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By Ragnhild E. Aune, Mark William Kennedy, Shahid Akhtar, Jon Arne Bakken

"To determine the heating rate of billets using ‘short coils’, an appropriate correction factor must be applied to the theoretical relationship. In 1945, Vaughan and Williamson published a semi-empirically modified Nagaoka coefficient applicable for moderate frequency induction heating processes (10 kHz). Recently it was demonstrated that the method of Vaughan and Williamson gives <10% error in the estimated power when heating aluminum billets at 50 Hz.In the present study, experiments have been conducted on aluminum billets in order to verify an empirical frequency corrected ‘short coil’ equation. Measurements of electrical conductivity (<± 0.5%), current (± 1%), heat (± 1-3%), and magnetic flux density (± 1-2%) have been performed. The results are compared with 1D analytical calculations, and 2D axial symmetric FEM modeling using COMSOL 4.2®. The frequency corrected equation has proven to provide accurate predictions of power (<4% error) within the frequency range 50 Hz to 500 kHz.IntroductionInduction heating is commonly applied to the re-heating of billets before forging or extrusion processes. The resistive heating produced by eddy currents in the solid or semi-solid work piece during this procedure, is driven by the time varying magnetic flux density in the air-gap between the work piece and the coil. The flux in the air-gap is created by the current flowing in the induction coil, i.e. the magneto-motive force. In Figure 1 it can be seen that the currents present in the work piece are concentrated in the outer ‘shell’, or the first electromagnetic penetration depth (dw), and flow in a direction which opposes the magnetic field produced by the induction coil."

Jan 1, 2012

By Lucas de A. Pontes, Lázaro A. Rohen, F. V. Carlos Maurício, Janaina da Silva Vieira, Sergio Monteiro, Dhyemila de P. Mantovani, Frederico M. Margem, Anna C. C. Neves

The lower density of the lignocellulosic fibers such as the hemp fibers and the other natural ones is one of the characteristics that allow the scientists to obtain high levels of specific properties that when compared to the properties of ordinary reinforcements gives to the hemp fibers an advantage as a material with an expressive potential in the mechanical properties area. Then, the aim of this present work is to characterize the relative density of the hemp fiber related to the water using the pycnometry technique. This technique uses the pycnometer and it is divided in two steps. In the first step the correction factor and the moisture content of the fresh hemp fiber specimen and in the other step some weightings were done such as the dry specimen (g), empty pycnometer (g), pycnometer + water (g) and pycnometer + water + specimen (g) using a digital balance with a precision scale of 0.001 g of the bran INNERSCAN. Based on these measurement and calculations using some formulations already established in previous studies, the relative density of the hemp fiber found was around 1.393 g/cm3 and the moisture content around 7.1%.

Mar 1, 2017

By Suzzann Nordwick

The metallurgical treatment of mercury-containing materials for precious or base metals recovery imposes many processing and environmental challenges. Mercury is usually present as elemental or cinnabar. Historically, mercury has been removed from mined ores pyrometallurgically by roasting, but hydrometallurgical methods have also been employed. For example, alkaline sodium sulfide solution acts as an universal solvent for most mercury compounds. While, most other metals are highly insoluble in this solution. This allows for a high degree of selective separation of mercury from other metals with the exception of tin, antimony and arsenic. Mercury leached with a solution of sodium hydroxide and sodium sulfide or sulfur can be re-covered by cementation or stabilized through sulfide precipitation. Hydrometallurgical technology for the pretreatment of mercury removal from gold, silver, and base metal ores using alkaline sulfide leaching will be discussed with a focus on alkaline sulfide leaching of mercury sulfide-containing materials.

Jan 1, 2003

By Shadia J. Ikhmayies

Zinc oxide (ZnO) flowered-fibrous micro/nanowebs were produced as thin films on glass substrates at 350 °C using the low cost spray pyrolysis (SP) method. The films were characterized using the XRD diffraction, scanning electron microscopy (SEM), and X-ray energy dispersive spectroscopy (EDS). Hexagonal structure was confirmed from X-ray diffractogram, which showed preferential orientation along the (002) line. SEM images showed two dimensional flowered-fibrous micro/nanowebs, and EDS elemental analysis revealed the presence of chlorine in the films in addition to zinc and oxygen. The obtained morphology is important for optoelectronic device industry and solar cells, where it provides large surface area that helps light harvesting.

Mar 1, 2018

By E. Fregeau-Wu

The mineralogy and grain size distribution of phases in a steelmaking slag and experimental products from the heating of the slag under various conditions were determined to explore the possibility of recycling of the iron and manganese to the blast furnace. The steelmaking slags consisted of three major phases: dicalcium silicate, dicalcium ferrite, and Mg-Mn-wustite. Most of the phosphorus was contained in the dicalcium silicate and to lesser extent in the dicalcium ferrite. Due to the fine grain size of the dicalcium silicate, grinding and magnetic separation required pretreatment to increase the grain size and hence the liberation. Experiments on a steelmaking slag were conducted by heating the slag to 1633-1748°K( and slow-cooling in an inert atmosphere at various rates with or without the addition of fluorspar (CaF2) as a flux. Grain size distribution analyses of the starting material and the slow-cooled products were performed using the SEM-IPP area scan method and the QEM*SEM linear scan method. Comparable and reproducible results were obtained on the same sample using both methods. A size versus volume percent plot showed the increased grain growth most effectively. Examples of the grain size distributions obtained were used to show that a higher soaking temperature prior to slow-cooling, a slower cooling rate, and the addition of fluorspar to the slag promoted grain growth.

Jan 1, 1989

By cheng Peng-fei, TANG Hai-yan, guo Xiao-chen, LI Jing-she, Liang Yong-cang, Zhao Baojun

In the process of oxygen blast furnace, the lower coke ratio and the higher coke load make the skeleton coke more important. To understand the dissolution of coke in melting and dropping zone, the influence of FeO content, temperature and reaction time on the dissolution of coke with slag were studied by single-factor experiment. Meanwhile, the three factors and three levels orthogonal were conducted. The dissolution degrees were characterized by the weight loss ratio and diameter variation. The results showed that the weight loss ratio increased and the diameter decreased with the increase of FeO content, temperature and time. The three factors and three levels orthogonal test showed that time was the most significant factor on coke dissolution, FeO content of the second, and finally the temperature. The microstructure of coke after reaction indicated that the dissolution occurred on coke surface.

Jan 1, 2016

By Qingguo Xue, Jingsong Wang, Yingli Liu, Guang Wang

In the dropping zone of blast furnace (BF), primary slag absorbing ash of pulverized coal and coke become to be intermediate slag. Due to viscosity and surface tension of slag and the pore between cokes, some slag remained in coke layer and affected the permeability of blast furnace. The flow behavior of slag with different basicity (0.55–1.10) and Al/Si (0.35–0.50) were studied. Meanwhile, the viscosity and surface tension of slag were calculated. The results showed that, with the increasing basicity of slag, surface tension increased and viscosity decreased. With the Al/Si increase, surface tension and viscosity increased. The smallest pore that all slag can pass through was 4.5 mm. However, the height between slag droplets and the bottom of crucible indicated that the ability of slag to pass through pore were weakened with the increasing basicity and Al/Si. Thus, slag which absorbed ash from fuel become difficult to pass through coke layer.

Mar 1, 2017

By Wei Lv, Xuewei Lv, Senwei Xuan, Chenguang Bai, Kai Tang

The contact angle between six iron ores and water were determined by the capillary pressure method with cyclohexane as the perfect wetting liquid. The factors influencing the contact angle were discussed, and a relationship between the content of oxy–hydroxides and the contact angle of iron ores was obtained. The results show that the ore F has the lowest contact angle but the ore D get the biggest, which are 32.09° and 78.16°, respectively. The volume fraction of oxy–hydroxides is linearly dependent on the contact angle. The contact angle decreased with increasing the volume fraction of Fe2O3*H2O.

Mar 1, 2017

By Shadia Ikhmayies

ZnO microprisms in thin film form were produced by the low cost spray pyrolysis technique at a substrate temperature of 350 ± 5 °C on glass substrates. Scanning electron microscopy (SEM) and energy dispersion X-ray spectroscopy (EDS) were used to explore morphology and composition of the films respectively. The films were found to be oxygen rich and contain chlorine. ImageJ software was used to analyze the size of the prisms, where the diameter and length of the microprisms were estimated.

Mar 1, 2017

By J. M. Demarthe

MINEMET RECHERCHE (IMETAL Group, formerly Le Nickel-Penarroya-Mokta) has studied on a laboratory scale and patented a new process to recover metal values -copper- from sulphide ores and concentrates. It combines a cupric leaching, solvent extraction and copper sulphate electrowinning according to the main following steps - A direct and selective leaching of copper sulphide ores or concentrates at atmospheric pressure with cupric chloride to form cuprous and ferrous chlorides and elemental sulphur. Pyrite remains in the sulphur residue. - The leach solution is separated into two parts -In the first one, air is injected to precipitate iron as goethite. The oxidation step can be easily realized at atmospheric pressure by maintaining an excess of cuprous and-ferrous chlorides in the liquor. Copper is extracted from the second part as cupric ion by an LIX reagent. Direct injection or air in the mixing chamber maintains good extraction conditions, so that only one mixer settler is required. - Iron, in the form of ferrous ion, is not coextracted. - Copper is stripped from the organic phase, transferred into a sulfuric phase and sent to sulphate electrowinning cells, which are now conventional in copper metallurgy. - Only electricity and air are required. After a feasibility study, the next step will be to develop it on a pilot and commercial scale.

Jan 1, 1976

By E. Oshima

The only one reverberatory furnace smelting in Japan has been alive in Onahama Smelter, Onahama Smelting and Refining Company. The fuel for the reverberatory furnaces had been changed from bunker C-oil to mainly coal and partially waste tires to reduce the energy cost. The steam, recovered by the waste heat boilers of the reverberatory furnaces, has been utilized fully for the power generation to save the purchase power. Copper concentrate has been smelted also by injection through tuyeres in the P.S. converters since 1983. The amount of concentrate, treated in the converters, was increased by the construction of small oxygen plant in December, 1990. In the paper, the current practice and improvements in the reverberatory and converter operations are described.

Jan 1, 1993

By V. Ramachandran

The Amarillo Copper Refinery, the newest and most modern copper refinery in the world, has been in operation for the last eleven years and has a rated capacity of 460,000 st/yr. The tankhouse - a structure that covers 500,000 ft2 under one roof - extends one-half mile in length and is a model of materials-handling efficiency. The use of recently developed and patented* reagent control technology, termed "Reatrol Process", has increased current efficiencies to an average of 98% and has considerably improved the physical and chemical quality of the cathode deposit. The present paper describes the current operations at the Amarillo Copper Plant with special emphasis on tankhouse operation.

Jan 1, 1987

By F. E. Wagner, L. J. Cabri, Y. G. Safonov, N. S. Bortnikov, A. D. Genkin, J. Friedl, G. N. Gamyanin

"A multidisciplinary investigation (including INAA, SIMS, EPMA, and Mossbauer Spectroscopy) was used to characterize gold in four of the largest Siberian mesothermal sulfide gold deposits. These are the Olympiada (""'750 metric tons gold) and Veduga (estimated at 75-100 metric tons gold) deposits in the Enisei Mountain Range and the Nezhdaninskoye (z500 metric tons gold) and Sentachan deposits in the Verchoyansk-Kolyma area. It was found that some of the mineralization is refractory in all four deposits, largely due to the occurrence of ""invisible"" gold in arsenopyrite as well as within pyrite, but with a lesser concentration. The gold concentration and its distribution varies considerably both within and between arsenopyrite grains, with implications for processing options such as heap leaching. The ore most likely to be amenable to heap leaching is the oxidized ore of the #4 orebody of the Olympiada deposit, but further quantitative mineralogical investigations are recommended for this orebody's sulfide ore and for the ores of the Nezhdaninskoye deposit. Following a full mineralogical characterization, it is possible that economic viability will depend on a combination of pre-concentration with or without pre-treatment, followed by heap leaching of some tailings products.Acknowledgements· The Russian authors performed this study under an ""Eco res"" Project which was financially supported by the Ministry of Science and New Technology of the Russian Federation. C.J. Stanley wishes to thank John Spratt and Terry Williams for help with EPMA. F.E. Wagner acknowledges the Deutsche Forschungsgemeinschaft for a grant supporting the Mossbauer studies. L.J. Cabri is grateful to the following: M. Beaulne, D. Carson and J.H.G. Laflamme for technical support, K.E. Haque for technical comments, and D.M. Hausen and W. Petruk for editorial suggestions."

Jan 1, 1997

By Jiann-Yang Hwang

A study on microwave assisted chalcocite leaching was carried out with a microwave hydrothermal reactor. The leaching was conducted with thick mineral slurries (50-100 g/l). The leaching media is a mixed solution of CuCL2 and NaCL The investigation included the effect of leaching temperature, quantities of the minerals per unit slurry volume as well as the initial concentration of cupric ions were investigated. The results were discussed and compared with that using conventional leaching method.

Jan 1, 2003

By K. B. Shedd

Questions regarding possible adverse health effects from exposure to zeolites arose when the inhabitants of two villages in Turkey were found to have high incidences of mesothelioma, a disease generally identified with exposure to asbestos. No asbestos deposits are known in the area, but some fibrous zeolites have been found. Further investigations have resulted in conflicting opinions as to whether fibrous zeolites are related to the high incidence of mesothelioma in Turkey. The U.S. Department of the Interior, Bureau of Mines examined the habits of domestic zeolites by scanning and transmission electron microscopy. Only erionite and mordenite particles possessed acicular to fibrous habits. With the exception of a rarely occurring woolly erionite sample, the fibrous zeolites were not dimensionally equivalent to asbestos.

Jan 1, 1982

By Valery Kaplan

Sulfur emission in the form of SO2 in flue gases is one of the most serious atmospheric pollutants associated with coal combustion and non-ferrous metals production. The carbonate eutectic method for removing SO2 from flue gases at 723–923 K was initially proposed in the 1970s but despite its great efficiency (SO2 concentration in the flue gas after purification reached 0.003 volume %), it could not be implemented by industry due to the complexity of the carbonate melt regeneration stage. Earlier we proposed a method suited to coal-firing power stations where the melt was regenerated using CO as a reducing agent. However, most metallurgical plants do not use coal and therefore lack a large source of CO. Here we propose a method for removing sulfur from the carbonate eutectic melt by purging it with natural gas or a natural gas/air mixture, which are available in the vast majority of metallurgical plants. This reaction leads to the reduction of sulfate to H2S gas that leaves the melt. The experiments we conducted show that nearly complete sulfur removal from the melt is possible at 823 K and that the reaction rate is sufficiently high for a large scale process. One can foresee that this carbonate melt-based SO2 removal technique may become a practical and economically attractive method for limiting sulfur emission to the atmosphere from non-ferrous metallurgical processing plants.

By Seref Sonmez, Onuralp Yücel, Kagan Benzeşik

The aim of this study is processing of domestic molybdenum concentrate to produce technical grade molybdenum trioxide may be the starting material for the production of various molybdenum products. In order to determine the optimum parameters for the total oxidizing roasting process of molybdenite concentrate to produce MoO3 and purify the MoO3 product by removing the copper content; first, MoS2 was roasted by controlling reaction temperature and duration in a chamber type furnace. The highest Mo concentration rate was obtained as 56.6 wt% of Mo at 650 °C for the roasting duration of 45 min. Secondly, roasted product was leached with H2SO4 to remove copper. Leaching conditions were optimized by investigating the effects of different H2SO4 concentrations and S/L ratios. The minimum copper content was obtained as 0.13 wt% at leach residue. The raw materials and the products were characterized by using AAS (atomic absorption spectrometry) and XRD (X-Ray Diffraction) techniques.

Mar 1, 2017

By H. Y. Sohn, S. PalDey

"Fine particles of nickel aluminides and Ni4Mo were synthesized by reducing mixtures of, respectively, A1Cl3 + NiC12 and NiC12 + MoC12 vapors with hydrogen. Though thermodynamically favorable, the coreduction of NiC12 and A1Cl3 by H2 to form Ni3Al did not readily happen experimentally. The addition of a small amount of aluminum vapor was needed to initiate the coreduction reaction. The product particles as observed by TEM were very fine but usually agglomerated. The electron diffraction pattern of particles identified NiAl and NiA13 along with Ni3Al and metallic Ni. The content of Ni3Al was maximized at 52 mol% at 1050°C under the partial pressures ofH2, A1Cl3, and NiC12 at 57, 1.4, and 0.5 kPa, respectively. When a mixture of NiC12 + MoC15 was reduced by hydrogen, Ni4Mo particles with some Ni or Mo particles were obtained, the maximum content of Ni4Mo obtained being 93 mol % . The particle size was in the range of 100 to 200 nm. An Ni4Mo coating of 700 nm thickness on an Ni substrate was also prepared.IntroductionThe search for new high-temperature structural materials has stimulated much research on intermetallic compounds. Nickel aluminides have low densities, relatively high melting points, and good high-temperature strength properties. They show an increase, rather than a decrease, in yield strength with increasing temperature (1). Ni4Mo is also of interest as a high-temperature structural material. The major shortcomings of these intermetallics are their inherent brittleness at room temperature when they are in polycrystalline form. For much the same reason, the conventional casting of intermetallics is difficult. Ingot metallurgy and powder metallurgy are two other processing techniques. The first technique is quite energy consuming. In powder metallurgy, the powders of metals and alloys are consolidated in near net shape and then subjected to secondary processing. It would, therefore, be advantageous if intermetallic compounds can be produced in fine powder form from inexpensive raw materials, using less energy."

Jan 1, 1998

By E. Oshima

In May 1991, a New Mitsubishi Continuous Copper Smelter Line started operation at Naoshima. Recently, it has been continuing steady operation and one and a half year campaign life has been achieved. In 1996, new records of on line time, the amount of copper concentrate treated and copper anode production were achieved. 1t proves the superiority of the process with respect to pollution control, energy efficiency, flexibility and easiness of the operation and over all economy including off gas handling cost. Furthermore, .plans are underway to prolong the campaign life for two years and to improve the process efficiency. This paper describes recent operation, improvements, and a future capability study.

Jan 1, 1998

By Andreas Dietrich

Laser off-gas measurement of CO, O2 and temperature has been carried online in EAFs. A visualization screen shows the values of CO and Oxygen and temperature for the entire heat, and includes the status of furnace equipment. The historical data of the heats are stored such that the furnace performance can be evaluated and optimized. A short comparison between laser based and conventional systems has been carried out related to speed, influence of dust, water, pressure, protection for bag house explosions. A high water and/or dust content in the sample does not represent a problem for this type of system. The measurement method works without interruption even under worst conditions such as dirty scrap, carbon injection etc. The installation was developed in conjunction with Marienhuette, Graz. They are 100% scrap based with a tap to tap time of ca. 46 min. Keywords: Laser Measurement, Off Gas, CO, O2, Temperature

Jan 1, 2003