Proposals for enhancing the functionality in the Whittle 4-X optimiser to make the evaluation of iron (and coal) deposits easier includes the creation of a new reporting function that will allow the user to specify which field(s) can be used as the divisor(s) for the reporting of the element grades in the model.

Jan 1, 2007

By A Batnasan, K Haga, A Shibayama, K Higuchi, H Takeuchi

High silica (SiO2), alumina (Al2O3), and phosphorus (P) contents in iron ore adversely affect the quality of iron products. The removal of those impurities from iron ore is an essential point in further iron ore processing. In this paper, the removal of P, SiO2 and Al2O3 impurities from iron ore by alkaline drying followed by reverse cationic flotation is discussed. The reverse cationic flotation experiments are performed using the iron ore samples without and with alkaline drying pretreatment. All other flotation conditions except pulp pH (4–12) and particle size distributions (-45 to -250 μm) are held constant. A typical collector and frother, such as dodecylamine acetate (DAA) and methylisobutylcarbinol (MIBC), are used in the flotation experiments. Alkaline treatment is conducted before flotation using sodium hydroxide at fixed conditions. The impact of alkaline drying on the performance of iron ore flotation is evaluated based on the removal rates of P and SiO2 + Al2O3, iron grade, and iron recovery compared with the iron ore flotation without alkaline drying (direct flotation). X-ray diffraction (XRD) analysis indicates hematite and goethite are the main minerals in the iron ore, which assays 62.8 mass per cent Fe, 0.232 mass per cent P, 7.1 mass per cent SiO2 + Al2O3 (total) determined by X-ray fluorescence analysis (XRF). Results indicate that a combined approach is more effective for removing P and SiO2 + Al2O3 impurities from iron ore than the direct processing technique because the maximum removal rates of P and SiO2 + Al2O3 are 48.2 per cent and 66.5 per cent from the alkaline dried iron ore when 8.4 per cent and 13.1 per cent from the non-alkaline dried iron ore.

Sep 18, 2023

The object of this paper is to give an insight into various metallurgical operations involved in the making and shaping of steel for shipbuilding at the Newcastle plants of the Broken Hill Proprietary Co. Ltd., Commonwealth Steel Co. Ltd. and the Port Kembla plant of Australian Iron and Steel Ltd. Whilst not steelmakers, inasmuch as their processes start with semi-finished. steel supplied by the Steelmaker, the plants of Stewarts and Lloyds (Aust.) Pty. Ltd. and their associate company, British Tube Mills, Rylands Bros. (Aust.) Pty. Ltd. and the Newcastle and Kembla plants of John Lysaghts (Aust.) Pty. Ltd. make substantial contributions to the Australian shipbuilding industry, principally by way of boiler tubing and wires for welding rods and sheet steel, including special silicon lamination sheet for electrical motors.THE MAKING OF STEELThe making of iron and steel began as an accident, slowly developed as an art and has not yet become an exact science. The iron age dawned on the day when, by chance, man&apos;s primitive ancestor built up the wall of his fire with ironstone. In the ashes of the fire he found pieces of sponge iron from which he hammered out the first sample&apos; of wrought iron. For many centuries iron &#183;was manufactured in bloomeries and occasionally, when the temperature was excessive, the iron combined with some carbon and steel was produced. But it was not till &apos;1740 that steel was manufactured under controlled conditions. In that year Huntsman invented the crucible process which held undisputed sway for over a 100 years until in 1856 the invention of the Bessemer process revolutionised the whole industry.From then on, rapid progress was made. The Siemens...

Jan 1, 1951

By A Tawadrous, D S. Preece

Cave mining is of interest to the mining community as it offers a chance to extract large, deep orebodies with low operating costs and high production rates. It allows for extracting large low-grade orebodies, which may not have previously been considered for mining. Cave mining is done either top down (ie sublevel caving) or bottom up (ie block/panel caving). Both approaches rely on gravity, stresses and weakness of the rock to fracture and achieve a controlled collapse.Block caving starts at the base of the orebody. It progresses upward and across through continuous collapse of the roof. To achieve this, a critical hydraulic radius must be exceeded. This is accomplished by blasting drawbells, through which the caved ore passes to the production level. An entire level above the drawbells (undercut level) is excavated to help initiate the cave. The undercut level ensures the connection between drawbells and achievement of the required hydraulic radius.Conventionally, drawbells are generated by drilling and blasting several times from the production level as well as the undercut level. Mucking between each shot is required to generate enough void space for the rock to swell. The need for several blasts necessitates some downtime between each blast. Also, the cost of developing and maintaining the undercut level can constitute up to 35 per cent of the cost of mining the panel.A new blasting technique was developed to create the drawbells in a single blast from the production level. The technique ensures the connection of the drawbell to the neighbouring ones, thus, the critical hydraulic radius is reached and propagation of the cave achieved without the need for the undercut level. The technique has the potential to reduce the capital cost of a block caving operation, increase its feasibility and reduce time to reach the ore and consequently the payback period. This paper presents the modelling of a traditional drawbell excavation process, the philosophy of the developed technique, the modelling of that new design and its implementation.CITATION:Tawadrous, A and Preece, D S, 2015. A novel blasting technique to create drawbells and eliminate the undercut level in block cave mining, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 617–624 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By E J. Y Koh, G J. McLachlan, E Amini, N Beaton

Preconcentration greatly reduces the ore mass input to the processing plant while upgrading the grade. One of the commonly used methods of preconcentration is optical sorting. These methods rely on optical sensors which classify the material stream into “accept-reject” streams. Currently, it is common to use near infrared (NIR) or colour cameras to classify streams based on reflectance or colour thresholds set by experts. The imaging is done through line-scan sensors where the material is scanned on a belt or a chute. Then, a separation apparatus like a diverter gate or air jet is controlled to separate the streams according to the classification made by the algorithm. Separation efficiency is dependent on the classification algorithm. Existing classification algorithms rely on low-level feature discrimination like observing individual pixel values for reflectance or colour hues. This limits discrimination between minerals with low contrast in colour. Human experts perform mineral segmentation using texture, colour distribution and shape, but it is difficult to translate these visual rules to mathematical thresholds. Deep learning methods like Convolutional Neural Networks (CNNs) provide high-level feature discrimination similar to a human expert. Instead of relying on pre-defined features, the CNNs learn complex features from the dataset. CNNs can construct a hierarchy of features based on pixel clusters to learn texture, shapes, and colour spectrums of the mineral grain surface to provide better separation. In this study, a state-of-the-art deep learning instance segmentation method is used to outline boundaries and classify grains from the background (mineral segmentation). The algorithm is trained on images collected from a flotation feed of a gold deposit, where the gold is mechanically locked inside pyrite. This method can process on-line video inputs at 5 frames per second to provide a live grade. The proposed method is inexpensive as it only uses a camera and a desktop computer.

Nov 10, 2020

The revival of the mining industry at Captain&apos;s Flat after a long period of years of inactivity has attracted attention to the importance of the ore-deposits of that field as potential sources of supply of lead and zinc. Mindful of the necessity for taking stock of the State&apos;s mineral resources, the Department of Mines of New South Wales as part of its programme of geological investigation, carried out a survey of the oredeposits and associated country rocks during 1938 and 1940.Surface geology was mapped in detail and all available exposures were examined and logged. Unfortunately, and this condition militates against the formulation of conclusions because of insufficiem.t data, some of the older workings, notably in Keating&apos;s Section, were inaccessible and the logging of levels and stopes is by no means as complete as could be desired. However, with the progress of development and exploration, further information of geological value will come to hand for incorporation in supplementary reports. It may be expected that, under such circumstances, modification of certain statements herein expressed may be necessary but it is not anticipated that any vital alteration will be occasioned.Within the State of, New South Wales, Captain&apos;s Flat ranks second to Broken Hill as a pqtem.tial producer of lead and zinc. In addition, large quantities of iron pyrites are available for the manufacture of sulphuric acid which finds application in the superphosphate industry.The mines are now controlled by an operating company known as Lake George Mines, Ltd., incorporated in New South Wales, the parent organisation being the Lake George Mining Gorporation Ltd., registered in London.Over &#163;600,000 has been spent by the Company in exploration, mine development, surface plant, housing and water &apos;conservation, while the State&apos; Government constructed a branch railway from Bungendore at a cost of &#163;200,000. The various activities consequent upon these development and construction programmes and the prospect of employment in the industry has led to a rapid increase in the population of the township.The State, generally, has benefited to the extent of a substantial contribution to the relief of the unemployment problem, and it is hoped that reasonable permanency will be assured to some hundreds of workers for many years.

Jan 1, 1941

By S Long, D Carnovale, L Louwrens

The Mt Wright underground mine (MTW) is located near the town of Ravenswood in north Queensland and is operated by Carpentaria Gold – a wholly owned subsidiary of Resolute Mining Limited.The Mt Wright mine has gone through many stages, from the conception and implementation of the world first ‘sub-level shrinkage’ stoping (SLS) with continuous fill mining method in 2010, through to steady state production. These have been outlined in detail in papers presented by Mackay (2011) and Mackay, Long and Koen (2014) at previous Underground Operators Conferences.Since the last paper was presented, MTW has experienced significant change in two key areas.The first significant change was the discovery of a previously unknown hazard in the form of flat rilling events (FREs) from closed drawpoints (DPs). These events are believed to be unique to MTW and pose a significant risk to both the safety of personnel and the business as a whole. The paper will discuss this hazard and the evolution of the controls and practices that have been introduced to mitigate the risk posed by the identified hazards. The material involved in these events is extremely dry, fine and hot.The second significant change is an altered stress regime bought on in part by a change in the production front orientation and a general deterioration in ground conditions in some areas of the mine. This has caused some production interruptions at MTW. The second half of the paper will describe the challenges encountered, the mechanisms behind these challenges and the strategies implemented to safely return MTW production to planned levels.It is believed that other operations can learn from the issues mentioned above, and the paper has been written with this in mind.`CITATION:Long, S, Carnovale, D and Louwrens, L, 2017. Mt Wright – managing unique risks, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 295–304 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

By J Ashford, Minniakhmetov

Geostatistical simulations are the best practice for uncertainty quantification in non-linear systems. Simulations are currently undertaken on an ad hoc basis in the mining industry due to high requirements in computing environments and advanced geostatistics. In contrast to the estimation process, multivariate simulations can be performed using different methods, tools, and computational environments, similar to data science. For large companies with multiple commodities it is important to have a standard framework to test, build, and run workflows using different methods, applications and computational environments. This work presents an auditable, modular and scalable framework to create geostatistical simulation workflows where the workflow is abstracted from the implementation. Key aspects: automation – workflows should be able to run automatically given updated data (if hands on modelling is not required); auditability – workflows should document key considerations and parameters; modularisation – workflows should permit swapping out components, for example substituting domaining in Leapfrog software with automated domaining using machine learning scripts; scalability – easy, repeatable, portable deployments on diverse infrastructure (for example, experimenting on a laptop, then moving to an on premise cluster or to the Cloud); reproducibility – parameters should be archived to permit re-running and reproduction of workflows in future years; and sensitivity analysis – any component of a workflow should be able to run with multiple scenarios of parameters and data to enable global uncertainty quantification and sensitivity analysis. The presented framework can be used to create different workflows for geostatistical simulations in multiple assets to quantify uncertainty in the value chain for resource categorisation, reserves uncertainty, value of information and robust mine planning amongst others.

Mar 22, 2022

By J H. Zietsman

The transition to more sustainable metal production is receiving much attention at present, and the iron and steel industry is at the centre of the conversation. New, more environmentally friendly production technologies, such as direct reduced iron (DRI) smelting furnaces, need to be developed in a short period of time. This necessitates increased use of computational modelling that incorporates more accurate material descriptions. The combination of large-scale multiphysics models of high-temperature processes with CALPHAD material descriptions leads to infeasible computation times. This can be resolved with the previously reported RapidThermo framework, which has been demonstrated to make equilibrium calculations orders of magnitude faster, within controllable limits of accuracy. In this paper, we explain how further material properties, which are important to modelling hightemperature reactors, can be added to the RapidThermo framework. This can improve the accuracy and usefulness of process and multiphysics models in the development of new technologies, which can significantly accelerate development cycles.

Aug 21, 2024

By H Chalcraft, T D. Mullen

Conditions encountered at a recently completed brownfields mining project provided valuable insight into, and development of, techniques for working in and around known underground mining voids in an open cut environment. The careful application of underground blasting principles to a pit environment and successful excavation whilst maintaining appropriate stand-off distances were two primary areas of innovation enabling the success of the project.Mary Mac Hill is a gold deposit situated less than 2 km south-west of the town of Laverton, Western Australia. It is owned and mined by Crescent Gold Limited. Previous underground mining by various other mining companies has left an extensive network of underground horizontal development, subvertical stopes and shafts, some of which daylighted at surface. This was identified as potentially posing substantial risks, which would prevent the application of conventional mining methods. Two major stopes were located under a hard banded iron ridge topped by a peak of cap, connected variously by narrow drives and vertical development. Due to the proximity of the first of these stopes to the surface, its dimensions and governed by procedures and advice provided by externally engaged engineers, Crescent Gold could not access the area of the ridge immediately overlying the stope using conventional open cut mining methods. This was the first of many hurdles surmounted in mining this deposit.The following report outlines how the challenges this geometrically complex deposit presented. Solving these problems enabled the team to mine the contained gold ore to a completed design, without subjecting personnel or mining equipment to harm due to a void breach incident. This paper outlines the numerous complications and difficulties Mary Mac Hill posed and explains the strategies developed to overcome them. The report also presents technical mass blasting details explaining two of the critical crown pillar blasts.CITATION:Mullen, T D and Chalcraft, H, 2012. Mary Mac Hill - The challenges and strategies of successful open cut mining: A complex underground gold deposit riddled with a network of complicated voids, in Proceedings Eighth Open Pit OperatorsÆ Conference , pp 89-96 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 18, 2012

By P Card

“Let’s get discipline and quality into easy to understand evaluations!” Project Managers and MetPlant Operators accept poor quality evaluations because they are generally unaware of what they should expect.The 2010 draft AusIMM ‘Guidelines for Techno-Economic Evaluations’ were collated by a subcommittee of practitioners and are regarded as best practice.They apply directly to projects and metallurgical plant evaluations, including those with a heavy technical basis. They can be applied to technical problem solving where there are no monetary computations. Project Managers and MetPlant Operators should demand that economic models and evaluations follow the six principles. They should become working tools which are easy to understand, fit for purpose, consistent, rigorous, record sources of input data, have key graphs and are rapid to audit.

Aug 8, 2011

By L E. Howard

Micro-computed tomography (Micro-CT) is an X-ray imaging technique that produces high-resolution 3D computerised ‘virtual’ models of geological specimens based on the X-ray attenuation of different materials in the specimen. The ‘virtual’ specimens are made up of voxels, the 3D equivalent of pixels, each assigned a gray value based on X-ray absorption. Micro-CT has enormous potential for allowing non-destructive, digital analysis of structure and composition when the mineralogical phases can be digitally separated. However, variation in X-ray flux between scans results in highly variable grayscale values for identical materials. Consequently, materials usually have to be segmented manually, which is subjective, inaccurate, labour-intensive and time consuming. Here we present a protocol and imaging software package that can be used to accurately and precisely extract quantifiable information in a repeatable and objective fashion. The software will allow the separation, visualisation, measurement and analysis of spatial and volumetric distribution of different mineral phases without damaging the specimen. This paper explains the potential use of this protocol and software package to ultimately allow automatic segmentation and quantification of gold in drill core samples, removing subjectivity and inaccuracies from data processing.

Sep 5, 2011

By R Bearman

The importance of crushers in the mining industry declined with the introduction and resultant dominance of AG and SAG based circuits, but the recent move to consider more energy efficient circuits has caused the industry to re-consider the role of crushers.Different types of comminution equipment have different efficiency in the way the energy is applied in the size reduction process. Because of the general trend towards more sustainable production processes and emission of carbon dioxide, energy use has become more important. To fully understand how crushers can contribute to optimising the energy application in comminution circuits, detailed models of process performance are required. Such models need to take into account the mechanical design factors and how the crusher performance changes in response to feed conditions, the control strategy utilised and the wear of the crusher liners.It is also critical to analyse the total circuit, not just the individual crushers. To fully understand the performance of the entire circuit, dynamic simulation should be applied. Without the holistic understanding of the total circuit and the incorporation of transient effects, the full circuit performance cannot be adequately determined and the true energy picture will not be quantified.Based on detailed mechanistic modelling of crushers by the authors and the application of dynamic simulation, the opportunities to optimise the use of crushers for energy efficiency are examined.

Aug 8, 2011

Continuous, steady-state laboratory flotation tests showed that the recovery of cha1copyrite from a naturally occurring ore, under conditions closely resembling those of plant practice, could be expressed in terms of a first order rate equation.Tests on full-scale plant flotation cells, using impulse tracers, indicated ideal mixing of the pulp in the cells.It was demonstrated that values of first order flotation rate constants can onlv be obtained from conventional methods of analysis in special cases.Analysis of a plant sampling campaign by the author supported a first order kinetic equation for two mineral species, and for the individual size fractions of one of these.The effect of stage-addition of reagents is interpreted in kinetic terms.

Jan 1, 1966

By V Rasouli, G Cavanough, A Mokaramian

The sampling time, the costs and its quality are the three factors that determine the best method of drilling in mineral exploration. The two principal methods of reverse circulation (RC) and diamond core drilling are often used in combination by mine operators. RC is used for drilling shallow holes and in-pit grade control, and core drilling for deeper holes to identify future resources. The RC method is faster and more flexible than coring and provides virtually uncontaminated cuttings (ranges from dust to 25 mm chips) to the surface cyclone suitable for geochemical anomalies. The diamond coring produces core samples to increase the level of geological knowledge and the 3D extension and distribution of the orebody. However, both of these methods are subjected to certain limitations and inefficiencies in reaching deeper depths and drilling complex hole geometries. Examples of such shortcomings include the inability to provide enough air pressure for RC drilling and high friction between drill pipe and the hole wall in diamond core drilling.Considering that delivering large volume of reliable samples from deep zones to the surface in shortest possible time is of paramount importance in mineral exploration, and assuming that obtaining core samples over whole overburden is not always essential, then drilling small size holes as fast as possible and delivering the small chip samples to the surface would be a good alternative with several advantages over conventional drilling methods for deep hard rocks mineral exploration. As a result, the use of coiled tube (CT) drilling technology has been proposed recently for such applications. CT is a continuous length of ductile steel or composite tube stored and transported on a large reel; and allows fast drilling by eliminating the connection time and providing continuous circulation during drilling. This enables quick access to the zone of interest to collect the cuttings or obtain core samples. CT is advantageous particularly in drilling directional boreholes and multi-laterals. In this paper, feasibility of using CT delivering reliable samples is discussed for deep mineral exploration. In addition, recent developments and practices are presented that make CT a reliable drilling technology to drill cheaper, faster and deeper and to deliver more continuous and reliable data and samples from deep formations.CITATION:Mokaramian, A, Rasouli, V and Cavanough, G, 2012. Quality sampling using coiled tubing drilling in deep mineral exploration, in Proceedings Sampling 2012 , pp 73-80 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 21, 2012

The ore deposits investigated are composed primarily of hcmatite and can be grouped into three categories depending on the amount of leaching of silica and carbonate which has occurred from the original iron formation, and on the amount of recrystallization of the hematite. Minor constituents are magnetite. goethite, and quartz.Texturally. there are five different types of hematite, formed at different stages during the genesis of the ores.These are1. anhedral hematite grains formed by recrystallization of hematite already present in the original iron formation.2. hematite formed by martitization of euhedral magnetite, 3. massive aggregates of fine- to medium-grain hematite formed by recrystallization of (l) and (2).4. tabular or prismatic hematite grains occurring around the boundaries of the massive aggregates or martite euhedra. and in fractures and5. specular hematite. which is present in fractures in ore types (l) to (4).Minor and trace-element analyses, determined using an electron-probe microanalyser. indicated that only silica (less than 0&#183;01 per cent) and cobalt (less than 0&#183;002 per cent) were present in the magnetite and hematite from unaltered iron formation and in the hematite from the ores. Low concentrations of trace elements are typical of magnetite in ores formed as marine precipitates. On the basis of the analyses alone. it proved impossible to distinguish between the five hematite types. A determination of the variation in rare-earth trace element contents between iron oxides in the iron formation and iron oxides in the ores indicates that the rare earths were depleted during ore formation. A possible explanation is that they were removed in solution with silica as it was leached from the iron formation.

Jan 1, 1971

The common notion that the Box Hole Bore mineralization represents a variant of the Mississippi Valley type, has not been supported by the present investigation. Most of the common characteristics of Mississippi Valley type, namely 1. saturated saline brines; 2. low temperature domain; 3. mineralization in intraformational breccias and collapsed anticlinal structures; 4. hydrocarbon-rich or foetid carbonates, and 5. very simple geochemistry seem not to be applicable. The Box Hole Bore mineralization features: 1. moderately saline brines (18% NaCl); 2. very high temperature (495¦-520¦C) and low density brines, of critical vapour:water ratio and low pressure of formation (700 bars); 3. mineralization confined by faults and ex- tending laterally into carbonates of high pore volume such as stromatolitic dolo- mites; 4. ore environment characterized by oxidizing conditions, such as ferruginous carbonate and silica sands of high energy environment (heavy mineral banding) and 5. more complex geochemistry than is normal for Mississippi Valley type deposits (copper sulphosalts, and appreciable silver content). Additionally, the ore has un- usual textures formed by the replacement of carbonates and barite by large idiomorphic galena crystals. The pressure and temperature domains of the Box Hole Bore mineralization indicate post- Devonian emplacement and local high heat flow, possibly related to the Alice Springs Orogeny. Because of high lead and zinc trace element con- tents (100-600 ppm) of the carbonates, even out- side mineralized areas, it is possible that the mineralizing fluids have derived their metal con- tent from a local source, possibly aided by evap- oritic concentrations of the tidal to supratidal sequences. The new model for Box Hole Bore gives treater importance to the confining faults.

Jan 1, 1984

Aspects of the formation, decomposition and acid solubility of zinc ferrite were examined to find potential ways of increasing the recovery of zinc from a calcination process of mineral concentrates. Ferrite can begin to form within 2 hours at 450¦C. while complete reaction can occur after 35 minutes at 700¦C. The nature of the starting materials has a pronounced effect on the rate of formation and below 700¦C. ZnSO4 and Fe2O3 proved to be the least reactive of the materials investigated. It is possible that iron in a mineral admixed h sphalerite can be converted to a relatively inactive form, however, it does not seem possible to prevent zince f formation when iron is in the sphalerite lattice. At the two temperatures examined, 650¦C. and 700¦C, the presence of SO2 in the atmosphere accelerate .e formation of ferrite. Prolonged exposure to such atmospheres, however, caused the ferrite to decompose to ZnSO4 and Fe203. The optimum temperature for decomposition was 650¦C. and it was virtually complete within 2 hours in an atmosphere of 10% SO2 in air. Zinc ferrite was also decomposed by CO at low concentrations, and by heating with limestone at 1000¦C. for at least 2 hours. The solubility of zinc ferrite in acid was influenced by the starting materials used. As both the reaction temperature and the time at temperature increased the acid solubility decreased. The acid solubility was a minimum when the ___i_.. n - I -r~...................c -..... F, fe..i+e --A frn... A01- +^ Z(lo/

Jan 1, 1970