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By Dever C. Ashmead

Coal companies in the anthracite region are studying various methods of mining, seeking one that will shorten considerably the life of the gangway and thus decrease the maintenance charges. In steep pitching measures, the maintenance charges of the gangways are high because of the cost of replacing timbers and cleaning up falls. Therefore, if the length of the gangways can be decreased and the mining made more concentrated, the life of the coal gangways will be decreased and the maintenance charges per ton of coal produced will be smaller. The practice in the anthracite region is to drive long coal gangways and to work the breasts as the gangway from which they were driven is advanced. In many cases these gangways are from 4000 to 6000 ft. in length; and some are even longer. As these must be maintained not only until they have reached their limit but until second mining begins (which may be some years later), the maintenance charges are high. If the gangway is allowed to close, when the time comes to remove the pillars the cost of re-opening it may be as expensive as the original driving cost. The Lehigh and Wilkes-Barre Coal Co., at its Wanamie Colliery at Wanamie, Pa., has been using a system of mining that, as far as the writer knows, is not used in any other place in the anthracite fields. The

Jan 1, 1925

ENGINEERS AVAILABLE. (Under this heading will be published notes sent to the Secretary of the Institute by members or other persons.) Member, graduate of College of Mines of University of California, with 12 years' operating experience in mining and milling in California, Canada, and Mexico, is open for engagement. Speaks Spanish fluently. No. 17. Mining engineer and metallurgist open for engagement Jan. 1 as superintendent of mines or constructing engineer. Technically educated, with 14 years' experience in United States and Latin America in concentration, amalgamation, cyaniding, constructing. At present building large modern .all-sliming cyanide mill in Central America. No. 18. Member, mining and metallurgical engineer, is open to engagement. Specialty, the treatment of copper ores. Nine years' experience in the operation and also in the design and erection of copper smelteries. Four years true pyrite smelting. Able to organize the administration, accounting, etc., of a large plant. Speaks a fair amount of Spanish, Russian, German, and French. Qualified to take charge of a large smeltery, or to act as assistant to manager of a combined mining and smelting concern. No. 19. Member, technical graduate, 33 years old, 11 years' experience as chemist, metallurgist, and superintendent of lixiviation plant and in charge of construction of cyanide mill, is open for engagement. Speaks Spanish. No. 21. Member, lately with the Bishop Creek Milling Co., California, is now open for engagement as mine superintendent or superintendent of construction of mine and mill structures. No. 25.

Jan 12, 1913

By Frederick Laist

F. N. FLYNN, Clifton, Ariz.-I would like to ask Mr. Mathewson what percentage of his leaching liquor is wasted at this time? It has a bearing on the question in connection with the New Cornelia, and I think it is a very important question. E. P. MATHEWSON, Anaconda, Mont.-I am not sure what the percentage is now, but we don't discard the strong liquors. Something like 25 per cent. of the wash water taken out each day is sent over a special set of scrap iron tanks, and the copper recovered there. We had a little trouble at first. We did not proceed to use the sponge iron for the reason that the plant we originally contemplated was abandoned for flotation. Our original idea was to use a leaching process on all the tailings of the mill, but we found it would take a great deal of time to build a plant; and the cost of operating the plant we estimated to be about the same and the recovery the same. It was a question of time with us, and we decided to adopt flotation. That changed our plans. We now have the leaching plant, treating the tailings of the old dump, and the flotation applied to the current tailings. The sponge iron was figured for the large plant. We can get all the scrap iron necessary for the small plant-plenty from the scrap produced in the main plant of the smelter.

Jan 12, 1916

By Kent E. McElhattan

Selecting efficient machinery for an underground mining operation is a highly skilled art that still depends largely on human judgment and experience. In a coal mine, for example, there is no better way to predict the results of operating with a cutting machine or a continuous miner than to go underground with a sharp-pointed miner's pick. The trained eye can detect the depth of point penetration, cleavage planes, roof and floor strata, and many other conditions impossible to determine in a laboratory. Even so, however, an entirely new set of conditions may lie unexposed just a few feet behind the solid face. The candid truth of the matter is that practically nothing is known of the phenomenon of extracting a mineral from a solid. Consequently, the selection of mineral extraction machinery and systems must be based on results obtained elsewhere under apparently similar conditions. A recent study of the problem of equipment and system analysis was conducted in the coal mining regions of West Virginia. This state was chosen for study because it afforded representative sampling. The 172 coal mines investigated ecompassed seam heights ranging from less than 30 in. to over 84 in. and covered virtually all known coal mining conditions except two. The exceptions are the extreme pitch of coal seams in the western United States and British Columbia and the "bumps" encountered in the Rocky Mountains. Both of these extreme conditions are worthy of individual study.

Jan 7, 1969

By J. E. Burke

THE origin of recrystallization textures continues to be a matter of controversy. One explanation is that a recrystallization texture occurs because only grains having a limited range of orientations ever appear in the deformed matrix—the oriented nuclea-tion* hypothesis. Another explanation is that grains essentially having all orientations are nucleated but that those having certain orientations grow much more rapidly than any others in the deformation texture, and thus only the rapidly growing grains survive when recrystallization is complete. There has recently appeared a great deal of evidence'- indicate that recrystallized grains of face-centered cubic metals are frequently related to their parent grains by rotations of 20" to 40" about a common [lll] direction. Furthermore, it has been observed that the growth rate of the new grains depends upon their orientations with respect to the matrix, and that the most rapidly growing grains lie within the stated range of orientations. In a recent note, Beck7 has concluded from observations of this type that oriented growth alone is responsible for the appearance of preferred orientations in re-crystallized metals. It should be pointed out. however, that many of the available data indicate that oriented nucleation operates in addition to oriented growth. Thus, while oriented growth may permit a selection to be made among nuclei of several orientations, only a limited number of orientations are available in the first place for such selection.

Jan 1, 1953

By H. R. Gardner

THE wide variation in tension and compression properties' which exist between the a,ß and ? phases of plutonium indicate that a study of the impact properties would give a greater insight into the variables affecting the mechanical properties and formability of plutonium. In tension the a phase is quite brittle with elongations less than 1 pct. The ß phase at normal test speeds is unusually ductile; elongations up to 621 pct have been obtained. However, the ß phase is quite sensitive to strain rate; elongations decrease rapidly as strain rate is increased. The y and 6 phases are less ductile than the ß phase, with the 5 phase the more ductile of the two. Neither are very sensitive to strain rate. Considering the brittle nature of a Pu in tension and compression and the strain rate sensitivity of ß -phase Pu, both unnotched Charpy specimens and standard V-notched Charpy specimens were fabricated for testing. In addition, since iron in amounts greater than 500 ppm forms a Pu-PlgFe eutectic network which inhibits microcracking in as-cast plutonium,' it was decided to prepare impact specimens with low and high iron contents. Chemical analysis and density data for the impact specimens are presented in Table I. A total of 55 impact specimens, 32 unnotched and 23 with the standard Charpy V-notch were tested at temperatures from —45' to 330°C. The test results for both unnotched and notched specimens are illustrated in Fig. 1.

Jan 1, 1962

By Arthur Taggart

IN 1900, Elmore found that if an acidulated pulp was stirred up with an oil which was relatively insoluble in and lighter than water, and the mixture was al-lowed to stratify, much of the sulfide would be found hanging to the lower surface of the floating body of oil and could be skimmed off or overflowed with it. The action of the flotation agent here is two-fold, first to select the sulfide from the gangue-what to-day is called collection-and second, to buoy the col-lected sulfide away from the gangue. The action in collecting is illustrated by Fig. 1, which contrasts the behavior of drops of oil brought, under water, to the surfaces of gangue and sulfide particles, respectively. The oil displaces water from the surface of the sulfide; the water displaces oil from the gangue surface. If, instead of considering the solid particles the fixed parts of the system of oil, water and solids, we consider the oil and water fixed and the solids pre-sented to the surface of contact, the condition will be as shown in Fig. 2 ; the sulfide tends to be drawn into the interface and the gangue to be excluded. The sul-fide particles are held in the oil-water surface by the tension of this surface. The buoyant effect is supplied by the oil droplets in bringing the sulfides to the water surface, but not in holding them there.

Jan 6, 1928

By R. Gatewood

The solution here offered is at once simple and important in its direct and indirect bearings. According to the principles of surface-tension, which will be found sufficiently enlarged upon for present purposes in Clerk Maxwell's excellent little treatise on The Theory of Heat, a mechanical mixture of liquids will frequently of itself divide into groups, consisting of liquids mixing among themselves but withdrawing from the other liquids. The following simple and familiar illustration will suffice: " If we mix water with alcohol, the liquids diffuse into each other. If we now attempt to mix oil with the alcohol and water, the two liquids separate from each other of themselves, and in the act of separation sufficient force is brought into play to set in motion considerable masses of the fluids." Maxwell goes on to show that this relative energy is one of arrangement, depending on the nature of the fluids and the area of the surface of contact, the act of separation tending to reduce this surface to a minimum consistent with equilibrium; that this surface-tension exists between a solid and touching fluid, either liquid or gaseous, being of one sign or the other, in the case of a liquid, according as it tends to draw itself up into a drop on its surface or to spread and wet the solid. After considering various cases, lie states that which particularly interests us, thus : " When a solid body is in contact with two fluids, then, if the

Jan 1, 1885

By H. O. Hofman

Lime-roasting is a term proposed by Ingalls' for the operation of forcing air under pressure through a mixture of galena and lime at the kindling-temperature with the object of oxidizing lead and sulphur and of fritting or fusing the charge. If finely-divided galena were treated in this manner without the addition of lime, the heat set free by the oxidation of part of the lead and the sulphur would be sufficiently great to fuse un-decomposed sulphide, and thus stop desulphurization. Besides the chemical action that the addition of lime, limestone or gypsum to the charge may have, the admixture has the physical effect that it keeps the particles of galena separated from one another and accessible to the oxidizing effect of the air. At present, three methods of lime-roasting are carried out on a working-scale,—the Huntington-Heberlein, the Carmichael-Bradford and the Savelsberg2 processes. In the last, which interests us here, an 8-ton charge is made up of galena, limestone and perhaps some siliceous or ferruginous flux; the whole is crushed to pass a screen with 3-mm. holes and moistened with 5 per cent. of water. It is fed gradually into a bowl-shaped converter, 6.56 ft. in diameter, supported by trunnions attached to a truck. On the bottom the converter has a grate with blast-inlet beneath. In starting, the truck with the converter

Jan 1, 1908

By R. P. Agarwala, M. S. Anand

Using residual activity technique, the diffusion of palladium, silver, cadmium, indium, and tin in alunzinum has been studied in the temperature range of 400" to 630°C. The diffusivities (in units of square centimeters per second) have been expressed as: IMPURITY diffusion in aluminum,1-9 silverand lead5 for cases of low solid solubility of the impurity in the host metal has yielded frequency factors in the range of l0-6 to l0-9 sq cm per sec whereas the activation energy is practically half the self-diffusion activation energy value. From the observed values of frequency factor, activation energy, and entropy of activation, it has been suggested' that these solutes are not diffusing by vacancy or interstitial mechanisms but by a mechanism which should be consistent with such low values of the diffusion parameters (Do and Q). However in spite of extensive work on these types of systems, the mechanism of diffusion is still not well understood. The present investigation on the diffusion of palladium, silver, cadmium, indium, and tin in aluminum has been carried out to throw further light on the diffusion mechanism in systems, where the solid solubility is very low (except for the case of silver). The results are discussed on the basis of solid solubility and the structural changes involved owing to the presence of the solutes in aluminum solid solution. An attempt has also been made to apply the existing theories of charge5-8 and size8 difference between the solute and the solvent. EXPERIMENTAL PROCEDURE Specimens (1/2 in. diam by 3/8 in. high) were machined out of pure aluminum (99.995 wt pct) rod obtained from Johnson Mattheys. They were sealed under vacuum in quartz tubes and annealed at 620° C for several hours; the grains thus developed were sufficiently large to eliminate the possibility of diffusion along the grain boundaries. The flat ends were prepared carefully after polishing as described previously,10 Radioactive nitrates of cadmium, indium, and tin and chloride of palladium containing, respectively, cd115, 1n114, sn113, and pd103 were dissolved in distilled water and mixed with 30 pct acetone. By means of a micropipet a drop of this solution was placed on a smoothly polished and lightly etched surface of the specimen. Due care was taken to see that the solution spread uniformly on the surface of specimen without trickling down its sides. Radioactive silver was elec-trodeposited using a AgCN-KCN bath. The amount of sample deposited in all the cases was not more than 0.1 µ thick. The samples were then sealed in quartz tubes in vacuum. The cadmium samples were sealed in a purified argon atmosphere to avoid evaporation. The samples were then diffusion-annealed. The temperature of annealing varied between 400° and 630°C and was controlled to ±5°C. On heating to -400°C,the deposits of cadmium, indium, and tin, which were of the order of 0.1 p in thickness, were converted to their respective oxides. The contribution of oxygen present in the lattice of aluminum due to these oxides has been calculated and found to be less than 10 ppm in all cases. Oxide method has already been used by other workers11'12 in diffusion studies without any controversy on the issue. However, in some of these investigations, metallic deposition was also tried. The diffusivities calculated from these measurements were found to agree very well with the diffusivities obtained by using the oxide method. Thus it is assumed that the measured diffusivities represent true diffusion coefficients. Since palladous chloride decomposes at about 500°C, the deposited samples which were to be diffusion-annealed below 500°C were heated in vacuum for a very short time at 500°C to allow the decomposition of palladous chloride to palladium metal. Time taken in decomposition of nitrates to oxides and chloride to metal was negligibly small as compared to the period of the diffusion anneals. The residual activity technique13 was used to study the diffusion profiles where thin layers from the specimen surface were removed by grinding it parallel to a flat surface on a 600-grade carborundum paper. The specimen was washed, dried, and weighed, the differ -ence of the weight being the measure of the thickness of the layer removed. After each such abrasion and weighing, the total residual activity on the surface of the specimens was measured by counting 0.656, 0.94,

Jan 1, 1968

By C. R. Clark, G. Swift, D. S. Roberts

The purpose of this investigation was to measure PVT behavior of various types and combinations of heavy hydrocarbon components from the paraffinic, naphthenic and aromatic classes where the relative proportions Of the various components were selected to approximate those of natural gas or gas condensate systems. Synthetic mixtures were used so that the compositions Of the various components could be measured accurately. n-Heptane, methylcyclohexane and methylbenzene were used to represent the paraffinic, naphthenic and aromatic components of the heavy fraction. In the mixtures studied, the heavy fraction composition was held constant at O. O5-mole lraction, the balance being methane except for one mixture where 0.10-mo1e fraction of an intermediate component, propane, was added. The PVT data for the mixtures were determined in a variable-volume, constant-mass apparatus at psuedo-reducedtemperatures from 1.84 to 2.00, over a pseudo-reduced pressure range from 2.3 to 12.0. The experimental results showed that, regardless of the type of heavy material (paraffinic, naphthenic, aromatic, or combinations thereof) mixed with methane or methane and propane, the compressibility factors at equal values of pseudo-reduced temperature and pressure varied by less than 2.2 percent. INTRODUCTION PVT data is used for natural gas and gas condensate fluids in determining reserves of reservoirs and performance of wells, in metering produced fluids, and in recombining samples for laboratory studies. While there are vast amounts of PVT data reported for natural gas and gas condensate systems from which useful correlations have been developed, ' the compositional analyses for these systems and the resultant correlations typically were made with components analyzed through some arbitrary carbon number, usually C6, with the residue reported as a lumped "heavy" fraction. The heavy fraction was stoichiometrically recombined on the basis of an apparent molecular weight to give the final compositional analysis. It is virtually impossible to make a systematic analysis of the effect that variation of the relative amounts of paraffinic, naphthenic and aromatic constituents of the heavy fraction of natural systems might have on PVT behavior. Because there is considerable latitude in the relative amounts of these constituents, one speaks of crudes or condensate liquids as being "paraffin base", etc. It is of interest to determine if changes in the relative amounts of these three types of hydrocarbons in the heavy fraction cause significant changes in PVT behavior. If so, steps should be taken to describe better the nature of the heavy fraction in PVT correlations. If not, more confidence can be placed in the correlations presently employed. DESIGN OF THE EXPERIMENTAL INVESTIGATION We attempted to determine if changes in the base of the heavy fraction would cause significant changes in the PVT behavior of gas or gas condensate fluids. Synthetic mixtures were used to enable us to systematically vary the base of the heavy fraction and to analyze accurately the fluids. We found that the heavy fraction of naturally occurring condensate systems seldom exceeds 0.05-mole fraction. Thus, the mole fraction of the heavy fraction in the synthetic systems studied was set arbitrarily at 0.05, to maximize whatever deviations in PVT behavior that might occur. Further, we judged that since the C7 hydrocarbons normally are present in greater quantities than higher carbon number hydrocarbons in naturally occurring systems, the use of n-heptane, methyl cyclohexane, and methylbenzene to represent the paraffinic, naphthenic, and aromatic species in the heavy fraction would be most appropriate. Finally, to enable us to compare our

Jan 1, 1970

By J. Philibert, A. G. Guy

Diffusion in the presence of deformation was studied by the method of vacuum dezincification of copper-rich and silver-rich solid solutions containing 7 to 30 pct Zn. The specimens were designed to permit the study of diffusion in separate portions of a given specimen characterized by strain rates ranging from essentially zero to approximately 10 sec-. No effect of deformation on diffusion was observed. BEGINNING with the work of Buffington and Cohen: interest in the question of the effect of stress or strain on diffusion has largely been concentrated on the enhancement of diffusion in specimens subjected to Continuous plastic deformation. The present research is a contribution to this limited area. However, as a preliminary to focusing attention on this special topic, it will be desirable to make a broad survey of the larger question, especially since there has been considerable foreign work in areas outside those of current interest in the United States. Since most of the topics referred to in the following section are both complex and imperfectly understood at present, it has been expedient in most instances to offer only a guide to the general nature of the work rather than a critical evaluation. PREVIOUS WORK The effect of elastic stress on diffusion has received considerable attention, especially with regard to the thermodynamic driving force for diffusion. The thermodynamic treatments have been based on the work of Gibb, Voigt, Planck, and Leontovich.' Konobeevskii and Selisski6 made a first attempt at treating the problem in 1933, and Gorskii7 a few years later gave a solution applicable to single crystals as well as to polycrystalline specimens. In 1943 Konobeevski8 published treatments that have been the basis of much Russian work up to the present. For example, Aleksandrov and Lyubov used his work in explaining the velocity of lateral growth of pearlite. Early work in the United States was that of Mooradian and Norton, which showed that lattice distortion tends to be relieved before it can significantly affect the diffusion process. Druyvesteyn and Berghoutl1 observed a slight effect of elastic strain on self-diffusion in copper, while de Kazinczy12 found that both elastic and plastic deformation increased the rate of diffusion of hydrogen in steel. On the other hand, Grimes58 observed no effect of either elastic or plastic straining on the diffusion of hydrogen in nickel. High-frequency alternating stresses have been reported by various investigator s13-l5 to increase the rate of diffusion. A special form of elastic stressing is the imposition of hydrostatic pressure, a condition that is amenable to Conventional thermodvnamic analysis. Most of the experimental results in this area are consistent in showing a slight decrease in diffusion rates at high pressures.16-l8 Although Geguzinl reported a pronounced effect of relatively small pressures, Barnes and Mazey20 failed to Corroborate this finding, while Guy and Spinelli21 advanced an explanation of the phenomenon observed by Geguzin. It has been recognized that the thermodynamic treatment of diffusion phenomena in an arbitrarily stressed body is complicated by the fact that the desired state of quasi-equilibrium of the shear stresses cannot be maintained during a general diffusion process. However, attempts have been made by Meix-ner22-24 and Fasto to treat certain restricted cases, such as relaxation. FastovZ7 has also incorporated the general stress tensor into the thermodynamics of irreversible processes. The lattice strain that accompanies the formation of a solid solution has been the subject of much study,28-s0 and indirectly it has entered into many recent theories of diffusion. However, some Russian investigators31'32 have taken other views of this matter and have predicted large effects on diffusion rates because of concentration stresses.o In completing this brief resume of previous work involving elastic strains and before proceeding to a consideration of the effect of continuous plastic deformation, it should be pointed out that deformation of various additional types may also influence diffusion. The effect of cold-working on subsequent diffusion has been studied directly by AndreevaS and by Schumann and Erdmann-Jesnitzer, while indirect evidence has been obtained by Miller and Guarnieri and by Vitman.38 Thermal stresses may also influence diffusion, contributions to this subject having been made by Fastovs7 and by Aleksandrov and Lyubv. The work of Johnson and Martin,o Dienes and Damask,3Band DamaskS considered the question of radiation-enhanced diffusion. In considering previous work on the subject of plastic deformation and diffusion, attention will be directed to those studies concerned primarily with diffusion rather than with its relation to Creep, e.g., the work of Dorn, or to the acceleration of diffusion -controlled reactions. Observations of the effect of

Jan 1, 1962

The greatest mining center in the state of Utah is the incorporated town of Bingham about twenty-five miles southwest of Salt Lake City. The principal industry of this vicinity, prior to the early fall of 1863, was lumbering and the first saw-mill in the state was built near the mouth of Bingham Canyon. Early in the fall of that year. George B. Ogilvie discovered gold and shortly afterward the first mining district in the state was organized. Some writers place the discovery of gold in the canyon in the late fifties. If this be so, however, the matter was kept extremely quiet because no mining was engaged in until after Ogilvie's discovery. Bingham was a placer mining camp, producing about one million dollars' worth of dust and nuggets from placers up and down the canyon and in Bear Gulch until early in the seventies, or about ten years after the discovery of gold, when a large body of argentiferous lead ore was discovered and soon after heavy shipments were made from a half dozen or more properties.

Jan 1, 1925

By C. S. Matthews, M. J. Fischer

Distortions caused by dip on five-spot sweep pattern were determined by visual experiments on a model composed of parallel plates of glass with holes drilled at the well positions. This model war designed to simulate a reservoir depleted of its primary oil and containing a gas phase. Prior to interference, it was found that the injected fluid took a nearly circular shape about the injection well for the cases studied. However, these circles moved down-dip considerably under the influence of gravity. It was concluded that pattern flooding should be practical for many dipping reservoirs. A quantitative measure is given of how much the well position should be altered to allow for dip. Experimental deternzinarions of injectivity showed this to be about the same in a dipping reservoir as in a horizontal one. INTRODUCTION This investigation was undertaken at the suggestion of the Pacific Coast area, Shell Oil Co., where a pilot water flood in a dipping reservoir was being carried out at the time this paper was in preparation. Prior to the undertaking of this flood there had been considerable speculation as to how gravity would distort a flood pattern in a dipping reservoir. The thought was expressed in some quarters that a five-spot flood would not be applicable to a dipping reservoir because the flood pattern would elongate in the direction of dip and would never form a "seal" around each five-spot. If the flood pattern elongated sufficiently, both the oil and the water might flow largely downdip rather than into the pattern producers. In view of the importance of the California water floods, it was deemed important to determine the effects of gravity on a five-spot pattern in a dipping reservoir. Previous work had also been carried out in this laboratory,1 but only for the single-fluid case. The present investigation extends these results to multifluid cases. Several sets of pictures of flood fronts are presented so that the process can be visualized. From these pictures, curves are obtained which show the correct drilling position for achieving equal times of oil-bank breakthrough. Several injectivity curves are also presented which may aid in prediction of injection rate. ASSUMPTIONS The present results were obtained with a model composed of two parallel plates of glass spaced about 1 mm apart. When the inertial forces are small, as in these experiments, the flow between the plates follows Darcy's law and is analogous to flow through porous media. In using these plates, it is not possible to scale effects of capillarity correctly as regards a transition zone between injected and displaced fluid. Calculations show, however, that effects of such capillarity should not be important in determining the gross flooding pattern in the field. In fact, in this model the capillary forces tend to circularize the pattern to a greater degree than in the field. To preserve a large ratio between the viscous forces and the circularizing capillary forces in the laboratory model, viswus glycerine was used as the flooding liquid and the rate of flooding was very high. The circularizing force is believed negligible in these experiments. In addition to the effect of the surface tension y, which tends to circularize the pattern, another capillary force must be considered. This is the adhesion tension y cos, which acts at right angles to the circularizing term y. If the plates in the model are "wetted" the same all around the periphery, then the adhesion tension,

Jan 1, 1957

By C. H. Li, R. J. Stokes, T. L. Johnston

The phenomenon of solid-solution strengthening has previously been studied in a number of binary alloy systems.1-8 There has been, however, very little information published concerning the strengthening effects of specific solutes in magnesium alloys. Schmid and his coworkers9,10 investigated the behavior of aluminum and zinc in binary and ternary magnesium-alloy single crystals, but this work was done before high-purity materials were readily available. Workers at the Dow Chemical companyH reported increases in the critical resolved shear stress upon alloying magnesium single crystals with zinc and indium. Recently, Hardie and parkins* investigated the extent of hardening produced by the addition of various solutes to poly crystalline magnesium. The present work was undertaken to provide data on the strengthening effects of a number of solutes in high-purity magnesium, for the purpose of supplying further experimental information which might be useful in describing a general mechanism for solid-solution strengthening. To simplify interpretation of the results, the mode of deformation was limited to basal slip, through the use of single crystals. EXPERIMENTAL PROCEDURE Magnesium and magnesium binary-alloy single crystals containing indium, cadmium, thallium, aluminum, and zinc were prepared in the form of l/2-in.-diam rods, approximately 8 in. long, using a modified Bridgman technique in which the crystals were slowly cooled from the melt in a steep temperature gradient, in an atmosphere of helium. It was found that a solid-liquid interface travel speed of about 0.7 in. per hr consistently produced single crystals. The poly crystalline starting materials for the preparation of single crystals consisted of 1/2-in.-diam extruded rods, prealloyed to the desired composition. The unalloyed magnesium and magnesium-indium extrusions were furnished by the Dow Chemical Co. The other alloys were prepared at the Rensselaer Polytechnic Institute Metallurgical Laboratories. Some preliminary studies of the strengthening effect of indium were conducted at room temperature using a constant rate of tensile loading of 1040 g per min. Stress was applied to the crystals by means of a simple 5:l lever arm. The lever was loaded by a constant rate of flow of shot into a receptacle suspended from the long arm of the lever. Plastic flow was detected by an electrical resistance strain gage cemented to the surface of the crystal normal to the minor axis of the predicted glide ellipse. The crystals were acid machined to produce tensile specimens with a reduced section between the grip ends, with an additional step in the center of the reduced section to compensate approximately for the slip-retarding effect of the strain gage. The balance of the single crystals were extended in an Instron tensile tester. This machine employs a synchronously driven screw and automatically records applied load as a function of cross-head separation. It became unnecessary therefore, to employ a strain gage to detect deformation or to acid machine a reduced section. Preparation for testing reduced merely to chemical cleaning of the surface, thus minimizing the amount of handling and probability of accidental damage to the crystals. The rate of elongation employed in all the tests was 0.002 in. per min, corresponding to a strain rate of approximately 0.0004 per min. EXPERIMENTAL RESULTS The investigation confirmed the finding of many workers that the yield strength of hexagonal metal crystals is strongly orientation-dependent. This is illustrated in Fig. 1, in which o, the tensile stress required to produce gross plastic flow in eleven unalloyed magnesium crystals stressed at a constant rate of loading is plotted as a function of sin X, cos Ao where X, is the angle between the

Jan 1, 1960

By T. D. Mueller

Many investigators have used the response of the "dimensionless aquifer" to a unit pressure drop or a unit fluid-withdrawal volume to calculate the performance of an aquifer in supplying water influx to an oil reservoir. In the past, these response functions have been calculated with the aid of the Laplace transform. With the advent of ultra highspeed digital computers, it becomes practical to solve for the response functions with finite-difference techniques. The computer method also permits extension of the dimensionless-aquifer concept to include the nonhomogeneous aquifer wherein the permeability and other properties vary as a function of the space co-ordinates. This paper gives results of calculating the response functions for a series of nonhomogeneous aquifers. Response functions are presented for both linear and radial aquifers whose thickness, permeability-viscosity ratio and porosity-compressibility vary. These functions are new and should prove useful to the petroleum engineer in analyzing the behavior of nonbomogeneous aquifers. Results are presented in the form of charts that can be easily used by the field engineer. INTRODUCTION Aquifers which surround many oil and gas reservoirs have the ability to supply water influx to such reservoirs as oil and gas are withdrawn. This water influx, called natural water drive, provides one of the most effective driving mechanisms for the production of oil and gas. In producing a reservoir, therefore, it behooves one to make the maximum use of natural water drive. To achieve the maximum use, the reservoir engineer must be able to predict the performance of an aquifer under a variety of production schemes that may be proposed for the reservoir. Unfortunately, the physical properties which dictate aquifer behavior often are known only within limits. Seldom do wells penetrate the porous strata of the aquifer. Even when they do, quantitative information regarding porosity, permeability and water compressibility is seldom available. It is known, however, that the water efflux from most aquifer systems is governed by a single, relatively simple, linear, partial differential equation. Also, the general physical location of the aquifer boundaries often are known. A technique originall proposed by Hurst1 and van Everdingen and Hurst2 has been found useful in analyzing reservoirs in this situation. The idea was later expanded by van Everdingen, Timmerman and McMahan3 to include the mathematical technique of least-squares fitting. This latter method will be referred to as the VTM method. The basic assumptions of the VTM method include the following. 1. The location of the physical boundaries of the aquifer are known. 2. The flow conditions at these physical bound-daries are also known. 3. The aquifer is homogeneous; e.g., thickness, permeability, water compressibility and porosity are constant throughout. In the VTM method, a material balance is made on the fluids entering and leaving the reservoir. In the balance equations, the water-influx term is represented as the product of the water influx from an arbitrarily-selected, dimensionless aquifer system times an unknown conversion number. This balance can be formed as many times as there are data points in the history of the reservoir. Each time, the conversion number can be evaluated. If the reservoir engineer has picked the correct dimensionless aquifer to represent the real aquifer, the conversion number remains constant for all balances that have been made over the history period. If such a situation occurs, the reservoir engineer can then predict the performance of the reservoir for any type of production scheme by using the function associated with that particular dimensionless system and the derived conversion number. These functions will be referred to as the response function of the aquifer. If the aquifer is nonhomogeneous (e.g., if the porosity, permeability, thickness, porosity, or

By Hans Lundberq

IINDUSTRY'S attention is now focused on the production of munitions thereby creating a demand for certain minerals which in prewar days were produced only in limited quantities. Now production of these minerals must he increased from the known deposits and new deposits must be found. Can geophysics help? "War minerals" such as tin, vanadium, tungsten, antimony, manganese, chromium, and cinnabar have no physical characteristics sufficiently different front the country rook to permit their direct location by ordinary geophysical methods. As already demonstrated in work on gold and oil, useful information may be obtained indirectly, however, outlining structural features or geological conditions favorable for the deposition of such ores or the accumulation of oil. Recently, more direct and truly qualitative methods have been brought into a useful and practical stage, and by the combined application of old and new methods a technique has been developed which, it is hoped, will be of importance in the search for these vital minerals.

Jan 1, 1941

By Robert H. Richards

Jan 1, 1883

By V. C. Allison

The explosibility of a dust is favored by its fineness and content of volatile combustible matter; its explosibility is decreased by its moisture and ash content. The explosibility of a dust can be reduced by admixture of either inert dust or water. The major effect of both the inert dust and water lies in their heat capacity; they absorb the heat of the explosion flame until the temperature of this flame drops below the ignition temperature of the explosive heat. The amount of inert dust necessary to make an explosive dust non-explosive can be calculated from its proximate analysis. FOREWORD LARGE-SCALE testing of the explosibility of coal dust as conducted by the Bureau of Mines in its Experimental Mine involves a large initial investment, and a high charge for maintenance and conduct of the test; in addition the work is necessarily slow because of the time required for the preparation of the tests and the cleaning and repairing of the mine after each test. These tests have been made along practical mining lines that admit of a range of mixtures of dust varying from 5 to 10 per cent. and with gas as low as 0.5 per cent. increments. Because of the time and expense involved, efforts have been made to devise a type of gallery for laboratory use in which the results obtained in the Experimental Mine may be correlated as an aid in a study of dusts, the explosibility of which might be approximately determined quickly and at a minimum of expense. The explosibility of coal dust has been studied by a number of European investors, using small laboratory devices; among these may be mentioned the experiments con¬ducted by Galloway, Vital, Hall and Clark, Abel, Mallard and Chatelier, Thorpe, Bedson and Widdas, Engler, Holwartz and Meyer, and Taffanel, results of whose experiments have been reviewed by the Bureau of Mines., The Bureau has conducted many tests with the Frazer-Clement2 apparatus, which gives the pressures set up when the dust cloud within is, ignited with a platinum coil or tube, heated to different temperatures, but for these tests the sample must be especially prepared as to size (200 mesh) and must be dry. An attempt has been made to design an apparatus that may be used for checking and correlating the experimental tests. The first design was a wooden gallery, 8 by

Jan 7, 1925

By Donald R. Rathburn, Jung K. Mok

An historical review and a survey of current practice in the application of fine dry grinding in the iron ore industry are given. Both closed and open-circuit applications are reviewed, and the advantages, disadvantages, and process considerations for these two systems are discussed. The ground ore temperature rise, and the cool-ing of ground ore and mill ventilation are also discussed, along with the agglomerating characteristics of dry ground ore. Screening during the production of high-grade lump ore for blast-furnace burden, particularly from recently developed ore deposits in Australia, South America, and Africa, has resulted in large tonnages of fine iron ore. Certain owners have decided to stockpile these fines until some later date. Others have either sold these fines "as is" for agglomeration at the steel plant or have established their own pelletizing plants to produce a premium quality agglomerate. In almost all cases some grinding is required prior to pelletizing. Most of these ores occur in the weathered state which may result in difficulty in the thickening and/or filtering stages when ground in a wet system. The resulting filter cake would probably require partial drying to provide a product suitable for the subsequent balling operation; however the partial drying and subsequent material-handling steps often produce random agglomeration. Normally, these agglomerates will cause problems in the green ball formation process. Thus dry grinding has developed as a solution to this problem. Most of the dry iron ore grinding installations utilizing the standard-type rod or ball mill are grinding high-grade natural ores that do not require beneficiation. Although power consumed per ton of final product is 120% or greater in dry grinding as compared with wet grinding, the additional power required for dewatering and handling a wet ground product can easily exceed the initial power savings. Dry grinding of raw feed and clinker has been practiced in the cement industry for many decades but its major application to the iron ore industry has taken place only within the past ten years. The successful application of dry grinding to iron ore has required the solution of several unique design and operating problems. The purpose of this paper is to review recent developments in fine dry grinding of iron ore for pelletizing and to discuss the various designs and operating parameters involved.

Jan 1, 1971