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By R. Woods

"Comments on the paper ""Formation of hydrogen peroxide by chalcopyrite and its influence on flotation,""by A. Javadi Nooshabadi and K. Hanumantha Rao (Minerals & Metallurgical Processing, 2013, Vol. 30,No. 4, pp. 212-219)The formation of hydrogen peroxide from water during the grinding of chalcopyrite in a nitrogen-sparged environment, as reported by Javadi Nooshabadi and Rao (Minerals & Metallurgical Processing, 2013, Vol. 30, No. 4, pp. 212-219), is questioned on the grounds that oxidation of water by the mineral is unlikely to be thermodynamically feasible. It is argued that it is more likely that any peroxide that had been formed would have been generated from residual oxygen in the nitrogen-flushed system than from the oxidation of water.The formation of hydrogen peroxide by finely divided pyrite had been reported by a number of authors (Borda et al., 2001; Borda et al., 2003; Cohn et al., 2006; Schoonen et al., 2006; Schoonen et al., 2010; Jones et al., 2011; Javadi Nooshabadi et al., 2013). That hydrogen peroxide is formed in the presence of oxygen in solution can be comprehended from wellestablished mechanisms. Pyrite in aerated solution is known to oxidize by an anodic process that is coupled with the cathodic reduction of oxygen (Holmes and Crundwell, 2000). The latter process has been shown to occur through the formation of hydrogen peroxide (Biegler et al., 1975; Ahlberg and Broo, 1996). The pH dependence of cathodic oxygen reduction at other sulfide minerals, including chalcopyrite (Biegler et al., 1977; Rand, 1977), implies a similar mechanism at these surfaces."

Jan 1, 2015

By David J. Dunn

Of many physical parameters critical to design of grinding processes, impact of grinding media is among the most difficult to measure or predict. Yet impact of falling grinding balls, pebbles, or rods accomplishes the fine grinding essential to metallurgical recovery of most important minerals. Unfortunately, the same impacts that break ore fragments deform or crack grinding mill liners. A project was undertaken at Climax Molybdenum Company to measure impact forces in operating ball mills so that they might be used to calculate stresses in liner materials and be correlated with service performance of mill liner alloys. Towards that end, a method of measuring impact forces on ball mill liners using an instrumented grinding ball has been developed. Preliminary tests show that impact forces and contact stresses imposed on bare mill liners are quite high but are greatly reduced by cushioning when coarse ore particles are crushed between balls and liners. Compressive and shear stresses induced in liners not protected by coarse ore are so severe that deformation or minute subsurface cracking are inevitable in all but the small production grinding mills, regardless of mill liner alloy strength or hardness.

Jan 1, 1977

By L. A. Feldkamp, L. I. Davis, F. Yuan, G. V. Puskorius

Emerging technologies such as neural networks and fuzzy logic have many potential industrial applications in diagnostics, modeling, and control. In the automotive industry, applications can be divided into those that impact manufacturing processes and those that relate directly to the product. Though discussion often centers on neural networks deployed in hardware, their potential in the development of problem solutions (however deployed) could easily be of greater importance. Here we concentrate on the use of neural networks for modeling and control, using a simulation of vehicle active suspension as a concrete example.

Jan 1, 1993

By Colin J. Booth

Hydrogeological impacts of active longwall mining were studied at two sites in Illinois. At the site with the more transmissive sandstone aquifer, aquifer permeabilities increased an order of magnitude due to subsidence. Piezometric levels declined with subsidence due to increased porosity, and ahead of mining due to a transmitted drawdown. Levels recovered rapidly at first and fully over two years. At the site with the less transmissive aquifer, impacts were similar except that recovery has been limited. Local aquifer enhancement through increased yield can occur, but only where the aquifer is transmissive enough for recovery.

Jan 1, 1986

By Russell J. Sheets

Reactivation of highwall slope failures during adverse weather had intermittently impacted haul road access into a previously mined open pit. These impacts ranged from limited access to full closures; however, the greater impact was to an underground mine that was developed within the open pit. Following several significant precipitation events, a rapid snow melts greatly accelerated movements finally closing the haul road and destabilizing other past failures. In addition to re-designing the overall pit access, the decision was made to relocate the primary portal to a more stable highwall. An accelerated surface geotechnical review was required to advance the portal relocation; however, only existing information from past investigation, existing geology model, visual inspections, and slope monitoring data were available for the assessment - no new investigations or data collection could be completed within the allowable timeframe. The evaluation included a review of the geology, an assessment of the current highwall condition and previously observed performance, and a rockfall analysis to evaluate existing catchment above the proposed new portal location.

Feb 1, 2024

By I. Iwasaki, T. Fujuita

The removal of phosphorus from steelmaking slags is essential for recycling such slags to blast furnaces for recovery of their manganese, iron, and lime contents. Phosphorus is mainly concentrated in the dicalcium silicate phase of the slags (Fujita and Iwasaki, 1988, 1989; Suito, et al., 1977). Slow-cooling of steelmaking slags in an air atmosphere increased the grain sizes of constituent minerals; however satisfactory magnetic separation results could not be attained because of the close association of a strongly magnetic ferrite phase with dicalcium silicate (Fujita and Iwasaki, 1988). Curie point of the strongly magnetic ferrite phase in the slow- cooled steelmaking slags was investigated and an attempt was made to separate the phosphorus-bearing dicalcium silicate phase in ground slag pulps heated to a temperature exceeding the Curie point. Materials and methods Slag samples, heated to its fusion temperature of 1370°C and slow-cooled in an air atmosphere, were ground dry to -90 µm (about 170mesh) in a ring grinder. The ground sample was pulped to 1% solids in distilled water using 1 kg/t sodium hexametaphosphate as a dispersant and separated in a Sala high gradient magnetic separator, Laboratory Model 10-15- 20B, using a 100-mesh expanded metal matrix and 300 m/h flow rate.

Jan 1, 1990

By C. T. Wallace

Evans Industries, Inc., a management coal consultant and company was assigned to evaluate National Steel Company's coal properties in Knott and Floyd Counties, Kentucky. The results of evaluation showed large reserves of good quality, high volatile metallurgical coal contained in the Elkhorn coal beds and resulted in the formation of Beaver Creek Consolidated Coal Company. Based on results of the exploration and feasibility work, the decision was to install a coal nine, preparation plant and related facilities having a production capacity of one' and three quarter million tons per year with Evans Industries acting as Beaver Creek's management company. The recoverable tonnage assigned to the Stinson Mine is approximately forty-five million tons. This paper discusses the general arrangement of storage, conveying, loading, refuse disposal facilities and the flow sheet of the preparation plant developed by engineers of Heyl & Patterson, Inc., and Evans Industries, Inc., with emphasis on practical flexibility, sulfur reduction in all circuits, and high product yield with the minimum amount of selective mining, Three and one-half miles of railroad have been built by the Chesepeake & Ohio Railroad to service this mine.

Jan 1, 1970

By Y. J. Wang

Optimal sizing of a ventilation shaft is a classical subject in mine ventilation economics.. The shaft size is optimized by minimizing the sum of shaft-construction and ventilation-power costs, or owning and operating costs. The length and air quantity of the shaft are held constant, and the location of the shaft, affecting its depth, and construction and ventilation power costs, is not considered (Hartman, 1961; Lambrechts, 1974; Wang et al., 1978). This paper proposes an approach by which the location and size for a new pair of shafts (intake and return shafts) are optimized for a coal-mine ventilation network. Specifically, the problem is to determine the location and size for a new pair of shafts, and the distribution of air between the new and old shafts so that the combined cost of shaft construction and ventilation power is minimized. The shaft length or depth corresponds to the height of overburden at any shaft location. To simplify the problem, the shaft locations will be limited to the line along the main or submain entries, and the connection entries at the shaft bottom neglected. In order to calculate the ventilation-power cost, the air power of the system should be determined. This in turn requires the calculations of the air quantity and pressure of each fan in the network, satisfying Kirchhoff's laws and Atkinson equation. After obtaining the air power, the cost calculation is straightforward. In the following, we shall assume that the resistances of all airways, and the quantity for each mining section, which is controlled by adjusting the air regulator, are all known. The resistances for the shafts are determined from the estimated friction factors, and shaft dimensions and lengths. Furthermore, it will be assumed that the fans can be selected to meet the duties called for by any network solutions.

Jan 1, 1982

By Don C. White

Santa Rosa is a mid-Tertiary, volcanic-hosted, gold-silver deposit. Current proven and probable reserves are 8.9 Mt (9.8 million st) grading 1.5 g/t (0.044 oz/ st) gold, minable by open pit and amenable to heap leaching. It is the product of hydrothermal mineralization along an arcuate segment of a caldera collapse ring fault in a probable maar volcanic setting. This segment was later broken by radial faults. Gold at Santa Rosa occurs principally as electrum, finely disseminated through intermediate tuffs, and associated with pyrite. The nearby Alto de la Mina deposit displays stockwork silica-pyrite-gold in a tectonically and hydrothermally shattered andesite flow. Miocene epithermal mineralization was accompanied by central silicification and pyritization and more distal argillization. An andesite flow cap rock at Santa Rosa played a pivotal role as an upward permeability barrier. Highest gold grades and most intense alteration occur closest to the ring faults and immediately beneath the andesite flow. Supergene alteration effects on the gold distribution are minimal.

Jan 1, 1995

By Paul Clifford

The Florida Institute of Phosphate Research (FIPR) is an independent, state of Florida research agency. It was created in 1978 to conduct research to enhance the competitiveness of the Florida phosphate industry. The institute also conducts research to prevent, minimize or rectify environmental impacts caused by the industry. And it helps educate the public concerning phosphate-related technology and issues. FIPR is funded by a severance tax on the industry and is governed by a five-member board of directors appointed by the governor. FIPR's research is playing a role in enhancing the competitiveness of the Florida phosphate industry. Its technology research program seeks to improve surface mining and pipeline transportation while reducing the energy cost for pumping phosphate matrix. It is developing new and improved methods of beneficiation and fertilizer production. This includes new process flowsheets and on-line analyzers and process control methods. FIPR is also developing uses for the phosphogypsum byproduct of phosphoric acid production and evaluating the risks associated with its uses.

Jan 1, 1998

By W. Robert Power

Stone is considered by many to be the premium material for beauty and durability in all kinds of construction. Its use dates to the dawn of civilization and only buildings made of stone have survived from ancient times. The use of stone relative to other materials declined from the beginning of the present century reaching a low point in the third quarter, but there has been a resurgence in the use of stone in construction during the past decade, due probably, to new techniques for producing stone, a greater recognition of its beauty and durability, and greater affluence among consumers. The aesthetic appeal of stone is attested to by the many attempts to simulate it in synthetic materials. Today, natural stone is considered by many to be the ultimate in aesthetic appeal, durability, and ease of maintenance. Consumption of dimension stone has increased dramatically during the past decade. The US Bureau of Mines reported that the total value of US consumption in 1978 was $1 13 million and that total imports were valued at $65 million in 1979 (Anon., 1980). In 1989 consumption of domestic dimension stone was valued at $208.3 million and imports at $525 million. This dramatic increase occurred after demand had decreased at an average rate of 2.5% in the two decades prior to 1978 (Anon., 1980). More than half of the imports come from Italy, but production of dimension stone has increased worldwide spectacularly. Meaningful statistics on dimension stone are hard to acquire. The finished piece of stone is a highly value-added product, but stone may be sold as rough blocks, sawed slabs, or finished product. The same piece of stone may therefore be sold and reported three or more times. Furthermore, although the quantity of stone is most commonly reported in tons, stone cladding is more often sold by the surface area and at the same price for different thicknesses. By any measure, however, the production and consumption of dimension stone has increased dramatically during the past decade. A significant indication of the resurgence of stone was the introduction of two new trade publications during the 1980s. Stone World (Tradelink Publishing Co., Inc., Oradell, NJ), introduced in 1984 is published monthly and Dimensional Stone (Dimensional Stone Institute, Inc., Woodland Hills, CA), introduced in 1985 is published monthly. Both magazines provide useful information on new technology, market trends, producing areas and companies, and other information not previously available.

Jan 1, 1994

By Robert A. Bauer

Geology and weather effects produce natural ground movements that may be misinterpreted as mine subsidence. Weather, local geology and vegetation clearly influence the elevation of the ground surface through frost action and changes in groundwater levels and soil moisture content. Common practices of monument and benchmark design and placement do not address the problem of natural ground movements. Monuments can be designed to minimize some natural ground movements. Differential displacements can be reduced by knowledgeable placement of benchmarks and monuments which are of similar design and construction. Commonly, the threshold values of movement for the determination of mine-induced subsidence are dependent on the closure errors (accuracy) of individual surveys. Accuracy is more than the amount of closure error; it should include the range of elevation changes (error band) determined for each monument over a period of time before it is disturbed by mining. Multiple baseline surveys of the entire monitoring system, conducted before the onset of subsidence, should be used to establish subsidence detection limits.

Jan 1, 1986

Bigger is indeed better in today's surface mining operations. That is especially true regarding haul trucks. Building larger, "supersize" trucks, however, means designing more powerful engines and drive systems that are also more efficient and environmentally friendly. And miners are demanding that these trucks have longer service lives with minimum maintenance. So truck makers are teaming with engine manufacturers and mining customers to design these larger trucks that will ultimately lead to reduced mining costs. About 180 of those truck makers, engine designers and miners gathered in Tucson, AZ in September to discuss the state of haul trucks in today's mining environment. Haulage 2000 was sponsored by World Mining Equipment and attracted attendees from around the world. Manufacturers described the latest in haul truck advancements. These included the design of more powerful engines, improvements to mechanical and ac and dc drive systems and suggestions on how to reduce maintenance spending. Technology improvements in tires for larger struck was discussed as was the cost efficiency of new, lighter-weight bed liners. The following is a summary of a handful of the presentations.

Jan 1, 1997

By J. Herbst, H. W. Kropholler, L. A. Cramer, E. T. Woodburn, J. C. A. Greene, G. Poling

A generalized mathematical structure is proposed whereby internal species mass flows within a flotation network are defined uniquely by a matrix of enhancement factors. An element of the enhancement factor matrix is defined as the ratio of the mass flow of that species leaving a given cell in the concentrate to the species mass flow leaving the same cell in the tailings. To predict the enhancement factors, knowledge of flotation kinetics effects is required. Recently experimental data has become available relating to the performance of industrial flotation circuits which indicate that the discrete or discrete-distributed kinetic schemes are capable of reasonably effective simulations. These simulations show the importance of including froth effects. The prediction of performance of networks from small-scale batch tests on flotation streams shows that the model for the froth phase used in the simulations does not scale-up well and that aeration effects are also difficult to predict. The network analysis should be useful in differential flotation of complex ores and it is disappointing in this context that little information on the kinetics of activation and depression is available.

Jan 1, 1976

By J. H. Rowland

Four different types of fire suppression systems were evaluated in large-scale fire experiments to study the effect of air velocity on the effectiveness to extinguish conveyor belt fires. The four different types of suppression systems were water sprinkler, deluge type water spray, and two different dry chemical fire suppression systems. The large-scale fire tests were conducted with 72-in-wide fire resistant rubber belt that met the Mine Safety and Health Administration flame resistant requirement specified in Title 30, Code of Federal Regulations, Part 18, section 18.65 (also known as the 2G Flame Test). Each fire suppression system was tested at air velocities of 500-550 feet per minute (fpm) and 1350-1500 fpm. Two tests were conducted at both air velocities for each fire suppression system. Both of the water-based fire suppression systems were able to suppress the fire to the point that a miner could extinguish it with a fire extinguisher. However, the amount of water needed to suppress the fire to the point where a miner could walk up to extinguish any smoldering belting was greater than the current MSHA regulations require. MSHA regulations only require 10 minutes of water supply to the suppression system. In the test set up neither of these systems would have suppressed the fire had the water been turned off to the system after 10 minutes. The dry chemical suppression systems produced mixed results. Dry chemical suppression system A did not suppress the conveyor belt fire at either air velocity. Dry chemical system B suppressed the fire at 500 fpm air velocity, but produced mixed results at the higher air velocity. Details are presented on the large-scale fire test set-up, arrangement of the fire suppression systems, and conclusions regarding the effect of air velocity on fire suppression system design and performance. Disclaimer: The findings and conclusions in this report are those of the authors and do not necessarily represent the views of NIOSH.

Jan 1, 2009

By Malcolm J. McPherson

Observations of environmental parameters in mines have traditionally been made by means of hand-held instruments, these being employed as a basis to ensure that atmospheric conditions in the mine remain within limits commensurate with safety, to safeguard the health of personnel, and to ensure that statutory requirements are met. Thus, starting from the first flame safety lamps of the early nineteenth century, numerous portable instruments have been devised over the years to indicate levels of dust, temperature, humidity, and concentrations of gases including oxygen, methane, and carbon monoxide. Similarly, portable instruments have been used to measure air velocity and pressure. For routine monitoring purposes, hand-held equipment suffers from many disadvantages. Readings are intermittent, often with long delays between successive observations, making short-term trend analysis impossible. Portable instruments are more liable to damage; they are labor intensive and provide a very limited amount of information either for control or planning purposes. The 1960's and 1970's have seen an accelerated development of mine environmental monitoring equipment. Alarm methanometers to give localized audiovisual signals became more common. These were followed by a variety of instruments which gave local, then local/remote continuous records, particularly of methane concentration and airflow. More sophisticated transducers and transmission systems were developed allowing further parameters to be monitored. This led to a proliferation of paper strip and chart recorders which had to be maintained and inspected regularly for trends and abnormalities.

Jan 1, 1979

By Russell. A. Smith

This paper describes some recent work on the identification and development of new chemical reagents aimed at improving the industrial processing of phosphate ores by froth flotation. In particular, three chemical product families which will be discussed appear to offer enhanced flexibility by: 1) utilizing a small amount of a silica control reagent which can significantly reduce the amount of anionic (carboxylic) collector required for a given P2O5 recovery level; 2) utilizing a new anionic collector family which offers high P2O5 recovery and selectivity versus standard carboxylic collectors; and 3) utilizing another new anionic collector family which has, in some tests, allowed for selective removal of dolomite from apatite. Examples and use characteristics of each of these new chemical ideas will be presented.

Jan 1, 1993

By Janusz S. Laskowski

The most important type of potash ores, sylvinite, contains sylvite, halite and a small percentage of insoluble gangue [sulfates (anhydrite), carbonates (dolomite), and clay minerals]. Primary normal long-chain amines are exlusively utilized to float sylvite from halite, but since mines are also adsorbed by insoluble slimes, the process requires prior desliming. This is carried out either by mechanical means, or by flotation of slimes and blocking off the adsorption centers on clays with the use of polyelectrolytes. Fractional crystallization is employed to produce fertilizer grade KC1 from disseminated ores with a high content of slimes. An extender oil is needed in addition to mine to float coarse sylvite fractions. The process is carried out in a saturated brine at mine concentrations exceeding the solubility limit and is strongly affected by temperature fluctuations. All these important features, which make this process differ from a conventional flotation, result from a high electrolyte concentration.

Jan 1, 1994

By C. Woofter

Quarry operators must continue to change and adapt environmental compliance methods to meet the increasingly demanding regulations. To fulfill industry needs, a computer-based decision support system is being developed to facilitate decision making that mine operators are required to make regarding environmental responsibilities. This system can help to determine permitting and compliance measures needed for air, surface water, groundwater, noise, aesthetics, vegetation, wetlands, hazardous wastes, storage tanks and wildlife habitats during the development, operation, and closure phases of mining. Operators will utilize the system's user-friendly interface consisting of mouse driven responses and limited keyboard entries on a desktop computer. The system is easy to upgrade according to the user's needs and changes in current laws and regulations. Data input models, user interfaces, and support of decision making are explained. The program permits inclusion of the decision maker's own insights through "what-if' analysis, in which the user can change ad hoc entries and check the related consequences. Using this approach, the user has complete control over all steps of the decision making process. A storm water example is selected to demonstrate the potential benefits of the support system to environmental decision makers.

Jan 1, 1995

By T. Altman

Using theory of network planning together with graph theory, an algorithm is presented that creates canonical diagrams for mine ventilation networks (M VN). The data generated by the algorithm is used in the construction and plotting phases of a program that automatically plots the canonical diagrams, which can then be used for further studies of a given MVN.

Jan 1, 1988