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By QUANWEN PU, Yonggang Wei, Bo Li

The spent catalyst is one of solid waste resources, which contains precious metals with considerable recovery value. However, due to the different compositions of catalyst, the recovery process is difficult. Most of the catalysts are supported by alumina which has good alkali-soluble properties, while platinum is insoluble in alkali. Platinum is enriched by pressurized alkaline solution which is a kind of hydrometallurgical process. The novelty of this study is the separation of alumina and platinum from the spent catalyst and the enrichment of platinum in the solid phase. In this study, a leaching process using NaOH as leaching agent under high temperature and pressure was employed. The effects of alkali concentration, leaching temperature, leaching time, and liquid–solid ratio on leaching efficiency were investigated. The optimum process conditions were determined as follows: alkali concentration of 240 g/L, temperature of 200℃, pressure of 1.20 MPa, time of 1 h, liquid–solid ratio of 5:1. It was concluded that the leaching rate of alumina can reach 99.69%. The content of platinum increased from 0.1749 to 21.12%, the loss of platinum was 3.39%, and the enrichment ratio of platinum increased by 120.82 times. The leaching kinetics of alumina was studied based on the shrinkage core model. The activation energy of alumina leaching is 19.53 kJ/mol, and the leaching process is controlled by chemical reaction. Pressurized alkali solution can not only efficiently leachate alumina from the spent catalyst and enrich platinum, but also reduce the reaction time and increase reaction rate.

Feb 11, 2022

By B Murphy, S O’Connell, J L. Heath

In the 1989 best-seller The 7 Habits of Highly Effective People, the author, Stephen Covey, highlights the importance of maintaining not only ‘production’, but also, ‘production capacity’. When operating a modern flotation concentrator, production is often measured in terms of concentrate tonnage, tonnes milled and plant utilisation. There are very few metrics that focus directly on flotation equipment condition in relation to performance, which is analogous to Covey’s production capacity principal. It is evident on many mine sites that flotation equipment condition is not monitored on a proactive basis and that the prevailing culture is to wait for a failure, before addressing an issue.This paper discusses examples of how poor equipment condition can lead to production loss through poor metallurgical performance. Actual examples are given where these problems have occurred in operating plants. An outline is provided on how metallurgical and maintenance departments can work together to protect production capacity and gain more from existing equipment.CITATION:Murphy, B, O’Connell, S and Heath, J L, 2014. Maximising value through maintaining your flotation equipment, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 71–76 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By D Kent

The introduction of digital technologies into the underground mining industry, in both coal and hard rock mining, has enabled many high bandwidth applications to be adopted by mines.Digital networks based on 802.11 b/g/n open Wi-Fi standards allow for many applications to be run over a single communication backbone. One important application has been tracking personnel and equipment via RFID tags. This tracking application has in turn formed the basis of a Proximity Detection System (PDS) or Collision Avoidance Systems (CAS). The paper discusses the growth in digital technology as the communication backbone in underground mines which has allowed the ‘convergence of technologies’ that has been occurring in the general business world to be available to underground mine operators. Then the paper will focus on the use of the technology in the increasingly important are of risk control around mobile plant underground. The specific use of digital devices for proximity detection, in both hard rock and coal mines, to provide a system that can deliver an additional level of control to the risks associated with people-vehicle interactions underground is discussed. The initial implementation of PDS in the hard rock mining environment is based on two zones of detection, required for large and relatively high speed vehicles. Information will include:•the principles of the underlying technology,•installation learnings and effectiveness, and•change management methodology and issues.The most recent development to integrate Mine Site Technologies (MST) PDS with Frederick Mining Controls’ HazardAvert® System to extend the overall Proximity System’s functionality in hard rock mines and for use in coal mines is overviewed.

Mar 21, 2011

By A. D. Davis

The disposal of spent ore from cyanide heap-leach processing facilities is of concern to the mining industry, regulatory agencies, and the public. Disposal of several hundred million tons of additional spent ore is planned in the western United States during the next decade, with increased amounts likely if gold prices rise. In the past decade, more than fifteen million tons of spent ore have been disposed of in the Black Hills. South Dakota's off-loading criterion for cyanide has been set by the state's Department of Environment and Natural Resources at 0.5 parts per million (ppm) as weak acid dissociable (WAD) cyanide. Nitrate off-loading limits vary for each mine in the state, depending on ore type and other factors. Nitrate concentrations in leachate from spent ore depositories could be caused by conversion from other nitrogen-containing species. One likely source of nitrate is residual explosives from blasting of ore. Previous work on the combustion products of nitrogen explosives has shown incomplete 3xidation (Johansson and Persson, 1970). Another likely nitrate source is degradation of cyanide to ammonia, followed by oxidation to nitrite and nitrate.

Jan 1, 1994

By D. F. Doerr, E. Blalock, D. R. Bush, K. D. Cohen

"INTRODUCTION The design, development, fabrication, and test of cryogenic breathing apparatus is part of a much larger effort funded by the National Institute for Occupational Safety and Health (NIOSH) and managed through a Space Act Agreement with the National Aeronautics and Space Administration (NASA) at the Kennedy Space Center (KSC) in Florida. This effort is designed to create cryogenically based life support equipment that is responsive to the needs of miners as required by the Miner Act of 2006. Our goal was to design and build a liquid air based self-contained breathing apparatus (SCBA) that lasted 2 hours and would be used for the egress of miners during a mining accident and be refillable while worn. Therefore, the current report describes tests of an Advanced Cryogenic Breathing Apparatus (termed the ACryoBA) designed to provide miners egressing an emergency situation with a two-hour open-circuit SCBA. The ACryoBA utilizes low pressure cryogenic liquid air instead of high pressure compressed air commonly used in most commercially available SCBA. The ACryoBA can also be self-filled from strategically placed Cryogenic Air Supply and Fill Stations (CryoASFS) initially, and thereafter on the egress route approximately every 1 hour and 30 minutes with a 30 minute air reserve. The ACryoBA evolved originally from a one hour Liquid Air Pack (LAP) developed in the 1980’s for Space Shuttle Rescue forces allowing for longer duration and cool air (Figure 1). It was used successfully for many years, through the end of the Space Shuttle Program. The first attempt at a mine egress pack was the Cryogenic Breathing Apparatus (Figure 2). It was to have a low profile, two hours of breathing, attitude independence, and a simple rapid refill while in use. The CryoBA met the two hour criteria, but with difficulty due to excessive heat leakage caused by the dual 4 liter Dewar design. Much of the stored air was lost as it vaporized faster than it could be used. However, the pack was successful in demonstrating both attitude independence and a simple rapid refill capability. The ACryoBA project was designed to continue the progression and address the deficiencies in the CryoBA. The ACryoBA pack was designed to last 2 hours. It minimizes the heat leakage with a single Dewar and thereby requires less liquid air. The single Dewar design also minimizes weight, making it much more manageable by the user (Figure 3). The ACryoBA complies with 42 CFR part 84 NIOSH certification test requirements. One critical requirement for the ACryoBA is operation in positions other than vertical for periods up to 1/4 (i.e. 30 minutes) of the rated service life of 2 hours; this was accomplished by use of new technology called the “attitude independent pickup” which is abbreviated “AIP.” The AIP, developed by BCS Life Support LLC (patent #8,899,226), has a tube going from the top flange down through the center of the Dewar. At the end it has a flexible bellows and a weighted end. Due to the flexible nature of the bellows, the pickup at the end is free to rotate and follow the liquid level around within +/- 90o of vertical."

Jan 1, 2016

By William G. Pariseau, Mark K. Larson, Douglas R. Tesarik, Heather E. Lawson

"This contribution describes development and application of a user-friendly finite element program, UT3PC, to address three important problems in underground coal mine design: (1) safety of main entries, (2) barrier pillar size needed for entry protection, and (3) safety of bleeder entries during the advance of an adjacent longwall panel. While the finite element method is by far the most popular engineering design tool of the digital age, widespread use by the mining community has been impeded by the relatively high cost of and the need for lengthy specialized training in numerical methods. Implementation of UT3PC overcomes these impediments in three easy steps: First, a material properties file is prepared for the considered site. Next, mesh generation is automatic through an interactive process. A third and last step is simply execution of the program. Examples using data from several western coal mines illustrate the ease of using the application for analysis of main entries, barrier pillars, and bleeder entry safety.INTRODUCTIONRational design of safe underground entries and crosscuts, barrier pillars, and bleeder entries begins with a site-specific analysis of stress. An analysis of stress identifies the critical regions of high-stress concentration where yielding is likely and additional or more focused ground control measures are needed. This analysis also identifies regions where stress concentration is low, and risk mitigation is less urgent. Displacements induced by mining, including roof sag, floor heave, and pillar squeeze, are also of importance to stability. The popular finite element method is well-suited for such analysis and has been in use for studying coal mine engineering problems since the late 1960s (Dahl, 1969). The method has been taught in undergraduate engineering curricula for many years and offers an alternative to existing design procedures based mostly on rules of thumb, empirical methods based on mine data, and predigital-age concepts of strata mechanics. However, despite the versatility of the finite element method, usage has been limited, mainly because of the cost of the software and the required training in numerical methods.The program UT3PC (Pariseau, 2017) has evolved from early two-dimensional versions in the era of mainframe computers. These early versions were still quite limited using only a few hundred elements that required overnight turnaround times. Recent versions of UT3PC are convenient and efficient desktop programs that use several million elements. With the advent of personal computers in the mid-1980s and subsequent increase in computer speed, expanded memory, and lower costs, applications for mining increased in three-way cooperative projects among industry, the former U.S. Bureau of Mines, and academia. The Spokane Research Center of the U.S. Bureau of Mines, in cooperation with the University of Utah, developed a two-dimensional desktop finite element program, UT2PC, available to the mining community in 1991. This was a short course offered at the 1991 SME Annual Meeting in Denver, CO."

Jan 1, 2017

By W. R. A. Graeser

"The Nordenham finishing mill is situated in the town of Nordenham, Fede1•al Republic of Germany, on the banks of the Weser River opposite the town of Bremerhaven, with access by water to the North Sea.The unfinished fibre, shipped j?•om Deception Bay during the sub-Arctic summer shipping season, is unloaded from bulk ocean carriers, stored and then processed throughout the year until the following shipping season. This paper describes the unloading and storage facilities,the finishing mill and the finished-fibre storage arrangement. Details of environmental and dust control practices and West German environmental standards are discussed. A resumé of fibre markets is included."

Jan 1, 1976

Under the AMIRA P9 project the three-product cyclone-an off-shoot of the conventional hydro-cyclone-that produces three distinct products has been developed. The three-product cyclone shows great promise as a classifier in mineral processing. Industrial and pilot plant trials performed to assess its performance in the classification of the UG2 platinum ore, indicate that the presence of an extra overflow product stream that captures the mid-sized particles, provides improved classification efficiency. To assess the split on component density, samples from the feed and product streams were screened and assays by size for chromite (? = 4.8) and silica (? = 2.65) were obtained. Results from tests performed using this type of hydrocyclone in a number of applications indicates that it can be applied successfully in circuit configurations where the conventional hydrocyc-lone is not suitable. Utilising the three-product cyclone to classify the UG2 platinum ore resulted in an intermediate overflow product stream containing the mid-sized low density silicates and relatively fine high density chromite particles while the finer overflow contained mostly fine silicates and chromite particles. The coarse chromite and silicates reported to the underflow. Due to the increased number of products, the method of using efficiency curves was extended to cater for the increased number of products in the three-product cyclone. Although significant differences in the classification performance of the three-product cyclone were noticed with variations in machine variables a consistent method of assessing the performance was applied. The efficiency curve was adopted and applied and separate efficiency curve properties were obtained for each product stream. The methodology was applied to the component data, and efficiency curve proper-ties for each key component were obtained and compared. This paper discusses the application of the efficiency curve to cyclones producing more than two products and extending the methodology to the different components in the feed.

Jan 1, 2014

By J. Larsson

In the pursuit of increased safety the mining industry has worked to develop systems for remote control and autonomous operation of both stationary and mobile equipment. This paper reports on a newly developed system for teleoperation and autonomous tramming of LHD (Load-Haul-Dump) mining vehicles that not only increases the safety of the operators, but also has the potential to increase productivity.

Jan 1, 2010

By I. Gaballah

Decontamination of synthetic solutions of PbC12 containing 10, 100 and 1000 ppm of lead, using chemically treated barks had been studied. The percentage of !cad cations' removal from solutions depends upon the pH and the initial concentration. About 99 % of the initial lead content can be removed at pH of about 3.5, 5.5 and 6.5 for initial concentrations of 10, 100 and 1000 ppm respectively. The maximum retention capacity of the treated bark is about 83 mg of lead per gram of modified bark. Bark loaded with lead had been analyzed by Infra Red spectroscopy. It seems that lead reacts with hydroxyl groups of the phenolic constituents of the bark. On the other hand, the removal of a lead cation by the bark leads to the release of two H+. This seems to show that the removal of lead could be interpreted as an ion exchange with hydrogen belonging to the hydroxyl groups of the modified bark.

Jan 1, 1994

At its Copper Cliff Smelter, Inco Limited processes a bulk copper-nickel concentrate in two Inco oxygen flash furnaces. The furnace matte is converted to low iron matte for further processing, and the molten converter slag is recycled to the flash furnaces. The flash furnace slag is discarded. Natural gas or coke supplies a minor proportion of the process heat requirements, thus limiting the flash furnace matte grade to the target 45% CuNiCo. Coke addition to the furnace offers a potential means of establishing a reducing barrier on the surface of the molten bath. Such a practice would be conducive to producing sulfur deficient (partially metallized) matte. At the same iron content, the iron activity of sulfur deficient matte is higher than that of regular matte. A supernatant coke barrier could, therefore, be expected to lead to higher nickel and cobalt recoveries, reduction or even elimination of magnetite furnace bottom build-up and increased sulfur elimination as SO2 in the flash furnace. Preliminary experiments were conducted in a mini plant flash furnace to investigate the effect on process metallurgy of the suggested modified scheme. This paper presents the experimental results and discusses key aspects of the possible operation of the Inco flash furnace with a coke barrier separating the freeboard from the molten bath.

Jan 1, 2003

By R. H. Jefferson

This Bureau of Mines report describes a series of rapid wet chemical methods for the analysis of blast furnace slags. A "complete" analysis for total iron, manganese, silica, lime (calcium oxide), magnesia (magnesium oxide), sulfur, and mixed oxides (R203) can be routinely performed in less than 3 hours. These methods were employed as the analytical control procedures for the Bureau's experimental blast furnace operations and have been satisfactorily applied to the analysis of other slags and calcareous materials.

Jan 1, 1974

By H. Dreissen

Upgrading of low-concentration ores is of growing importance today. The Heavy Medium Cyclone Process, thanks to strong centrifugal forces, effectively separates particles varying only slightly in specific gravity but widely in size. The paper discusses the separation efficiency, the method of assessing that efficiency, and the influence of such factors as medium solids. The operating results of nine heavy medium cyclone plants handling following minerals are reported: barite, wolfram, iron, magnesite, diamond, lead-zinc, fluorspar, rocksalt potash. Highlighted are an improved recovery system for heavy medium and some other developments, such as techniques for separation down to 0.1mm and the application in the field of recycling.

Jan 1, 1980

By E. Neumann

With fuel costs unstable but escalating, solid fuels are playing an increasingly larger part in industrial concerns. Coal, petroleum coke and wood are examined from a burner system design viewpoint and from operational experience in kilns, hot gas generators, etc. The burner of today must also handle multi-fuel tasks and allow immediate, painless switching from one fuel to the next as well as the simultaneous burning of two or mope fuels. The paper discusses the principle of burning alternate pulverized fuels as well as the practice both in the United States and around the world.

Jan 1, 1983

By Tugba Cebeci, Bahjat Khoshaba, Bern Klein, Libin Tong, Andrew Bamber

"Sensor-based sorting technologies have potential to pre-concentrate low grade subeconomic ores through discarding the barren waste particles. However, the inability of sensors to accurately discriminate ore from waste is a barrier to prevent their wide applications. The present study focuses on the development of more intelligent sensing systems by using correlation and regression analysis of X-ray fluorescence (XRF) sensor responses on the copper ore samples obtained from Chile. The responses obtained through XRF scanning were reported both in the form of counts and the grades of elements. Linear and multiple linear correlation analyses were made between the XRF counts and the copper grades obtained through chemical analysis. Both the heterogeneity of the ore particles and the matrix effect in the XRF measurement are discussed in the study.INTRODUCTIONSorting can not only discard waste rocks away from the concentrator but also recover metal bearing ore particles that would be lost to the waste dump. The benefits of ore sorting include reduced energy consumption, water and reagent usage in the downstream operations (Bamber, 2008; Gunson, Klein, Veiga, & Dunbar, 2012; Kleine & Wotruba, 2010; Knapp, Neubert, Schropp, & Wotruba, 2014; Kobzev, 2014; Lessard, de Bakker, & McHugh, 2014; Mazhary & Klein, 2015; Robben, Wotruba, Robben, von Ketelhodt, & Kowalzcyk, 2013). X-ray fluorescence belongs to sensor-based sorting technologies and Xrays are a high energy-high frequency form of electromagnetic radiation inhabiting the region between the ultraviolet radiation and gamma rays (Shackley, 2011). Recent XRF sorting studies on low grade copper ores were carried out at MineSense Technologies Ltd. aimed at increasing the capacity related to improving the understanding of ore heterogeneity as the basis for developing semi-bulk or bulk sorting systems (MineSense Technologies Ltd., 2016)."

Jan 1, 2016

By H. R. Wells

The Blackbird district, Lemhi County, Idaho, has long been recognized as a potential source of cobalt and copper. However, the comparatively low grade and small size of the known ore bodies, the small demand for cobalt, and. the lack of adequate roads throughout the region precluded extensive exploration of the early discoveries in the area. Recent advances in alloy metallurgy, accentuated by wartime activities, greatly increased the demand for sources of domestic cobalt. Beginning In 1941, engineers of the Bureau of Mines conducted an examination and exploration program in the Blackbird district. This work was supplemented by an exploration program by engineers of the Howe Sound Mining Co., 730 Fifth Ave., New York 19, N.Y.

Jan 1, 1948

By M. J. U. T. Van Wijngaarden, R. J. Dippenaar, P. M. Van Den Heever

Some of the important properties of solid electrolytes that influence the performance of electrochemical oxygen probes are discussed in the first part of this paper. It is shown that accurate and reproducible measurements of oxygen in liquid steel are possible with commercial oxygen probes only if great care is exercised in the make-up of the chemical and phase composition, as well as the microstructure of the solid electrolytes used in these probes. To prove this premise, the second part of this study reports on the results of an experimental evaluation of new commercially available oxygen probe. An evaluation of the solid electrolytes used in this probe indicated that the consistency of the chemical composition, degree of stabilization, and microstructure of the electrolytes used are well controlled. The successful application of this particular oxygen probe under industrial conditions was confirmed. It was also found possible to make reliable and reproducible measurements, with acceptable uncertainty, by proper handling of the probe. Some recommendations are made as to the interpretation of the e.m.f. response curve and the use of the electronic processing unit supplied with the probe.

Jan 1, 1987

By Xiqing Wu, Tao Yue

"Magnetic seeding co-agglomeration, i.e. adding magnetic seeds, organic depressant (such as the starch), and pre-magnetization for co-agglomeration, was applied in the reverse flotation for hematite ore slimes. Samples of the hematite ore slimes and the pure hematite fines were investigated by the co-agglomeration, respectively. Flotation tests suggest that the depressing effect of starch in the flotation was further enhanced with the addition of magnetic seeds and the pre-magnetization. Following the laser size analysis and flotation tests, TOC adsorption analysis, VSM, surface charge measurement, AFM, FTIR study, and SEM imaging have been utilized to understand the depressing mechanism. Based on the results it was demonstrated that with the addition of magnetic seeds and the low field pre-magnetization, the adsorption of starch onto hematite minerals was strengthened through the magnetic seeding co-agglomeration. The co-agglomeration improved the flotation performance by introducing the magnetic interactions and acting the bridging adsorption of starch between fine hematite and magnetic seeds in a suspension, and then resulting in an intensified coverage of the starch onto hematite particles and positive action in the coagglomeration under the pre-magnetization.INTRODUCTIONFlotation is undoubtedly the most important and versatile mineral processing technique, and both its use and application are continually being expanded to treat greater tonnages and to cover new area. However, its influence was limited to a relatively narrow particle size range of 5–300 µm (Wills and Napier-Munn, 2006). The main reason behind this limitation lies in that fine particles have high specific surface area, so need relatively high dosage of reagents (collectors or depressants), and exhibit poor flotation performance while intermediate or properly-sized particles produce high flotation kinetics and need low consumption of reagents. In order to increase the recovery of fine particles, quite a few of flotation techniques have been investigated. Most of them are based on particle aggregation, namely, by enlarging the apparent particle size, such as carrier flotation (Valderrama and Rubio, 1998; Zhu et al., 2009), shear flocculation (Duzyola and Ozkan, 2010; Yin et al., 2011), selective polymer flocculation (Rubio et al., 2007; Song et al., 2012; Ng et al., 2015), oil agglomeration (Laskowski and Lopez- Vladivieso, 2004; Forbes, 2011), temperature responsive polymer flocculation flotation (Forbes et al, 2011), and etc. However, these techniques above-mentioned are mainly studied for the direct flotation of fine minerals, and most of these techniques have not found applications for iron ore slimes especially recovered by the reverse cationic or anionic flotation."

Jan 1, 2018

By Surendra K. Mishra

With increasing regulatory pressure from the environmental authorities, waste management has become a focal point of industrial operation. To offset the waste management costs, industry has made conscious effort to recover usable resources from the waste streams. This paper reviews the technical developments and current practices in processing of waste materials. Methods for recovering metallic, non-metallic and organic species from solid wastes and effluents generated by operating plants are discussed.

Jan 1, 1997

By Edinson Terán, Delia Cieza

El Perú, enfrenta crisis y entrampamiento político institucional; sin embargo, las regiones evidencian diversos esfuerzos por superar las limitaciones políticas, mediante la participación del conjunto de actores en la gestión de su desarrollo. La presente experiencia parte de este proceso, Cajamarca tiene un especial significado considerando que se convirtió en el icono de las manifestaciones en contra de la minería en el 2011. Actualmente la región vive procesos de cambio con iniciativas de diversos actores que buscan nuevas condiciones para aprovechar sus recursos y convertirla en un territorio competitivo nacional e internacionalmente.

Sep 29, 2023