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The Bureau of Mines is active in programs pertaining to solid waste disposal and land reclamation. Nine reclamation projects of mining companies and six projects of the Commonwealth of Pennsylvania were investigated to provide information on the procedures, costs, and results obtained from reclamation projects of bituminous coal-waste disposal areas. Refuse disposal costs of mining companies ranged from 9 to 28 cents per ton-mile, and quantities disposed of ranged from 600 to 4,500 tons per day. Spreading and compacting the refuse at the dump site ranged from 3 to 20 cents per ton. Cost of covering with soil and planting ranged from $750 to $1,646 per acre. Total costs of reclamation for the Pennsylvania projects ranged from about $1,800 to more than $15,000 per acre. Refuse preparation costs ranged from $772 to $5,550 per acre. Soil covering and planting costs ranged from $1,083 to $5,086 per acre. The best results were obtained by soil preparation and conditioning prior to planting. The type and depth of soil and effect of climate were also factors.

Jan 1, 1973

By M. Hertzberg

Results of a comprehensive study of the absolute spectral radiance of the infrared emissions from methane-air explosions are reported. The spectral growth of these expanding flames were recorded with a time resolution of 1 msec in the spectral range of 1.7 to 5.0 µm. Time-resolved spectra were obtained for methane-air mixtures as a function of stoichiometry, nitrogen dilution, and Halon dilution, in a 9-liter vessel under different venting conditions. Data are also presented for coal dust-air explosions. Temperatures, obtained from the absolute radiances and from a band ratio technique for methane-air, are internally consistent and are generally 50° to 200°K below adiabatic flame temperatures. All near limit mixtures gave essentially the same flame temperatures (1,500° to 1,600° K) regardless of whether the limit was obtained by dilution with excess air, excess methane, excess nitrogen, or Halon. The coal dust explosion spectrum is essentially a blackbody continuum at 1,500° K with some selective emission at 4.4 µm from hotter CO2. The data are analyzed in terms of the radiative dynamics of a sperically expanding flame zone. The importance of radiative transport is assessed. An equation is derived which relates the instantaneous fraction of combustion power radiated to adiabatic variables.

Jan 1, 1973

By Richard L. Ash

Introduction The blasting capabilities of commercial explosives are often rated according to their loading densities and detonation velocities. Both the density and velocity are relatively easily measured, the values of which can be used for determining the approximate detonation pressure developed by an explosive during any given set of blasting conditions (1-5). Knowledge of the actual rate of detonation attained at all points along a charger's length also is considered to give a good indication of how well the explosive is functioning. Many factors affect the density and velocity and have been thoroughly discussed by various authors (4, 6-12). For recording velocities several methods are available, but the resistance-wire, or probe, continuously recording technique has the distinct advantage of providing a record of the complete progress of an explosive reaction from the time it first initiates. Figure 1 is a copy of a typical record obtained by the procedure with certain significant information indicated. The theory and applications of the method are extensively covered in the literature so need not be reviewed for this report (13-18). Only the specific equipment and procedure employed for this investigation are presented.

Jan 1, 1973

By Frederick M. Fowkes

Dusts can be filtered out of air streams onto polymer surfaces by electrostatic trapping resulting from the spontaneous transfer of electrons upon contact between dust particles and the polymer surfaces. Such spontaneous contact electrification has been studied quantitatively in this contract with the aid of modern semiconductor charge-sensors with the aim of determining what basic principles govern the sign and magnitude of contact electrification. Information obtained by capacitance-voltage measurements of thin polymer films on silicon showed that charges as large as 4 x 1012 electrons per cm2 develop spontaneously, and that such a charge gives adhesional forces of 165 pounds per square inch (11 atmospheres). Direct measurement of dust polymer contact electrification, using silicon surface channel conductance sensors, also showed spontaneous charges of more than 1012 electrons per cm2. Some polymers can either donate or accept electrons. These included chlorinated polyethylene, chlorinated polypropylene, polyethylmethacrylate, and a copolymer of maleic anhydride with n-octadecylvinylether. Other polymers never accepted electrons but could donate electrons; these included polystyrene, pulychlorostyrune, polyvinylchloride, polyvinylacetate, a polycarbonate (Lexan), and cellulose tributyrate. Contact electrification studies were made with dusts (coal dust, a channel black, or a silica powder) contacting thin films of various polymers solvent-cast onto the semiconductor charge-sensor. Sometimes charging was instantaneous and sometimes slower, but in all but one case (coal dust on a copolymer of maleic anhydride with n-octadecylvinyl ether) the charge trunsfer was a donation of electrons by the polymer to the dust. Some

Jan 1, 1973

By J. B. Rosenbaum

Prolonged laboratory and limited pilot plant tests have shown that the Bureau of Mines buffered S02 -H2S process is capable of removing 95 to 99 percent of the S02 from industrial waste gases. Most of the S02 is converted to elemental sulfur; only about I percent converted to sulfate The process comprises (1) washing the flue gas to remove particulates and S03, (2) absorption of the S02 in citric acid or other carboxylate solution, (3) reaction of the loaded solution with H2S in a closed vessel to precipitate the absorbed S02 as elemental sulfur, and (4) separation of the sulfur from the regenerated solution by oil flotation and melting. Two-thirds of the molten sulfur is converted to H2S for use in the sulfur precipitation step by reacting sulfur vapor with natural gas and steam in the presence of an alumina catalyst. The chemistry and mechanism of the process are described, initial laboratory and pilot plant data are summarized, and second-generation laboratory operation and pilot plant design are reviewed. Preliminary cost estimates are presented for recovering sulfur from copper smelter gas, powerplant flue gas, and Claus plant tail gas.

Jan 1, 1973

By Parviz F. Rad

This Bureau of Mines report reviews laboratory and in-mine techniques for determining mechanical properties of coals, with special emphasis on the relationship between these properties and the minability of coal. An extensive bibliography is included.

Jan 1, 1973

By L. K. Barker

The purpose of this research was to determine how much, if any, improvement would be made by subjecting hydrogenated shale-oil naphtha to a catalytic reforming process. Preselected ranges of temperature and pressure within the commercial reforming ranges were chosen for investigation and other possible variables were held constant. All tests were made with a liquid hourly space velocity (LHSV) of 3 volumes of liquid feed per volume of catalyst per hour (Vf/Vc/hr) and a hydrogen feed rate of 3,000 scf/bbl. Operating temperatures of 850°,875°, and 900° F were used at pressures of 200,400, and 600 psig. The greatest octane improvement in the naphtha was obtained at a temperature of 900° F and pressure of 200 psig. The reformed naphtha had a clear research octane number of 89, a liquid yield of 80 vol pct, and a yield-octane number of 71.1. The data indicate that a higher temperature could have produced a higher yield-octane number.

Jan 1, 1973

By Donald W. Breck

Zeolites were first recognized as a new group of minerals by Cronstedt with the discovery of stilbite in 1756. The word zeolite was coined from the two Greek words meaning "to boil" and "a stone" because of the loss of water when heated in the mineralogist's blow pipe. (1) In 1845 it was discovered that certain soils have the power of retaining ammonium Salts. (2) These were the first ion exchange experiments. Later it was discovered that it was the hydrated silicates in the soil that produced this phenomenon and several years later a paper was published dealing with the action of dilute salt solutions on silicates which showed that this base exchange principal, which we now call cation exchange, is reversible. The quantitative cation exchange behavior of zeolite minerals, such as chabazite, was studied. As a result any aluminosilicate which exhibited the property of ion exchange was referred to as a "zeolite;" even today the term has been applied to clay minerals as well as synthetic organic ion exchange resins.

Jan 1, 1973

By W. Chi, R. Regan, R. A. Washington

"In uranium mines, the purification of underground mine air can be accomplished by the removal of dust particles and radon daughters using filters. Full-scale statistically designed experiments with flow rates up to 10,000 cfm have been conducted at Denison Mines Ltd. on mine air filtration with vermiculite as a filter material. Various filtration bed thicknesses were chosen, with different face velocities through each bed thickness. Results on total dust, respirable dust and radon daughter collection efficiencies were analysed statistically. It is shown that these collection efficiencies are directly related to the filter bed thickness. However, the different face velocities seem to affect only the collection of radon daughters. Optimum collection efficiencies for a clean bed of about 30% were found for respirable dust and radon daughters, and about 41>% for total dust, using an 8-in.-thick bed and a face velocity of 500 fpm. Dust build-up on the filter bed during operation led to an increase in collection efficiency, reaching 40 to 60% after two weeks."

Jan 1, 1973

By Robert Stefanko

The following tables contain the average, maximum and minimum power parameter levels for several mining machines. Power factor is listed only for defined transducer output regions. The reasons for the undefined areas are provided in the Instrumentation Chapter. Several maximum voltage drops are included, and are computed from the no load line-to-line voltage: Again, the drops are from measurements at the low side of the load center. The machines are: Continuous Miners; F6A Alpine 76AM Jeffrey (d-c) 8CM Joy 8CM (10CM) Joy 9CM-2AH Joy loam Joy CU-43-2H Joy 2 each CM26H Lee-Norse CM28E Lee-Norse Shuttle Cars; 18SC Joy 48S Torkar (a-c) 2 - 10SC Joys input to rectifier 2 - 16SC Joys input to rectifier

Jan 1, 1973

By H. B. Carroll

This Bureau of Mines report evaluates the performance of commercially available portable instrumentation for the detection of carbon monoxide, carbon dioxide, oxygen, and methane at conditions simulating an industrial work atmosphere. Portable instrumentation included in the study was gas-detection tubes (length-of-stain and color intensity), catalytic detector, liquid absorption detectors, paramagnetic oxygen detector, galvanic detector, and pelement or hot-wire methane detectors. Evaluation of the instruments was in atmospheres with 50 and 80 percent relative humidities at 75° F and containing test gas concentrations of 0.1, 0.25, 0.50, 1.0, 1.5, and 2.0 times the thresh-old limit value. Correlation of the results from the portable gao analyzer with measurement from the standard instruments was made by calculating and plotting an estimated line of regression, prediction, and confidence limits and the correlation coefficient for each detector system. Relative humidity in the 50-to 80-percent range did not appear to contribute to instrumental uncertainties in either performance or operation. Considerable deviation in detection precision between the portable gas-detection systems and the standard systems was established, especially at the lower gas concentration levels. The main difference or inconsistency in toxic gas concentrations determined with length-of-stain tubes resulted from the observer's interpretation of the results rather than difference in the tubes themselves.

Jan 1, 1973

By Kenneth L. Whitehead

After many years of research, the occurrence of pneumoconiosis, black lung disease, among miners has been related to the mass of respirable coal dust to which mining personnel have been exposed. Congress passed Public Law No. 91-173 in 1969, which limited the dust concentration of respirable dust allowed in the mine working areas to 2.0 mg /M3 as of December 31, 1972. As a result of these restrictions, much work has been done in determining methods of either eliminating or suppressing respirable dust. The purpose of this project is to determine the state-of-the-art in continuous mining machine bit technology, particularly with regard to dust production.

Jan 1, 1973

By R. D. Saltsman

This report is in fulfillment of Contract No. H023001.5 awarded to Bituminous Coal Research, Inc., on November 15, 1972. The scope of the work under this contract was to perform a two-phase survey for the purpose of determining the status of work in the following specific areas of industry needs under the Technology Transfer Program and to increase industry's awareness of research efforts under the Federal Coal Mine Health and Safety Act of 1969 6f (P.L. 91-173): 1. Research and development of respirable dust sampling instruments which will more accurately collect the respirable Cuss as defined by the Federal Coal Mine Health and Safety Act of 1969. 2. Development of a better means of control of respirable dust and float dust.

Jan 1, 1973

By A. L. Podia

The purpose of this research was to develop a system capable of detecting changes in the structure of rocks, leading to failure of mine roofs, and/or excavations. A prototype system was developed, field tested and delivered to the United States Bureau of Mines for further evaluation and research. This system is based on the analysis of acoustic signals generated on the surface of the roof by an impact device and which are reflected or backscattered by flaws and discontinuities in the rock. The specially designed impact source is capable of generating high frequency acoustic signals with excellent repeatability. The system can also be used in conjunction with conventional acoustic pulse transducers. The received signal is digitized and the data transferred to a minicomputer for processing and display. This capability allows the immediate determination of wave velocity and/or distance to a reflecting interface. Various data processing techniques such as averaging, differentiating, and comparing of different signals can be selected by entering the appropriate commands on the keyboard. Being a programmable system it is possible to implement more advanced signal processing techniques. All results as well as the signal are displayed on a CRT. Furthermore, a permanent record of the data can be generated on paper tape, which can be reentered and processed at a later date. A communications interface allows transmission of the sampled signal to a large scale re-mote computer. The system was tested extensively in the laboratory, and field tested at the York Canyon Coal Mine. These tests proved the feasibility of operation in the mining environment. Results indicate that further investigation and development will have to be undertaken to fully develop the potential of this system in satisfying the goals of this research.

Jan 1, 1973

By K. L. Paciorek

The aim of the present study is to determine on a gram per gram basis the toxic products of the thermal oxidative degradations of selected compositions. Four families of materials were investigated under the subject contract namely polyvinyl chloride and neoprene compositions, rigid urethane foams I and woods. Three methods were employed to conduct the thermal oxidative degradations: a sealed system (quiescent environment) I a stagnation burner arrangement (dynamic environment) I and a flow-through apparatus (dynamic I but less severe than stagnation burner conditions). The majority of tests were conducted using the first two systems; only limited experiments were carried out employing the third decomposition procedure. All decomposition was done at temperatures of 370 -4000C I the higher temperature being used in the stagnation burner. It has to be stressed that the nature of the products and the relative product concentration are temperature dependent. Thermogravimetric and differential thermal analyses were performed to supplement and extend the above delineated studies and to explore the feasibility of using these analyses as a method for material differentiation.

Jan 1, 1973

By Robert Stefanko

This report, rather than attempting to replace previous annual reports, supplements, and more importantly, coordinates and summarizes the entire effort. Even with such restrictions, the report is voluminous and, therefore, a decision has been made to divide it into two parts. The first volume is basically narrative and includes tabular results and analyses. The second volume is in appendix form giving detailed information. Together, they permit a logical discussion of all aspects of the project (Volume I) without cumbersome distractions but, at the same time, provide all the details to permit others to evaluate and explain the results or develop similar research programs (Volume II). The aim of the original proposal was basically to develop instruments and techniques and then make measurements of suitable power parameters, ground fault currents and ground resistance beds. With such information available, it was possible to develop a meaningful simulator which would permit investigating electrical systems and components on paper without costly trial and error procedures in the third year, a cable splice testing program was added to the project. While there were the usual delays attendant in such original research, these objectives were achieved.

Jan 1, 1973

Electrical trailing cable used to power coal mining machinery is frequently damaged in usage because of tensile strain or crushing effect of mining machines running over the cable. One of the repair problems is finding the exact location of a short or open in this cable so it may be spliced or otherwise repaired. The U.S. Bureau of Mines and FMC corporation signed Contract No. H0 122011 in August, 1971, to develop instrumentation for finding faults in coal mine trailing cable. This report describes performance of several existing instruments as trailing cable fault locators and also construction details and performance records of several cable fault location instruments that FMC designed, built and tested as part of this project.

Jan 1, 1973

U.S. Bureau of Mines contract H0122053, "Improved Sensors and Fire Control Systems for Mining Equipment", was an investigative effort involving: ? Study of the fire problem on large mobile mining equipment ? Identification of equipment most prone to fire, to serve as a design case example ? Design of an improved fire protection system ? Demonstration of the developed system This effort was performed during the period June 1972 through May 1973, and was conducted in two phases. Phase I, June through November 1972, was devoted to identifying the fire problem and developing and evaluating design criteria. Phase II involved translating the design into hardware and demonstrating its effectiveness during actual fire tests, first on a wooden mockup of a truck, then on an operating truck at a working mine site.

Jan 1, 1973

By J. W. Allen

This report reviews the work performed on Task M of Bu-Mines Contract H0220073 to develop an engineering model of a surface and subsurface communications system for normal mine operations and for post disaster rescue operations. The system concept provides for one-way transmission of digital information between a number of identifiable subsurface terminals or subcenters and a single surface station. It also provides 2-way voice communications between the subcenters and the surface station. The basic communications link is electromagnetic signaling through-the-earth, but the system is also capable of using mine phone lines as an alternate link. Engineering models of three subcenters and one surface terminal (see Figure 1-1) have been fabricated in order to demonstrate the system's performance. The system concept, however, permits up to 20 subcenters to be incorporated if desired. Additional subcenters are also feasible for large mines if they can be deployed in the mine to operate on a noninterfering basis.

Jan 1, 1973

By Alfred Petrick

This study gives an analysis of the copper system byproducts and discusses the identification and classification of byproduct metals and their supply systems. Arsenic, platinum-group metals, silver, gold, selenium, tellurium, molybdenum, rhenium, uranium, aluminum, magnesium, and byproduct copper, lead, and zinc from complex ores are covered. The report describes several metallurgical systems, the marginal and incremental products costs of byproduct subsystems, industry structure and organization, and the historical data on price, consumption, and supply. Supply curves are presented for about one-half of the byproduct metals studied. The study develops a conceptual framework for analysis by reviewing the present concepts of byproduct supply and the related price theory. It gives the sources of supply of the individual byproduct metals to indicate the importance of the byproduct supply to the total supply. Mills, smelters, and refineries processing byproduct materials for their metal content are identified by geographic location and company ownership, The study also includes information on the reserves-resource base supporting byproduct output, reserve estimates, and the demand aspects of each byproduct metal.

Jan 1, 1973