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By GRANT COLLIGAN, BROCK O’KELLEY, Corby Anderson

With the world’s ever-growing push to expand technological capabilities, the need for specialized materials including rare earth elements has exploded. One source of rare earths found in the United States is bastnaesite, a rare-earth-bearing fluorocarbonate, mined at the Mountain Pass Mine in California. To increase production, it has been essential to optimize existing processes and create new ones to capture current reserves. This paper presents the results of a research program conducted to expand the understanding of the bastnaesite leaching system. With the help of prior knowledge and thermodynamic calculations, a novel single-stage hydrochloric acid leach system was created to optimize the extraction of rare earths from bastnaesite. Historically, this extraction has entailed the use of a two-stage leach system involving a high-temperature hydrochloric acid leach followed by a caustic crack. We ran a series of single-stage leach experiments by reacting locked-cycle flotation concentrate with hydrochloric acid to test common leaching parameters. The results of these single-stage tests showed significantly higher rare-earth recoveries than the reported recoveries of the historic two-stage caustic crack processes, all while decreasing the number and amount of reagents needed.

Feb 1, 2023

By R. E. J. Putman

Rising demand, artificial market conditions, increased overseas competition, and a fluctuating international situation have brought ever increasing pressures to bear on the nonferrous metals industries, and particularly in the United States, Although capacity is being expanded by the construction of new plants and the development of new ore deposits, increasing attention is being focused on the possibilities of improving the performance of the existing installations and of getting the most out of the new equipment now installed. At first sight the task appears formidable. Based on raw materials which are nonhomogeneous, and possessing characteristics which are hard to quantify, even the processes by which the values in the ores are concentrated and extracted are in many cases not fully understood. The necessary analytical equipment and transducers demanded by these industries have also been slow in development and their earlier absence has hampered the application of modern control technology, This is reflected in plants which have been designed for ease of manual rather than automatic control, and in which the application of control techniques at first sight appears economically prohibitive. However, in any industry progress often comes only in small steps, It may be that by the wise choice of limited objectives and perhaps only partial solutions, substantial improvements in plant performance can be implemented now, and with only a modest investment. If modern control equipment is chosen of the type which can be reprogrammed, advantage can be taken later of more sophisticated solutions as the technology of the industry advances. This task of improving plant performance can and must be commenced even though our knowledge is incomplete. The experience of a related mineral consuming industry, with similar problems in the past, can be encouraging.

Jan 1, 1967

By Kamran Esmaeili, MINGLIANG TANG

An understanding of the spatial and temporal variations of surface moisture content over a heap leach pad is essential for leaching production and to achieve a high ore recovery. The current leach-pad monitoring and data-collection practice remains highly labor intensive and exposes technical staff to cyanide solution, a hazardous material. To address these challenges, we propose using unmanned aerial vehicles (UAVs) equipped with thermal imaging sensors to remotely obtain image data with high temporal and spatial resolution for monitoring the surface moisture distribution over heap leach pads. A field study was conducted over a sprinkler-irrigated heap leach pad at El Gallo gold mine in Sinaloa, Mexico, and the acquired data were used to generate moisture distribution maps of the heap leach pad’s surface. The created moisture maps provide direct visualizations of surface moisture variation over the surveyed area. Such graphical results are effective tools for inspecting heap-leaching operations.

By Isabel F. Barton, Christian A. Rathkopf, Mark D. Barton

Rhenium (Re) is one of the rarest elements on earth and is a designated critical element in the United States and European Union for its uses in superalloys. Unusually among critical elements, Re is produced entirely as a byproduct of molybdenite (MoS2) mining, as pure Re minerals are extremely rare. However, Re concentration in natural molybdenites varies from a few parts per trillion to tens of percent. There are few known consistent patterns and no firmly established reason for this variation, making it difficult to use molybdenite Re content as a proxy for metal grades, a vector to high grades, a clue to the geological and geochemical nature of the ore deposit, a guide to overall Re resources or for any other of the applications that have been suggested for it over time. 

By James A. L. White

Although the quantity of native sulphur associated with volcanism is large, production from such deposits represents only a very small percentage of total world production, This paper describes the location of the known deposits, the typical geology of these deposits and the nature of the sulphur mineralization. Methods of treatment are discussed and some comments are offered on the economic position of these occurences in world sulphur markets.

Jan 1, 1967

By Mark D. Cocker

Georgia?s Coastal Plain contains important sediment-hosted deposits of kaolin, bauxite, heavy minerals, sand and gravel, silica sand, carbonate rocks, and fuller's earth. Genesis, location, size, and quality of these deposits are related to terrestrial, marginal-marine, and shallow-marine depositional environments that evolved during development of the southeastern North American continental margin. From the Cretaceous to Eocene, kaolin and aluminous sediments, which contained mica and feldspar, were deposited in marshes, ponds, and bays located in deltas or behind barrier islands or spits. In the Cretaceous sediments, subsequent, intensive, in situ chemical weathering converted mica and feldspar to kaolin. Kaolin eroded from deeply weathered granitic rocks in the Georgia Piedmont was deposited in Paleocene to Eocene sediments. Subaerial exposure during the Paleocene and Eocene desilicated kaolin sediments to form bauxite. Sand and gravel, silica sand, and heavy-mineral deposits are found in Cretaceous to Eocene fluvial and shoreline sediments, some of which are associated with the kaolin and bauxite deposits. Source areas, intensive chemical weathering in the source areas, transportation by the major river systems, and deposition of these clastic sediments in similar or nearby depositional environments are common elements in the genesis of these resources. Eocene fuller's-earth deposits are opaline claystones in near-shore to shelf-marine sediments, which overlie the kaolin-bearing strata. These claystones consist of montmorillonite and opal/ cristobalite derived from alteration of diatom frustules. Favorable ocean currents provided nutrients for extensive planktonic growth. Oligocene and Miocene carbonate rocks were deposited principally in shallow-marine embayments. Miocene fuller's- earth deposits in south-central Georgia and adjacent parts of Florida contain palygorskite that formed through alteration of montmorillonite/bentonite clays. Deposition and subsequent alteration occurred in shallow, brackish-water lagoons under relatively high temperature and subtropical conditions. Middle and late Miocene phosphorites were deposited on a shallow carbonate-shelf platform and were concentrated proximal to anticlinal highs. Numerous marine transgressions and regressions since the beginning of the Pleistocene resulted in shoreline detrital deposits containing aggregate sand, silica sand, and heavy minerals on the Coastal Plain and on the Continental Shelf. Major river systems transported sand and heavy minerals from source areas in the Piedmont and Upper Coastal Plain. Deltaic deposits of heavy minerals were redistributed and concentrated by longshore currents, shoreline processes, and aeolian processes. River-terrace sediments, correlative with the Pleistocene shoreline deposits, contain sand-and-gravel and silica-sand deposits. Aeolian dune sands are associated with both Pleistocene fluvial and shoreline detrital deposits.

Jan 1, 1999

By Jeffery Leavy, Ken Davis, Kirk H. McDaniel

The Waste Isolation Pilot Plant (WIPP) is a United States Department of Energy facility located in southeastern New Mexico. It is designed for the safe disposal of transuranic radioactive waste in deep geologic salt beds. Westinghouse TRU Solutions, LLC, the managing and operating contractor, undertook a project to simulate the processes at WIPP in order to identify bottlenecks and optimize available resources. The activities simulated in the model included the receipt, processing and disposal of radioactive waste underground, the mining of new areas for future waste disposal and the transportation of salt out of the mine. The complexity of the processes and the interactive requirements between processes required the use of advanced modeling techniques. The simulation model includes a huge number of locations and path network node points, with movement to and from the locations controlled using parameters rather than explicit routing. Information for the timing and sequence of the mining and nuclear waste emplacement operations is brought into the model via spreadsheets. Arrays in the simulation model keep track of past and future events that occur. Routing to the multiple possible positions in the underground mine is done using attributes, and system functions within ProModel in order to allow for a highly flexible sequence of planned events and to reduce the level of effort in creating the ProModel processing. Considerable use of subroutines in the simulation model is utilized for parametric decision-making that is repetitive. This presentation describes the modeling techniques used to accurately simulate the surface and underground operations. The surface and underground operations are considerably different, thus they will be treated in their own sections.

Jan 1, 2002

By John P. Hunt

Early disseminated copper mineralization at Quebrada Blanca, Chile, accompanied 38 million year old quartz monzonite stocks and dikes. Early mineralization was followed by hydrothermal mineralization, mineralized breccias, and post-mineral faulting. After supergene leaching and enrichment, Quebrada Blanca was buried under late Tertiary gravels, and then partially re- exposed in Quaternary time. Based on work to date the orebody appears to contain more than one hundred million tons of plus one percent secondarily enriched copper ore, overlying several hundred million tons of protore averaging more than 0.5% copper. A source of industrial water appears to have been located. Pilot scale metallurgical tests, mine planning, and feasibility studies are in progress.

Jan 1, 1981

By Travis S. Wellman, Jon C. Volkwein

The Bureau of Mines conducted a study to assess the impact of a directional water spray system on a unique single inlet dust scrubber on a low profile mining machine. Tests were conducted in a full scale model mine using a Joy 12 CM 10-AA continuous mining machine. Tracer gas was introduced at the face and concentrations of the tracer gas were monitored at the face and in the return. Various parameters included: mining position, depth of cut, brattice setback and combinations of scrubber, directional sprays or symmetrical sprays. Results indicated that either directional or symmetrical water spray configuration improved the ventilation effectiveness of the scrubber by a factor of 2 to 3. Average face ventilation effectiveness (FVE) values for all testing of the scrubber and directional sprays were 0.95, versus 0.37 for a standard 6 m (20-ft) blowing curtain without sprays. No FVE values were less than the standard 6 m (20-ft) blowing results.

Jan 1, 1989

By Panshi Xie, Xicai Gao, Yi Luo, Youfu Zeng, Yongping Wu, Shenghu Luo

For the first time, surface subsidence prediction theory was used to investigate roof movement around longwall face mining in a steeply dipping coal seam. A physical simulation experiment was conducted to quantitatively study the roof migration patterns, the gob materials, and the characteristics of bed separation and compression caused by mining two adjacent panels to gain a better understanding of ground control issues in multipanel mining in steeply dipping seam. This approach provides an in-depth analysis of the movement of the roof. Compared to movement observation of survey point using total station, the Photogrammetry Analysis for Physical Modeling of Mine Subsidence Program (PAPMMSP) method is easier to perform, faster and yields the much higher accuracy required for scale physical modeling. It is also a more effective observation method for underground-mining physical simulation experiments.

By Hamed Khodadadi, Hamid Ghadiri

The ball mill grinding circuit has widespread application in mining, metallurgy, chemistry, pharmacy and research. It faces some challenges because a grinding circuit is a multivariable system in which high interaction between loops, variation of system parameters with time, and time delays are problems. In this study, a fuzzy logic self-tuning proportional–integral–derivative (FLST-PID) controller based on an improved disturbance observer is designed for control of ball mill grinding circuits. It is combined with an improved disturbance observer (IDOB) to eliminate system interaction, attenuate internal and external disturbances and compensate the effect of system uncertainty on the performance of the ball mill grinding circuit.

By R. Houot, C. Leschevin, G. Gillet

In mineral processing, conventional magnetic separators are equipped with traditional magnetic circuits (magnetic iron yoke with copper coils or iron-clad solenoid) that develop magnetic fields of less than 2 T'. For minerals of low magnetic susceptibility, use of these circuits has many disadvantages. Only a separator with a superconducting magnet can contribute to solving the problems and produce a high magnetic field. This paper presents and describes a magnetic separator having a superconducting magnet with integrated closed circuit for helium liquefaction. The system generator and maintenance are simplified by extensive automation realized by a versatile program- mable autocontrol unit. A comparative study if the results on concentration and purification of different raw materials with the new and with conventional separators is described.

Jan 1, 1987

By James A. Finch, Xiang Zhou, Yue Hua Tan

Widely used as collectors for nonsulfides, amines also show some frothing properties. Evaluating frother functions of amines and their combination with conventional frothers addresses whether one reagent delivering both collector and frother functions compromises the efficacy of either. From the findings, whether blending with frother confers any benefit requires knowledge of the residual amine concentration. If it is below about 10 ppm, blending eliminated coalescence, but there appears to be no benefit if the concentration is above 15 ppm.

By Leandro Augusto Viana Teixeira, Angela Avelar, Ruberlan Gomes Silva, Virginia S. T. Ciminelli, Daniel Majuste

Rare earth elements are essential for modern life products and green technologies. Recent supply constraints have boosted the development of rare earth projects after the price peak of 2011. The feasibility of a project depends on the definition of a processing route, which in turn depends primarily on the rare earth mineral, with monazite and bastnaesite representing the two most relevant minerals. Monazite-type ores usually contain high acid consumption impurities, such as iron, aluminum, calcium, magnesium and phosphates, and may also contain prohibitive levels of radioactive thorium in its composition. Based on thermodynamic analysis, the present work discusses the fundamentals of a selective process route for rare earth extraction from monazite ores with high iron content. This process involves sulfation by means of concentrated sulfuric acid and roasting at a high temperature. The route yields high rare earth extraction with low iron and thorium extraction and low acid consumption. Rare earth extractions as high as 80 percent were achieved, while iron and thorium extractions were lower than 1 percent, and acid consumption was lower than 0.34 kg of sulfuric acid per kg of ore. The operational window was compared to the one predicted by thermodynamic modeling, with 700 °C representing the optimal roasting temperature.

By Brenda B. Mehnert

Long-term monitoring is necessary to successfully develop predictive subsidence models. Thus, the Illinois Mine Subsidence Research Program (IMSRP) has documented subsidence over a longwall mine in south-central Illinois throughout a 3-year period. No monitoring results of this duration have been previously published for longwall mining in Illinois. To study the effects of surface subsidence and the rate of subsidence, precise level surveying was conducted at the site two or three times a year. Level surveys were conducted at approximately the same time of year using a WILD NA-2 level with a micrometer. Second-Order, Class-I, closure errors were obtained in each survey. Survey monuments were designed to minimize frost-induced movements. At this particular site in southern Illinois, subsidence over chain pillars and the panel centerline continued 3 years after mining. Since mining in 1988, 6.67 feet of subsidence or 70% of the extracted height has been documented over the panel centerline, with almost 0.30 feet in the last two years. The area over the chain pillars has subsided a total of 1.44 feet, with 0.44 feet occurring within the last 2 years. Monitoring over the chain pillars and at the centerline shows the residual subsidence to be fairly uniform. Monitoring is continuing over both of these areas. Long-term monitoring data can be used to improve evaluation of subsidence effects on land and structures. However, coal companies will time mitigation activities depending on other factors including the threshold of structural damage, type of repair needed, and maintenance of landowner and company relations.

Jan 1, 1986

By M. Galetakis, C. Roumpos

A sustainable coal industry needs to achieve a number objectives concerning mainly with superior utilisation of deposits and improved environmental performance. Modern quality control systems, which are greatly based on the on-line analysers, play an important role in achieving sustainability targets. This paper discusses the testing and application of on-line ash analysers installed in the Ptolemais and Megalopolis lignite mines in Greece and examines the possibility of using this type of analyser to control blending and homogenisation operations. The effect of the accuracy of on-line analyser to control process, when used for the characterization of low rank coals with complex and variable composition, such as greek lignites, is examined.

Jan 1, 2005

By P. Bevilacqua, G. Ferrara

Hydrocyclones and other dynamic separators are normally fed with pulps consisting of water and solid particles. The solids usually consist of particles of different sizes, shapes and densities. Except in the special case of monocharacteristic particles, the particles are segregated by these differences in size, shape and density. Segregation is magnified by the high values of centrifugal acceleration in the hydrocyclones. This paper develops a segregation theory that indicates the major variables involved. Experimental data on segregation under different operating conditions for mixtures of magnetite and/or ferrosilicon and nonmagnetic minerals are reported.

Jan 1, 1997

By YUSONG MIAO, DI WU, XIANRONG YAN, YIPING ZHANG, JIE LIN, KEBIN LI

Rock fragmentation has been a concern in hard-rock mining for the mining industry. Rock fragmentation distribution is an important index to measure the blasting effect. It not only affects the cost of drilling and blasting, but also affects the efficiency of subsequent operations, such as loading, transportation and secondary crushing.

By C. D. Hebert, T. Gregor, M. Ghazi, G. J. E. Kramer

This paper describes the recent application of gasketed, precast concrete segmental lining design that has improved tunneling productivity and quality. The speci?c segment arrangement includes: six-piece ring with equal 60 degree gasketed segments, juxtaposed key and counter-key segments, trapezoidal and parallelogram shaped segments, inclined and skewed radial joints and plastic circumferential joint connectors. This allows rapid, but accurate ring erection, reducing mine cycle times. The design avoids cruciform joints, minimizes potential gasket damage and eliminates the need for separate left and right ring molds. The implementation on the Los Angeles ECIS and NEIS sewer projects is described.

Jan 1, 2003

By Mark Leggett, Kevin Roberts

The need to modernise and increase the safety provision of older road tunnels raises challenges in maintaining the operation of the tunnel during such improvement works. The Mersey Kingsway twin road tunnels located in Liverpool UK, constructed in the late 1960s, have had three new cross passages constructed to allow emergency evacuation from one tunnel to the other tunnel and provide safer access for emergency services. The 3200m long road tunnels are lined with an unusual reinforced concrete steel-faced segmental lining with a paint finish. Construction of the cross passages occurred during night possessions with the tunnels returned to normal operation during the daytime. Constructed through water bearing sandstone and lined with precast concrete segments, the passages required advance ground treatment and support works. This paper presents the historical background to the Mersey Tunnels and describes the procurement strategy, design and construction approach adopted for these important safety improvements.

Jan 1, 2003