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By William J. Shampine

The Floridan aquifer, which underlies all of Florida, yields water with a sulfate content of less than 50 parts per million in the north-western part and throughout most of the center of the State. In the southern part of Florida and along the most of the east coast, the sulfate concentration generally exceeds 100 parts per million and is as much as 1,700 parts per million. The sulfate concentration tends to be higher in the deeper zones of the aquifer. This map shows the sulfate concentration in the upper part of the aquifer. Sulfate is found in almost all natural water. Sulfate in rainwater is dissolved from impurities and gases in the atmosphere. Rankama and Sahama (1955, p. 314) report that the average sulfate content of rainwater is two parts per million; however, concentrations have been as high as 283 parts per million. Much of the sulfate in rainwater comes from hydrogen sulfide gas which is generated in shallow water on the continental shelves. The combustion of bituminous coal used for heating and industrial purposes seems to be an important local source of sulfate.

Jan 1, 1966

By George A. Desborough, Stephen J. Sutley, Reinhard W. Leinz, Paul H. Briggs

The mode of occurrence of metals in mine wastes is investigated using sequential extractions. Metals are extracted from some or all of seven operationally-defined phases: water-soluble, ion-exchangeable, carbonate, amorphous Fe-oxide, crystalline Fe-oxide, sulfide, and silicate. The quantity of metals extracted from each phase varies with particle size. The presence of jarosite (potassium end-member formula, KFe3[SO4]2[OH]6) influences the selection of the procedure for extracting the crystalline Fe-oxide phase. Anglesite (PbSO4) and cerussite (PbCO3) are extracted as several phases. Extraction results can be explained only in part by X-ray diffraction (XRD) mineralogy because of lack of specificity of the extraction procedures, relatively high XRD detection limits, and the presence of 40% XRD-amorphous matter in each waste. The increasing chemical strength of the sequentially applied methods provides a basis for judging metal availability, water-soluble metals being most available and silicate-bound metals being least available.

Jan 1, 2000

By Michael Li, Kathryn Rogers, Arie Moerman, Mike Cooper

The Brunswick Mine, a Division of Noranda Inc., produces zinc, lead, copper, and bulk lead-zinc concentrates through underground mining of a large massive sulphide deposit. The mining method employed is longhole open stoping with delayed backfilling. In 1996 Brunswick began a review of its mining methods and backfilling operations. In 1997 the decision was made to convert the backfill system from cemented and uncemented rockfill to paste backfill prepared from mill tailings. This paper will describe the features of the backfill preparation and distribution systems, review the handling of technical issues, and discuss experiences since plant commissioning.

Jan 1, 2001

By Charles F. Herbert

It is difficult to decide who most deserves credit for discovery of a mining district that has produced over 19.8 Mg (7,000,000 fine oz) of gold and still contains a large reserve of low grade ore. Fred Culver may have made the first discovery. In the summer of 1867, the ship's log of the Hudson's Bay Co.'s steamer Otter stated that Fred Culver had been found nearly lifeless from wounds, without provisions, but with some 2.3 kg (80 oz) of rough, placer gold in the bottom of his canoe; he told of finding a rich creek and an attack by Indians that caused the death of his two companions. The place of rescue was about 24 km (15 miles) southeast from the present site of Juneau. Possibly John Muir, the hero of modem environmentalists, should be given important credit. In 1879 he reported finding mineralization along what later became to be known as the Juneau Gold Belt, and it was his report that induced the cantankerous German mining engineer, George Pilz, to grub- stake some of the prospectors who had drifted into Sitka from the declining gold placers of Cassiar, British Columbia. Pilz also offered rewards to Indians who might report gold discoveries.

Jan 1, 1990

By Lynn B. Hales, Randy A. Ynchausti

Introduction There continues to be a large economic opportunity associated with improving process performance through advanced process control systems within the minerals industry. The basis for this opportunity lies in the inherently low efficiencies of many of the unit operations found in mineral processing plants as well as the continual variation that is present in the ores being processed. The ageless target of such control systems is improved recoveries and concentrate grades, higher processing rates and lower unit costs. Many plants are enjoying the benefits of modem, well functioning process control systems but few if any have achieved plant-wide optimization in an economical sense. As new process modeling and control technologies, such as neural networks, continue to evolve and develop, the potential for plant- wide optimization is becoming a closer reality. Neural network technology appears to have a significant potential in the general field of process control and control of mineral processing operations. Neural networks are an emerging technology that have been evolving out of the study of biological systems since the early 1940's. The first software simulation of neural computing networks was reported in 1956 by Nathanial Rochester of IBM Research during the first conference on artificial intelligence which was sponsored by the Rockefeller Foundation. Neural Networks Neural networks can be considered to be a class of computer program that perform their problem solving functions based on a rudimentary model of the human brain and how it solves problems. Traditional computer programs and even computers themselves solve problems or process data sequentially and in a deterministic manner. The human brain, on the other hand, processes data and solves problems in a massively parallel fashion. We think of computers normally in terms of having a single processing unit, sometimes a co-processor to assist in certain activities such as mathematical functions or communications, bytes of memory, processing speed and program/data storage size.

Jan 1, 1992

By Fiona M. Doyle, Christopher R. Lubeck, Michael C. Chin

The fundamentals behind a novel approach for creating inorganic/polymer hybrids are described. The binding of +2 charged ions, specifically Cue-and Cat+, to ionic functional groups is explored through UV-Vis spectroscopy and zeta potential measurements. The novel approach uses an electric field to drive ions into a functionalized polymeric matrix, thereby inducing the precipitation of calcium phosphate species. Scanning electron microscopy images of the resulting composite illustrate the results of these precipitations with two distinct morphologies observed.

Jan 1, 2003

By Adrian Smith

14.1 INTRODUCTION From the time the last recoverable gold is extracted from ore on a heap leach, the ore - now spent ore - changes from being the resource, indeed the raison d'etre of the operator, to a potential liability. The spent ore contains process chemicals and constituents leached from the ore both in the interstitial pore water in the heap and on the surfaces of spent ore. If these chemical species were released to the environment, it could have a potential impact on the quality of both surface water and groundwater resources. Accordingly, the spent ore must be left in a condition where it does not present a potential environmental liability. This can be accomplished either on a decommissioned pad or, if the heap leach is operated as a load/unload scheme, in a waste facility. In general, the residual cyanide level in the spent ore is the perceived controlling factor when determining whether the leached material is suitable for abandonment. Regulatory authorities set permit conditions for heap leach abandonment in terms of residual cyanide levels, for example, Smith and Struhsacker (1987). This chapter discusses cyanide degradation and methods for detoxifying a heap leach in order to meet regulatory limits/permit conditions for abandonment. Cyanide degradation and detoxification by "natural" processes are described initially, based on the chemistry and geochemistry discussed in Chapter 13. This leads to a review of chemical treatment processes for detoxification of spent ore. The advantages and apparent disadvantages are then appraised. 14.2 NATURAL DEGRADATION AND DETOXIFICATION For the purposes of discussion, "natural" detoxification processes can be divided into two alternatives: • Passive abandonment (the so-called "do nothing" option); and • Water In the first alternative, the spent ore is merely left on the leach pad to age; the second alternative involves the flushing of the spent ore with water.

Jan 1, 1988

By Clete Stephan, John Urosek, Ian Anderson

The Endeavour Colliery is operated by Powercoal Pty Ltd. It is located in the Central Coast of New South Wales, Australia. The mine has been in operation for about 30 years, producing around 600,000 tons of export coal annually from two production sections. On June 28. 1995, an explosion occurred underground in the 300 Panel at approximately 9:50 a.m.. There were thirty miners underground at the time of the explosion, all of whom were safely evacuated. From June 29 through July 10, personnel did not enter the mine. However, gas samples of the mine atmosphere were obtained from underground monitoring stations and analyzed. Samples were also obtained from boreholes that were drilled from an adjacent mine. On July 10, the atmosphere at the underground monitoring locations and at the boreholes appeared stable with minimal risk of combustion occurring underground. Plans were developed to begin the recovery of the underground workings. The recovery of the underground workings was completed on July 13. The underground investigation of the explosion began on July 14. The investigation was conducted by the New South Wales Department of Mineral Resources. Technical assistance was pro- vided by the United States Department of Labor's Mine Safety and Health Administration (MSHA).

Jan 1, 1997

By Yelloji M. K. Rao, P. Somasundaran

Reagents of biological origin are becoming more and more important in the field of metallurgy, especially in the areas of mineral processing and hydrometallurgy. The advantage of lower operating cost over physical and chemical processes and the capacity to operate with low grade ores make the microbial processes further attractive. In this paper, the role of microbes directly as a reagent and microbially produced reagents or secreted metabolites in mineral processing and hydrometallurgy will be discussed. Adhesion of microbes to surfaces is known to alter the hydrophobicity of minerals. Applications include surface modification to impart hydrophobicity or hydrophilicity on sulfide or non-sulfide minerals and dissolution of precious metals. Microbes can also perform the role of flocculating agents. Biosorption of toxic and heavy metal ions by microbes are finding application in treating tailing ponds. Mechanisms associated with the use for microbially produced reagents are discussed along with some recent results.

Jan 1, 1994

By M. Robb, S. J. Bate, M. Boisvert

The never-ending quest for gold-bearing ore deposits is a primary industry in Canada, employing people of widely differing expertise. The exploration models for gold deposits are generally geologically complex and the targets have relatively small cross-sectional areas. These problems are compounded in Canada by the minimal outcrop exposure in most mineral provinces and the high percentage of water-covered areas. Naturally the chances of successfully delineating an economic gold deposit are very much greater if all parties involved can act as a team of explorationists constantly confemng amongst themselves particularly as the applicable disciplines generally overlap and complement each other. Three case histories (see Figure 1) are presented to illustrate this philosophy with emphasis placed on the role of the geophysicist in translating the exploration model as defined by the geologist into physically measurable parameters and identifying target areas with similar characteristics. The Conwest-Miminiska property in Ontario is a grassroots exploration play. Additional ore reserves needed to be delineated on the Salmita property in the Northwest Territories. At Laura Lake, near Chapais, Quebec geophysical methods were employed to trace thin high-grade mineral intersections under deep overburden and severe cultural interference.

Jan 1, 1989

By Grażyna Dzik, Adam Mirek, Krzysztof Król

The Upper Silesian Coal Basin is located in the area of the Upper Silesian Syncline and belongs to one of the most complex tectonic units in Europe. It occupies 5,650 km2. In 2020, there were 20 hard coal mines operating in the area. Seismological research in this area consists of observation of precursors/symptoms of shock generation and understanding of their effects. Studies (Teisseyre R. 1972, Mutke G. & Stec K. 1997, Stec K. 2007, Dubiński J. & other 2010, Idziak A. 2010) of complex impacts of rock mass provided a background for determining the conditions for the formation of exploitation and regional seismic shocks. Issues related to tectonic and exploitation stresses, successive extraction of coal seams at higher depths, operation in the vicinity of fault zones, often complex geological and organic conditions result in the activation of a discontinuity surface due to stress caused by deformation of rock layers, which, as a result, causes the emergence of strong shocks above 107 J. The article was based on analyses of extraction value, high-energy shocks, both of mining and tectonic-mining (so-called regional shocks) origin, against the background of changing operating conditions, which, as a result, creates an image of periodically changing seismic activity and location of strong shocks. Observation results show that, with an increase in exploitation depth and declining extraction, the number of strong shocks caused by tectonic stress (107 - 109 J) and exploitation stress (≥105 J) has been steadily increasing over the last 25 years.

Apr 26, 2022

By Richard S. Ghent, Daniel G. Warnock

JOHN HAMRIC: Our next speakers are Richard Ghent, manager of environmental health and safety for CF Industries, Hardee Phosphate Complex, in Wauchula, Florida. Richard has 20 years' experience with environmental health and safety affairs. He has a bachelor of science degree from the University of South Carolina. With him is Daniel Warnock, who is supervisor of safety and training also at the Hardee Phosphate Complex. Daniel's experience is in safety programs and electrical training. Their presentation is "Regulations Versus Management Practice." RICHARD GHENT: Written procedures give structure to safety programs. At their best, they are brief and understandable to facility personnel and clearly identify roles and responsibilities. At worst, they attempt to recite the entire regulation they are intended to address. Some regulations, such as OHSA's Hazard Communication Standard, require employers to develop, implement, and maintain a written program. As written programs and procedures are developed, some basic questions arise: Is the program designed to achieve compliance with regulatory requirements or does management expect the program to go beyond compliance to some higher level of performance? Management may have difficulty in measuring and communicating performance expectations in safety. A facility with 4 million safe work hours does not suddenly become unsafe the day their safety record is broken. Generally, management expects safety programs to meet regulatory requirements and to protect the employer from enforcement actions and fines from regulatory agencies. Management also expects that safety programs will result in a safer work environment with fewer incidents, accidents, and near misses. But it is difficult to know when a safety program has succeeded. If the program is expected to go beyond compliance, what other standards should be included (e.g., ANSI standards, company management practices, lessons learned from inspections and audits, recommendations from safety committees, etc.) in the

Jan 1, 1998

By Vijenac Quarry, A. Iljazagic, t. Knezicek, T. Omeragic

Limestone quarry Vijenac, is one of the key limestone producers in B&H. Conventional massive drilling and blasting is the technique applied for limestone exploitation. Utilized blasting scheme causes appearance of large oversize stone pieces, uncontrolled flying stone and undesirable seismic effects. In order to reduce or eliminate exposed disadvantages and to improve environment in the area of Vijenac quarry, an innovative blasting scheme was tested. Conventional blasting scheme was changed from single row, deep inclined blast holes combined with two lines short horizontal holes to multi row, inclined blast holes combined with a single line short horizontal blastholes. Applied innovative blasting scheme reduces negative blasting impact on the environment through safer working conditions, reduced amount of dust after blasting, reduced explosive and energy consumption, reduced appearance of explosive gasses and reduced earth and air vibrations as the result of seismic effects.

Jan 1, 2005

By J. Linhart

In vertical airways, falling material - solids-or water - may cause undesirable disturbances in the ventilation in the airway itself and also in neig¬bouring airways unless precautions are taken to stabilize the air flow. Such cases can occur, for example, - in shaft sinking by drilling from a pilot hole, - during the filling up of shafts, and - during the introduction of water into shafts in the case of mine fires. In an airway with upward ventilation the falling material will reduce the air flow and may even re¬verse its direction. In an airway with downward ventilation the air flow can only increase, but a reversal of the direction of ventilation may result in a parallel airway. These disturbances in the normal ventilation are undesirable as it must be the aim to have ventilation that is stable in quantity and direction throughout a mine. In order to be able to prepare suitable stabilization measures one must know the pressure generated by the falling material; this pressure will henceforth be called "aeromotive" pressure. The main factors determining the influence of falling material on the ventilation are - the amount of falling material and its height of fall, - the cross sectional area of the airway, - the pressure. difference prevailing in it, - the-position of the. airway in the ventilation. network, - the air velocity, and - other parameters, e. g. the density and grain size of the falling material. To determine the aeromotive pressure-measurements have been made underground during the sinking and filling of shafts and systematic studies have been carried out during the supply of water into a staple shaft. The present paper deals first with some fundamental theoretical considerations and then describes the measuring arrangements and the results of the series of experiments that have been carried out.

Jan 1, 1980

By James A. Decker

Hanna has developed three production planning systems to help the mine engineers determine the sequence of mining from available ore supples. The Production Scheduling System was developed to give the staff a tool for long range planning by sequencing the removal of blocks from an open pit property. It was needed to determine the year of removal for each block so that the optimum present-valued pit limits could be established by our pit design program. Since in this type of planning short term grade control is less of a factor than it is in daily or monthly planning, the system gives the program greater control and more latitude in block selection. It permits only full blocks to be taken.

Jan 1, 1984

By Peter N. Yanker

The two types of dryers used in the drying of copper concentrates are the rotary dryer and the spray dryer. The rotary dryer has until recent history been the traditional drying method used, Although spray dryers have been used in the chemical field for many years it is only recently that they have been accepted for drying of copper concentrates. The comparison made here will apply in a narrower sense to the drying of copper concentrates as fed into the reverbatory furnaces of the Smelter. To compare a rotary dryer and a spray dryer, which are two totally different methods and pieces of equipment, it is best to view them as systems each made up of certain elements

Jan 1, 1976

By M. Szatkowski

The studies conducted by Laplante and coworkers (1983,1984) with flotation of galena and quartz, showed that the rate of flotation reaches a maximum value for a certain intermediate value of the air flow rate. A similar, though less pronounced, effect of the air flow rate on the selectivity was also observed. Luttrell and coworkers (1985) showed that the size of air bubbles has a significant effect on both rate and selectivity of coal flotation. These two studies used flotation tests in which no froth layer was formed. This note describes effects of the air flow rate and bubble size on the rate constant and selectivity of coal flotation, using a mechanical laboratory machine with a froth layer allowed to form. Experimental A raw, dry ground Illinois coal was used in flotation tests. The size distribution and ash content of the samples are : Particle size (µm) Weight (%) Ash (%) +600 4.30 41.7 600/200 43.05 19.0 200/74 22.25 16.0 - 74 30.40 24.0 average 20.8 No. 2 fuel oil with a concentration of 200 g/t of feed and M.IBC with concentrations of 11, 22, and 33 mg/L of pulp (128, 256, 384 g/t, respectively) were used as flotation reagents. Tap water with a natural pH of 7.0 to 7.8 was used throughout the tests. No other reagents were used. The starting concentration of coal in the pulp was 86 g/L. A standard flotation machine with the pulp volume of 5 L was used in experiments. Three different air flow rates were employed, resulting in three air escape velocity values of 14, 30, and 70 cm/min. The air escape velocity (AEV) was calculated as the ratio of air flow rate (Qa) to the slurry surface (Ss) in the machine. For a comparison, the upper limit of air escape velocity values used in commercial size flotation machines is between 70 and 100 cm/min (WEMCO, 1983). A machine consisting of a generator of fine bubbles and a separatory column, described elsewhere (Szatkowski and Freyberger, 1985), was used for some tests where bubble size lower than that generated in the standard machines was required. Prior to a flotation test, a batch of coal was mixed with water in the flotation cell for at least 10 minutes to ensure that all coal was thoroughly wet. Then the specified amount of fuel oil was added and the pulp was conditioned for five minutes. The specified amount of MIBC was added 15 seconds before the end of conditioning. After air flow was opened, flotation products were collected for 0 to 30, 30 to 60, and 60 to 120 second intervals. Content of the combustible material in samples was determined by subtracting the ash content from 100%. A photographic technique was used to determine initial distributions of bubble size generated by the flotation machines. Bubbles generated in water containing the prescribed amount of the frother but no solids were photographed against a black background. The average diameter and standard deviation were then calculated for each set of flotation conditions. The method gives results reproducible within k 5% of the average bubble size. Table 1 contains information about the measured bubble size distributions expressed by the average bubble diameter (Db) and the standard deviation ( SD ) . Results and discussion The general formula for calculating the flotation selectivity is: o = recovery of coal/recovery of ash (1)

Jan 1, 1988

By R. R. Klimpel

The process of flotation is an extremely important solids separation technique employed in a wide variety of industrial process applications. Froth flotation is practiced in the coal industry to recover fines produced during the mining and cleaning of coal. A recent review article by Aplan (1) covers the processing variables encountered in the flotation of coal and the variety of chemicals and operating conditions which affect recovery. Numerous engineering and scientific studies have been performed with the goal of providing semifundamental laws of flotation behavior for improved screening of flotation chemicals, better equipment scale-up factors, etc. Often the results of such work are expressed in the form of mathematical models (e.g. 2, 3, 4, 5, 6) which are potentially useful for evaluating (simulating) on paper such alternatives as possibles process operating or configuration changes, the effects of ore and reagent changes, etc. It appears to be commonly accepted that a complete scientific/engineering characterization of flotation is immensely complicated and not sufficiently developed at the present to accurately predict (or understand) many important industrial facets of flotation. Thus, one is often reduced to detailed experimental characterization in both the laboratory and plant in order to fully evaluate flotation changes or alternatives. It is the purpose of this paper to describe a method of batch laboratory data characterization that is useful in evaluating flotation chemical reagents including froth flotation of coal. The approach consists of running a series of time-recovery curves in a batch float cell followed by the computer curve fitting of this data to a series of mathematical models based on semi-physical reasoning. The unknowns or parameters of these models are then optimally chosen so as to best fit the experimental data. It has been found in both coal and mineral systems that changes in reagent type, concentration, system pH, grind, etc. cause very consistent and logical changes to

Jan 1, 1979

By Henry P. Cole, Andrzej M. Wala

Engineers and psychologists at the University of Kentucky have developed simulation exercises that teach and test proficiency of mining technical personnel for coping with planned and accidental connections between separate air courses in underground mines. The exercises are based upon investigations of actual mine disasters. The exercises are judged as valuable and interesting training materials by experienced mining personnel. Although these specialists generally perform well on the exercises, potentially fatal errors are not uncommon. The use of such realistic exercises may better prepare miners for preventing and coping with underground mine ventilation emergencies.

Jan 1, 1987

By P. W. King

The performance of the versatile McNally Wedag horizontal vibratory centrifuge for dewatering ultra fine 0.5 x 0.15 mm (28 x 100 mesh) material has proven to be success¬ful and the results presented herein will examine its capabilities in terms of capacity, solids capture, product moisture, effluent solids, and size analysis. Centrifugal dewatering of fine refuse has proven t to be another application for which this unit has performed exceptionally well.

Jan 1, 1985