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By D. H. Ryan, J. T. Graham, A. Navarra, J. A. Finch, S. Somot

Pyrrhotite (Po) is widely considered to be the most significant mineral in the self-heating of sulphides. It is therefore desirable to determine the amount of Po in mineral samples. This is commonly accomplished through x-ray diffraction (XRD) or quantitative evaluation of materials by scanning electron microscopy (QEM-SEM). This paper introduces another quantitative method based on Mossbauer analysis that requires limited sample preparation and has the additional potential to detect the sulphur/iron ratio within Po. The technique is explored using pentlandite/pyrrhotite mixtures.

Jan 1, 2009

By M. Tamlin

The state of the lithium mineral industry is closely linked to the performance of the glass and ceramic industries and to the overall economy. Demand for the glass/ceramic products in Europe, Asia and North America remained strong during 1999. This was due to a slight improvement in the economy during the latter half of the year. Consequently, demand for lithium minerals was firm, with a positive outlook. The major economic minerals for lithium are spodumene, petalite and lepidolite. The latter was once the primary mineral. But its importance hasdeclined since the 1960s. The lithium industry consists of two different segments: •The lithium minerals segment mines from hard-rock deposits and physically processes the material to high-grade concentrates. •The lithium chemicals and metal industry segment. The major feedstock for specialty lithium chemicals was previously high-grade spodumene ore converted to lithium carbonate. However, most lithium carbonate is now sourced from salars in North and South America.

Jan 1, 2000

By Q. Zhang

Phosphate tailings through Flotation contains large amount of dolomite which is difficult to be separated from apatite. In this present research, phosphate tailings is recycled by Flotation i.e. re-processing. High-purity dolomite with purity as high as 91.17% is seperated, which contains 19.82% of MgO. The results of orthogonal test show that the effect of various levels of different factors on the high-purity dolomite floatated. Future utilization of purified dolomite is also discussed: magnesium fertiliser especially magnesium phosphate is expected to be an ideal product from high-purity dolomite.

Jan 1, 2014

By Leoncio Méndez, Jesús Arguijo, Juan José Frausto, Daniel Castruita, Daniel Aguilar

Minera Sabinas (Grupo Peñoles), localizada en Sombrerete, Zacatecas, México, produce concentrados de cobre y zinc. Su proceso es un circuito de conminución de quebradoras y dos molinos de bolas en circuito cerrado con hidrociclones seguido de un circuito de flotación, a partir de mineral polimetálico extraído de una mina subterránea. Su problemática consiste en que la recuperación por flotación disminuye significativamente cuando minerales con contenido de pirrotita son procesados. La flotabilidad natural de la pirrotita supera la cinética de flotación de las especies de cobre y zinc y limita la capacidad de la concentradora para generar concentrados vendibles. Este artículo presenta un diagnosticó de los problemas que se tienen cuando se procesan minerales con alto contenido de pirrotita, así como resultados de un programa experimental a escala laboratorio realizado en el CIDT de Peñoles y en sitio. La investigación se enfocó en definir un esquema de reactivos para poder procesar minerales con pirrotita en su composición. Compósitos de alta y baja ley de cobre fueron usados en la investigación. Se identificó el agua de proceso como una fuente de iones calcio y sulfato. Se desarrolló un esquema de reactivos orientado a promover la selectividad de las especies de valor respecto a la pirrotita, incluyendo tratamiento del agua de proceso.

Sep 20, 2019

By R. Hurman Eric

The dew-point technique of activity measurements take advantage of the volatility of a component in solution. The pressure of the volatile component over a sample is determined from observations of the temperature at which condensation of the vapor occurs. The method is applicable best when the vapor pressure of the components would differ by about two to three orders of magnitude. Experimentally, this is a closed system involving the use of evacuated and sealed transparent quartz sample probes. Furthermore reliable vapor pressure data of the volatile component is essential along with a specialized high temperature furnace capable of giving reproducible results. In this context, the vertical Dew-Point Furnace (DPF) was designed and built after elaborate trails until enough proficiency was gained for reproducible results. Over the years the DPF was modified and improved. The DPF developed was versatile and could easily be used for activity measurements in the isopiestic mode (another method of measuring activities of a volatile component in a solution). The necessary ancillary systems; namely evacuation-flushing-evacuation followed by sealing of quartz sample probes under vacuum were also perfected over the years. As and when necessary the dew-point technique was supplemented by classical equilibration-quenching method employed on the sealed quartz sample probes to reveal necessary phase equilibrium information. The following were studied utilizing the above technique: (i) Activities in CU2S-PbS and FeS-PbS binaries and CU2S-FeS- PbS ternary at 1200°C; (ii) Activities in Cu2S-SnS and FeS-SnS binaries and Cu2S-FeS-SnS ternary at I200°C; (iii) Phase equilibria and thermodynamic in Cu-Pb-S, Fe-Pb-S, Fe-Sn-S, Cu-Sn-S and Ag-Sn-S systems. Most recently the following systems have been tackled: (i) Phase equilibria and thermodynamics in the Ag-Pb-S and Sn-Pb-S systems; and (ii) Activities in Ag2S-FeS-CuzS-PbS quaternary at 1200°C.

Jan 1, 2003

By J. R. Thoenen

During 1928 questionnaires covering the calendar year 1927 were sent to over 1700 quarries: producing stone for purposes other thaw cutting to dimension. These inclined producers of stone for limn burning; cement manufacture, rip rag, and crushed stone. The various rinds of stone represented were limestone, trap rock, sandstone, granite, and marble. Replies received from limestone producers prior to November, 1928, were compiled into tables and published in February, 1925, as a preliminary report (Bureau of Mines Report of Investigation 2911).

Jan 1, 1930

By H. L. Riley, B. W. Gandrud

"INTRODUCTION The Bureau of Mines, United States Department of the Interior, with the cooperation of the University of Alabama and coal producers, has made a series of washability studies to obtain technically and commercially important data regarding the productive coal beds of the State. Based on the system followed in these studies, this report consists principally of screen-sizing and float-and-sink data on the Clark and Gholson beds at Boothton, Ala. A previous washability study 4/ has been made on the Clark bed at Marvel, Ala.SAMPLING AT MINESThe coal from the Gholson and the Clark beds was sampled at the tipple which receives the output,the Boothten No. 3 and No. 4 mines. These two mines are on the Gholson and Clark beds, respectively, but the coal. from both mines is mixed on the tipple and washed in the same washery. The samples taken were minus 4-inch raw coal. The plus 4-inch raw coal is hand¬picked and not washed. AS the 4-inch screen had a capacity in excess of the output of the mines, it was stopped at the end of each mine-car trip. By Observing from which mine incline each trip was hoisted, a separate sample from each bed was cut from the discharge stream of an endless belt which conveys the through 4-inch raw coal to the bin ahead of the washer. The output from each bed was sampled uniformly over the period of a working shift. The two washability samples weighed approximately 3,000 pounds each."

Dec 1, 1947

pAbad, Leopoldo F., Min, Engr,, Div. of Mines, Bureau of Science Manila, P. 1. '23 Abadilla, Quirico A,, Geol., Lago Pet. Corp Box 172, Maracaibo, Venezuela, '20 Abbey, Robert Graham, The W. W. Sly Mfg, Co Train Ave., Cleveland, Ohio. '21 Abbott, A. N., Mines Supt., Mazapil Copper Co., Ltd Concepcion del Oro, Mexico, '28 Abbott, Clarence E., Mgr., Mines & Quarries, Tenn, Coal, Iron & R. R, Co,, 1242 Brown Marx Bldg,, Birmingham, Ala. '04]

Jan 1, 1928

By Kenneth N. Han

The effect of anions such as sulfate, chloride, and nitrate on the solubility of rare earth element-bearing phosphates and fluorocarbonates has been examined using relevant thermodynamic data. The study has found that these anions have significant influences on the overall dissolution of rare earth elements (REEs) from various sources in the aqueous media. The thermodynamic calculations in this study have indicated that the speciation of REEs with the anions tends to increase the overall solubility of the REE-bearing minerals. However, in some cases, strong precipitation of REEs with some of these anions causes an adverse effect on the solubility of these elements. It has been found that sulfate ion has the most pronounced effect on the solubility compared to nitrate and chloride, in which the latter two acids exhibited almost identical results. The calculated results have indicated that REE-oxide (hydrated) is the easiest compound to dissolve, followed by carbonate, phosphate, fluoride, sulfate, fluoro-carbonate, and oxalate in that order.

By D. S. Colby

Statistics on the volume of natural gas produced in the United States were first collected for 1906. A summary of those statistics covering 1906-35 was incorporated in the 1937 Minerals Yearbook. This summary, covering 1936-50 presents, by States, a number of the more important statistics that have appeared in the natural-gas chapter of the Minerals Yearbooks. The period covered has been one of rapid expansion, especially of long-distance transmission lines. Natural gas was made available to some States for the first time; in other States the degree of dependence upon supplies transported from outside their boundaries changed rapidly. Thus, an isolated series of statistics cannot be studied without considering other regional influences that reflect in the overall operations of the industry. These tables accordingly have been designed to show for each State the simultaneous changes taking place in the various sectors surveyed. The tables show production data in the upper portion and consumption data in the lower portion. They are arranged alphabetically, by States. A copy of the 1906-35 production summary from the 1937 Minerals Yearbook has been included.

Jan 1, 1952

By S. A. Ghoreishi-Madiseh

Underground mines, with their relatively high ground temperature and their extensive backfilled stopes provide a great opportunity for producing geothermal heat. The novel idea of installing a network of heat exchange tubes into stopes prior to backfill placement converts each mine stope into a heat producing battery. In this system, backfill plays the role of the heat exchange medium conducting heat from the surrounding rockwalls to the heat exchange tubes. This geothermal heat can be used for heating: mine facilities and buildings, the intake air, a close-by mineral processing plant, or even nearby communities. This paper investigates the possibility of extracting renewable geothermal energy from backfilled mine stopes by means of closed-loop geothermal cycles. To simulate realistic operational conditions a heat transfer model is developed and solved numerically. To evaluate the numerical results, a small scale physical model is constructed and the experimental results are compared with the simulation results. The study estimates the sustainable rate at which heat can be extracted from a typical underground mine stope, the resulting outlet temperature and performance of the geothermal system. The results show that mine stopes are capable of sustainably producing geothermal heat not only when the mine is active, but also after the depletion of the ore body. Therefore, an underground mine will no longer be perceived as an enduring economic liability, but as a long-lasting source of clean, renewable, and inexpensive low-grade geothermal heat.

Aug 1, 2013

The viscosity of high magnesium content FeO-Fe3O4-SiO2-CaO-MgO slags at nickel flash smelting conditions was investigated using a commercial rotational viscometer. The studied parameters were compositions of slag and temperature. The viscosity of these slags was measured as a function of CaO, MgO, SiO2, FeO. Fe3O4 and Fe/SiO2 in temperature range from 1473K to 1723K. These slags contained 5.81 to 10.59 pct MgO, 0 to 10.37 pct CaO, 28.21 to 36.21 pct SiO2, 39.40 to 55.42 pct Fe and 1.1 to 1.5 Fe/SiO2.

Jan 1, 1999

ABSTRACT Understanding process histories and worker exposures in nickel production operations is critical in determining the role nickel compounds play in respiratory cancer incidence. As part of a series on Vale Canada’s (previously known as Inco) nickel processing operations, this paper includes descriptions of Ni electrolytic operations at refineries in Port Colborne, Ontario (1922–1984), and Thompson, Manitoba (1961–present). Industrial hygiene measurements, by area and personal sampling, of workplace aerosols at these operations are reported.

Jan 1, 2014

By Nadir Ansari, Brian W. Wilson, Marina S. W. Li

"A hybrid shoring system consisting of cast-in-place soldier piles with Cutter Soil Mixing (CSM) infill panels was constructed for temporary support of a 19.8 m (65 ft) deep excavation in Vancouver, British Columbia, Canada. Deep Mixing (DM) was completed up to 9.7 m (32 ft) in fill, peat, wood waste and clayey silt with embedment in dense till, and soldier piles constructed through the dense till extending to below final excavation level. Two trial CSM panels were installed ahead of production to assist with developing the termination criteria of the CSM panels in the dense till. The constructed depth of the CSM panels was based on interpretation of real-time monitoring data obtained through the Bauer B-tronic system. Inclinometer monitoring data from two CSM panels and two soldier piles, as well as soldier pile survey target data was used to assess and monitor the performance of the hybrid shoring system throughout bulk excavation. The objectives of this paper are to provide an overview of the design and construction aspects of the hybrid DM shoring system and to present inclinometer and pile target data to demonstrate the lateral performance of the CSM infill panels and soldier piles. This paper also discusses the merits of using real-time monitoring data as part of the engineering decision-making process for validating CSM panel construction. BACKGROUND A hybrid DM shoring design was recently completed for a high-rise development in downtown Vancouver, British Columbia for temporary support of a five level basement excavation. Deep mixing was proposed by the excavation and shoring design-build team as the preferred method to construct infill panels between soldier piles because of the speed at which the shoring system could be constructed in variable fill, peat, wood waste and overburden compared with traditional secant piling methods. The development site is generally a truncated triangle in plan, with the longest side of the triangle being approximately 115.7 m (380 ft) long and the two shorter sides being approximately 71.6 m (235 ft) (Hybrid Shoring Wall 1) to 75.0 m (246 ft) (Hybrid Shoring Wall 2) long. The site is bounded by an existing bridge off-ramp structure along its longest side, and by city streets on the other two sides, as shown in Figure 1. The truncated section is approximately 16.8 m (55 ft) (Hybrid Shoring Wall 3) long. Due to project constraints, the hybrid DM and soldier pile shoring system was only proposed for the two shorter sides of the triangle and the truncated section. Traditional secant piles were installed for the longest side. This paper focusses on the hybrid shoring system. A typical detail showing the CSM infill panel with the soldier piles is presented in Figure 2."

Jan 1, 2017

By Richard J. Bielicki

This Bureau of Mines study estimates the number of major pieces of coal- mining equipment that will be required to produce 950 million tons of marketable coal in 1980 and 1.2 billion tons in 1985. The coal tonnages were projected in the intermediate coal supply scenario of Project Independence Blueprint (PIB). The equipment projections were determined by consideration of historical trends and by evaluation of information from equipment manufacturers and mining companies. The ability of the manufacturers to meet the projected equipment demands was also determined. It was concluded that equipment supply offers no presently discernible constraint to mining 1.2 billion tons of coal in 1985. A shortfall in projected production for the intervening years, however, is probable owing to anticipated shortages of draglines.

Jan 1, 1976

By G. Wang, L. R. Moore, Y. Xiong, J. Gu

"Quartz is the second most abundant mineral in the earth’s crust. Not only does quartz have many valuable industrial applications, it is also one of the most concentrated gangue minerals encountered in the processing of other minerals. Minerals such as hematite, apatite, calcite, feldspar, barite, and many more. Numerous applications of industrial minerals are sensitive to the hardness and abrasiveness encountered with quartz minerals, while other applications may lead to processing challenges for the end user. Therefore, process and chemistry optimization must be applied to ensure optimal grade is obtained for these valued industrial minerals. Extensive studies have been conducted in processing various industrial minerals, thus achieving a range of quality specifications, which entailed the application of ArrMaz’s CustoFloat and CustAmine collectors towards the separation of quartz from other minerals. INTRODUCTION Industrial minerals often have the misfortune of the gangue mineral being very similar in surface charge, and coordination properties, to that of the mineral of interest. An example is seen in phosphate beneficiation, when dolomite can be a gangue minerals (Table 1). Therefore, the development of processing reagents are quite complicated. Some minerals, like clays, may be washed away. However, most require the manipulation of the pH, in efforts to fine tune the system to the narrow difference in isoelectric points of the different minerals, as well as the knowledge, and resources that are necessary to exploit the differences to yield and an optimal grade/recovery. In some cases, the application of a depressant may be required, such as the phosphoric acid commonly applied to achieve the optimal balance of grade/recovery for phosphate from a mineral with elevated concentrations of dolomite (Wang, 2016), or the application of hydrofluoric acid to assist in producing feldspar product from a mineral rich in quartz (Heyes, 2012).ArrMaz's CustoFloat and CustAmine product lines have successfully been applied to the processing of industrial minerals for more than 50 years. Applications include, but not limited to phosphate, sand (glass, foundry & high purity quartz), clays (feldspar, kaolin, etc.), and many carbonaceous and sulfate minerals. The successes of these 50 years are largely due to ArrMaz's ability to tailor make the processing chemistries to fit the ever changing and declining mineral feed grade and variations in water quality (Moore, 2015; Moore, 2016). This technical knowledge of mineral processing is strongly complimented by the intimate service programs in place at many of the beneficiation plants."

Jan 1, 2018

By Edmundo Alfaro, Álvaro Ordoñez

En el Perú existen diversos yacimientos mineros con contenidos de oro, plata y de metales base tales como el cobre, zinc, plomo, hierro, presentándose tanto como especies mineralógicas sulfuradas como de óxidos. En la zona sur del Perú se encuentran yacimientos de Zn–Pb–Cu–Ag–Au con depósitos híbridos de carbonatos y sulfuros masivos polimetálicos en rocas volcánicas. El tratamiento de este tipo de minerales presenta diversas dificultades para la recuperación de todos los metales de valor. En este sentido, se ha desarrollado investigación técnica preliminar utilizando el sistema peróxido de hidrógeno / amoniaco. (H2O2 / NH3); el peróxido actúa como agente oxidante y el amoniaco como agente acomplejante, dentro de una solución alcalina.

Sep 30, 2022

By Mingyang Li, Yan Lv, Xiaolong Ma, Xudong Gao, Jie Zhao, Yingyi Zhang

The reduction process of pre-oxidized ilmenite concentrate powder in 30%CO–70%N2 atmosphere was characterized by thermogravimetric and differential thermogravimetric (TG-DTG) analysis system at the temperature from 1073 to1223 K. The isothermal reduction results show that the reduction process is divided into three stages and the corresponding apparent activation energies are obtained by iso-conversional method and model-fitting method, respectively. For the first stage, the conversion degree increases sharply with increasing time, and the reduction process is controlled by the random nucleation and subsequent growth model (A2 model). For the second stage, the conversion degree increases slowly with increasing time, and the reduction process is controlled by the diffusion of carbon monoxide in the reduced layer (D1 model). For the third stage, the reduction processes at different temperatures are controlled by the diffusion of carbon monoxide in the reduced layer (1073 K and D1 model), phase boundary chemical reaction (1123 K and R2 model), random nucleation and subsequent growth (1173 to 1223 K, A2, and A3 models), respectively. For the whole reduction process, the apparent activation energies obtained by iso-conversional method and model-fitting method are 71.72 and 31.92 kJ mol−1 , respectively

By M. F. Werneke

Flotation of the carbonate, oxide and silicate minerals of copper (malachite, azurite, chrysocolla) has been the subject of much research in recent years, but few effective solutions to this problem have been found. With decreasing reserves of sulfide minerals, the economic recovery of these "oxides" appears to be an important source of copper for the future. Xanthates have been known for many years to be malachite collectors (1), but only at very high dosages, or at lower dosages following activation of the mineral by sulfide ion. Dewitt and Batchelder (2, 3) found that chelating agents such as certain oximes were collectors for malachite and azurite, but also required high reagent dosages. Fuerstenau (4) has suggested, for example, that potassium octylhydroxamate may be an effective collector for malachite, On the other hand, Balberyszski (5) has found that oxide minerals may be completely sulfidized at high temperatures with gaseous sulfur or H2S, and then floated with conventional collectors. None of the above approaches appear to offer an economically effective method for the direct flotation of these oxide minerals.

Jan 1, 1977

By Patricio Berrios, David Barriga, Peter Amelunxen, Gerson Sandoval, Roger Amelunxen

Laboratory test equipment and methods have undergone relatively little change since their introduction in the 1950’s. The Denver sub-A cell is still by far the most commonly used laboratory batch cell, but bottom-driven and instrumented cells are beginning to appear. Test procedures have also changed little over the past 60 years, and most engineers continue to rely on empirical models for predicted plant scale performance from laboratory scale tests. This approach is problematic, because changes in the froth phase characteristics in the lab hamper the reliability and reproducibility of the empirical extrapolation to plant scale. In a previous work, the authors reported on the impact of froth recovery at the laboratory cell, showing that variability in the froth recovery can lead to significant error in the modeled kinetic rate constant unless it is properly accounted for in the scale-up model. In this work, we review the role of hydraulic entrainment in the lab cell, and how variability in particle specific gravity, shape factor, and froth residence time can impact the entrainment recovery.

Jan 1, 2014