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By Hsun Hu

The microstructural changes during rolling and at various stages of recrystallization in (111)[112] oriented single crystals of Si-Fe have been studied by transmission electron microscopy. At very low deformation, the dislocation structure consists of jogged dislocation lines, edge dislocation dipoles, and numerous dislocation loops, which may be interpreted by the jog-formation mechanism in moving screw dislocations. Up to 70 pct rolling reduction, no sharply defined cells are formed. Subgrain forma- tion takes place somewhat earlier in the annealing process than in a similarly processed (110)[001] crystal. This may be partly responsible for the reported difference in the rate of recrystallization between (111)[112] and (110)[001] crystals. Evidence indicates that the formation of recrystallization nuclei occurs largely by the coalescence of sub -grains. This is consistent with previous observations on other Si-Fe crystals. AVAILABLE data in the literature indicate that the main features of rolling and annealing textures in (111)[112] and (110)[001] crystals are essentially similar. A (111)[112] or (111)[112] crystal can be rolled 70 pct without changing its initial orienta-

Jan 1, 1964

By R. R. Byran, M. H. Kuryla

The Compania de Real del Monte y Pachuca started a 10-ton pilot plant in March, 1906. The distinctive features of the first cyanide installations at Pachuca were: grinding in cyanide solution, all-sliming and filtration of ore in which silver constituted the major value. Loreto started with a 300-ton " all-sliming" plant, using jaw crushers, grinding in stamps, Chilean mills and pebble mills in cyanide solution, concentrating with Wilfley tables and Johnson vanners, classification by cones and Dorr classifiers, intermittent thickening by decantation, mechanical agitation in flat tanks by stirrers and centrifugal pumps, filtration in Butters filters and precipitation by zinc shavings. The "San Francisco" mill No, 1 was contemporaneous, using a rather similar flow sheet. We shall trace the main developlnents in the three large mills of the district to their present practice. Developments in Large Mills of District Crushing and Grinding.—The trend of development in this part of the work has been the same as throughout the milling world; via., all increase in the degree of comminution of the ore in dry-crushing machines, the advance from pebble mill to rock mill and then to ball mill and the elimination of the stamp battery through the encroachment upon its field on the one side by finer dry crushing and on the other by more efficient wet grinding. The single-stage crushing in jaw type crushers, used at the start, has been replaced by two stages; at first, both stages by gyratory type and later the present practice, which is the same in all three mills, consisting of gyratory as primary followed by cone as secondary and delivering a product that may be rated at 56 to 1 inch. Primary wet grinding, at first performed by stamps and Chilean mills, is now by hall and/or rod mills; present practice differing widely in the three mills. Santa Gertrudis uses a 7 by 15 ft. rod mill, San Rafael

Jan 1, 1935

By B. Paul

1. INTRODUCTION It is known that the elastic modulus of a metal may be considerably increased by dispersing

Jan 1, 1961

By Max W. Ball

An intelligent discussion of the oil situation and its needs, whether from the standpoint of the prospector, the operator, the engineer, or the public administrative officer, must be founded upon a knowledge of the law under which oil lands are obtained. A consideration of new legislation must be prefaced by an understanding of the present law and its results. This paper undertakes to present no new remedy for the ills of the present situation, no new solution of the problems the oil business is facing. It attempts merely to summarize the present law, its provisions, its origin, its development, and its effects. The discussion does not pretend to be exhaustive from a legal standpoint. It aims to avoid legal intricacies which tend to. confuse rather than clarify. It seeks but to present the essentials of the existing situation. The title to government lands known to contain valuable deposits of petroleum may be acquired only under the terms of the placer law as embodied in Section 2329 et seq. of the Revised Statutes. As a preliminary to considering the desirability of this situation it is profitable to examine into its origin. Origin of the Law Congress has left no room for doubt as to the legal applicability of the placer law to oil lands. The Act of Feb.11, 1897(29 Stat., 526), provides: "that any person authorized to enter lands under the mining laws of the United States may enter and obtain patent to land containing petroleum or other mineral oils, and chiefly valuable therefor, under the provisions of the laws relating to placer mineral claims.' . The immediate cause for the passage of this Act was stated in a brief report in the, House of Representatives (there was no debate in the Senate) to be a decision of the Department rendered Aug. 27, 1896 (Union Oil Co., 23 L. D., 223), directing the cancellation of an oil placer entry on the ground that land containing petroleum cannot be located and entered as a placer mine. The report of the Public Lands Committee of the House contains the following interesting statements Congressional Record, vol. xxix, p. 1409):

Jan 1, 1915

By Eric R. Jette

In order to control a chemical process by other than empirical, rule of thumb methods, two types of knowledge concerning the reactions involved must be available: (1) the thermodynamics of the reactions, and (2), by no means less important for efficient operation, the mechanisms and kinetics of the reactions. Information on the thermodynamic side enables the operator to decide upon initial and final conditions, whether heat must be added or removed from the system, whether the reactions proceed farthest in the desired direction at high pressure or low, etc. Knowledge of the mechanisms involves the determination of the individual steps by which an initial set of reactants, under given conditions, proceed to give the desired final products and kinetic studies upon which the mechanisms are based give the speed at which each of these reactions or steps take place. Thus thermodynamic studies of a reaction enable the operator to control the direction and extent to which the reaction can proceed, while kinetic studies enable him to control rates and thus the time efficiency of the operations. The thermodynamics set the limit to which the reacting system approaches; the kinetics tell how fast the system actually approaches this limit. The two types of information are complementary and not antagonistic even though in discussing the mechanism the introduction of thermodynamics is entirely needless and generally of no assistance, while in thermodynamic studies mechanism need not even be mentioned. Heterogeneous Reactions The thermodynamic side of metallurgical reactions has received much attention in the past; the mechanisms, relatively, very little. The main reason for our present lack of information on the mechanisms of these reactions lies in the fact that every one of importance is a heterogenkous reaction; i. e., the substances involved in the reaction exist in more than one phase, while, if we neglect the large amount of work which has been

Jan 1, 1931

By Walter Crafts, W. D. Forging, John J. Egan

Although many elements reduce the tendency to porosity in steel castings, manganese, silicon, aluminum, calcium, titanium and zirconium appear to be most generally suitable for the purpose. The manganese and silicon contents are usually maintained in a fairly constant range. Silicon-killed castings often are made to be sound with little or no addition of the stronger degasifiers. In many cases, however, it is more practical to utilize the stronger degasifying elements, aluminum, calcium, titanium and zirconium. Since they greatly modify the composition, shape, and distribution of the nonmetallic inclusions, and thereby the ductility, the strong deoxidizers must be used in such a way as to form the least harmful types of inclusions. As the reasons for failure always to obtain good results have not been obvious, an effort has been made to determine the mechanism of solidification of steels deoxidized to produce certain types of inclusions. Diagrams representsing the mechanism of their formation have been constructed from the appearance of the nonmetallic constituents and have not only illustrated the limiting features of specific deoxidizing treatments with respect to inclusion formation and ductility, but have also indicated a relation between inclusions and resistance to hot tearing. Three different types of deoxidation treatment have been used for obtaining sound castings with relatively high ductility. The first method is to make and cast the steel under such conditions that deoxidation with silicon and a small addition of a strong deoxidizer assures soundness. The effective addition that will promote soundness without causing the formation of intergranular inclusions varies with the furnace practice and composition, but may be limitled to about 0.025 per cent Al, Zr or Ti. Up to 8.10 per cent Ca and 0.15 per cent V are also used for this purpose. The inclusions in these steels are characteristically glassy silicates and round or irregular sulphides. As pointed out by Sims and Lillieqvist,1 the formation of fine intergranular inclusions, which are detrimental to ductility, limits the amount of strong deoxidizers that may be added.

Jan 1, 1940

By John J. Egan, W. D. Forging, Walter Crafts

Although many elements reduce the tendency to porosity in steel castings, manganese, silicon, aluminum, calcium, titanium and zirconium appear to be most generally suitable for the purpose. The manganese and silicon contents are usually maintained in a fairly constant range. Silicon-killed castings often are made to be sound with little or no addition of the stronger degasifiers. In many cases, however, it is more practical to utilize the stronger degasifying elements, aluminum, calcium, titanium and zirconium. Since they greatly modify the composition, shape, and distribution of the nonmetallic inclusions, and thereby the ductility, the strong deoxidizers must be used in such a way as to form the least harmful types of inclusions. As the reasons for failure always to obtain good results have not been obvious, an effort has been made to determine the mechanism of solidification of steels deoxidized to produce certain types of inclusions. Diagrams representsing the mechanism of their formation have been constructed from the appearance of the nonmetallic constituents and have not only illustrated the limiting features of specific deoxidizing treatments with respect to inclusion formation and ductility, but have also indicated a relation between inclusions and resistance to hot tearing. Three different types of deoxidation treatment have been used for obtaining sound castings with relatively high ductility. The first method is to make and cast the steel under such conditions that deoxidation with silicon and a small addition of a strong deoxidizer assures soundness. The effective addition that will promote soundness without causing the formation of intergranular inclusions varies with the furnace practice and composition, but may be limitled to about 0.025 per cent Al, Zr or Ti. Up to 8.10 per cent Ca and 0.15 per cent V are also used for this purpose. The inclusions in these steels are characteristically glassy silicates and round or irregular sulphides. As pointed out by Sims and Lillieqvist,1 the formation of fine intergranular inclusions, which are detrimental to ductility, limits the amount of strong deoxidizers that may be added.

Jan 1, 1940

By Donald E. Crowell

In the fall of 1969, ASARCO and Newmont Mining Co. began the design of the 700tpd concentrator at their Black Cloud shaft located near Leadville, Colo. The concentractor would treat by flotation a Pb-Zn-Ag ore containing minor gold values. Flowsheet design was based on laboratory test work performed at the Minerals Research Testing Laboratory of ASARCO. Since the concentrator is located at an elevation of 11,000 ft, cold weather was a major factor in design considerations. The original capacity was designed as 700 tpd but for various reasons an ultimate capacity of 1,000 tpd was desired. This necessitated special consideration in the design of several areas, particularly the grinding circuit. The grinding circuit chosen was a single 9 X 12 ball mill operating in closed circuit with one 20-in. cyclone. The ball mill will operate at low speed and as an overflow type originally. The mill can be speeded up and converted to grate type for handling the larger tonnage when required. Thickeners and filters were oversized and space was left for additional flotation cells in order to handle the increased tonnage in these areas. Pumps were sized so that they could handle the increased tonnage by increasing their speed. Construction began in May 1970; the Black Cloud concentrator went on-stream in April 1791.

Jan 1, 1974

Human engineering was the keynote of the thirty-ninth annual meeting of the American Society of Mechanical Engineers, which was held in New York, December 3-6. This note was sounded by President Charles T. Main in his address at the opening session and was carried through by all the speakers. In his survey of the year's work, he said that more than 6000 names of engineers were furnished the Government for filling a wide variety of positions. In addition to the 1400 members in service, two members of the council of the society are in uniform in France and one, as a distinct war service, is in charge of one of the largest shipyards. After giving other ways in which the Society has helped the Government, President Main called attention to the necessity for thoroughgoing efforts to increase production and the settlement of questions involving industrial relationships. At the following meeting, President Adams of the American Institute of Electrical Engineers called attention to the necessity of meeting labor in a progressive way, facing labor questions fairly and squarely, as the real interests of labor cannot be separated from those of the engineer. Charles E. Knoeppel, discussing "Industrial Organization as It Affects Executives and Workers," said the problem of the cost of living might be settled in two ways: 1, there must be more producers, and 2, there must be a greater amount supplied by those now producing. The first solution is practicable, he said, if labor is allowed shorter hours, better conditions, and a remuneration that will attract workers. The second can be employed by eliminating waste, standardizing conditions, setting fair tasks, and allowing men to earn an amount that will compensate them for' their skill and cooperation. Dudley R. Kennedy of Philadelphia, employment manager of the American International Shipbuilding Corporation, said the human-engineering phase of the country's industrial development had generally been overlooked. "We hardly yet know what competition means; we will learn it within a few years. Permit me to prophesy that the executive of the next decade will be the man who best knows men. He will be an originator, a handler of men as individuals, a handler of men in the mass, a leader not a driver, a very human man. The science of human engineering is here to stay. The study of human characteristics is the most enduring, as well as the most fascinating in the world, and still the most complex."

Jan 1, 1919

By Fred E. Beasley

Metallurgists have, in the last ten years, overcome many difficulties of high zinc in lead blast-furnace slags. This problem was brought to the front at the close of the war, by the price obtained for lead and the high cost of labor, fuel, and flux. The Port Pirie plant of the Broken Hill Associated Smelters, Australia, early in 1919 had increased the zinc oxide in its blast-furnace slags from 13.5 to 20 per cent., at the same time reducing the iron oxide in the slag from 33.5 to 25.6 per cent. These results were obtained by the addition of 10 to 12 per cent. granulated slag to the roaster charge, improved conditions of the crushing, mixing, and roasting of the constituents of the sinter. By experiments and improvements, the practice at this plant has developed a normal slag that carries 22 per cent. zinc oxide, and at times runs as high as 33 per cent. zinc oxide, with only slight furnace trouble. The granulated slag is used not only as a diluent to the sulfur in the roaster charge, but on account of its value as a slag-forming material and the physical properties it imparts to the finished sinter. The ore is mixed with flux and given a double roast. All the first roasting is by sintering with the Dwight & Lloyd machines. The final roasting is performed partly by Dwight & Lloyd machines and partly by H. & H. pots. The charge to the blast furnace consists chiefly of the final sinter, slag shells, siliceous and non-bearing sulfur lead ores. High blast and ore columns are the practice. The greatest care is taken to obtain in the final sinter as low a sulfur content as possible. Attracted by the success of the Port Pirie plant, The Consolidated Mining & Smelting Co. of Canada, at Trail, B. C., in 1920 treated its crushed primary sinter with about 15 per cent. granulated slag. The Trail smelter at this time was short of ore and a large part of the charge to the roasters consisted of the zinc-plant residue having the following analysis: 12 to 16 per cent. lead, 12 to 16 per cent. zinc, and 25 to 30 per cent. iron. The lead in the final sinter was low and the physical condition was so bad that all the sinter had to be screened before it could be charged to the blast furnace. Also it disintegrated on being trammed and dumped

Jan 1, 1925

By John L. Baum

Tests show that 50 times the earth's normal field can exist near stacked drill rods. Protection against the effect of these strong fields can be obtained by means of a removable sleeve of common iron pipe. GEOLOGISTS and engineers working around a diamond drill rig have often had the opportunity to observe the magnetic attraction of drill rods pulled out of the hole for core removal. This is sometimes an amusing pastime, but this same magnetic force inadvertently applied to a compass needle can cause it to lose its polarity entirely or to become reverse polarized when placed in the immediate vicinity of stacked rods. The first recommendation, of course, would be to avoid the rods, but in surveying an operating drillhole this is not always possible; therefore steps must be taken to neutralize the magnetic effect of the drill rods. Early in the summer of 1949 the geological department of the New Jersey Zinc Co. undertook at Franklin, N. J., an extensive program of surveying the course of deep diamond drillholes. The majority of the holes were surveyed while in the process of being drilled, and considerable difficulty was encountered. A pattern for the deviation of drillholes had been established for the district from surveys in holes from which the drill rig had been removed. It was observed that a certain operating deep drillhole being surveyed did not fit this pattern. In the resulting confusion of repeated surveys and cementing a plug for wedging operations, the lower 1800 ft of the hole was lost. Because of this incident studies were initiated to determine the source of the difficulties and to develop safeguards against recurrence of faulty surveys. Using a hand magnet easily shows that the polarity of a compass needle can be reversed if rotation of the needle is hindered through tilting of the compass or clamping of the mechanism. Such experiments are not recommended, especially in the case of the clockwork type of instruments. A magnetized hairspring in a clockwork instrument will cause the compass card to assume a periodic motion which will not stop until the clockwork runs down. Routine check readings of instrument north before and after each survey are not always sufficient to catch instances of reversed polarity of the compass needle. Although the majority of instances probably take place while the instrument is being removed from the hole with needle in fixed position, it is demonstrable that a 'luggish needle, weakened during a previous test, can be reverse polarized

Jan 1, 1955

By Carl E. Swartz

The Joint Session on Continuous Casting, of the Institute of Metals Division and the Iron and Steel Division of the American Institute of Mining and Metallurgical Engineers, convened in the Jade Room of the Hotel Waldorf-Astoria, New York City, on Feb. 23, 1944, at 9:15 o'clock, Carl E. Swartz presiding. C. E. SWartz.—It is gratifying to see so many out at what may seem an early hour for the beginning of A.I.M.E. sessions, but I think this number-—some fifty or sixty of you —is an adequate expression of the interest in these processes all over the United States, and possibly in foreign countries. I would like to ask those who feel that this type of program is of value to you to write or speak to some one of the Institute of Metals Division officers and suggest other topics for symposiums. We have a feeling that some of these current practices are of interest and we believe that under proper sponsorship many of the companies mill be willing to give publicity to processes such as those that will be discussed today. Also, we would like suggestions and criticisms, so that the next ones can be better. The subject of continuous casting is not new, of course. The two papers on the program this morning will adequately cover the history and some of the earlier processes, some of the theory and some of the practice, some of the reasons why these various methods did not work. I was rather interested in discovering, when thumbing through one of the A.I.M.E. publications tile other night, an article on continuous casting. I was not aware that the A.I.M.E. had published any papers on continuous casting, but there may be a number. The one that I happened to find was published in the 1915 volume, on the Mellen rod-casting process, and so we might say this is not the first session in which these subjects have been under discussion. However, there have been many improvements since then in all fields of metallurgical and mechanical engineering; consequently, I think that the papers today will be a little more involved and a little more complete in their technique. The first paper today will be given by one of our gentlemen of the press, who has done one of the outstanding jobs in this country in calling to our attention some of the newer processes that are being considered and being used in the metallurgical indus-

Jan 1, 1945

By R. W. Woodward, G. K. Burgess

minum bronze. Nearly all copper-base alloys are improved by rolling processes, but the copper-aluminum alloys seem to possess equally good properties when cast or rolled; this is a remarkable metallurgical fact. Another important property of these copper-aluminum alloys is their resistance to alternating stress. Many tests indicate that their resistance is greater in this respect than that of some steels, and I have seen instances when cast aluminum-bronze bolts have outlived five steel bolts in foundation work subject to severe shocks. I mention these various instances to indicate that work originally started as research for substitution of one material for another frequently develops 212 article which has properties not possessed by the original metal or alloy. I have dwelt particularly on the aluminum bronzes because recently I have done more special work on them than on other alloys, but I believe that the use of aluminum itself, in many combinations of metals, is a very important subject for investigation. Undoubtedly, after the war, the cost of aluminum will be reduced from its present price, and considering its low specific gravity it offers a very interesting and important field for research in the non-ferrous business. Naturally, if combinations containing aluminum can be developed in view of a probably increasing supply of metal, the cost will be reduced. This will benefit the industry generally and will immediately conserve tin. Bronzes, Bearing Metals, and Solders G. K. Burgess* and R. W. Woodward,† Washington, D. C.— From a metallurgical standpoint, there are several ways in which a reduction of the tin consumed in commercial non-ferrous and white-metal alloys can be effected. First, a reduction of the tin content of the alloy; second, substitution of part or all of the tin content by some other metal; third, a substitution of a different type of alloy, which in some cases also involves a change in mechanical design. The Bureau of Standards has been studying these methods of conservation for tin alloys, particularly in regard to babbitts and bearing metals, bronzes, and solders. Much of the information sewed by the Bureau was obtained from answers to questionnaires sent to manufacturers and users of these materials, so that, in general, any of the following suggestions or recommendations can be considered as being practical and as having already been thoroughly tried. Bearing Metals There is no question that the tin content of nearly all bearing metals can be reduced to some extent, and in some cases actually eliminated

Jan 1, 1919

By Grover J. Holt

A DETAILED description of the many variations in iron mining and transportation practice in Minnesota would require much space. Since a fairly detailed description of the practices then in use was published in the guidebook issued in connection with the meeting of the Institute on the iron ranges in I920, and subsequent developments have been described by E. E. Hunner,1 M. H. Barber,2 and A. E. Anderson, J. M. Riddell and G. J. Holt,3 it will not be necessary here to do more than review the highlights of current practice. Details on any points of interest can be obtained through correspondence with the operators involved. [T] The iron ores of Minnesota, which have been formed through enrichment of the iron formation in which they occur, largely by the removal of silica, are usually covered by a blanket of glacial drift known locally as "surface." Surface material, including sand, clay, hardpan and boulders, makes up the greater portion of the stripping in open-pit operations. In some instances, stripping also includes taconite and "paint rock," directly below the surface material and overlying the ore. Taconite is the iron formation, a ferruginous chert with interbedded slate layers. "Paint rock" is a local term for oxidized slate layers interbedded in the iron formation, high in phosphorus, alumina and moisture. The iron ores fall into two classes: (I) direct shipping (merchantable ores or ores requiring no treatment except possibly crushing or screening to make an acceptable sized product), and (2) ores requiring beneficiation (such as sintering, drying, washing, jigging, high-density treatment, or magnetic separation in the case of magnetite). The Mesabi Range produces chiefly soft Bessemer and non-Bessemer ores. The Cuyuna Range produces mainly low-manganese brown ore and high-manganese black ores, with some iron ore. The Vermilion Range yields mainly Besse¬mer and non-Bessemer iron ore, with some hard or lump ore that finds use in the open hearth. Open-pit mining is limited to the Mesabi and Cuyuna Ranges but underground mining is done on all three. The choice of mining methods is determined by the relative economics of overburden¬-removal and shaft-mining costs. STRIPPING PRACTICE Common practice has been to remove the bulk of the overburden during the winter season and to mine during the summer. In the present emergency many operators are forced to forego the economies attained by year-round utilization of equipment and to equip for, and carry on, stripping and mining simultaneously. In the normal years or lean years to come, most properties probably will be over-equipped and high depreciation charges will have to be absorbed.

Jan 1, 1942

By W. C. Hagel

Previous inuestigators have repovted unusually low H* and Do values for self-dzf@szon in certazn bcc metals, e.g., chromium nnd y -uvanium. It has been postulated that this is nn experimental crl -tetion for the existpnce of a four -atom ring meclzanzsm, mid there could be. zmpovtant theoretrcal Implicatlons. By utilizing a precise sectioning technique with Cr51 as the tracer, self-dzffi-lsion measurements in large grains of 99.99-pct Cr were extended from 1200° fo 1600"C. A least- squares analysis of the data yields that D 0.280 exp (-73,20U/RT) cm2 sec-'. These AH* and Do unlues are not anomalous; there is little reason to believe that n vacancy mechanism is not opevatiue. Apparent differences at lower temperatures may result from preferential diffusion along short-circuititing paths and/or sample contamination. WITH continued technological effort, chromium and chromium-base alloys should ultimately become useful high-temperature structural materials. Accurate measurements of self-diffusion coefficients in the pure metal are necessary for a quantitative understanding of sintering, grain growth, creep, and other related rate processes. However, two conflicting determinations have been reported.* Using an Since careful diffusion studies normally yield Do values ranging from 0.1 to 10 cm2 sec-l, the Paxton-Gondolf results require independent experimental corroboration before an undue amount of speculation arises to explain the apparent anomaly. As discussed by Nowick6 and clearly shown by Hoffman and Turn-bull7 for self-diffusion in silver, a low AH* and Do can arise from preferential diffusion along grain boundaries or other short-circuiting paths. The most reliable data come from high-temperature measurements where volume effects predominate. Following a precise sectioning technique developed for determining silver diffusion in the intermetallic compound AgMg8 and cation diffusion in the corundum oxide Cr2O3,9 the purpose of this study was to measure true volume diffusion in high-purity, large-grain samples at higher temperatures than considered previously. Another point of interest is the frequent proposal10-12 that chromium undergoes an allotropic transformation between 1375" and 1800°C where the diffusion data might then show a discontinuity. I EXPERIMENTAL 1) Sample Preparation. The highest purity (99.997 pet) Cr currently available is produced by reduction of chromium tri-iodide. Three pounds of the resulting crystal bar were shipped in a sealed container with a complete chemical analysis from the vendor.* In conformity with the procedure used for

Jan 1, 1962

By E. R. Buchanan, R. E. Reed-Hill

A transmission electron microscope study was made of magnesium single crystals deformed in torsion using the basal pole as the forsional axis. While this type of deformation is predicted to result in the formation of hexagonal networks of screw dislocations, these networks were not observed. The basic dislocation arrangement consisted of arrays of nearly parallel and approximately equally spaced dislocations. The average dislocation density was over an order of magnitude higher than that required to account for the torsional deformation. The observed high rate of work hardening in these crystals is consistent with both their high dislocation densities and the arrangement of dislocations in pile-ups. The experimental observations are also in agreement with the assumption that dislocation sources are activated not only at the surface but at interior locations as well. In considering torsional deformation, Amelinckx and Dekeyser1 postulated that when a torque is applied to a crystal oriented with a glide plane normal to the specimen axis, deformation occurs by the following steps: 1) Nucleation of dislocation sources at or near the specimen surface in areas where the shear stress, resolved along a slip Burgers vector, is a maximum; 2) the screw orientations of the dislocations accommodating the twist move inwards towards the specimen center. If two glide directions lie on the glide plane, the geometry shown in Fig. 1 should result; 3) the screw dislocations that pile up in the central part of the specimen cross-slip to form a grid. At the same time, screws of opposite sign and most edges leave the specimen. Tinder,2 using zinc crystals twisted about the basal pole, independently reached essentially the same conclusions. He suggested a mechanism involving nucleation of ?(1120) screw dislocations at the six points of highest resolved shear stress that lie on the cross-section near the surface. Under the applied shear stress these dislocations were assumed to move inward and interact so as to form a hexagonal network of screw dislocations. Today it is often accepted that rotational slip occurs by a mechanism of the above type, but to our understanding this has never been experimentally proved. This paper reports an experimental study of rotational slip, using magnesium single crystals, that indicates that in this metal rotational slip does not conform well to this mechanism. EXPERIMENTAL PROCEDURES Mechanical Testing. Specimens with a (0002) axis were prepared from magnesium crystals of 99.95 pct purity grown by Jillson's3 modified Bridgman technique. The crystals were acid machined into cylindri-

Jan 1, 1970

By Z. E. Arlin, R. D. Lynn

A deep well injection system is used by The Anaconda Co. for the disposal of uranium mill tailing water near Grants, N. M. A 2511-ft hole was cored and tested through Triassic, Permian, and Pennsylvanian (?) sediments and bottomed in Precambrian granite gneiss. The disposal well was plugged back to 1830 ft and completed in 563 ft of sandstones in the Yeso formation. The reservoir sandstones contain water similar to the injected waste water, and are isolated from overlying fresh-water aquifers by an evaporite barrier zone. Mill tailing water is decanted, filtered, and introduced into the well by gravity at an average rate of 400 gpm. The reservoir has a life expectancy of 10 years. The Anaconda Co. began uranium milling operations near Grants, N. M. in 1953 with a small mill that processed limestone ores. A larger second mill was built in 1955 to treat sandstone ores. In 1956 it became apparent that a large tailing pond would be required to contain the increased discharge of mill waste water. Research was begun on supplementary methods of disposal by which a minimal pond size could be maintained to avert excessive seepage losses. An intensive sampling program was begun to monitor the fresh-water wells in the area. The original limestone mill ceased operation in 1959. The present mill treats sandstone ores by sulfuric acid leach and a resin-in-pulp ion exchange recovery circuit that uses chloride elution. Process waste water is discharged to a tailing pond where, after evaporation losses, an annual average of about 400 gpm are available for injection into the disposal well. The waste water is a mildly acid solution that contains large amounts of manganese, iron, and the sulfate and chloride salts of sodium, calcium, and magnesium. It is a low-level radioactive fluid that contains small amounts of Uranium-natural, Thorium-230, and Radium-226. The average chemical and radioactive analyses of the waste water injected into the disposal well are shown in Column B of Table I. Disposal of the excess mill waste water by deep well injection was investigated after extensive research had proved that alternate methods were not satisfactory. A study of the regional geology and hydrology indicated that a disposal well was feasible, and a test well to basement rock was planned. Tentative plans for the test well and the results of the geologic and hydrologic studies were submitted to the New Mexico Dept. of Public Health, the New Mexico State Engineer's Office, the U.S. Atomic

Jan 1, 1962

A cooperative service for engineers and their employers under the direction, of the American Institute of Mining and Metallurgical Engineers; American Society of Civil Engineers; American Society of Mechanical Engineers; and American Institute of Electrical Engineers, and with the cooperation in Chicago of the Western Society of Engineers, and in San Francisco of the California Section of the American Chemical Society and the Engineers Club of San Francisco. For information as to men available or positions open, address the nearest office. New York Walter V. Brown Manager, 31 West 39th St., Telephone Penn. 9220 Chicago A. Krauser, Manager, Room 1736, 53 West Jackson Boulevard, Telephone Harrison 1238 San Francisco Newton D. Cook, Manager, Room 715, 57 Post . St., Telephone Sutter 1684 UNITED ENGINEERING SOCIETY This is a corporation organized by the American Institute of Mining Engineers, American Society of Mechanical Engineers and the American Institute of Electrical Engineers to hold the title and administer the property at 29 West 39th St. In 1916 the American Society of Civil Engineers was admitted, and each society now holds an equal one-fourth interest in the ownership, occupancy, and administration of the building. The value of this property is estimated at two million dollars. A. I. M. E. representatives are : Arthur S. Dwight, J. Vipond Davies and J. V. N. Dorr. ALFRED D. FLINN, Secretary, 29 West 39th St., New York City. ENGINEERING FOUNDATION This is a fund established by the United Engineering Society in 1915 with a gift of $200,000 from Ambrose Swasey. Subsequent gifts had increased the fund to $600,000 on Jan. 1, 1927. The income, of the fund is used to further research in science and engineering and to advance the profession of engineering and the good of mankind. A. T. M. E. representatives are: H, M. Boylston, J. Vipond Davies, Galen H, Clevenger. ALFRED D. FLINN, Secretary, 29 West 39th St,, New York City.

Jan 1, 1928

By D. C. Buffum, L. D. Jaffee

THAT the path of brittle fracture in temper brit-tle steel differs from the path in unembrittled steel has been known for some years1 More recently it has been recognized that alloy steels, at least, display two forms of temper brittleness1 which may be called upper-nose and lower-nose. No experimental evidence has been published, however, to show that the two forms can be distinguished by simple inspection of brittle fractures. Fig. 1 is a photograph of the fractured surface of a V-notch Charpy specimen of SAE 3140 steel in which temper brittleness developed during heat treatment in the lower-nose temperature range.' The steel was austenitized 1 hr at 900°, tempered 1 hr at 675", and embrittled 48 hr at 500°C, with water-quenching after each treatment. The temperature of transition from ductile to brittle fracture in the Charpy test was + 2°C (criterion of transition: 100 pet fibrous). The hardness was Re 25; the austenite grain size ASTM 8. This specimen was broken at 150°C in the standard Charpy test and absorbed 6.6 ft-lb; its fracture was rated 0 pet fibrous. Fig. 1 shows that the fracture appeared rough to the naked eye. At the side of the specimen away from the notch (the side which was in compression during the test), the surface as a whole deviated sharply from a plane. At higher magnification, X60, the surface gave

Jan 1, 1959

By J. F. Butler

The degree and type of carbide dispersion resulting from changes in the cooling rate from austenite determine the amount of carbon remaining in solution after slow cooling- from a subsequent subcritical annealing treatment. A difjusion model has been proposecl to explain the effect of carbide dispersion on the amount of carbon retained in solution and the amount of carbon in solution has been related to the degree of carbon strain aging. COTTRELL and Leak' have shown that the rate of strain aging in low-carbon steels is dependent upon the amount of carbon and nitrogen in solution. Carbon can be effectively removed from solution as Fe , C by quench aging at temperatures of 200" C or lower; however, the relatively higher solubility of nitrogen at these temperatures prevents sufficient removal of nitrogen as iron nitrides. For this reason, nitrogen in solution has been considered the major cause of strain aging in rimming grades of commercial low-carbon steels. Nitrogen can be effectively removed from solution and nonaging steel produced through the addition of aluminum to form the stable nitride, AlN; however, the aluminum also causes deoxidation resulting in a killed steel. III an attempt to produce a rimmed steel which was also nonaging, Morgan and Shyne 2 investigated tile strain-aging properties of low-carban steels containing boron and found that strain aging was suplx-essed in steels containing as little as 0.007 pet B. The original purpose of this investigation was to determine the mechanism of strain-aging suppression by boron. Early in the study, the function of boron was discovered to be much like that of aluminum in that the formation of a nitride, BN, removed the nitrogen from solution.' However, during the course of the investigation, an effect of heat treatment upon the strain-aging properties and the amount of carbon in solution was found which could be related to the microstructure of the steel. The purpose of this paper is to examine these relationships among heat treatment, microstructure, carbon in solution, and strain aging in steels where nondetectable amounts of nitrogen are present in solution. EXPERIMENTAL PROCEDURE The investigation was carried out using 0.030 in. by 12. in wire specimens which had been cold swaged and drawn to the final diameter. Table I lists the compositions of the low-carbon steels used. Those with 'V' designations were vacuum melted and cast; the alloys designated 'AISI' were prepared from high-purity iron obtained from the American

Jan 1, 1962