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By James Douglas

IN discussing the waste upon which hinges, or is supposed to hinge, so largely the preservation of our national resources, the conclusions reached would be more reliable if actual ex¬perience were consulted, and fewer deductions were drawn from general statements, which are often the product of the imagination. It cannot be questioned that the value of by-products has not been sufficiently appreciated by us, and that our, tardiness in recovering the useful ingredients of the escaping gas of our coke-ovens is one of the most glaring instances of shortcoming in that direction. And yet even for that sin there is some palliation in the immature condition of affiliated industries. I presume that it is admitted, without argument, that, except under very exceptional conditions, all the elements cannot be recovered from most of the ores or natural products. which we treat. While it is a shame that the by-products from our coke-ovens should be dissipated, Edward W. Parker's report to the U. S. Geological Survey for 1906' supplies a fairly good excuse in justification of this appalling waste. He says (pp. 773 to 774.)

May 1, 1909

By Christopher J. Bise

It is somewhat reassuring to note that the United States has an abundance of coal reserves which can be used to bridge the widening gap between the nation's energy production and consumption. The U. S. Bureau of Mines has recently established a demonstrated coal reserve base of 434 billion tons. (31)(Figure 1) As can be observed, the major percentage of the reserves is in the West. Although surface coal mining in the West has been gaining increased attention in recent years, western reserves that must be deep mined are significantly greater. Though deep mining activity in the west is very limited and accounts for less than 2% of the annual production, the primary reason, quite probably, is the greater thickness of the seams as compared to those found in the East. Forty-five billion tons of the western demonstrated coal reserve base for underground mining are in seams greater than 10 ft. in thickness. (37) Thick coal seams do not lend themselves readily to extraction with the underground mining methods practiced in the United States today. Experiences from the practices in other countries can serve only as guidelines. Consequently, a concerted effort is necessary to overcome the technical difficulties.

Jan 1, 1975

By K Knorr

Desktop X-ray powder diffraction using a D2 PHASER equipped with fast linear detector was performed on several iron ore and mill scale samples. Data were analysed using cluster analysis and Rietveld quantitative phase analysis. The quantitative mineralogy of both materials could be established. Thus the input is provided for understanding the energy consumption and the CO2 emission during iron production. Furthermore, tabletop XRD allows to distinguish iron ore from mill scales and to quantify their mixtures.

Jul 11, 2011

By Xun Hu, Jian Pan, Hongbin Yu, Deqing Zhu, Yanhong Luo

Lump ores are one kind of important burdens for blast furnace (BF), their metallurgical properties have significant influence on BF performance. In this paper, the relationships between the mineralogy of five natural lump ores and the metallurgical performance have been studied. The mineralogy study includes mineral compositions, microstructure and porosity, and the metallurgical performance covers reducibility index (RI), low-temperature reduction degradation index (RDI) and decrepitation index (DI). The results show that the complex lump containing hematite, and goethite has better overall metallurgical performance. For single lump, the RI of goetihte ores is higher, the RDI and the DI is strongly influenced by porosity. The hematite and magnetite ores have good anti-decrepitation and anti-RDI, but generally the RI is lower due to lower porosity, and the RI is related to the grain size, the smaller grain size is, the better reduction will be.

Jan 1, 2015

By Mike Ghassemi

It is clear that precise overground and under-ground mapping is an important factor for all designers. Due to rapid changes in underground construction, tunnel designers are increasingly in need of updating project information. This article explains the latest techniques for detecting under-ground utilities as well as underground mapping. Global Positioning System (GPS) is a very ac-curate and popular navigation and mapping system that has been used extensively above ground, but is not used for underground mapping as signals are not strong enough to pass through ground or water. Most underground techniques were developed for military applications during the first and second world wars. Later, the techniques became public. For example, ground penetrating radar was developed for the military in 1970 to be used for locating tunnels under the demilitarized zone between North and South Korea. Later, the same technique was used for detecting unexploded ordinance such as plastic land mines.

Jan 1, 2011

By U. Kammer

The reduction of the lead content in the separator fraction produced during the mechanical processing of spent lead-acid batteries is an important environmental and economical issues. The reduction of lead down to less than 1 percent is very difficult using hydroseparators that are common in battery recycling facilities. Very promising results were achieved performing experiments on a test rig using a new technology in battery treatment: a discharge-type jigging unit. The materials is fed onto the jigging bed and transported through the machine. Due to the intensive movement of the feed, an additional washing effect is also obtained in addition to separation of the lead and plastic fractions. The knowledge gained from this development work at UVR-FIA GmbH in Freiberg, Germany, led to a patent application. This paper focuses on the results of the development work and the start-up and one year's operation of the industrial-scale application at Harz-Metall GmbH in Goslar, Gennany.

Jan 1, 2000

By S. S. Clarke

ABOUT two years ago some of my friends were discussing the amount of drill-steel breakage that was permissible or not excessive, per month, per rock ton, per ton of steel or any unit of measure or output that would give a comparison between different kinds of drill steel. No one seemed to know what life to expect of steel, or what percentage of breakage might be termed excessive. In fact there were no operating data available to guide one in selecting the best steel for our mines, nor could any ideas or information be secured from the steel manufacturers. One was merely told that so and so used their steel and it was very satisfactory; or else one was given a highly technical lecture on their specific heat-treatment. Any estimates on expected breakage were just guesses, ranging from a fraction of a per cent to as high as ten per cent per month.

Jan 1, 1933

By James O'Brien, Lyman Frost, S. Elangovan, J. Stephen Herring, Joseph Hartvigsen, Carl Stoots, Anthony Nickens

"Carbon dioxide recovered from concentrated sources, such as metallurgical reduction furnaces, cement kilns and fossil power plants can provide a valuable feedstock for a synthetic fuels industry based on energy from nuclear, solar, wind and hydropower sources. High temperature co-electrolysis of CO2 and steam to produce synthesis gas has been demonstrated using reversible solid oxide fuel cell technology. Where a source of high temperature process heat is available, such as from an advanced high temperature nuclear reactor or solar dish concentrator, the endothermic electrolysis reactions can utilize both thermal and electrical inputs in such a way that the conversion efficiency within the cell is 100%. Synthesis gas produced in a coelectrolysis cell has been further reacted over a catalyst to produce conventional hydrocarbon fuels. Widespread implementation of synfuel production from CO2 will enable a much larger reliance on intermittent renewable energy than can be accommodated by conventional electric demand profiles.IntroductionFor the past several years, Ceramatec, Inc and the Idaho National Laboratory (INL), have been studying the feasibility of high temperature solid oxide electrolysis for large-scale, nuclearpowered hydrogen production under the U.S. DOE’s nuclear hydrogen initiative (NHI) as an alternative to the thermochemical process. Parallel to this effort, the INL and Ceramatec have been researching high temperature co-electrolysis of mixtures of steam and CO2 to produce syngas:"

Jan 1, 2008

By Christine Wenzl, Christoph Wagner, Christoph Sagadin, Stefan Luidold

Corrosion mechanisms have been investigated between MgO refractory substrates and synthetic FeNi slags. The materials taken into consideration comprised a simple synthetically mixed slag with specific oxides of slags from a ferroalloy producer. The MgO refractory substrates with the slag specimens on it were heated in a hot stage microscope to two different characteristic temperatures, 1350 and 1650 °C. The experiments proceeded under a controlled gas atmosphere that simulates the relevant process conditions. The corrosion mechanisms of each system were determined by SEM analyses. The obtained results showed that slag corrosion is dominating with a pronounced partial dissolution of refractory. It was also observed that iron oxide present in the slag diffused into the coarse refractory grains forming the relative low melting magnesia wuestite. Finally,the comparison of these findings with those predicted by thermodynamic calculation (FactSage) indicated the corrosion mechanisms and draw implications for improving the refractory performance and lifetime.

Mar 1, 2017

By R. Guest

Reichert cone concentrators are used successfully in many applications, but have as yet not found favour in the gold mining industry on the Witwatersrand, because, for optimum operation, the cones need to have specially designed feed-preparation and circuit details. In addition, good liberation of the valuable minerals is essential. Gravity tests, in which a pilot plant was used on refractory gold ore, showed that 94 per cent of the gold could be extracted after gravity concentration and preferential grinding, roasting, and cyanidation of the concentrate, whereas 96 per cent could be extracted by flotation followed by the same preferential treatment. However, the capital and operating costs for gravity separation are expected to be considerably lower than those for flotation.

Jan 1, 1982

By M. Tanaka, T. Oishi, K. Koyama, S. Alam

"A novel hydrometallurgical process for copper recovery from waste printed circuit boards has been proposed, which consists of selective leaching of copper metal as Cu(I) by Cu(II) in ammoniacal alkaline solution, purification, and electrowinning. The distinct feature of this process is much lower power consumption during the electrowinning than that during the conventional one from acidic copper sulfate media, because the deposition of copper metal from Cu(I) at the cathode and the oxidation of Cu(I) to Cu(II) at the anode take place in the present method. In the laboratory-scale tests using waste printed circuit boards, high purity copper which contains 1.1ppm of impurities was obtained in a chloride system. INTRODUCTIONThe recovery of various metals from waste materials is an important issue in order to conserve the environment and metal resources. Copper is used for cables, electric appliances, etc., and is currently a very important material for industries and will continue to be in the future. Among the wastes that contain copper, one of the most complex recycling materials is electronic scrap like printed circuit boards (PCB), which generally contain 10-30% copper as well as plastics, fibreglass and other metals. There are two ways to recover copper, either pyrometallurgical or hydrometallurgical. Hydrometallurgical treatments generally have more flexibilities in the process scale and control. The separation processes tend to become complicated because of the poor selectivity during the leaching in the sulphuric and hydrochloric acid media. On the other hand, the use of ammonia as a complexing agent, gave a higher selectivity for copper leaching (Nigo, Majima, Hirato, Awakura, & Iwai, 1993; Majima, Nigo, Hirato, Awakura, & Iwai, 1993; Zhou, Shinme, & Anezaki, 1995; Koyama, Tanaka, & Lee, 2006) .In this study, recycling process containing leaching, copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) is introduced. Furthermore, copper recovery from a waste printed circuit boards and impurity behaviour was examined in ammonia-ammonium sulfate (sulfate system) and ammonia-ammonium chloride (chloride system) systems."

Jan 1, 2012

By Gary G. Grim

The reliable performance of the coal reclaim system is essential to the continued availability of a coal-fired electric generating unit. The control of fugitive coal dust within the areas housing the reclaiming equipment is necessary not only to minimize maintenance and clean-up costs, but is also a safety and health consideration. This paper describes the reclaim system control and dust suppression systems as initially installed, the shortcomings of these systems and the steps eventually taken to correct these shortcomings.

Jan 1, 1983

By J. Huisman

With the introduction of ever-stricter environmental operating guidelines, capital expenditure restrictions and operational budget cutbacks, the biological method of SO2 removal becomes more and more attractive. Biological treatment of dilute flue gases is a more cost effective technology in comparison to conventional sodium hydroxide scrubbing. Although the investment costs for sodium hydroxide scrubbing is lower, the operational costs are significantly higher. In addition, the end product of the biological installation is sulfur instead of sodium sulfate; and no further wastewater treatment of the bleed from the biological installation is required since heavy metals are removed simultaneously. Another option for the treatment of SO2 containing gas at a sulfuric acid plant is the production of extra sulfuric acid of the discharged SO2 by applying an additional converter. Comparing biological treatment with this option shows much lower investment costs for the biological installation. Sulfur is produced which can be converted to sulfuric acid, so the bio-route will be more cost-effective than an additional converter. In principle, the biotechnological gas cleaning system is an integration of an absorber with a wastewater treatment facility. In the absorber, the SO2 containing gas is brought into contact with the washing water. The effluent absorber liquid contains a mixture of sulfite and sulfate that is converted into elemental sulfur. This conversion takes place in an integrated system; first, the sulfite/sulfate mixture is converted anaerobically into sulfide; secondly, the sulfide is converted aerobically into elemental sulfur. Subsequently the sulfur is separated and the water is returned to the absorber. Due to the buffer capacity of the washing water, removal efficiencies over 98% are possible. In addition to SO2 removal, it is possible to convert for example other bleeds streams such as scrubber acid or weak acid to sulfur in the same SO2 installation. Recent evaluations concluded that biological desulphurization of flue gases is not only economically attractive in comparison to convention sodium hydroxide scrubbing but also in comparison to gypsum producing systems and even seawater scrubbers. This paper describes the technological and economical viability of biological flue gas desulphurization.

Jan 1, 2005

By Justin Lukens, Di Stasim Jeffrey, Frank Di Salvo

Columbia University’s Manhattanville Campus expansion includes the construction of two new business school buildings. The new buildings require development of an entire city block bound by 12th Avenue, W 131st Street, W 130th Street and Broadway in Upper Manhattan. A support of excavation (SOE) package was first released, followed by a foundation package. The SOE package consisted of approximately 100 soldier piles and 280 anchors, up to 215’ long, to support a cut anywhere from 30’- 50’ below street level. The foundation package alone included approximately 1600 drilled micropiles. Given the breadth of the work scope, Hayward Baker Inc and Moretrench joint ventured on these two projects to bring sufficient knowledge and work resources to complete the work in an efficient and timely manner. This included working with the Owner/Engineer to propose different means and methods for construction to significantly reduce the schedule while meeting the design intent, such as large diameter (36” diameter) augercast piles in place of conventionally drilled soldier piles and large hollow-bar micropiles (103/51 bars) in lieu of pressure-grouted micropiles. The anchors, ranging from 3 to 22 strands, were used for earth retention through both soldier pile and lagging walls and existing slurry walls. These anchors were complicated based not only on their size and length, but also the need to drill some of them under the historic Studebaker building. The overall magnitude of the project with considerations to resource management and material lead times will be addressed, highlighting critical strengths provided by the Contractor to ensure project success. The scope of work discussed in this paper was executed under two separate competitive bid contracts. The first contract included the support of excavation work and the second contract included the foundation package. The support of excavation comprised of drilled soldier piles (performed by Case Foundation as a subcontractor to the JV), driven soldier piles, driven sheet piles, hollow bar tiebacks, multi-strand tieback anchors and micropile soldier piles. The foundation package consisted of drilled micropiles. Due to the large scope of work and critical schedule requirements of the project, the JV had to think outside the box and present value engineered alternates to expedite installation durations.

Jan 1, 2019

By Allan MacRae

Freeport-McMoRan Inc. operates an ISASMELTTM furnace for the smelting of copper concentrate at the Miami Smelter in Claypool, Arizona. In May 2017, the furnace was restarted after incorporating newly designed copper cooling elements from just above the tap hole to the underside of the roof. The objective of the improved cooling design was to extend campaign life by eliminating existing failure mechanisms with the wall refractory. In addition to upgraded bathline coolers and complete coverage of the gas offtake transition, or ‘kettle’, with plate coolers, a novel arrangement of coolers was installed in the remaining freeboard area. The shell required significant cutting and re-stiffening, as well as extensive modification of the cooling water piping. Based on performance observed to date, it is expected that smelter throughput will be increased due to extended ISASMELTTM refractory campaign life.

By Ralph W. Barbaro

In the mineral industry, the objective of a mining venture is to extract, process, and market a mineral commodity in such a manner that the profit of the venture is maximized. In a mining venture, a company normally has control over mine production scheduling, the selection and location of processing facilities (mineral beneficiation plants, smelting plants, refineries, or blending facilities), processed ore blending, and the selection of markets. The flexibility of the above factors provides many alternatives to satisfy the needs of each market with regard to quantity and quality of ore. The purpose of this paper is to present a mathematical model for determining the alternative that yields the maximum profit. Production planning is generally concerned with the best utilization of fixed resources, more specifically, with the determination of production and inventory levels to meet fluctuating demand requirements. A mine can be any source of ore such as an entire mine, a production unit within a mine, or an independent supplier. The objective of production scheduling is to determine the times at which each mine will be used and to allocate a required level of production. Production planning and scheduling problems are intimately associated with the location of new and existing mines and processing facilities. Although the location of the mines is usually fixed, there can be considerable flexibility in locating new processing facilities, in the selection of the processing plant, and in blending the ore before and after processing.

Jan 1, 1983

By H. R. Manouchehri

"Pyrrhotite (Po) is one of the most abundant sulfide minerals in processing industry and must be rejected in most cases. Particularly, Po rejection and its selectivity against pentlandite (Pn) have long been a challenge due to similarities in the mineral composition of the two minerals and the collectorless flotation characteristics of Po. Xanthates have been widely used to promote sulfide mineral flotation; however, in the presence of xanthates, the redox potential established at the mineral/solution interface is most important, determining the flotation performance. In this paper, the importance of electrochemistry in Po and Pn flotation has been demonstrated and a comprehensive study was conducted on two different feed streams (i.e., magnetic concentrate and scavenger cleaner streams, containing magnetic and nonmagnetic forms of Po, respectively), from Vale’s Clarabelle Mill in Sudbury, Ontario, with an objective to determine if improvements in Po rejection and Pn recovery could be achieved by controlling pulp electrochemistry. By conducting a series of flotation tests under different Eh conditions and reagent usage schemes, it was revealed that higher Po content in the magnetic stream may protect Pn from being oxidized, improving Pn recovery. The results indicated that at low oxidizing pulp chemistry, the rest potential for the Pn is still high enough to allow the formation of dixanthogen to promote its flotation. Using a Pt electrode, it was found that by controlling pulp potential at -50<Eh< +50 mV, the Pn recovery and Po depression would be satisfactory. The results, using mineral electrodes (Outotec Chena analyzer), indicated that selective separation can be achieved if low-to-moderate oxidation potentials (0 to 100 mV) or reduction (0 to -100 mV) potentials are monitored using Pn and Po electrodes. Mixing two streams at 50:50 wt % would be possibly beneficial in selective separation.IntroductionPyrrhotite (Po), Fe1-xS, is one of the most abundant sulfide minerals in the processing industry. It is an iron-deficient sulfide that occurs either in monoclinic or hexagonal form. The monoclinic one is richer in sulfur and is ferromagnetic, whereas the hexagonal Po is poorer in sulfur and has no magnetic properties. In general, the ferromagnetic properties of natural Po increase with increasing sulfur content. Although Po holds significant iron content, it is not used as a feedstock for the iron and steel industry due to the difficulty in achieving complete removal of sulfur. The common availability of iron oxide ores makes the iron sulfides irrelevant for the steel industry."

Jan 1, 2015

By Luis Noval García

El presente texto describe la importancia de la explotación de yacimientos carboníferos. Para ello, revisa la potenciación del PROCARBÓN como institución mediadora entre productores y consumidores donde se establecen reglas adecuadas a la realidad económica del Perú.

Jan 1, 1986

By R. Ribeiro

The designers of the new Arafertil concentrator in Brazil provided for complete automatic control of the grinding circuit to meet the operating objective of maximum throughput at a specified grind. Analog control methods were selected because of proven reliability and simple maintenance, and in order to minimize commissioning time and effort. This paper summarizes the step-by-step effort required to progress from local loop control of certain individual parameters to an integrated system capable of achieving the design goal. Emphasis is placed on the practical aspects of commissioning a control system.

Jan 1, 1979

By N. Dashbold, E. Rudnik

"Waste electric and electronic equipment currently comprises the fastest-growing waste stream in the world, but at the same time it is seen as an important source of metals for the recycling industry. E-waste is usually treated pyrometallurgically, with hydrometallurgical methods used to a lesser extent. This paper reports the results of research on the selective recovery of copper from smelted low-value electronic waste. Pyrometallurgical pretreatment of the scrap allowed the removal of plastics and the increase of metal content in the material. The obtained alloy of copper, zinc, tin and silver was a multiphase solid consisting of two brass phases and inclusions rich in iron, lead and silver. Copper alloy was further anodically dissolved in ammoniacal chloride solution. It resulted in high degradation of the material and accumulation of the metals mainly in the slime. The slime was then leached in acid or ammoniacal chloride and sulfate solutions followed by selective copper electrowinning. Hydrochloric acid was the most efficient solvent for the slime, but ammoniacal solutions were more selective for copper. Copper could be leached with 96 to 100 percent and 87 percent efficiency from the slime by the chloride and sulfate solutions, respectively. Copper with 90 to 99 percent purity at current efficiency of 42 to 76 percent was obtained from the acid solutions, while copper with 98 to 99 percent purity at current efficiency of 60 to 86 percent was deposited from the ammoniacal baths. IntroductionObsolete electrical and electronic equipment makes up the fastest-growing waste stream in the world (Baldé et al., 2015), due not only to the introduction of wider ranges of new types and models of a variety of electronic products but also to the shortening of their life-spans, sometimes referred to as planned obsolescence by producers (Keeble, 2013). About 42 million tons of electronic waste, or e-waste, are estimated to have been generated globally in 2014 (Baldé et al., 2015), and it is expected that in the European Union alone the waste electrical and electronic equipment (WEEE) stream will reach more than 12 million tons by 2020 (European Commission, 2015). Accurate evaluation of e-waste generation (Wang et al., 2013) and its global transport (Breivik et al., 2014) is difficult, mainly due to a lack of high-quality data related to its market and socio-economic dynamics.Many countries introduced legislation to control e-waste flow, collection and recycling. For example, Directive 2012/19/EU on waste electrical and electronic equipment (European Parliament and the Council of the European Union, 2012) obliges all E.U. members from 2016 to maintain a minimum collection rate of 45 percent of the total weight of WEEE collected. From 2019, the minimum collection rate to be achieved annually shall be 65 percent of the average weight of electronics placed on the domestic market in the three preceding years, or alternatively 85 percent of WEEE generated in the territory of the particular member."

Jan 1, 2017