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By G. E. Agar, W. B. Kipkie, R. A. Tenbergen

"This paper describes the successful pilot plant testing of a flowsheet, developed at INCO Ltd.'s J.Roy Gordon Research Laboratory (JRGRL), for improved separation of the constituent minerals in a bulk copper nickel concentrate.The flowsheet utilized the fact that xanthate concentration on the mineral surfaces is the most important variable affecting the high lime separation and that reduction of the xanthate concentration could be effected by an oxidative conditioning stage.When the adsorbed xanthate was reduced to a suitably low level, chalcopyrite and pyrrhotite could be floated to leave a high grade nickel concentrate as the residue. Sodium cyanide was added to the froth product to depress pyrrhotite and any remaining pentlandite. The temporary depression of chalcopyrite by the sodium cyanide was overcome by introducing a conditioning step following cyanide addition. The advantages of the flowsheet; improved copper-nickel separation, operation without heating of the pulp, production of both high grade nickel concentrate ( 29. 5% Ni, . 26% Cu) and copper concentrate ( <O. 5% Ni, 30% Cu) were all realized."

Jan 1, 1984

By Coll Aníbal Gastañaga

La presente investigación señala la relación entre el factor tiempo-concentración y la silicosis, a partir de los resultados obtenidos por la sección Ingeniería en su estudio de ambiente de trabajo con los hallazgos del examen realizado a los obreros en un yacimiento minera del sur peruano. Para dicha correlación, se consideró únicamente el subsuelo y el personal que lo labora, excluyendo todo lo relacionado con la superficie, a fin de no diluir la tasa de prevalencia de silicosis y por la diferencia que existe en el medio ambiente del trabajo de cada trabajador. La minera se encuentra a 4600 m.s.n.m y está compuesta por rocas volcánicas terciarias y metamórficas, donde la ventilación es de tipo natural, la extracción del mineral se efectúa por el nivel inferior mediante una locomotora y el personal minero carece de implementos de protección personal. De acuerdo a la exposición de polvo, concentración, contenido de sílice libre y datos de la minera, se concluyó que la tasa de prevalencia de la silicosis fue de 11% y estuvo asociada directamente a la exposición de polvo por ocupaciones y tiempo de trabajo.Por tanto, es necesario crear un programa de prevención de silicosis, donde se instale un sistema de tuberías de agua para la perforación en húmedo, se reduzca la jornada laboral a ocho horas, se emplee atomizadores de agua después de los disparos, efectuando las operaciones de cargo mineral en estado húmedo y por último, se realice un examen periódico a los trabajadores.

Jul 20, 1959

By S. S. Chabot, S. E. James

A recent survey of CEOs from major steel companies worldwide revealed the importance of recycling zinc units from EAF dust, mill scale, blast furnace dust, and other zinc containing streams in their plants. Many processes were developed and installed in response to this challenge. The most successful approach involves the production of a crude zinc oxide and selling it to primary zinc producers to recover the metal value. The problem with this process is the high concentration of halides in the crude oxide. This type of material cannot be processed directly in an electrolytic zinc plant because of corrosion problems it will cause in electrolysis. In 1999, BRZ installed a zinc oxide receiving and washing plant to minimize the impact of halides to its circuit. A description of the washing plant and initial operating results are included.

Jan 1, 2000

By E. Ghali, A. D. Bas

There is a lack of electrochemical studies of oxidized gold ores since the majority of previous studies were conducted with sulphidic gold ores. In this study, the influence of agitation and iron oxide minerals, i.e. magnetite, hematite, and maghemite on gold leaching was investigated by means of galvanic and passivation phenomena. Cyclic voltammetry studies of Roasted Gold Ore (RGO) in de-aerated electrolyte have shown one oxidation and one reduction reaction while three oxidation and one reduction peaks were observed with gold electrode. Galvanic coupling results by Zero Resistance Ammeter (ZRA) mode indicated that magnetite showed a negative effect on gold dissolution while maghemite and hematite showed a positive effect, relatively, as a result of higher galvanic corrosion rates. Generally, gold dissolution was found to increase in the initial 15 minutes. Increasing agitation speed from 100 to 400 rpm resulted in higher galvanic corrosion rates for RGO, magnetite, and maghemite electrodes, while 250 rpm was found to be optimum for hematite electrode. Passive products such as silver and iron-oxide were identified by XPS and SEM-EDS analysis, respectively.

Jan 1, 2015

By Jian Li, Tiejun Chun, Jian Pan, Deqing Zhu, Vinicius Mendes

"A study of the coal-based direct reduction behaviors of composite binder magnetite pellets was carried out in a simulating coal-based grate-rotary kiln process. It is shown that preheated pellets possess much better reducibility than fired oxide pellets: 40 min are required for preheated pellets to reach over 90% metallization degree compared to 100 min for fired oxide pellets. The compressive strength of preheated pellets decreases dramatically at the earlier stage of reduction, climbs quickly after reducing for 30min and achieves a high value at the end of reduction. However, the compressive strength of metallized pellets from reducing of fired pellets is much lower, more cracks and fractures being formed. In the preheated pellets, crystallite of metal iron is coarse. In the oxide pellet, a large number of interconnected crystals of metal iron are formed inside pellets, and pellet structure is very compact.IntroductionDirectly reduced iron is an excellent feed in electric arc furnace (EAF) steelmaking, and possesses low tramp element content and steady component. It is generally preferred in the production of high quality steel [1-3]. Nearly 64.44 million tons of DRI were produced in 2009 over the world, over 80% of which were produced by gas-based processes, the left by coal-based processes. However, the DRI capacity was only 600 thousand tons in China in 2009. The EAF steel production has exceeded 40 million tons annually, and most of EAF operate on hot metal as feed [4]."

Jan 1, 2011

By P. C. M. Knops, K. Rijnsburger, R. M. Santos

To overcome the challenges of mineral CO2 sequestration, this work utilizes a unique proprietary Gravity Pressure Vessel (GPV) reactor technology, and focuses on reaction products of high economic value. The GPV provides intense process conditions through hydrostatic pressurization and heat exchange integration that harvests exothermic reaction energy. Here, laboratory-scale tests of the envisioned process was performed in tubular and continuously stirred tank reactor (CSTR) autoclave reactors. The mineral used was Olivine (~Mg1.6Fe2+0.4(SiO4) + ppm Ni/Cr), although asbestos, steel slags and oil shale residues are also under investigation. The effect of several process parameters on reaction extent and product properties was tested: CO2 pressure, temperature, residence time, additives (buffers, lixiviants, chelators, oxidizers), solids loading, and mixing rate. The products (carbonates, amorphous silica and Chromite) were physically separated (based on size, density and magnetic properties), characterized (for chemistry, mineralogy and morphology) and tested in intended applications (e.g. as pozzolanic carbon-negative building material). Economically, it is found that product value is the main driver for mineral carbonation, rather than, or in addition to, the sequestered CO2. The approach of using a GPV and focusing on valuable reaction products could thus make CO2 mineralization a feasible and sustainable hydrometallurgical process.

Jan 1, 2015

By Dieter Wittenberg

The use of thc ultrasound technique for monitoring rockbolt support has at last provided support engineers with a measunng system capable of pinpointing fracture failuns in fully-grouted rockbolts. The measurement data are based on the operatmg characteristics of the bolt type, which are determined both under test-bench conditions (DIN 21521) as well as in underground trials. Practical experience acquired to date suggests that this new measuring system is both effective and reliable.

Jan 1, 2001

By D. Puckett

The feasibility of maintaining equipment location, personnel location and vital statistics in surface and underground mining operations has increased with advances in radio frequency identification (RFID) technology. The paper addresses the use of this technology, relatively new in the mining industry, to track surface equipment in mine pits, loading points, and processing facilities. Specific applications are discussed including a simplified and a complex truck tracking system and an automatic pit ticket system. The paper concludes with a discussion of the future possibilities of RFID technology in mining, such as monitoring biofeedback of personnel (heart and respiration rate, body temperature, exertion level, etc.) repetitious movements to study work habits, and logging air quality via personnel sensors.

Jan 1, 1996

By Jonnie M. Estes

A two-constant equation is presented for helium from 30° = T = 1,473° K. This equation is developed by modifying a generalized equation of state originally presented by Redlich and Kwong (20).3 The modification consists of setting B = 0.06372 Tc/PeT. This modified equation represents the compressibility factors of each of 80 isotherms tested in this temperature range to less than 1 percent average deviation.

Jan 1, 1967

Beach sands on the Morobe coast of New Guinea contain significant amounts of chromite. This chromite, together with the more abundant associated minerals such as olivine, enstatite, tremolite, antigorite and feldspar has been de- rived from rocks of the Papuan Ultramafic Belt and transported to the beaches by three rivers, the Paiawa, the Saia and the Sesimbai. Of the hundreds of samples taken, 26 have been analysed mineralogically and chemically in some detail. On this basis, five groups of samples, four on- shore and one offshore, representing character- istic mineral assemblages, have been recognized. The chromite grains themselves have been exam- ined to determine variations in amount and in the Cr/Fe ratio, since this is of economic importance. Much of the chromite fails to reach a high Cr/Fe ratio as a result of magnetite rims around chromite grains. The precious metal content of the sands is negligible.

Jan 1, 1973

By C. M. Frost

The hydrodesulfurization characteristics of a residual fuel prepared from Wilmington, Calif., crude oil were determined at temperatures from 600° to 900° F, pressures of 200 to 800 pSig, and space velocities from 0.2 to 2.0 Vo/Vc/hr, using cobalt molybdate type catalysts. A prediction equation, developed from the experimental data, satisfactorily predicts the fraction of total sulfur that can be removed under any combination of operating conditions within the ranges investigated. Yields and properties of the low sulfur product are correlated with the fraction of total sulfur removed. Kinetic calculations show that the apparent reaction order and activation energy change with space velocity and temperature.

Jan 1, 1970

By Rocío Cruz, Joseph Chancasanampa

Constantemente las operaciones mineras están buscando como optimizar y reducir sus costos de operación, bajo esta premisa en la planta concentradora “Victoria” se realizó una serie de investigaciones para buscar nuevas alternativas en los reactivos de flotación que nos permita reducir los costos operativos. Como resultado de las evaluaciones metalúrgicas se logró remplazar parcialmente al Sulfato de Zinc con el Depresor RA-116 y se redujo su consumo en un 50%, esto significó un ahorro de 0.5 $/tn.

Sep 29, 2023

By Howard P. Hamlin, John W. Sweeney

Shales from 14 locations in Indiana were sampled , tested , and evaluated to determine feasibility of producing lightweight aggregates by rotary - kiln and sintering methods . Sampling procedures and the geology of the significant shale units are discussed . Preliminary testing was conducted in a muffle furnace , and continuous tests were made in a 16 - inch by 14 - foot rotary kiln . The aggregate weighed 37.0 to 47.2 pounds per cubic foot . Concrete cubes employing the aggregate were tested to determine the qualities of the concrete . Compressive strength of the concrete using seven bags of cement per cubic yard , after autoclave curing for 6 hours , ranged from 3,600 to 5,850 pounds per square inch . Four samples made suitable lightweight aggregate in the laboratory rotary kiln . Four samples tested by sintering methods made unsatisfactory aggregate .

Jan 1, 1965

By C. A. Stetefeldt

Metallurgical processes cannot be conducted successfully With out the aid of analytical chemistry. The great perfection of Iead smelting in the West, for instance, has only been accomplished by the analysis of ores, fluxes, slags and all products of the furnace. Ores are mixed and fluxed to obtain a slag of desired composition. Account is even taken of the composition of the ashes obtained from the coke. The " muscular " smelter has left the field forever! This state of affairs has been induced by sharp competition, i.e., by a com plete separation of the industries of mining and reducing ores, not by the liberality and wisdom of directors and stockholders to pro vide laboratories and engage chemists, or by their love for scientific investigation. It would be considered absurd, at present, to run a lead-smelter, a blast-furnace for pig-iron, or a Bessemer plant without the assist ance of a well-equipped laboratory and a chemist; but it is con sidered quite sufficient to provide amalgamation- or lixiviation works merely with a crude assay-office, and an assayer who is paid less than a laborer in the mill. In my opinion, this will change in the near future. By the ex clusion of Mexican lead-ores, and their growiring scarcity in the West, smelters have been forced to raise their charges on so-called dry silver-ores, and cannot handle the latter now in such unlimited quantities as formerly. The inevitable result must be that the sur plus of these dry silver-ores, especially those of low grade, will be reduced by processes cheaper than smelbing; and here the introduc tion of lixiviation has an excellent field, provided the muscular lixiviator has an able chemist for an assistant. It is to be regretted that so little analytical work has been done in lixiviation. We know almost nothing of the composition of roasted ores before and after lixiviation; of the constitution of the first wash water and of lixiviation-solutions after prolonged use; of the chemistry of sodium and calcium sulphides; of the col-hposition

Jan 1, 1892

By M Araos, I Onederra

A novel explosive formulation that substitutes the use of ammonium nitrate (AN) with hydrogen peroxide (HP) as the main oxidising agent has been developed and tested as part of an Australian Coal Industry Research Program (ACARP) project. The main objective was to provide a step-change solution that has the potential to completely eliminate NOx fumes in blasting. The development of this HP/fuel-based explosive started with a comprehensive detonation characterisation program, consisting of unconfined velocity of detonation (VOD) measurements of samples at different diameters, densities and void sensitisation techniques. VOD results showed that the HP/fuel-based explosive mixtures behaved similarly to non-ideal commercial explosives; in that way mixtures could be tailored to achieve specific detonation performance targets. The next stage of testing in this development involved preliminary confined tests to evaluate the rock breakage potential of the HP/fuel-based explosive mixtures. Fully instrumented single-hole tests were conducted in a limestone quarry. Results from these preliminary trials confirmed the rock breakage performance of HP/fuel-based explosive mixtures. The confined VOD measured in one of the tests was 5100 m/s in a 102 mm diameter blasthole at a density of 0.96 g/ml. The corresponding borehole pressure measurement of this HP charge was 2.61 GPa with a detonation temperature of 2921&#176;C. Based on near-field accelerations, both HP and ANFO charges displayed similar attenuation characteristics in the test conditions. Post-blast observations indicated that the breakage performance of the HP mixtures clearly reflected the in-hole detonation performance measurements obtained, confirming the ability of these explosive mixtures to both fragment and effectively displace the rock mass under evaluation. Further research work continues with the future commissioning of a prototype mixing and delivery unit, the successful completion and analysis of data from multiple-hole trials, and further characterisation work associated with product stability, reliability and performance under different geotechnical conditions.CITATION:Onederra, I and Araos, M, 2015. Detonation and breakage performance of a hydrogen peroxide-based explosive formulation, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 565–574 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Jack D. Ramsdell

The objective of this investigation was to make a preliminary evaluation of titanium-vanadium-zirconium, alloys using room-temperature tensile properties as criteria for selecting promising alloys for future critical studies. Arc-melted titanium-vanadium-zirconium alloys ranging in composition from 5 to 20 a/o (atomic-percent) vanadium and 5 to 30 a/o zirconium, were investigated to evaluate hardness, hot workability, and room-temperature tensile properties. Metallographic examination coupled with hardness measurements were used to follow structural changes and aging response. Room-temperature tensile properties were criteria for evaluating mechanical and engineering properties of the alloys.

Jan 1, 1960

By Carlton E. Brown

Impinger dust-counting methods are used by industrial hygienists for determining the number concentration of unhygienic siliceous dusts in industrial atmospheres. Various statements have been made regarding the size of the smallest particles revealed by the microscopic employed in such determinations. Published data on the subject are quite limited. This report presents information on the size of the smallest particles revealed by light-field and dark-field techniques applied to impinger and electric precipitator samples collected from experimentally established aerosols of silica dust and bituminous-coal dust. Size distribution and number concentration of particles of the various sizes in the aerosols were determined from samples collected by thermal precipitation simultaneously with the impinger and electric precipitator samples. The size of the smallest silica and bituminous-coal dust particles determined in the light-field counting method used was about 1./1, . There was relatively little variation in the values from 8 impinger and 33 A.-C. precipitator samples of silica dust and 13 impinger and 13 A.-C. precipitator samples of coal dust. The coefficients of variation of the values from the four sets of determinations were low, ranging from ± 7.7 to t 10 percent. This size of 1,14 is close to the limit of resolution of the microscopic method used and to various previously suggested values. The size of the particles determined in the dark-field counting method used was smaller than the size (about 0.28A ) of the smallest particles determined in the light-field, oil-immersion method used for the thermal precipitator samples.

Jan 1, 1951

By John D. Corrick

The environmental and nutritional characteristics necessary for maximum copper extraction from a low-grade ore by Ferrobacillus ferrooxidans have been explored as have many of the limiting parameters. Criteria considered were oxygen consumption, copper extracted, soluble copper concentration, temperature, pH, particle size, nutrients, and other inorganic salt concentrations. A set of environmental and nutritional conditions were developed for E. ferrooxidans Which supported cell reproduction and maximum microbial oxidation of a low-grade copper sulfide ore. Percolator tests conducted under these optimum conditions resulted in an 18 percent increase in the quantity of copper microbially extracted over that extracted under conditions considered to be standard. Manometric tests determined those extremes of environmental conditions and nutritional factors Which were detrimental to the extraction of copper by E. ferrooxidans.

Jan 1, 1965

By L. Yuan, J. H. Rowland III

"In 1995 and 2003, the Mine Safety Health Administration (MSHA) conducted surveys to determine the number of atmospheric monitoring systems (AMS) being used in underground coal mines in the United States. The survey reports showed data for the different AMS manufacturers, the different types of equipment monitored, and the different type of gas sensors and their locations. Since the last survey in 2003, MSHA has changed the regulation requirements for early fire detection along the belt haulage entries. As of December 31, 2009, point-type heat sensors were prohibited for use for an early fire detection system; instead carbon monoxide (CO) sensors are now required. This report will examine the number of AMS currently used in underground mines in the United States to see if there is a change in their use. The locations and parameters monitored by AMS are also discussed. INTRODUCTION The last survey conducted by the Mine Safety and Health Administration (MSHA) on atmospheric monitoring systems (AMS) used in underground coal mines in the United States (US) was in 2003 [1]. The survey report states that since 1995 there had been a steady increase in the use of AMS in underground coal mines as the technology of CO sensors was improved by manufacturers. AMS had become more reliable and some CO sensors could be purchased with the capability to discriminate between the CO produced from a fire versus CO produced from diesel equipment. This increase in reliability had reduced the number of false alarms and the response time. The faster response time to a developing fire allowed for the miners to take the necessary action to put out the fire or exit the mine. It should also be noted that at the time of last MSHA survey, some mines still used point-type heat sensors to detect the presence of a fire on conveyor belts. This detection method works by measuring the temperature of the air around the sensor. As a fire starts to develop, smoke and hot gases are produced from the combustion process, and the air is heated up. Once the air and gases reach a designated temperature detected by the point-type heat sensor, a fire alarm signal is generated. Studies have shown that the response times for detecting the presence of a fire using CO sensors are much shorter than using point-type heat sensors [2]. Finally, since the last MSHA survey, regulations have changed on the type of automatic fire detection systems permitted to be used in conveyor belt entries. As of December 31, 2009, point-type heat sensors are not permitted to be used for fire detection in underground coal mines in the US; instead CO sensors are required as a replacement (30 CFR 75.1103-4). This study will examine how the changing of the above regulations has impacted the use of CO sensors in underground coal mines in the US compared to their use based on the last MSHA survey. Importantly, in the previous MSHA survey, the data was recorded for producing and non-producing coal mines. In this study, only the data from the producing coal mines was recorded. Data was collected from a total of 235 coal mines for this study with the help of the MSHA district offices."

Jan 1, 2017

By Otávio da Fonseca Martins Gomes, Renata Hiraga de Vasconcellos Cruz

Maghemite is a mineral formed from magnetite oxidation at low temperatures, an intermediate term of the magnetite-hematite series. Maghemite could be misidentified as magnetite by X-ray diffraction, and/or as hematite by spot chemical analysis. Nevertheless, non-stoichiometric magnetite was detected and quantified in samples of Brazilian soils and iron ores by the Rietveld method refinement of its structure. The results were confirmed by optical microscopy and Raman spectroscopy, thus validating the method. X-ray diffraction with the refinement of the isomorphic substitution of Fe2+ by Fe3+ along the magnetite-maghemite solid solution could help to suitably characterize maghemite in iron ores.

Oct 3, 2019