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By Yeonuk Choi, Gus Van Weert

cyanide control in effluents is becoming a critical environmental issue for the gold extraction industry. Silver impregnated carbon removes free cyanide effectively to the ppb level from solution in high throughput columns. By re-calcining the cyanide saturated carbon, the impregnated silver is restored to activity and the cyanide destroyed outside the effluent stream. Many gold mills already have an activation kiln on site, which could make retrofit relatively easy.

Jan 1, 1993

By Tracy Braun, Dan Lampshire

Over the past decade, heap leaching at Cortez has evolved from a rather small operation producing around 30,000 ounces per year of gold to an operation scheduled to produce over 400,000 ounces in 2004. Evolution and expansions in the heap leach operations are discussed including plant design criteria and some of the design features in the various facilities. Operating parameters and production forecasting are also discussed.

Jan 1, 2005

By Corale L. Brierley

This paper lists commercial bioheap and stirred tank bioleach operations and explains the status of these operations. A total of 17 commercial-scale bioleaching plants have been commissioned. Bioleaching plants are divided into two technology applications: bioheaps and aerated stirred­tanks. In bioheap leaching, secondary copper ores or sulfidic refractory precious metal ores are crushed and bioleached on pads. Stirred-tank technology is used to bioleach base and precious metal concentrates.

Jan 1, 1999

By R. R. Pierce, C. E. Semler, K. G. Thomas, R. A. Williams, H. J. . H. Pieterse

This paper highlights the experience and knowledge gained at Barrick Goldstrike Mines Inc. with reference to the pressure oxidation circuit. Particular attention is given to the different linings employed on the autoclaves, flash and condenser vessels. Experience gained during the three years of operation is given. A test program and results are discussed. Quality assurance is highlighted. Barrick Goldstrike is 100% owned by American Barrick Resources Corporation, Toronto, Ontario, Canada.

Jan 1, 1993

By W. C. Labys

This chapter reports on recent modelling effects to analyze the US steam coal market with an econometric as well as a programming approach. The background to coal modelling is examined first. The particular aspects of the steam coal market to be modelled are then presented and the corresponding coal model described. Empirical results are presented and analyzed. Conclusions are then drawn regarding potential modelling applications in the policy area.

Jan 1, 1979

By W. H. Jay, F. Lawson, D. F. A. Koch

Ion exchange resins may in the future displace activated carbon in gold plants where cyanidation is practiced. Recently patented technology based on interpenetrated polyurethane polymers shows that these new materials offer significantly improved loading kinetics over both activated carbon and commercially available ion exchange resins. These polymers are not restricted either in particle size or in density and therefore offer the gold industry the potential for a further technological advancement.

Jan 1, 1995

By Robert J. Storms, David J. Malone, Thomas E. Crandall

Corrosion and abrasion have been present in hydrometallurgical processes for many years. Ceramic lining materials have been used in several applications to protect process vessels from the corrosive and abrasive effects of a wide range of ore slurry processes. This paper reviews the history of ceramic lining systems utilized in hydrometallurgical vessels, the commercial benefits associated with their use, and additional areas of opportunity for the Mining Industry.

Jan 1, 1995

By Claus Becker

In Europe, approx. 50 km of traffic tunnels are under construction using Slurry-or EPB Shields or Convertibles of all sizes, among them the biggest slurry shield ever built up to now with 14,20 m diameter. Main characteristics and special features of the machines will be explained relating to geology, cover and water pressure. This gives a comprehensive overview of the latest developments of this kind of machines.

Jan 1, 1999

By V. Nenov

The study is based on the so called METASEP process which includes selective sorption of heavy metals by special bonding agents (BA), separation of boding agents from the water by means of microfiltration and/or flotation and regenerating the loaded bonding agents, leading to a metal concentrate for reuse or discharge. The bonding abilities of different bonding agents suitable for application in METASEP process were evaluated. Two groups of BA are studied, namely: chelating ion exchange resins and water soluble oligomers. The group of ion exchange resins studied includes eight organic resins, mostly chelating cation exchangers and representatives of conventional strong and weak cation exchangers. The resins with iminodiacetic and aminomethyl phosphoric acid groups showed highest affinity towards several heavy metals. The study of resin particle size showed that this parameter is a key factor influencing the kinetics of heavy metal sorption. The group of water soluble oligomers (WSO) includes polyvinyl alcohol, carboxyl-methyl-cellulose, polyvinylethylenimin and pectin. The Metal-WSO complexes were separated by Ultra Filtration. The effect of Metal-WSO mole ratio and pH was studied. Depending on the operational conditions the heavy metal retention varies within 68-99%. It was shown that regardless of pH and mole ratio Metal-WSO, separation of certain ion from the metal mixture is not possible.

Jan 1, 2006

By Andreas Rubo, Stephen Gos

Over the past couple of decades several endeavours have been made to develop lixiviants with the intention of replacing cyanide in gold leaching. In 1980s these endeavours were largely economically driven, due to cyanide shortages at that time. In more recent times, the driving force has shifted to occupational health and environmental considerations. It is often argued that the high acute toxicity of cyanide alone makes it worthwhile considering to replace it completely by less toxic alternative lixiviants. This has led to having to consider more criteria in the choice of any alternative lixiviants, which have often not been taken into account in the past. The intention of this paper is to review these alternative lixiviants and also review the criteria, which have ultimately led to most of these lixiviants never having found any large scale application, if they passed laboratory stage at all. It is also intended to show, that by handling and treating cyanide in a proper manner, the overall profile for the use of cyanide compared to these alternative lixiviants is very favourable. The question to really be answered is whether there is actually any chemical or process applicable to gold leaching that does not show the high toxicity potential of cyanide and that is still favourable with regard to looking at a broader spectrum of criteria and not only acute toxicity.

Jan 1, 2000

By Kathleen A. Altman

INTRODUCTION The basic premise of the ideas presented in this paper are as follows: Engineers believe that "theoretically" it will work. Operators ask what they must do to make it work. And, people can screw it up. r Today the challenges conf onted during the engineering, startup and operation of mines are becoming more complex. As mining and processing professionals, we are called upon to trav­el all over the world, are subjected to a wide variety of climates and must deal with a numerous cultures and people. Historically, for the majority of the people working in the mining industry, the primary challenges related to projects have focused on the differing perspectives of the disciplines involved. For example, geologists focus on resources and reserves, mining engineers relate to tons or tonnes, metallurgists count ounces or pounds or kilograms of product, mechanics emphasize availabil­ity, human resources personnel deal with absentee rates and turnover and accountants watch the bottom line ($$'s). As the world has become "smaller" and the mining industry has become more globalized, the puzzle is becoming increasingly difficult. Even the most experienced in the crowd of mining profes­sionals are oftentimes surprised by the types of problems that are encountered. Try as we may, we cannot anticipate the complex­ity of dealing with the human side of an operation.

Jan 1, 1998

By David C. Sanders, Rodney H. Sergent, Victor C. Storhok, Batric Pesic

In the past, considerable work has been done on the applica­bility of bromine chemistry in the extractive metallurgy of gold. While the research in this area spanned from the understanding of fundamental dissolution chemistry to the demonstration on a pilot plant scale, no work was done on the fate of discarded leach residues with respect to the stability of accompanied heavy met­als. Because the leach residues were the discharge products of halide/halogen systems, the general perception was that the con­tained heavy metals would be more susceptible to dissolution than in typical sulfate systems, thus causing increased environ­mental problems. A long-term study was performed to obtain the information on the stability of heavy metals contained in the leaching residues after bromination. The study involved the leach residues of three different ores, as well the precipitates prepared from the synthetic solutions (not presented here). The conclusion of this study is that the stability of solid residues produced by bromination leaching was same as the sta­bility of leach residues produced by leaching in the sulfate sys­tems. Also, contrary to the past expectations, the presence of bromide ions in the test solutions (up to 1 g/L NaBr) did not enhance the solubility of heavy metals (Cu, Zn, Pb, As) beyond the solubilities found in the sulfate systems.

Jan 1, 1998

By Antonio Peralta

Mining activity in Mexico began in the 16th century when the Spanish realized the mining potential of the new territory. Since that time, mining has evolved into a strong and vital industry for the country. Good professionals in the mining-related fields are fundamental to the growth and improvement of this industry. Since the end of the 18th century, formal education in mining has been available at the University of Guanajuato, in Guanajuato, Mexico. This school created one of the first schools of mines on the North American continent in 1828. In recent times, some other programs have been created at other universities. Universities offering mining related programs Listed here are the seven universities in Mexico that offer mining related degrees. They are the University of Guanajuato, UNAM, the University of Zacatecas, the University of Chihuahua, the University of Sonora, the University of Coahuila and the University of San Luis Potosi. The University of Guanajuato is the only Mexican university that offers graduate studies at the master's level. No PhD programs in mining engineering are offered at any Mexican university. Programs at each university are of different duration. They are: • University of Guanajuato-Five-and-a-half years, divided into five years of classroom instruction and six months in the working place. • University of Zacatecas - Five years of classroom instruction.

Jan 1, 1994

By Walter Hoecker

The dissolution of gold in cyanide_ leaching has been we11 published with the genera1 acceptance that gold is oxidised by oxygen and stabilized by complexation with cyanide [1]. The dissolution of gold is essentially an electrochemical process. The rate of the anodic gold dissolution is controlled by the cyanide concentration. - (2) While the cathode reduction of oxygen is controlled by dissolved oxygen concentration - (3) There are a number of factors influencing the concentration of oxygen, and if 1owered substanth.lly will effect the efficiency of the leaching plant. These include: "' salinity "' temperature "'partial pressure "'oxygen consumption rate The use of pure oxygen for· cyanidation is only beneficial if oxygen is rate limiting, Conversely a slurry saturated with air (typically 5 - 8 ppm) may not be enough for maximum leach rate. The diagram below shows the maximum dissolved oxygen levels obtainable with pure oxygen and air. DISSOLVED OXYGEN (MAXIMUM) IN WATER At steady state, the rate of the cathodic reaction must equal the rate of the anodic reaction. Thus the rate of gold dissolution is dependent on both the· cyanide and oxygen concentrations. - (4) Using an average of Do/Den =· 1.5 [2] (where Do and Den are the oxygen and cyanide diffusion coefficients) the table below illustrates the maximum effective oxygen concentrations for given cyanide levels in clean water [3].

Jan 1, 1992

By Barry A. Hillman

The rapid evolution of computer and field sensor technology is now providing the ability to integrate mine and office opera­tions. Digital maps and mine plans as well as CAD and GIS can be transferred to ruggcdized field computers for development of real-time mine surveys and real-time GPS machine navigation and monitoring. Surveyors can insure that their surveys arc accu­rate before returning to the office. Engineers and surveyors are also able to upload field computer-based surveys to mine plan­ning software and directly to mine equipment including shovels, drills, and dozers providing the operator of the equipment with a real-time view of their work space. Production information can be transmitted through dispatch and/or centralized mine servers to update mine plans with mining progress and production data. Static mine models then become a dynamic element of opera­tions, providing greater use of information that emphasizes the spatial aspects of the mine by providing real-time maps, produc­tivity charts, and graphs. This information can be disseminated through various mine communication systems to provide opera­tors and management with real-time feedback as well as daily and weekly reports. Integrated systems now being used in exten­sive trials arc reporting productivity increases of 4 - 7% or more thereby providing rapid payback to the mine.

Jan 1, 1998

By Denis McDermott

This paper describes the process used at three mines to devel­op safety and training programs. The mines are located in Australia, New Zealand and the United States of America. The aims of the programs were to promote and reinforce safe and healthy behaviour, increase productivity and efficiency and to provide a fair and objective basis for the payment of wages. There were common aspects to each of the projects: • mandatory legislation required employers to provide employ­ee training in work performance • employees had little previous involvement in the design and development of the training provided • training had been unstructured with employees relying on the "buddy system" to acquire new skills; the degree of skill acquired by an employee depended on the knowledge and teach­ing capacity of the worker to whom the novice was assigned • appointments and promotions had been based on judgements by supervisors and these were not generally understood by employees • employment conditions for employees were covered by an industrial agreement between management, unions and employ­ees. The degree of sophistication of the industrial agreements varied however none provided a description of work performed in each classification, nor the career or promotional path for an individual • supervisors with the responsibility to train, develop, motivate and reward employees expressed concern that there were no structured processes ( eg work standards or wage progression cri­teria) to support their role.

Jan 1, 1998

By S. A. Bunk, W. P. Wood

In the early 1980's BHP identified several potential gold deposits in West Africa. One of these deposits was located in Mali, near the village of Syama. As a result of extensive explo­ration activities, an oxide ore as well as an underlying sulphide ore was identified. After agreement with the government of Mali was reached the development of the deposit was undertak­en. The plan for the development of the mine included the treat­ment of the oxide ore followed by the treatment of the underly­ing transition and sulphide ore. The development of the deposit was extremely aggressive. Following the approval of the project in early 1989, engineer­ing was started, equipment purchased sitework was started, and the first ore was introduced in December of 1989. This was accomplished in spite of the difficulties of the site. These diffi­culties included: • remote site location without air or road or water access • no existing infrastructure including water, power, or communication • high health risks • limited construction and manufacturing support in West Africa The operation began with a conventional crushing/grind-ing/CIL/elution and electrowinning facility. The facility was designed to treat 2000 metric tonnes of ore per day. After start­up in December of 1989, the operation was improved to the point that plant throughput was averaging nearly 3000 tpd and running at 92 to 93% availability.

Jan 1, 1996

By A. Iordanidis

Ieropigi Fe-Ni deposit is located in northern Greece, in Kastoria?s prefecture near Albania?s borders. A laterite profile exposed by opencast mining and placed near the basement of the mine was chosen for sampling. Ten samples, representing ?pure? Fe-Ni ore, ophiolite-bedrock, ?red? ophiolite and ?enriched? ophiolite were collected, based on macroscopic observation. The samples were analysed by X-Ray powder Diffraction (XRD) for the determination of the mineral phases. Iron and Nickel concentrations of the same samples were also determined by X-Ray Fluorescence (XRF) methodology. The Fe-Ni ore samples consists predomi-nantly of hematite, goethite, chrysotile (serpentine), saponite and quartz. ?Red? ophiolite samples consists mainly of chrysotile, hematite, quartz, calcite and small amounts of paragonite and goethite. Bedrock and ?enriched ophiolite samples are comprised of chrysotile, hematite, calcite, quartz, nontronite, paragonite and sepiolite. The Fe content ranges between 13% and 49% in Fe-Ni ore samples and between 7% and 10% in ophiolite samples. The Ni content ranges between 1% and 3% in Fe-Ni ore samples and between 0.3% and 4.5% in ophiolite samples (the higher content is observed in the so-called ?enriched? ophiolite). A correlation between Fe-Ni concentrations and mineral assemblages is being attempted in order to evaluate the nickel-rich mineral phases. It is shown that the nickeliferous minerals are serpentine, hematite, goethite and saponite.

Jan 1, 2006

By Ora H. Rostad

Some gold production was obtained from placer deposits in Puerto Rico during the period of Spanish colonial rule, but most of the gold was produced prior to 1536. There had been no significant hard rock mining, other than in quarries for road metal or construction purposes or for raw materials to make cement, prior to 1954 when the government of the Commonwealth of Puerto Rico recognized that changes in the mining code were necessary to stimulate exploration for metalliferous ore deposits. The Puerto Rican Legislature passed an act (No. 6), which was approved on Oct. 6, 1954, that reiterated that the title to all "commercial minerals" is vested in the Commonwealth of Puerto Rico. The act provided for the establishment of a Mining Commission, stipulated the power% with which the Mining Commission was vested, and provided that no one may dispose of "commercial minerals" in Puerto Rico without a Commonwealth grant issued on its behalf by the Mining Commission. Act No. 6 also provided for prospecting permits, mining leases, and grants. The Mining Commission, by authority granted to it by Act No. 6, adopted regulations effective Nov. 21, 1957, relating to prospecting, leasing, and producing commercial minerals in Puerto Rico. Royalty rates were also specified for various types of deposits at different annual tonnage production levels.

Jan 1, 1991

By Paul G. Schmidt

Exxon Minerals Co. was exploring for mineral deposits in Precambrian terranes of the US portion of the Lake Superior region in the late 1960s. Exploration drilling and other activities had been concentrated on massive sulfide prospects in northeastern Minnesota, but general exploration studies and competitor scouting were conducted in other areas of the region. These activities drew attention to Wisconsin in 1969 when it became apparent that Bear Creek Mining Co. had made a discovery near Ladysmith in the northwestern part of the state. Observation of their drill hole pattern suggested that a massive sulfide deposit, since named the Flambeau deposit (Schwenk, 1977), had been found. With this background, Exxon initiated an exploration program for Precambrian massive sulfide deposits in northern Wisconsin in 1970 (Figs. 1 and 2). Northern Wisconsin is extensively mantled by Pleistocene glacial drift and bedrock outcrop is sparse. Other than iron mines in the extensive iron formations along the Wisconsin-Michigan border and Jackson County, no significant mineral deposits were known in the Wisconsin portion of the Precambrian Shield until the discovery of the Flambeau deposit. Until the mid-1970s, the only specific published literature on the Wisconsin Precambrian consisted of old outcrop locations and descriptions in journals of the Wisconsin Geological and Natural History Survey (Chamberlain, 1882; [ ] Weidman, 1907; Hotchkiss, 1915) and the summary maps of Dutton and Bradley (1970).

Jan 1, 1991