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By T. Bednarski, T. McCallum, L. Moya, B. Gay

"Molybdenum recovery by solvent extraction has gained interest partly due to advances in concentrate leach technology. Historically, both molybdenum and rhenium have been produced using amine-based extractants with the ability to co-extract both metals. Alternatively, a phosphinic acid-based extractant (CYANEX® 600) can be used depending on the flow sheet. CYANEX® 600 selectively extracts Mo leaving Re in the raffinate, which is a valuable feature in plants which require rejection of the rhenium from the molybdenum circuit. CYANEX® 600 piloting results are reviewed and compared to commercial experiences with an amine-based extractant. INTRODUCTION Molybdenum is most commonly found as molybdenite (MoS2) in primary porphyry deposits (about 59% of global reserves) and copper porphyries (about 39% of molybdenum reserves)[1]. Recovery from molybdenite traditionally involves flotation (concentrates typically containing 85 – 95% MoS2) followed by roasting to produce MoO3. Solvent extraction is also used to recover molybdenum from acidic aqueous solutions resulting from scrubbing of roaster and smelter off gasses and leaching of molybdenite (uranium ores). Molybdenum is also frequently found in low concentrations in copper leach inventories[2]. More recently, pressure oxidation has gained interest to treat molybdenite concentrates. Molybdenum Chemistry The chemistry of molybdenum is complex with a series of extractable species existing dependent on the pH and oxidation state as shown in Figure 1.Under strongly basic conditions, molybdenum primarily exists as MoO42- while under strongly acidic conditions MoO22+ becomes the predominant species. In between, a number of isopolymolybdates such as Mo7O246- and Mo8O264- are dominant. Equations (1) – (3) demonstrate some of the proposed molybdenum equilibrium reactions[1]."

Jan 1, 2017

By S. R. LaBrooy, J. Avraamides

Thermal reactivation of eluted carbon is an essential part of most carbon-in-pulp gold recovery plants. The effectiveness of the reactivation procedure depends on the nature and level of contaminants adsorbed on the carbon, the efficiency of the elution and the temperature, residence time and atmosphere within the kiln. The most commonly used kilns are evaluated in terms of their operating parameters and performance. Data obtained both in the laboratory and in the field emphasize the importance of carbon feed moisture content, kiln atmosphere and carbon conditioning on the activity of the kiln product.

Jan 1, 1998

By Jan Luca Grunow, Ansgar Bendiek, Klaus Böde

According to the Markowitz portfolio theory the value of a diversified portfolio is higher than the sum of the parts of a portfolio, which is an important consideration for the correct valuation. This is valid for real estate portfolios as well as for mining assets (or enterprises). This paper analyses the application of the portfolio theory to a diversified portfolio of assets in the real estate industry and draws conclusions on further research work to be done in the minerals industry. The volume of real estate transactions is increasing over recent years. As such, the nature of those transactions is constantly changing and in some cases portfolios become more heterogeneous as they are composed of different property categories, e.g. locations and types of use. This makes their economic evaluation more difficult. This paper focuses on the acquisition of a fairly heterogeneous real estate property portfolio purchased by “Commerz Real” in Germany in Q4 2019. For economic evaluation the widely used Markowitz portfolio theory (Markowitz, 1952) was applied. It was investigated whether diversification effects could achieve added value in the form of a reduction in risk compared to the sum of their individual components. As a result the findings of this research could be applied to other heterogeneous real estate transactions and even to mine property portfolio or PPP1 project portfolio transactions.

Jun 25, 2023

By S. E. Vanderslice, J. A. Hummer

"The results of laboratory evaluations were used to compare the potential of two alternative, biomass-derived fuels as a control strategy to reduce the exposure of underground miners to aerosols and gases emitted by diesel-powered equipment. The effects of fatty acid methyl ester (FAME) biodiesel and hydrotreated vegetable oil renewable diesel (HVORD) on criteria aerosol and gaseous emissions from an older-technology, naturally aspirated, mechanically controlled engine equipped with a diesel oxidation catalytic converter were compared with those of widely used petroleum-derived, ultralow-sulfur diesels (ULSDs). The emissions were characterized for four selected steady-state conditions. When fueled with FAME biodiesel and HVORD, the engine emitted less aerosols by total particulate mass, total carbon mass, elemental carbon mass and total number than when it was fueled with ULSDs. Compared with ULSDs, FAME biodiesel and HVORD produced aerosols that were characterized by single modal distributions, smaller count median diameters, and lower total and peak concentrations. For the majority of test cases, FAME biodiesel and HVORD favorably affected nitric oxide (NO) and adversely affected nitrogen dioxide (NO2) generation. Therefore, the use of these alternative fuels appears to be a viable tool for the underground mining industry to address the issues related to emissions from diesel engines, and to transition toward more universal solutions provided by advanced engines with integrated exhaust aftertreatment technologies. IntroductionDiesel engines have been the workhorses of modern society for industrial and transportation enterprises. Diesel engines of all generations are extensively used in a variety of light-, medium- and heavy-duty applications in underground mining operations around the world. Fuels obtained from various sources and with wide-ranging chemistries have been combusted in diesel engines. However, the bulk of the currently used fuel can still be traced to nonrenewable petroleum sources. The petroleum-derived diesel fuels are primarily made up of saturated acyclic hydrocarbons (parafins or alkanes), aromatic hydrocarbons (arenes or aryl hydrocarbon), and unsaturated hydrocarbons with double bonds (olefins and alkenes). Improvements in the quality of petroleum-based diesel fuels was identified in federal regulations as an important piece in resolving the puzzle of diesel engine emissions (Environmental Protection Agency, 2001, 2004). The reduction of U.S. diesel fuel sulfur content below 15 ppm had the effect of lowering sulfate emissions and enabling the development and implementation of catalyzed emissions control technology across a wide spectrum of applications."

Jan 12, 2017

By Frank E. McCall, John K. Marshal, Fred Garcia

Since the advent of longwall mining systems in the United States, mine operators are increasingly relying on methane drainage techniques to supplement the ventilation system. The most commonly used technique is the vertical gob borehole. The number and spacing of vertical gob boreholes per panel is generally based on experience and underground conditions. To design a more efficient methane drainage systems, mine operators must accurately determine methane gas produced. Thus, mine operators must monitor gas flow and methane gas concentration on every vertical gob borehole on active panels at least once or twice during each 8-hr shift. As the mine grows, it is possible to have more than one operating longwall and many vertical gob boreholes. Thus, daily visits to each vertical gob borehole site can become very time consuming. During weekends when methane gas concentrations typically drop because there is no mining activity, borehole sites may not be visited. To obtain accurate gas flow data, a gob borehole monitoring system was designed and constructed by the U.S. Bureau of Mines (USBM). Gas flow, methane gas concentration, gas temperature, barometric pressure, and vacuum pressure of the exhaust fan are the parameters collected by the system. The system also includes circuitry for automatic shutdown of the exhaust fan and an alarm system before an unsafe condition is created. Telemetry components were also integrated into the system to allow for transmission of borehole data to the mine office. As a test, the system was installed and operated on a vertical gob borehole for six months. Test results indicated that intermittent measurements with hand-held instruments from vertical gob boreholes were always higher than gas flows measurements made by the gob gas analyzer system. This paper describes the system components, operational characteristics, and the results of the test program.

Jan 1, 1995

By C. Maltesh

Anionic conditioning of phosphate ores prior to fatty acid flotation is a very critical step that determines the eventual selectivity, recovery and hence the economics of the process. However the chemical mechanisms operating during this conditioning step are not established. Several studies have been conducted in the past to determine the mode of interaction of collectors with the phosphate fractions however these have been done on a laboratory scale using pure phosphate minerals. In order to test the relevance of the observed effects to plant practice in this work a comprehensive survey of plant practice was first conducted and then adsorption on flotation feed and francolite were studied under simulated plant conditions. Effects of conditioning energy and water chemistry as well as solids loading and fuel oil were determined. Most importantly, different adsorption mechanisms were found to be dominant under laboratory and plant conditions. In plant water, there was some physisorption of oleic acid on phosphate flotation feed and francolite in addition to chemisorption. However, in distilled water under laboratory conditions only chemisorption was detected. Fuel oil reduced the residual oleic acid in solution after adsorption, which explains the beneficial role of extender in phosphate flotation. The dissolved species in solution arising from the flotation feed or plant processing water are shown to clearly play a major role in determining the adsorption of oleic acid on the substrates. The study also specifically demonstrates the importance of conducting research tests under plant mixing conditions and plant water chemistry for the results to be useful commercially.

Jan 1, 1996

By G. B. Amicucci

A Denver Autometrics Particle Size Monitor, PSM-400, was installed at Golden Sunlight Mines, Inc. in October 1988. The PSM-400 measures the grind product's particle size and percent solids. The particle size is used to control grind size by automatically adjusting mill feed rate. The PSM's continuous response to ore changes has improved grind product uniformity and mill throughput. Metallurgical testing has shown the PSM's accuracy to be +/-1 % + 150 µm (100 mesh).

Jan 1, 1991

Optimal gold recoveries largely depend on efficient liberation of the gold or gold-bearing minerals as well as on maximum access for the lixiviant. Thus, crushing and grinding may become the most costly part of gold ore processing. It may, in fact, represent 50% to 70% of a plant's operating costs (Michaelis, 1989). The increasing significance of refractory gold will require even more cost-efficient comminution of ultrafine sulfides and/or native gold. Transitional ore zones with semi refractory gold may respond to direct leaching if better particle fracturing is being achieved (Baum, 1991, 1993a). Many oxide ores have been left in the ground because they were unsuitable for heap leaching since conventional comminution could not facilitate economic gold extraction. Also, the costs of conventional bal1 mill operations did not permit the recovery of gold from many ultrafine, low-grade refractory ores. As shown by Marsden et al. (1993), the trend to treat ores with progressively lower grades will involve power-and leach-efficient grinding applications. Our current laboratory work shows that high-pressure grinding roll (HPGR) Polycom grinding may enable many mining companies to add large amounts of these "non-leachable" ores to their current heap or mill leach feeds. This finding may dramatically change the economics of many oxide gold ore operations and may add significant reserves to ores amenable to direct cyanidation.

Jan 1, 1994

By C. L. Lin

A PC image-based, on-line instrument for the measurement of coarse particle size on a conveyor belt is under development. Both the hardware and software required to implement such a system are discussed, including the interface for the special image acquisition hardware. The system concept is given with examples to illustrate the step-by-step procedure for the implementation of image-processing algorithms.

Jan 1, 1992

By Todd Kilduff, Ryan O’Connell

Pipe canopies continue to gain momentum as a reliable methodology for construction of excavations below critical facilities with minimal surface settlement tolerances, such as railroads or roadways. Two tunnel projects designed by Kilduff Underground Engineering in the Salt Lake City, UT area, each at varying stages of completion, had project design criteria for selection of a tunneling methodology to minimize surface settlement. Both projects consist of a pedestrian tunnel, one crossing beneath a major roadway in downtown Salt Lake City and the second beneath UPRR tracks. Both projects were in difficult, coarse alluvium/fan ground conditions with project criteria that resulted in minimal cover above the tunnel. For each project, a pre-support pipe canopy was designed, requiring the placement of steel, canopy pipes driven the extent of the tunnel length. The pipe canopy is installed using a trenchless technology and then excavated with SEM tunneling and shoring provided by traditional support of excavation methods. The pipe canopy pre-support method offers a low-impact method to install an underpass beneath critical structures by adding significant stiffness to the subgrade to mitigate surface settlement during the main tunnel excavation sequence. These case studies seek to communicate the challenges associated with pipe canopy installation in site-specific ground conditions and explains how these challenges were overcome. This paper aims to define the project risks and describes the pipe canopy methodology as a viable solution to mitigate surface settlement in low cover tunneling scenarios.

Jun 13, 2023

By Stanley M. Moos

In reviewing available vacuum filtration equipment in this paper, several types of filters have been included which are probably not familiar to operators in the mining industry. However, it was felt that these units might be of interest in the event that an application should arise for the filtration of a product in the future that does not exist today. In addition, exposure of our industry to equipment used in other industries might have a tendency to be thought provoking and perhaps lead to the development of equipment and/or applications in our industry which do not necessarily exist at this time. Most innovations in filtration equipment have been confined to the improvement or design change of components and accessories, particularly reflecting the availability of materials of construction that have been developed. Recent developments in the application of horizontal belt filters have been innovative. The application of this unit as a substitute for or an adjunct to thickeners in a CO circuit can certainly be innovative and perhaps provide a basis for reduction in capital and operating costs in this area. For example, mill tails are generally pumped at the highest possible density that will adequately flow. Tailings ponds and dams with their attendant design requirements are based upon this estimated water volume. Availability of a much dryer, non-flowing filter cake opens up several new options for disposal. Considerable cost savings could result in the design and planning of disposal areas for containing dryer material. . No attempt has been made in this paper to provide a manual for the operation of all of the many types of equipment that are available. Rather, the paper tries to present an overview.

Jan 1, 1978

By Rong Lu, Hao Wu, Bing Dai, Guoyan Zhao, Li Cheng, Weizhang Liang

Affected by the disturbance of blasting activities, deformation instability and rock dynamic disasters are prone to occur in deep hard rock roadways. Thus, it is particularly necessary to understand the failure behavior of rocks and roadways under dynamic loads. In this study, a series of impact loading tests were carried out on sandstone samples with and without a circular cavity by a modified split Hopkinson pressure bar (SHPB) test system. The mechanical properties and energy evolution of the samples were systematically investigated, and the effect of cavity size was analyzed. The results showed that the presence of the cavity in the samples weakens the dynamic compressive strength by more than 10%, and the peak strain and brittleness are also reduced to varying degrees. Under dynamic loading, spalling cracks occur first on the roof and floor of the cavity, and then different numbers of shear cracks are formed on the sample diagonals. The eventual shear failure mode is the result of the connection of the shear cracks and the cavity. As the cavity radius increases, the dissipated energy density and fractal dimension both grow accordingly, leading to smaller and smaller rock fragments. The dynamic failure behavior of the circular cavity can be well explained based on the dynamic stress distribution law. Overall, this study can provide a reference for the study of the mechanism of rock burst in deep roadways.

Feb 18, 2021

By R. J. Nankee

Coal is our most abundant, low cost energy resource. Expansion of its use is being challenged due to "SO2 emission" regulation with even more restrictive legislation pending. High quality coal reserves are becoming more limited due to greater use in recent years. Aids to allow more use of coal in today's environment include beneficiation of coal before combustion and scrubbing the emissions from coal during combustion. Dow's efforts to help meet these challenges by beneficiating coal include true heavy media gravity separations with chlorinated solvents and liquid/liquid partitioning processes and "Dow Solvent Recovery Technology" to recover the solvent from product (or floats) and rejects (sinks), The objectives of the efforts to clean coal are to reduce sulfur and ash. In this paper, the solvents will be described; a general flow diagram presented; some of the results on upgrading various coals will be described, and projected costs of full-scale plants using chlorinated solvents will be compared to conventional cleaning plants.

Jan 1, 1985

By Andrew J. Petruska, Austin F. Oltmanns

The paper proposes a capacitive load cell for detecting changes in material and tool wear conditions for conical picks used in underground mining. The current process is dangerous and subjective, relying on human operators near the cutting interface. The new sensor aims to improve worker safety by allowing operators to perform their functions from a greater distance.

Aug 1, 2023

By Ehsan Moosavi, Kamyar Tolouei, Mehran Gholinejad

The literature defines rockbursts in slightly different ways based on their generation mechanisms, field phenomena, and degree of damage, but in a way that is almost consistent. Generally, a rockburst refers to seismic events that mainly happen in underground excavations, for purposes such as underground mining, road and railway tunnels, nuclear power, etc., and that are followed by the collapse and outburst of rocks. Long-term rockburst prediction can be abstracted as a classification problem mathematically, in which we can introduce deep learning to solve it. Further, using deep learning in rockburst prediction can overcome drawbacks such as subjectivity and inconsistency brought from previous traditional approaches. A rockburst data-set, was employed to evaluate the current method for predicting rockburst grade, and the good results of overall success rate were obtained. The results indicated that the proposed algorithms can speed up parameter optimization search, the proposed method is robust model and might hold a high potential to become a useful tool in rockburst prediction research.

Apr 26, 2022

By S. Uihteenmaki

Pyhasalmi is a massive sulfide orebody located in central Finland. The mine has been in operation since 1962. The flotation concentrator produces Cu, Zn, Pb and pyrite concentrates. The plant has used an on-stream analyzer for process control since 1968. The original analyzer has overlived a few generations of minicomputers, but the analytical parts are essentially unchanged. The on-stream analyzer is a critical component in plant process control system, which has made Pyhasaltni one of the pioneers in the art of computer control and optimization of flotation plants. The paper summarizes the experiences gained from the use of the high performance elemental analyzer system and the proven benefits from the use of on-stream analyzers at a complex sulfide flotation. The aging analyzer is approaching the end of its useful life. A new state of the art analyzer system is undergoing testing at Pyhasalmi.

Jan 1, 1999

By ANGELA NAIR AVELAR, Reiner Neumann, PAULO R. G. BRANDÃO

Three types of apatite were identified by means of cathodoluminescence (CL) images in flotation concentrate and tailing samples from the Catalão Mine in Brazil. They are predominantly blue apatite, followed by green apatite and, less frequently, yellow apatite. The chemical compositions of these types of apatite were determined by electron microprobe analysis and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Blue and green apatite responded well to the process, thus remaining in the concentrate, while yellow apatite remained in the tailings. Yellow apatite has the lowest phosphorus pentoxide (P2O5 ) content and largest anionic and cationic sites substitution, followed by green apatite, whereas blue apatite is the most homogeneous, with highest phosphorus (P) and calcium (Ca) grades and lowest substitution level.

By Kanaan Hanna, Mir Heydari, Dipack Sengupta, Gordon B. French

This article, first in two, discusses the safety, technology, and economic impact of eliminating safety fuse from metal and nonmetal mines. It is based on operation and manufacturer experience over the past five to 10 years. If safety fuse is eliminated, blasting accidents will decrease. There should be only limited technical impact. The economic impact will be minor for large operations, but will be significant enough for small operations that some will likely close rather than change. Most mines would probably change over, with the market absorbing the extra cost. Elimination of safety fuse would obviously have an impact on the two safety fuse manufacturers. One manufacturer produces an alternative system and would be unaffected. The other, however, will be affected if it does not change its production strategy. From the standpoint of employment and production, abolishing safety fuse will have a very minor effect on the mining industry as a whole. This article discusses the current use of initiation systems, incidence of accidents, and fuse consumption. Next month, part two describes the economic impact of eliminating safety fuse on the mining industry and manufacturers, and presents an economic analysis of the initiation systems. Introduction The objective of this study was to determine the safety, technology, and economics of eliminating safety fuse from metal and non-metal mines. There were five major tasks: • Studying initiation-related accidents from the Health and Safety Accident Center (HSAC) data file; • Visiting mines, collecting relevant data, and interviewing mine operators; • Establishing the trend in safety fuse consumption and type of users; • Corresponding with fuse manufacturers, domestic and foreign; and • Developing an idealized blasting cycle to evaluate the possible economic impact of safety fuse elimination on large and small operations. More than 450 explosives-related accident reports have been screened and analyzed by investigating HSAC files. These reports have been studied and classified according to the four initiation systems, size and type of mines, and time and frequency of accidents from 1973 through 1978. Twenty-four mining operations were visited to obtain supporting data for this study. Mine personnel were interviewed to determine attitudes about safety fuse and alternative detonating systems. This article decribes available data. It also attempts to provide information that can be used to answer such questions as: • Is the use of safety fuse (an antiquated detonation system) a major cause of mining accidents? • Are alternative systems available that could result in fewer in-juries to miners?

Jan 1, 1984

By M. E. Poad

In 1986, a cooperative effort by the Homestake Mining company, the U.S. Bureau of Mines and the University of Utah was initiated to determine shaft stability while recovering high grade ore in a nearby pillar. Premining finite element simulations indicated the shaft would remain in elastic ground. Six years have elapsed and, despite some initial concern during the first lifts, it appears that the bulk of the original reserve will be safely and profitably recovered. An integrated application of rock mechanics tools from laboratory testing through numerical modelling to mine measurements and observations contributed substantially to the operational success of the project.

Jan 1, 1994

By Edward (Ted) M. Dowey

Shaft 26B of New York City’s Third Water Tunnel was constructed by Frontier-Kemper Constructors, Inc. of Evansville, Indiana. The 176.8 m (580 ft) deep shaft will serve as the construction shaft for the Manhattan spur of Water Tunnel No. 3. Twelve m (40 ft) of over-burden was supported by a rectangular cofferdam. This shaft was excavated in 13 months, through 164.6 m (540 ft) of rock, using 24,040 kg (26.5 tons) of explosives. Concrete lining cycles included the installation of stainless steel pipes embedded in the lining as the shaft advanced. A total of 635 m (2,084 linear feet) of stainless steel pipe was installed.

Jan 1, 1997