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By J. J. Kantner

CREEP investigators have made extensive studies to determine the interrelation of stress, temperature and the tensile creep rates of metals. It has been suggested that at small stresses the secondary or constant creep rates obey a simple viscous law. Building upon this suggestion, departure from pure viscosity as stress increases may be expressed mathematically as a consequence of reversibly altered viscosity or "flowability" in the same sense that temperature change reversibly alters viscosity. From the index to alteration of viscosity, a value for the energy of secondary creep may be derived having the magnitude of the free energy of vaporized metal. The suggestion is made that applica-tion of stress alters the energy of secondary creep. Strain energy is argued to be but a minor factor in the energetics of secondary creep. A deformation mechanism involving the large energy associated with secondary creep implies a sort of solid self-diffusion process. Evidence indicates that creep strain above the recrystallization temperature takes place by crystallographically directed self-diffusion at grain boundaries and points of crystal defects. A self-diffusion theory of secondary creep is proposed, embracing the principles of the Dushman-Langmuir theory of solid diffusion. An equation is suggested whereby the rate of tensile creep may be related directly to the physical and struc-tural character of the solid metal.

Jan 1, 1937

By C. E. Mills

Studies of ground movement and subsidence resulting from mining operations cover a broad field. It is also a very important consideration and one that eventually affects nearly every mining operation of any extent. The damage to surface buildings, removal of mine surface plants and replacements of main hoisting shafts must reach an astounding expenditure were these cost figures available over a period of years. Were the subject one of mathematical formula and dependent only on the angle of draw of the walls or country rocks, the problem would be relatively simple. Consideration must be given to depth and extent of workings; structural conditions of the orebodies and enclosing country rock; physical properties of these same rocks, including schistosity, bedding, jointing, slips, dikes, faults, and other structural weaknesses. The method of mining, extent of openings, supporting pillars, and amount of moisture or water underground are other pertinent factors. With such a large number of variable factors, it is apparent that the subject of subsidence is one that must be based largely on experience and results at other mines where conditions are somewhat comparable. In presenting this paper, it is the intent to describe the progressive results of past ground movements at the United Verde, to bring out physical conditions largely responsible for this movement, but to refrain from theorizing on the ultimate extent of subsidence resulting from future mining operations. Geology and Structure1 The ore deposits of the United Verde are of the massive sulfide, schist-replacement type. A structural anticline formed by the intrusion of diorite between bedding planes of steeply dipping and severely folded greenstones and porphyry localized the deposit of sulfide. The mineralized zone is of great horizontal extent varying from 200,000 to 400,-000 sq. ft., and extends from the surface to the lowest levels at a steep dip of from 50° to 75. The irregular interfingering of the sulfide with

Jan 1, 1934

By Walter English

THE four papers making up this symposum have been prepared espe-cially for those who have no knowledge of seismograph prospecting. To many people mathematics is a formidable subject, and many are discouraged from studying seismograph prospecting under the mistaken assumption that the mathematical requirements are severe. In the papers presented here there is not a single mathematical equation. We believe that considerable competence in dealing with some of the most important problems of this work can be attained without any mathe-matical training whatever. At the present time, there is a real need for interpretation of results by persons thoroughly competent to bring geologic experience and imagination to bear on data that are subject to multiple interpretation from a strictly physical viewpoint. Likewise, those charged with the responsibility of planning seismo-graph exploration campaigns would do well to become familiar with as much as possible of the technical aspects of the work. They would then be in better position to judge of its success in individual cases. It has often been said that the seismograph is a new structure-finding tool for the geologists to use. Using a tool and using its product are two different things. One does not use an automatic screw-threading machine when he buys a box of screws at the hardware store. Neither does the geologist

Jan 1, 1939

By E. A. Devuyst, M. A. Mosoiu, V. A. Ettel

Nickelic hydroxide is an important metallurgical reagent used for precipitating cobalt from nickel sulfate solutions. Existing methods of preparation of nickelic hydroxide involve electrolytic oxidation of Ni(OH)2 or the use of strong oxidizing agents such as chlorine, ozone and persulfate. Although the oxidizing properties of the SO2 + O2 system have been known for some time, e.g., detection of SO2 and oxidation on iron in acidic solution, the application of this system for the preparation of nickelic hydroxide as a process was not considered in the past. The present paper describes a new method for chemical preparation of nickelic hydroxide which has been developed in INCO laboratories. The technique consists of reacting nickelous hydroxide suspensions with a slurry of calcium sulfite in the presence of air or oxygen. The main advantage of the process is the cost of reagents and an absence of soluble by-products (e.g., C1-). The chemistry of this process is unusual since the redox potential obtained during the reaction exceeds that of the oxygen electrode. Therefore, the effect of CaS03 is not just a catalytic acceleration of the reaction NI(OH)~ + 02. The so3= must be involved in the stoichiometry of the overall reaction producing in the initla1 phase some strongly oxidizing intermediate species.

Jan 1, 1981

By Arthur E. Bousu, C. T. Eddy, L. W. Eastwood

THE recrystallization and grain-growth phenomena of cold-worked metals have considerable industrial importance because of their role in the fabrication of metals. For this reason, and because of the general academic interest in the subject, these processes have received considerable attention since the time of J. E. Stead's paper1 on The Crystalline Structure of Iron and Steel. There are considerable differences of opinion regarding the theory of recrystallization and grain growth and also differences in the observation of the modus operandi of the processes themselves. The value of many of the existing quantitative data on grain growth is decreased by the failure to distinguish between the grain sizes just after complete recrystallization and those resulting from coalescence. For this reason also, the value of the diagrams of stable grain sizes, like those produced by . Bass and Glocker2 and Czochralski3, is lessened in so far as an interpretation of the facts of recrystallization is concerned. It is hoped that the data presented in this paper will help to clarify and to simplify the facts relating to recrystallization, and at the same time will show that some of the present-day conceptions are untenable. A paper on the theory of recrystallization with additional data will be completed in the near future by the writers.

Jan 1, 1935

By W. M. Wojcik, R. F. Kowal

Oxygen and sulfur distributions in commercial, 5-ton ingots of killed, medium carbon steel are described. Oxygen distribution is found to vary with deoxidation practice. Irregular distribution of oxygen within ingots makes necessary special precautions in sampling of rolled products for analysis of oxygen. Oxygen distribution is discussed in terms of recently published solidification concepts which had been successfully applied to simpler cases of segregation. These concepts have been found inadequate to explain observed oxygen distributions. Convective movements of the liquid metal, as determined by tracer elements, are shown to be capable of accounting for the observed distributions of oxygen. IN an effort to explore the origin of surface and subsurface imperfections in pierced steel products, a study of oxygen and sulfur segregation was made on ingots cast in open-top and hot-top molds. The results of our previous investigations1"3 have indicated the importance of the location and amount of oxide inclusions in an ingot. Inclusions close to the surface of the ingot have been found to contribute greatly to the formation of imperfections in the surface of finished products. This study of the effects of deoxidation and casting practice on segregation and the resulting oxygen distribution in ingots was initiated to determine the parameters controlling the location of inclusions in an ingot. Segregation of solute elements during solidification of low-melting binary alloys has been studied in the past.1, 5 Formation and growth of inclusions in iron melts have been studied under specific conditions."- In spite of these and other recent studies,10-12 segregation during solidification of commercial, killed steel ingots is not well understood. Consideration of solidification rates, of segregation during solidification of the chill, dendritic, and central zones, and of material balances for the segregated elements has indicated that a simplified theoretical solidification model is not adequate. However, the observed high oxygen contents in localized volumes of the dendritic zone can be rationalized if additional effects of convection currents in the ingots, precipitation, and rapid growth of new phases are considered. EXPERIMENTAL PROCEDURE Steelmaking and Processing. A group of nine killed. medium carbon steel heats having compositions listed in Table I have been studied. The deoxidation and mold practices used were varied to give a wide range of steel oxygen contents. The amounts of aluminum added to the ladle and the ingot casting practices (hot top and open top) were the main variables. The steel was made by a duplex practice in 160-ton tilting basic open-hearth furnaces. All nine heats were top-cast into 24 by 24 in. big end down, fluted molds, to a height between 60 and 76 in., using both open tops and exothermic hot tops. The deoxidation practice and the tapping and teeming details for each heat and ingot studied are given in Tables II and III, respectively. Hot-top practice is indicated by the letter H following the heat designation. Furnace and ladle temperatures were measured by standard disposable-tip, Pt/10 pet PtRh thermocouples. Teeming-stream temperatures were obtained as described by Samways et al.,13 by immersing a Pt/10 pet PtRh thermocouple, covered by a silica sheath, into the teeming stream under the nozzle. The output of this thermocouple was recorded with Leeds & Northrup Speedomax potentiometer. Calibration of the latter thermocouples was based on the freezing point of a pure iron/oxygen alloy (2795°F). The accumulated errors of measurements were within ±10°F. The thermocouple measurements were supplemented in this investigation by continuous recording of a ratioing, two-color pyrometer (Shawmeter), protected from smoke by a blast of clean air within the sighting tube, and calibrated to read with better than ±10°F accuracy. Following teeming of three heats, P, R, and T, tracer elements were added to the steel in the molds to obtain a record of the progress of solidification. As soon as the teeming stream was shut off, a 0.010-in.-thick steel can containing a mixture of crushed standard ferro-titanium and ferro-vanadium (0.05 pet of each alloy element) was plunged into the middle of the steel pool to a depth of 6 in. In about 30 sec no indication of the can or its contents remained. The surface of the open-top ingots solidified in 20 to 30 sec. A study of liquid metal movement and the precipitation of oxides was facilitated materially by use of the tracer technique as titanium has a low distribution coefficient between solid and liquid steel while vanadium has a high distribution coefficient.

Jan 1, 1965

By N. A. Ziegler

IN every research it is desirable to eliminate as many variables as possible and to leave only a few to be investigated one at a time. Metallurgical problems are no exception. Some of the variables that are difficult to control are the size, the distribution, and the orientation of the grains in a metallic test piece. It is therefore very desirable to obtain isolated metallic grains (single crystals, as they are commonly called) large enough to enable one to study their mechanical and physical properties. The present investigation is a part of magnetic research work on iron and iron alloys, undertaken to obtain, if possible, the magnetic properties of pure iron (Fe). This paper will deal primarily with the preparation of single crystals of iron and their mechanical properties, while another paper, by T. D. Yensen, now in preparation, will deal specifically with their magnetic properties. The work with "single crystals" is attracting more attention every year among the investigators in metallurgy. Van Liempt1 gives an interesting summary of the work done and the different methods used in the preparation of metallic single crystals. Briefly stated, the four principal methods used are the following: 1. The cooling of a liquid metal in such a way that the crystallization would start at one point only, causing the entire liquid to solidify as one crystalline unit. This method can be successfully applied to the majority of the metals that do not have any allotropic transformations in the solid state. It has been used and described by a number of investigators,2 but it has never been successfully applied to iron on account of allotropic transformations.

Jan 1, 1930

By Y. C. Liu, G. A. Alers, S. S. Choi

In searching for an explanation for the obvious difference between the copper and the brass type of rolling texture, it is common practice to look for correlations with other properties. For example, there are obvious differences between copper and brass in the critical resolved shear stress, the extent of easy glide or stage I, and the amount of "overshooting)) during single-crystal deformation.' Also, the slip lines in copper are fine and wavy while those in brass are more coarse and better described as slip bands.' Since neutron irradiation is known to make these properties in copper change in such a way as to resemble brass,2'3 an excellent test for these possible correlations is to see whether neutron irradiation produces a corresponding change in the texture, i.e., whether irradiated copper develops a brass-type rolling texture. The experiment would also answer the more important question of whether or not lattice defects like those introduced by neutron irradiation have any effect on the development of rolling textures in fcc metals. Experimental studies using conventional X-ray pole figure techniques are inconvenient because the X-ray detection system must be modified to discriminate against the radioactivity which is induced in the specimen by the necessarily long exposure to neutrons. Nevertheless, some texture determinations have been

Jan 1, 1968

By H. B. Muller

Single stage autogenous grinding of run-of-mine ore was selected by Broken Hill South Ltd., parent Company of Cobar Mines Pty. Ltd. for the concentrator to treat 60,000 tons per four weekly period of copper and complex copper-lead-zinc sulphide ores from the C.S.A. Mine at Cobar, Australia. Ore is mined by mechanised horizontal cut-and-fill stoping and is prepared for grinding by crushing under- ground in a 60 in. x 48 in. jaw-crusher set at 5 in. closed side setting. The ore is reduced to 80% minus 76 microns in two parallel sections each of one 22 ft. dim. x 7 ft. long autogenous grinding mill, powered by a 1,250 H.P. motor, operating in closed circuit with a single stage 20 in. dim. cyclone. Broken Hill South's original concept of the concentrator required the maximum use of reliable instrumentation, centralised control, and the minimum of manning. To achieve this objective the control room, housing the process recorders, alarms, closed circuit television monitors and all the control equipment, overlooks the grinding and flotation sections, and the whole plant is serviced by a public address system. The grinding units and associated equipment are located in the open and are serviced with the aid of a mobile crane and a mobile hydraulically-operated liner lifting device.

Jan 1, 1970

By P. A. Boeck

(San Francisco Meeting, September, 1915) THE thermal insulation of high-temperature equipment for industrial purposes is a subject that has not received from engineers and designers the attention its importance deserves. This may be attributed to a number of causes: In the first place, heat flow is a rather difficult factor to measure under the working conditions of an industrial furnace, and until the comparatively recent introduction into certain operations of the heat balance sheet, with a systematic attempt to account for the discrepancies in the totals, the various causes of heat losses and the reasons for their existence were not brought to light. Moreover, such rapid advancement and radical changes in the design of equipment, especially in metallurgical lines, have occurred that practice has apparently outdistanced the theory of design. In the modern tendency toward greatly increased size of units, effort has seemingly been made to utilize the heat of fuel gases without proper. attention having been paid to conserving heat energy and confining it strictly to the points of maximum activity. The systematic study of the thermal properties of structural materials, which is being carried out by various government bureaus and also by a number of technical societies, is forming the basis for more intelligent and consistent work in the economically important subject of prevention of fuel waste.

Jan 8, 1915

ALTHOUGH everybody is familiar with coal, few persons have an exact idea of, the great impor-tance of this precious fuel. Coal is the black bread of industry. Without it, industrial activity is much restrained; and so the great industrial countries of Europe and the United States of America are the great producers of coal. The 1913 production of coal in Belgium was 22,842,-000 tons, valued at 418,700,000 fr., nearly a half billion. In 1919, it was 18,483,000 tons, about 81 per cent. of the production before the war; in 1920, it had reached 22,414,000 tons, approximately the production before the war. To show the importance of coal production of Belgium, let us say that the coal industry employed 168,000 workers in the year of 1920, the metallurgical industry only 129,000 and the textile industry 103,000. The coal industry, then, employs the greatest number of workers. The value of the coal production in 1919 is estimated at 1,121,000,000 fr. On the basis of the production before the war, the value of the production of iron in 1919 would have been 701,000,000, of finished steel 1,086,000,000, and of zinc 415,000,000; therefore, in 1919 the value of the coal industry was greater than that of the metallurgical production.

Jan 8, 1922

Hunkered up against the spine of the Andes in a tight valley where natural refuge from avalanche hardly exists is the daring Rio Blanco project of Cerro Corp. The deposit here was found in 1904, but nature has foiled all previous attempts to open it. To an experienced mountaineer or a highway engineer with mountain experience, the avalanche hazard in the valley of the Blanco river would be immediately apparent. The collar shaft is at the head of the valley at an elevation of 3600 m and for 12 km down the valley there is no space on the floor for building very much; the dissected rock walls are roadways for avalanches and even a highway could not be maintained sufficiently passable. This is the proposition taken on by the Cerro Corp. Chilean National Decree #1699, passed on December 9, 1966, signified "Go" to the Compania Minera Andina, a company whose shares are held 70% by the Cerro Corp. and 30% by the government of Chile. The orebody, although only partially delineated, contains proven reserves of 120 million tons of ore averaging 1.58% Cu. When the operation comes on stream in the last quarter of 1970, it will be at the rate of 11,000 tpd. Annual production will be 65,000 tpy of recoverable copper in concentrates.

Jan 11, 1969

By George M. Schwartz

WHEN reviewing the progress made in mining geology for the year 1953, one might say that not much has been accomplished and, indeed, in a subject such as economic geology not much progress should be expected in the 10 months of the year which elapsed before this article was prepared. This seeming lack of progress, however, disappears when the facts are investigated a bit. There undoubtedly are more economic geologists at work than ever before. It is probably not an exaggeration to say that more geologists are now employed by a single company in the Lake Superior district than were employed in the whole district 20 years ago. In most mining districts geologists are busy with numerous problems of production, development, and exploration and some give an occasional thought to the scientific problems of the science, or rather the art, of mining geology. In fact, this very intense activity of mining geologists is one reason why progress seems slow; they do not have time to write up results of investigations. There is also a great amount of work being done which is not released because of company policy. Conditions have improved very much in recent years but mining corporations, in general, have some distance to go before attaining par with the petroleum industry in this respect.

Jan 2, 1954

By E. H. Rose

It must be evident to almost everyone by now that a massive transformation is occurring in our iron ore economy. Its equal has been seen only once before in the entire history of the North American steel industry, and not even once before within the personal memory of anyone now engaged in it. The lone precedent was the beginning of ore shipments from the Mesabi Range in October, 1892, which was before anyone still short of normal retirement age had been born. No younger observer, in the steel industry or in any other, has ever known anything else than that the Lake Superior region-in which the Mesabi is the giant-has supplied all but a small fraction of total North American blast furnace ore for the use of three generations of steelmakers. Directly or indirectly, it was the discovery of the Mesabi which created most of the prime and satellite companies that have since come to prominence in the various ore-consuming phases, and it was the same discovery that had broader effects on the entire spectrum of their technologies than any other single event that has ever happened since, although the advent of byproduct coke is a close runnerup. It affected every sector of the national economy and was a keystone in making our standard of living what it is today.

Jan 9, 1961

By Edward L. Clark

The year 1954 witnessed great activity in the field of geology as applied to mining. The search for in nearly all districts is becoming more and more intensified as established reserves are being depleted. Much geologic work has been directed to finding extensions of known orebodies, but prospecting in new areas has constituted a large part of the program of many operators. The acute need for additional reserves has brought into the search all the tools known to the geologic profession. This is reflected directly by frequent references to geophysical and geochemical methods in the regional reviews that follow. The lone prospector of the early days of metal mining has been eliminated almost completely by modern scientific methods involving surface and subsurface geology, exploratory drilling, geophysics, and geochemistry. Nearly all new exploration is based on long-range programs coupled with studies of regional geology to determine the structural environment of areas of mineralization. The success of this approach has encouraged new operators in the field of exploration to adopt similar policies. Only in the search for uranium ores is the individual prospector still active, but the familiar picture of the burro heavily loaded with grubstake, gold pan, and pick and shovel has been replaced by the Geiger counter and the scintillometer carried by hand, by truck, or by airplane.

Jan 3, 1955

By Joseph D. Weeks

Manganese has, until recently, been most highly esteemed as a good thing to keep out of steel. Its value in the process of mannfacture has been fully recognized, but after it has played its part in the crucible or the converter, then the less of it the better. It is true that the mission of this metal and its influence upon the character of steel has been a source of much controversy. Our own Holley, in one of his special reports on ferromanganese: I, states that ''it has been suspected by some, and believed by a few, while it is still denied by many, that manganese as an ingredient in steel has not only a body-giving and toughening influence, but a positive neutralizing influence upon any excess of hardening or cold-shortening substances, as phosphorus." In another paper on the same subject he states that " it should appear from such facts as we have that manganese toughens" the structural steels, "increases their soundness and prevents red-shortness." Notwithstanding these rather guarded assertions as to its value, the general belief, it will be found, is with Dr. Siemens, that manganese is " merely a cloak to hide impurities," and its presence in steel has been endured, not welcomed. But whatever may have been the difference in opinion as to the

Jan 1, 1885

By Waldemar Gooskov

IN his well-known work,1 published in 1867, P. Ritter von Rittinger gives the following formula for the velocity of a particle settling in still water: v=C/D(a -1) and for average grains he assigns to the constant C a value of 2.44. As is well known, the value of C depends on the shape of the grains resulting from crushing, and it is obvious that values obtained for coal particles will not only be very different from those for ore particles but will even be characteristic of coal from a certain seam. The only way of finding an accurate value of C, applicable to conditions in Russia, where all coal-washing plants are built on German principles, is to conduct a series of tests of which the results will determine what value of C is to be used. In the investigation outlined in this paper the theories of Prof. Robert H. Richards2 were taken as the basis of the tests; the slimes were removed from the charges to eliminate the trouble of handling them; and to obtain accurate results free from errors inevitably resulting from human observation, photographic apparatus was used and a series of pictures taken which form the basis for constructing a suitable diagram of velocity vs. time.3

Jan 1, 1928

By A. B. Young

IT is the he object of this paper to describe a Cottrell treater that was placed in operation, in April, 1919, at the Tooele plant of the International Smelting Co., for the purpose of recovering solids from the gases from the McDougall roasting furnaces. Fundamentally, the treater is simply a flue containing rows of vertical plates, forming the grounded electrode, alternated with rows of small horizontal pipes, forming the negative electrode, with proper provision underneath for taking away collected dust. There are advantages in construction over the more cumbersome types, both the vertical-tube and the vertical-box, particularly in the elimination of heavy supporting columns and massive foundations, giving a much lower first cost. There are no right-angle turns to interfere with gas distribution; consequently there is greater efficiency, or, in other words, a greater volume of gas per minute can be effectively treated. Another advantage of the horizontal installation over the vertical is that the principle of the selective precipitation of the various components of the dust and fume as they pass along the electric field may be utilized. Since the treater has been placed in operation, the results have been quite satisfactory and, in many ways, particularly in regard to the volume of gas that may be treated, have greatly exceeded expectations.

Jan 8, 1920

By Jerry G. Rose, Robert C. Howell

This paper addresses a process by which both the disposal and utilization of preparation plant coal refuse can be simultaneously accomplished with an attendant benefit of significantly increasing the percentage of extractable coal. A laboratory study is described in which coal refuse was successfully utilized as an aggregate in low cost concrete (coal-crete) mixes under simulated mine environments. Coal-crete specimens with compressive strengths of 14 000 kPa (2000 psd were consistently produced. A construction sequence and mining plans are offered for placing the low-cost coal-crete pillars in accessible areas in room and-pillar mines so that a substantial portion of the remaining coal pillars could be extracted. The method could be applicable in areas where mining procedures do not permit pillar extraction because of possible surface subsidence, roof problems, or other conditions. Possible structural difficulties with the coal-crete pillar support system are discussed. Using a discounted cash flow analysis, the economic feasibility of mining with the coal-crete pillar system is investigated. The cost of the system is compared to the cost of a mining system which would have less coal recovery. The analysis indicates that although at higher coal selling prices the coal-crete mining system may yield an acceptable rate of return, the alternative of leaving the coal pillars is more attractive at the present time.

Jan 1, 1980

By C. R. Woodcock, J. S. Mason

In almost any situation where particulate or granular bulk solids have to be conveyed, whether for a distance of a few metres or for many hundreds of metres, a pneumatic conveying system may be considered. Conveying by pipeline is convenient and clean, but running costs may be substantial because of the heavy air consumption and the trend has therefore been towards dense-phase transport in which the ratio of conveyed solids to conveying air is kept high. This paper concentrates on air-float conveying, which can be regarded as an extreme form of dense-phase conveying where the bulk solid is fluidised in a channel and then caused to flow, either by inclining the channel or creating a pressure gradient along 'it. Various designs of air-float conveyor for upward, horizontal and down- ward transport of powders are discussed, with special emphasis on the latter case. In situations where a continuous downward slope can be provided, the combination of air-fluidisation and gravity flow results in a conveying system that, for many kinds of bulk particulate solid, would be hard to better in terms of convenience, reliability and economy. The paper is concluded with a discussion of design features and performance of practical air-gravity conveyors, involving the handling of various bulk particulate solids, both in research and in full-scale industria1 applications.

Jan 1, 1980