Search Documents

By Luis Toron, Salvador Cortes-Obregon

John D. Price (Colorado Fuel and Iron Corp., Pueblo, Colo)—The paper on the coal fields of the Oaxaca district as prepared by engineers Toron and Cortes-Obregon of the staff of the Bank of Mexico bears witness to the thorough and careful way in which the men associated with this organization perform their work. There is little to be added to their paper in way of discussion other than to confirm and amplify some of their statements. Since the only extensive and well-developed field of coking coal lies in the northeastern section of the country adjacent to Sabinas in the state of Coahuila, it follows that blast furnace plants would be located in that same region. Two such plants are now operating at Monterrey and Monclova, using coke produced at the Sabinas district mines. But the nearer of these two plants is 600 miles from Mexico City and even farther from the center of population. Transportation of products from these mills to the market area is therefore expensive, both because of the distance and the difficulty of the terrain over which it must be carried. The development of an integrated steel industry closer to the center of population has therefore long been a goal toward which the Mexican technicians have been striving. While the presence of coal of some grade has been reported in many of the states, and many ideas have been advanced regarding its possible uses in iron and steel production, deposits of anthracite in Sonora and the various coals of the Oaxaca district as reported on in this paper are the only ones that have been explored in a serious manner. The coking coal from the Mix-tepec zone appears to offer promise of producing a coke which could be used in a standard blast furnace. Several problems are indicated, however: 1—The ash in the coal is high as mined, but indications are that it can be washed to an ash content of 15 pct with a recovery of 70 pct of washed coal. 2—Such washing would increase the volatile content from 17.4 pct to about 20 pct, and in a byproduct oven this should give a coke yield of close to 80 pct with an ash content of coke under 20 pct. 3—A free swelling index of 5 appears low for a good coking coal, and below that of the coals from the Sabinas district, which show between 6 and 9. But washing of the coal should result in an improvement in this regard; in the United States coals from Utah with an index even lower than 5 have made a usable coke. 4—A coal with volatile as low as 17.4 in raw coal and 20 in washed coal would come close to being classed as a low-volatile rather than medium-volatile coal, and low-volatile coals are notorious for their high expansion properties. Several plants in the United States are making coke from straight medium-volatile coal of 26 to 28 volatile content, and one at Rosita,, Mexico, from coal of 25 volatile. But no plants to my knowledge are using coal as low as 20 volatile. Since the Rosita coal appears to be a borderline coal from the angle of its expansion properties the coking of one of the straight lower volatile must be approached with caution. 5—There are few coals possessing any degree of coking properties which cannot be used in coke production by careful attention to its preparation and blending. The fact that coals of other types are available in this same region make improvement through blending very possible. 6—There are other workable methods of reducing iron ore other than the conventional coke-blast-furnace method. These will not be discussed here but it is known that their use has been considered. The technicians of not only Mexico but also of the other Latin American countries are keenly aware of their natural resources and their national needs. This paper emphasizes the fact that the Mexican technicians are working on their problem and attempting to speed the day of self-sufficiency for their country. Salvatore Cortes-Obregon (author's reply)—I wish to thank Mr. Price for his kind remarks. The Mixtepec coal as shown in Table II has 30 pct ash and a free swelling index of 5, but when the same coal is washed to 15 pct ash it has a free swelling index of 8 to 9 and the volatiles increased from 17.4 to 20.7 pct. A satisfactory coke has been produced from blends made in the Mexican laboratory using at least 40 pct of the Mixtepec coking coals with the other Oaxaca non-coking coals. Koppers in Germany report good coke obtained from the Oaxaca coal with a blend of 80 pct Mixtepec coal. Consideration is being given the possibility of using methods other than the conventional blast furnace for the reduction of iron ore near the Oaxaca area; electric furnaces appear promising. The non-coking coals could be used to produce cheap electric energy and the coking coals to make metallurgical coke.

Jan 1, 1955

By Jiawang Hao, Qinglong Zhang, Liang Han, Chuhan Wang, Shenfang Chen, Lan Qiao

The surface collapse and surrounding rock failure caused by goaf instability are the mining disasters that cannot be ignored. It is of great value to evaluate the stability of goaf accurately and treat it economically for the mine safety and the maintenance of ecological environment. However, in previous studies based on numerical simulation methods, the spatial complexity and the irregularity of actual goaf were not considered. Therefore, based on the internal space data of goaf obtained by high-precision laser detector, the goaf stability was comprehensively analyzed through Plaxis software and two-stage fuzzy judgment theory in this study. To effectively improve the goaf stability, the optimal backfill parameters for the goaf treatment were obtained by a series of mechanical tests. The research results provide some good references for the stability evaluation and the treatment of underground goaf.

Sep 26, 2023

In this paper, uniaxial compression tests were conducted on intact rocks and broken rocks that were reinforced by grouting, and the effects of grouting on the strength of broken rocks were analyzed. The results show that after grouting reinforcement, the bearing capacity of broken rocks with different lithologies increased, and their uniaxial compressive strength recovered by approximately 6%–16%. The results indicated that the stronger the rock, the smaller the strength recovery of the consolidated body formed after grouting. At the same time, using borehole camera observation and deep overburden strata separations, the fracture development characteristics of surrounding rocks of the gob-side retained entry were analyzed and divided into different regions. On this basis, a guided grouting method was proposed; that is, shallow hole grouting was first used in the plastic zone of the broken surrounding rocks to form the isolation layer, and then deep grouting holes were arranged in the elastic-plastic zone of the transition zone to guide the slurry flow to the shallow unfilled zone. Therefore, the broken surrounding rocks were reinforced into an integrated body and selfbearing capacity improved.

Jul 28, 2020

By G. H. Hope

"Pamour Porcupine Mines of Timmins, Ontario operates two 3,000 ton per day concentrators which receive ore from eight to ten mines in the area. The area milling concept was adopted by Pamour in 1971 and has been used successfully since then. The purpose of this paper is to discuss the advantages and the problems of area milling. Pamour Porcupine Mines Limited operates two 3,000 ton per day concentrators which receive ore from eight to ten mines in the Porcupine region. The area milling concept was adopted as the route to survival for Pamour and has worked successfully. HISTORICAL BACKGROUNDProduction of gold from the Porcupine region in Northern Ontario started in the early 1900's and has been continuous since that time. Some of the major operators were companies such as Mcintyre, Hollinger, Dome, Pamour, Paymaster and the list goes on. An underground survey would reveal hundreds of miles of drifts and raises. The main group of mines extends from South East of Timmins to the Pamour Mine, 15 miles to the east. During the lean years of the sixties when gold prices were low, labour costs were rising rapidly, and ore grades were dropping, many of the area mines closed down their operations."

Jan 1, 1981

By K. Yathavan

Fracturing of rock at low stress levels can be a source of unexpected problems in rock engineering: • the resulting instability can be a safety hazard; • in very brittle rocks it may be associated with violent failure of the rock and strainbursting (rockbursting); • it usually leads to an unexpected requirement for rock support, with time and cost implications; • in rock boring projects, it may result in fracture of the rock ahead of the bored face and in the walls of the bore behind the face. This may lead to cutter head vibration, increased cutter wear and consequently decreased performance and increased costs. Examples of situations in which fracturing of rock at very low stress levels has been observed will be described. This will include details or estimates of the in situ stress magnitudes and the rock strengths involved. La brisure de roche sous faibles contraintes peut être l’origine de problèmes inattendus en génie minier : • L’instabilité résultante peut devenir un danger • Elle peut provoquer des éclatements violents des roches fragiles • Elle nécessite souvent une infrastructure de soutien de la roche, ayant des implications sur les coûts et les délais • Les forages de la roche peuvent provoquer une brisure de celle-ci au niveau de la surface forée mais ainsi à l’intérieur de la roche, causant parfois des vibrations et une fatigue de la tête de forage, induisant une baisse de performance et un accroissement des coûts. Nous avons décrit ci-après des exemples de situations de brisure de roche sous faibles contraintes. Cette description comprend des détails ou des estimations des forces et des contraintes impliquées. Cette étude représente la base du travail de recherche effectué sur le phénomène. ißbildung im Gestein unter niedrigen Stressbedingung kann eine mögliche Ursache sein für unerwartet auftretende Probleme in der Felsmechaniklehre: • Die resultierende Instabilität stellt ein mögliches Sicherheitsrisiko dar; • In sehr sprödem Gestein kann es verbunden sein mit einem plötzlichen und gewaltsamen Zerfall des Gesteins; • In den meisten Fällen ist eine nicht eingeplante Gesteinsabstützung erforderlich, und damit ein Zeit- und Kostenaufwand verbunden; • Bei Bohrungsprojekten kann es dazu führen, daß es während des Bohrvorganges zu einer Rißbildung im Gestein hinter und vor der gebohrten Felswand kommt. Dies kann Bohrkopfvibrationen, eine erhöhte Bohrkopfabnutzung und folglich eine Bohrleistungssenkung, sowie Kostenerhöhung zur Folge haben. Das Phenomen von Gesteinsrißbildung unter niedrigen Stressbedingung wird anhand von einigen dokumentierten Beispielen erörtert. Diese beinhalten zudem Details oder Schätzungen bezüglich der Stärke des in situ Stressfeldes, sowie der gegebenen Gesteinsstärken. Die mit diesem Beitrag dokumentierten Ergebnisse formen eine Grundlage zur weiteren Forschung dieses Phenomens.

Jan 1, 2003

The Influence of Particle Shape in Rock Fracture

Sep 13, 2010

By D. W. Dew

Billiton Process Research has carried out extensive research over the past four years to develop new process technology using bioleaching for extraction of copper and nickel from their sulphide concentrates. Continuous pilot scale and laboratory batch testwork has been carried out with adapted mesophile bacterial cultures at40°C?45°C, moderate thermophile cultures at 50°C?55°C and thermophile cultures at 65°C?85°C. Pilot scale work has demonstrated the commercial viability of mesophile cultures for bioleaching of secondary copper sulphide and nickel sulphide concentrates. Moderate thermophiles offer benefits in terms of reduced cooling requirements for commercial reactors and, in the case of bioleaching of nickel concentrates, some selectivity over bioleaching of pyrite. Continuous pilot scale testwork has shown that thermophiles achieve efficient bioleaching of primary copper sulphide and nickel sulphide concentrates, giving much higher recoveries than achieved by bioleaching with a mesophile or moderate thermophile culture.

Jan 1, 2000

This study was conducted to determine the effects of a machine-mounted scrubber and water sprays on face methane levels. Testing was conducted in the NIOSH ventilation test gallery which was designed to simulate a full-scale mine entry. In the test entry, a model mining machine, equipped with water sprays and a simulated dust scrubber, was located at the face of a 20-ft box cut. Blowing ventilation was provided using a curtain with a 40-ft setback distance. Methane released from a pipe manifold located inby the mining machine was monitored at six locations that were 1 ft outby the pipe manifold. Tests were first conducted to evaluate the effects of using sprays and scrubber separately on face methane levels. Additional tests were conducted to determine how a scrubber used with various water spray systems would affect face methane levels. The use of either sprays or scrubber reduced face methane levels significantly. The combined use of sprays with the scrubber further reduced face methane levels a small amount. Primarily the sprays affected methane levels by changing airflow distribution close to the face.

By Mark A. Willian

The purpose of this short paper is to present soil profiles and basic soils information for the portion of the I-880 Replacement Project alignment where highway structures are to be built. The information presented here is derived primarily from foundation investigations conducted by the Caltrans Foundation Unit (currently the Structures Foundation Branch, Office of Structural Foundations) and by others under Caltrans direction. The foundation investigation for the I-880 Replacement Project began in May of 1991. The field work was completed in May of 1992 and consisted of 93 rotary sample borings, 11 consolidation sample borings, 6 TEXAM® pressure meter borings, six in-place vane shear borings and 57 electronic cone penetrometer soundings.

Jan 1, 1996

By M. J. Miller, N. Ripepi, M. Karmis, J. M. Conrad

Unmineable coal seams present an opportunity to sequester carbon dioxide emissions from power plants, while enhancing the recovery of coalbed methane. Injected carbon dioxide is adsorbed and stored on the coal surface while releasing methane that can be commercially recovered. Carbon sequestration, therefore, allows the utilization of unexploited mineral resources while reducing “greenhouse” gas emissions. This paper presents the feasibility, efficiency and enhanced recovery potential of coalbed methane production using carbon dioxide sequestration in the Central Appalachian Basin. The focus of research is on geological characterization of unmineable coal seams in Central Appalachia and the corresponding carbon dioxide storage capacity. Virginia Tech and Marshall Miller & Associates, Inc. conducted this research under the Department of Energy’s Southeast Regional Carbon Sequestration Partnership program.

Jan 1, 2006

By Johnna Muinonen

"The Thompson Mill processes ores from the Thompson and Birchtree Mines. While the Thompson ore has very little magnesium containing gangue, the Birchtree orebody consists of veins of massive sulphide in a rock matrix that contains a high proportion of magnesium silicate minerals. A significant fraction of the magnesium is floatable, which lead to MgO levels varying from 3-11 wt% in the Birchtree concentrate. The magnesium in the concentrate causes a higher operating temperature in the smelter, reducing furnace life.Birchtree ore represented 20-30% of the mill ore receipts prior to October 2003. Since then the fraction of Birchtree ore has increased to 50%. A reduction of the MgO in concentrate to less than 3% in the total mill concentrate was required to allow safe and economic smelter operation.In October of 2002 a miniplant was set up to simulate the Birchtree plant circuit. Several flow sheet modifications were tested that led to a proposal for a circuit having increased cleaning capacity for the scavenger concentrate and a recleaner on this concentrate. Addition of CMC in rougher cleaner feed was also found to be required. The solution was confirmed through pilot plant testing in the mill in December of 2002. A full-scale installation was designed, engineered, and installed between February and September of 2003 with commissioning in September and October of 2003. Target metallurgy was achieved one week after start-up on slurry to coincide with the Birchtree Mine tonnage increase. This paper highlights the development, design and commissioning stages of the project.The new MgO rejection circuit has successfully allowed the processing of Birchtree ores producing concentrate consistently below 3% MgO. In addition, the new circuit increased overall nickel recovery in the mill.INTRODUCTIONThe Thompson Nickel Belt located approximately 700km north of Winnipeg was discovered in the early 1950’s. Inco first produced nickel from the area in 1960. Over the years the mill has processed several ores from different ore bodies in the area. Currently the Thompson Mill processes two significantly different ores from two mines, Thompson and Birchtree. The Thompson ore is a massive sulphide orebody hosted in schist, containing feldspars, quartz and biotite. Thompson Ore is characterized by high nickel recoveries and clean, low MgO containing concentrates (<2.5% MgO). The Birchtree ore is ultramafic and contains a high percentage of Mg-silicates such as serpentine, chlorite, biotite, amphiboles and talc. Some of these Mg-silicates report to the nickel concentrate and prior to commissioning of the MgO rejection circuit the Birchtree nickel concentrate typically contained 5-8% MgO"

Jan 1, 2006

By Steven R. Musselman

The bending strength and flexural stiffness of a micropile at its threaded connection is less than its intact strength and may fail due to thread slippage or by fracture through the pin (reduced cross-sectional area of male threads in the threaded zone of the casing). The mode of failure depends on the reduction in cross-section necessary for machining the threads, and details of the threaded connection such as the length of threaded connection, size and shape of threads, and the thread density (threads per inch). Based on data from bending tests conducted on 9-5/8 inch diameter micropile casing, a method has been developed to predict the ultimate moment capacity and initial bending stiffness of round threaded micropile connections. Two modes of failure were observed from four-point bending tests conducted at the University of Illinois on 9-5/8 inch casing with round threads. Threaded micropile casing connections with an effective thread length of 1.35 inches typically failed by slippage at the threads (jump out), while connections using an effective thread length of 1.89 inches failed by fracture of the pin. These two failure modes were described by W.O. Clinedinst in his report to the American Petroleum Institute on tension tests of threaded pipe casing. Clinedinst developed an empirical formula to determine the tensile strength of threaded connections. A method to predict moment capacity for threaded micropile connections by modeling the micropile cross-section and applying Clinedinst?s equation to determine the max tensile stress along the threaded connection while satisfying force equilibrium is proposed. The predicted moment capacity for threaded connections using this approach is within ten percent of measured for both modes of failure observed from the bending tests.

Jan 1, 2007

By Afonso Rangel Garcez de Azevedo

O polo produtor de cerâmica vermelha localizado no Norte Fluminense, mais precisamente no município de Campos dos Goytacazes é considerado um dos maiores do pais. O objetivo deste trabalho é analisar a influência da temperatura de queima em nas propriedades de retração linear, absorção de água e resistência mecânica em artefatos cerâmicos. Para isto foram confeccionados corpos de provas prismáticos pelo processo de extrusão, utilizado para produção dos blocos cerâmicos da região, e submetidos a temperaturas de queima de 700, 800 e 900 oC. Os resultados mostraram que com o aumento da temperatura de queima a resistência mecânica e absorção de água melhoram substancialmente melhorando a qualidade do produto final, enquanto a retração também aumenta mas está propriedade não é benéfica ao produto. Em baixas temperaturas (700 oC) o produto não apresentou características aceitáveis segundo a norma técnica brasileira.

Oct 30, 2017

By Ove Alm

Wet and dry specimens of three rocks of approximately granitic composition were deformed at different experimental conditions. These experiments were carried out in order to study the extent to which water, either added or released from mineral reactions, may affect the mechanical properties and the microstructure of these rocks. The experiments were conducted in a Griggs&apos; hot creep apparatus at temperatures and pressures up to 900ºC and 1000 MPa respectively; and most of them were performed in the constant strain rate mode [(1.10-6 < t < 1 • 10-4 s-1 )]. All three rocks were low porosity rocks, and the wet specimens never contained more than 0.9 wt % of added water. The experimental results are, however, quite unequivocal: They show that wet rocks are weaker than dry ones. A significant difference is even found for rocks tested in uniaxial compression at room temperature. A few experiments carried out on specimens obtained from larger prestressed rock cores indicated that the central parts of these cores were more likely to contain more microcracks than the ends. Optical microscope examinations revealed that extensive microcracking takes place even at the highest temperatures, where other mechanisms such as slip and dislocation creep also become important. Very little partial melting could be observed except for the specimens deformed at 900ºC.

Jan 1, 1982

By José L. M. Clemente, John R. Davie

"Abstract An extensive pre-production static and dynamic pile load testing program was conducted for a coal-fired power plant. The static load testing program included axial compression, uplift (tension), and lateral load tests. Three types of piles were tested: Monotube, closed-end pipe, and step-tapered. The load tests were used to (a) determine pile driveability characteristics for each pile, (b) verify pile load response behavior, and (c) provide data to support the selection of a cost-effective piled-foundation system for the plant. A recent publication (Clemente and Lewis, 2013) describes the compression load testing program, the interpretation of instrumentation measurement results, and pile selection criteria. This manuscript describes site subsurface and groundwater conditions and installation of probe piles for testing, focuses on the uplift and lateral load testing program, and provides a comparative interpretation of the load test results.INTRODUCTIONThe pre-production probe pile load testing program described here was conducted for a 202-megawatt, coal-fired power and steam generating (cogeneration) facility. A schematic layout of the main plant (power block area) is shown in Figure 1, which also includes the locations of clusters of preproduction probe piles and boreholes drilled near these clusters.The load testing program included 24 pre-production probe piles driven throughout the power block area. The probe piles were driven at locations T-1 through T-8, shown in Figure 1. Three types of piles were driven at each location: Monotube pile; closed end, straight shaft pipe pile; and step-tapered pile. At each location, the three piles were driven in a row with the pipe pile at the center, and the center-tocenter spacing between piles was equal to about 1.5 m (> 3.5 pile diameters for the largest pile). No pile cap was used to connect the three piles, and the three piles driven at locations T-1 through T-8 will be referred to as pile clusters. A complete suite of static load testing (compression, tension, and lateral) was performed on each individual pile at Cluster T-2 and on the step-tapered piles only at Cluster T-8, shown in Figure 1.Clemente and Lewis (2013) provide details of the compression load testing program, the interpretation of instrumentation measurement results, and pile selection criteria. This manuscript focuses on the uplift (tension) and lateral load testing program. A brief summary of the site geology and existing subsurface and groundwater conditions in the vicinity of the test pile clusters is presented, with emphasis on T-2 and T-8. Probe pile driving results at T-2 and T-8 are also presented. Descriptions of the static uplift and lateral load test program at T-2 and T-8 are given along with a comparative evaluation of the load test results."

Jan 1, 2014

By LJ Aspinall, Paulo Sérgio Soares Santiago

Monitorar adequadamente a qualidade da água em sistemas de resfriamento é fundamental para assegurar um bom condicionamento de seus indicadores chave de desempenho: a corrosão, a incrustação, a formação de depósitos e a atividade microbiológica, de forma que as unidades operacionais possam atingir suas metas com relação aos seus respectivos índices chaves de performance do processo industrial. Enquanto a confiabilidade deste monitoramento em antever problemas assume, então, elevada importância, os métodos utilizados até o presente na indústria não têm efetivamente fornecido resultados realísticos pela ausência de troca térmica nos dispositivos usados. A Knew Value desenvolveu e patenteou uma nova tecnologia, o Sentinel, que permite aplicar métodos inovadores de monitoramento on-line, permitindo realizar simulações em condições críticas de velocidade de escoamento e temperatura de película e atingindo excelência em monitoramento de indicadores chaves de desempenho do tratamento químico aplicado em sistemas de resfriamento. O objetivo deste trabalho é apresentar esta tecnologia e casos históricos de desempenho.

Aug 1, 2019

By P. K. Sahoo, C. R. Ray, S. S. Rao

This paper deals with various factors affecting the strength of chromite briquettes which plays a vital role in the smelting of charge chrome / ferro chrome production. Appropriate briquetting parameters like molasses and lime binder level, molasses quality, particle size distribution and segment condition etc. are essential to guarantee quality briquettes in the successful use of briquette and chromite ore fines. In developing a technology for briquetting of chromite ores, it is important not only to study the grain size characteristics of the chrome ore fines but also to make an informed choice of the type and quality of the binder and the condition for producing a physically and chemically competent green and cured briquette. This paper also describes the effect of strength of briquettes on various parameters of charge chrome production as the use of quality briquettes in the production of high carbon ferrochrome alloys has a number of operational, metallurgical and economic advantages. It is also a requirement for submerged arc furnace operation that the charge be adequately porous to allow gaseous products of the reduction reaction to escape from the furnace charge burden without hindrance. Otherwise, furnace material would erupt causing electrodes and furnace other equipments damage and risking the safety of the work force. The briquette, because it replaces lumpy charge but has an advantage of smaller size, allows for an uniform and porous charge so that the ascending gaseous products can escape freely. Finally this paper deals with furnace operational results with varying proportion of briquettes having same strength.

Jan 1, 2007

By H. E. Urtubia

"BHP-Billiton’s Minera Escondida Limitada, in Chile, is one of the world’s largest copper producers. It treats a combined 10,500 tph of copper ore through its two concentrators: Los Colorados and Laguna Seca. The performance of the rougher circuit at each concentrator was measured and analysed using the JKTech flotation optimisation methodology. This involved developing a flotation model for each concentrator based on cell operating parameters (for example bubble surface area flux and froth recovery) and feed ore floatability characteristics. The rougher circuit performance was evaluated in terms of traditional measures, such as grade and recovery. The operation was also analysed using the measured cell operating parameters and ore floatability and the effect of these with regard to performance (grade / recovery) was assessed.This paper presents a comparison of the rougher circuit at each concentrator in terms of these parameters. The main differences in rougher circuit performance between the two plants were attributed to differences in feed ore floatability characteristics and froth recovery. The comparison highlighted opportunities where performance improvements could be made. The study also showed the usefulness of separating the flotation process into easily measurable subprocesses to further identify the different mechanisms occurring in each rougher circuit. Traditional measures like grade and recovery are useful for monitoring flotation operation but this data lacks the depth to determine the root cause behind operational issues. Determining the operating parameters and ore floatability provides the operating plant metallurgist better tools to assess and manage these issues."

Jan 1, 2006

By I. G. Gonçalves

For most industrial minerals, the color is directly associated with economic value. In terms of physics, the principal property that defines the term ?color? is the intensity of light reflected (or transmitted) by an object over the visible band, comprehended between 400 and 700 nm. This reflectance spectrum serves as the starting point for a variety of color-describing factors, the most common in the mineral industry being the brightness (TAPPI, 1977 and 1986) and the L*a*b* system (HunterLab, 2008). Quality specifications for mineral products are usually based on these colorimetric parameters. This market is becoming increasingly more selective and demanding over the quality of raw materials and alongside the traditionally controlled characteristics, such as particle size distribution and chemical composition, a trend exists towards the establishment of increasingly more strict specifications for the optical properties of these materials. This is due to the fact that most plants consuming these industrial minerals incorporate them into products in which the visual appearance is controlled. For these plants, most of them being the manufacturers of plastics, paper, paints, and ceramics, variations in the color of mineral materials result in difficulties to achieve the right color in the final product. Therefore, these plants set strict specifications for colorimetric parameters such as whiteness and yellowness, as well as colorimetric coordinates like L*, a*, and b*. For the manufacturer of industrial minerals, this translates into difficulties simply because many of these parameters are usually alien to the tradition of the mining industry. The main quality parameter in the kaolin industry is brightness, which is a weighted average of reflectance values over the range of 400-510 nm (TAPPI, 1977). Due to the lack of a better property, producers tend to use brightness to also assess the quality of the in situ ore and along the processing operations. However, the unprocessed kaolin is often accompanied by ?contaminant? minerals. For Brazilian kaolins, which are the object of this study, the most important contaminants are hematite (Fe2O3), goethite (FeOOH), and anatase (TiO2). Each of these contaminant minerals has a distinct color and behaves differently during the processing of the kaolin ore. Hematite and goethite in particular are particularly strong pigmenting agents and at concentrations as low as 100 ppm they can make the difference between a high-quality white pigment product for paper coating and waste material. As each Fe-bearing contaminant has a different color and responds differently to processing operations (for example, magnetic separation, chemical bleaching, selective flocculation, and/or flotation in the case of kaolin), the in situ brightness tends to show a poor correlation with the brightness of the final product. Brightness measurements are sometimes complemented with X-Ray Fluorescence (XRF) analysis of Fe and Ti, but the total oxide content provided by XRF is also poorly correlated with product quality because Fe may be in the form of goethite, hematite, or inside the crystalline structure of kaolinite. Thus, a more robust technique capable of distinguishing each mineral phase is desirable. Diffuse reflectance spectroscopy has been used to analyze iron oxide/hydroxide content both qualitatively (Torrent and Barrón, 2003; Liu et al., 2011) and quantitatively (Jiet al., 2002 and 2006). These authors correlate slopes and inflection points at characteristic absorption bands with oxide/hydroxide content in natural soils. The approach presented here involves the extensive use of the Kubelka-Munk (K-M) theory, which has been used for color matching (Schabbachet al., 2009 and 2011) and particle size determination (Otsuka, 2004) in a simplified version. Unfortunately, the scattering constant S is very difficult to measure for dry powders, because the equations require a thin layer of material. Attempts have been made (Gonçalves and Petter, 2007, and Gonçalves, 2009) but the experimental errors tend to be high. Thus, this paper aims to develop a tool for the quantification of contaminant minerals in kaolin based on the K-M theory without resorting to measurements over thin layers. This tool is based on a new two-constant approach, which takes into account differences in scattering between materials over the whole measured spectrum. The experimental dataset consists of the reflectance spectra of mixtures between a bleached kaolin and synthetic Fe pigments.

Feb 27, 2013

By F. J. Cservenyak

The Bureau of Mines Solid Waste Program is directed toward three main areas of research: (1) Extraction of mineral, metal, and energy values from urban refuse; (2) recovery of mineral and metal values from wastes generated in the industrial extraction, processing, and utilization of raw materials and mineral-base products; and (3) upgrading and utilization of automotive scrap. The Bureau also has a contract and grant program which supplements the in-house research and aids in the training of personnel in the proper management of mineral- and metal-based solid wastes.

Jan 1, 1970