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By S. D. Hill

State-of-the art precious metal recovery practice uses cyanide leach solutions to extract the valuable constituents from ores, wastes, and tailings. Activated carbon is then used as an adsorbent in either a carbon-in-pulp system or counter-current flow columns to concentrate and recover the precious metals. Existing techniques for recovering precious metals from carbon prior to the precipitation or electrowinning of the metal involve either the use of dilute aqueous hydroxide solutions at elevated temperature and pressure or, as in a more recent method, the use of a strong cyanide soak followed by a water strip solution at an elevated temperature. Despite past Bureau efforts in the area of precious metal recovery, the ex- traction of gold from pregnant leach solutions remains the most serious drawback in carbon-in- pulp and heap leach processing of low-grade ores containing precious metal values. A second disadvantage in the current practice is the interference in adsorption and desorption that occurs due to the presence of other heavy metal cations in cyanide leach solutions. Specific objectives of current Salt Lake City Research Center precious metals research are to develop less energy intensive and more economic methods for recovering gold, silver, and by- product metals from low-grade resources. To meet these objectives, we are investigating noncyanide leaching reagents, ion exchange resins, solvent extractants, and novel electrowinnlng procedures.

Jan 1, 1984

By W. A. Haley

The use of diesel engines in underground hard-rock mines dates back to the late 1940s. For the first several years, they were used only occasionally, being limited to a few metal mines that experimented with crawler¬mounted front-end loaders, tractor-trailer hauling units, a few tractors for drill-compressor mounts, and utility cleanup machines. By the mid-1950s, track loaders had become commonplace in limestone mines and uranium mines on the Colorado Plateau in the United States, as well as in Canada. Use of crawler-mounted tractors as drill and compressor mounts also increased. By the end of the 1950s, rubber-tired loaders and some haulers began to replace the track-type machines and rail-mounted cars that had been in use. About 1960, the rubber-tired machines brought about a new era of underground mining mobility and flexibility, centered on a method commonly known as "trackless mining." Ultimately, many of the underground rail-type systems for loading and hauling were replaced by the trackless mining technique. ECONOMIC CONSIDERATIONS The size and nature of mineral deposits, plus ground control techniques, historically had dictated small open¬ings to the surface from many underground mines. The small mine openings led to the development of special rubber-tired loaders and haulers designed specifically for access through the small openings. However, some mines, particularly those in massive mineral deposits, are able to excavate and maintain very large openings, and some use modified room-and-pillar systems. With the large mine openings, the use of larger, more produc¬tive equipment such as that commonly found in surface mining becomes economical. In fact, productivity gen¬erally increases at a more pronounced rate than machine size increases because many of the larger machines were designed for heavy-duty shot-rock applications in surface mines and construction sites where the handling of blasted rock is common. Table 1 can be used as a very Table 1. General Productivity Comparison for Conventional Machines In Underground Use (Shot-Rock Conditions) 2.3 m3 (3 cu yd) 4.6 m3 (6 cu yd) Loader Loader Expected Surface 230 t/h 540 t/h Production (250 stph) (600 stph) Expected Underground 90 t/h 270 t/h Production (100 stph) (300 stph) Expected Total Efficiency: Surface 40%-60% 50%75% Underground 25%.-40% 30%50% Expected Useful Machine 8000 hr 12,000 hr Life Before Replacement general comparison of the production and efficiency between small and large machines. Combining greater productivity often inherent in larger machines, with reduced downtime resulting from using fully developed machines with fast parts and service backup, some mine operators have been able to reduce material handling costs appreciably while reduc¬ing manpower requirements for operators and main¬tenance men. Large mine openings increase the amount of rock that must be handled in the development work, and they sometimes increase the dilution in stopes or rooms, de¬pending upon the dimensions of the ore zone. Providing adequate space for the unrestricted operation of large surface mining machines could, therefore, lead to more waste segregation and handling costs. It could also cause greater ore dilution that would result in a lower grade of ore being delivered to the processing plant. The tradeoffs between opposing cost factors must be reconciled and balanced to achieve the best overall cost of the crude ore, concentrates, or product. EQUIPMENT MODIFICATIONS Loaders and haulers designed for surface mining are seldom used underground in their standard con¬figurations without some modifications. If done, the modifications generally are made by the equipment dealer and/or the user, and the modifications usually include one or more of the following items: 1) The exhaust stack is lowered, and its direction is changed. Usually, it is repositioned horizontally to the rear, or it is fed into the engine fan to diffuse the exhaust gases. 2) The operator's position is lowered by either lowering the seat or changing the seat to a side mount. 3) The operator controls are adjusted to fit the new operator position. 4) Other components, such as the radiator and loader tower, are lowered. 5) Special bumper guards are mounted at the base of the radiator area. 6) An exhaust conditioner is mounted and con¬nected, using either a catalytic or a water-type condi¬tioner, or both. This usually is controlled by the safety and health regulatory authority having jurisdiction. 7) The positions of other components are rearranged

Jan 1, 1982

By Jindrich Fiala, Jirí Kout

The paper contains knowledge that have been achieved when the problem of airflow temperature and humidity changes prediction in mine airways was investigated. The substance of physical processes has been consistently applied. The methods of dry-bulb and wet-bulb temperatures calculations can be applied in any type of mine airway. The exceptionality of auxiliary ventilated airways is in the original solution of so called losing air flowing when a ventilation pipe is leaky. The combination of aerodynamics and thermodynamics solutions enable to determine climatic conditions on projected workplaces with a sufficient accuracy.

Jan 1, 1991

By L. J. Nicks

The current U.S. Bureau of Mines research program is addressing the recovery of flake graphite from kish, a steelmaking waste product, and the use of zeolites from abundant domestic natural deposits for efficiently cleaning up mining industry wastewater. The United States is almost totally dependent on imports for its graphite needs, but this may change depending upon the results from a pilot plant being constructed by industry using Bureau technology. Standard mineral processing techniques were applied by the Bureau to recover high-quality flake graphite from kish. It was considered innovative enough to receive an R&D 100 Award in 1992, and its commercialization has the potential to supply the total U.S. demands for graphite many times over. Zeolites have ion exchange properties similar to ion exchange resins, but are less expensive and available in large quantities. Samples of naturally occurring zeolites were tested for their efficiency in removing metal ions from synthetic and industrial waste solutions. The tests focused on defining their selecting, loading, eluting, and regenerating characteristics, and on developing a method for recovering the metal ions as added value products. The results showed that the removal of metal ions with zeolites from acid rock drainage (ARD) solutions is technically feasible and that this technique has the potential for being used in an integrated chemical treatment systems approach either as a primary or secondary cleaning step.

Jan 1, 1995

By D. R. Spears, C. E. Jordan

The U.S. Bureau of Mines examined the influence of turbulence on the fine bubble flotation of fine-sized (minus 40 micron) galena in order to improve flotation efficiency. Fine bubble flotation was carried out in a spinning-disk flotation cell and was compared to results obtained from flotation in a conventional cell at equivalent agitation levels. An automated electrochemical technique was used to monitor the turbulent velocity distributions of the fluid within the cell as a function of time and position. The velocity profiles were used to increase the precision of the fine particle, turbulent flotation model. While improved flotation response was obtained with intense agitation, the effect of bubble size was small. These results matched the model's predicted response for fine particle flotation.

Jan 1, 1989

By M. A. Bronston

A drill system configuration capable of working in the arctic offshore environment was developed to evaluate the placer gold resources contained in the glacio-fluvial sediments offshore Nome, Alaska. This system is capable of working on the shore fast ice during the winter months and is deployed on a drill ship during the summer. Transfer of the drill between its summer and winter configurations is accomplished with a minimum of modification to the design. The system is designed around the Becker drill. This percussive, reverse circulation drill is capable of penetrating the indurated glacial sediments present in the offshore Nome environment. This drill has operated effectively to depths in excess of 50 m (164 ft) below sea level. Since early 1987, in excess of 2000 holes have been drilled using the system. The drill system often operates in extreme weather conditions. It has averaged approximately 10 holes a day of drill production. The ore reserves defined during these drilling programs have resulted in the recovery of more than 70,000 oz (2.18 t) of gold to date, by the mining vessel Bima.

Jan 1, 1990

By Faust William A.

At Gold Fields' Chimney Creek Mine, gold ore deliveries to the milling and leaching circuits will come from three separate pits. The challenges in mine scheduling are to combine tonnage flows from these distinct ore bodies to produce a minimum of 4.665 kilogram (150,000 ounces) per year while maintaining a stable workforce and constant mine equipment requirements. A secondary goal is to have the end of milling operations coincide with the completion of leaching of the oxide ore reserves. This paper discusses the techniques used to prepare the long range plan and some of the considerations and practices that will be required for the plan's accomplishment.

Jan 1, 1989

By G. S. Austin, L. A. Brandvold, J. Renault

A series of tests were run on soil samples collected near the site of a Socorro, NM lead smelter that was abandoned more than 98 years ago. Three 30.5- x 30.5-m (100-X 100-ft) squares provided 13 samples each. As described in Part I (this issue), each sample was divided into seven splits according to particle size. A mineralogical examination of the fine-size fraction of Pb-contaminated soils failed to reveal crystalline Pb compounds. These authors conclude that Pb is present as amorphous phases or is adsorbed on the surfaces of soil particles. Site vegetation contained elevated Pb levels that increased with increasing Pb amounts in the soil. However, the biological absorption coefficient (BAC) indicates that some of the site's Pb is unavailable, or the plants are able to limit their uptake. Of the vegetation tested, rabbit bush showed the greatest increase of Pb levels in its roots, whereas levels in creosote were highest in the foliage. In cactus, the Pb levels varied. The amount of Pb due to dust incorporated in plant tissue is almost negligible compared to the amount absorbed through the plant vascular system.

Jan 1, 1994

By P. H. Williams

Experiences gained using computers in the mining and geological environment have shown that it is quite rare for a system or the data it stores to be truly stand alone. Just as the mining enterprise aims to have a smooth integration of operations from exploration through mining and extraction to sales, so it should develop all its information systems within an overall framework or architecture which covers the applications and data as well as the computer hardware and communications. This paper discusses methods of achieving such an architecture, and describes some of the benefits it can have on the development and implementation of information systems. The key aspects are the identification of the business functions and the data that they use, and ensuring that the IS plan supports the overall objectives of the enterprise. Hardware and communications policies should be based on the plans for the applications and data, rather than the reverse.

Jan 1, 1986

By G. P. Brahmaprakash, K. A. Natarajan, N. Jyothi, K. N. Sudha

Some important electrochemical aspects involved in the bioleaching of mixed sulfides have been discussed with reference to selective sphalerite dissolution from different binary mineral combinations. Combination potentials and galvanic currents were measured in different binary combinations of sphalerite with other minerals such as galena, chalcopyrite and pyrite in order to under- stand the electrochemical dissolution behaviour of sphalerite when coupled with other minerals. The effect of applied DC potential was also studied with reference to selective sphalerite dissolution from a binary mineral mixture. An application of a potential of -500 mV (vs SCE) was found to enhance bacterial growth as well as selective sphalerite dissolution. Factors influencing bioleaching of sphalerite under a negative applied potential are discussed.

Jan 1, 1989

By R. W. Bartlett

Aeration curing, over- a long duration in wet- red stockpiles, shows promise as an affordable pretreatment method for oxidizing gold encapsulating sulfide minerals, and possibly organic matter, in low grade refractory ores. Following aeration pretreatment, the ore is reclaimed, neutralized, and cyanide leached by conventional practices. Large tonnages of subeconomic material, including mine stripping waste, may he converted into ore by this new technology. The results presented show that a successful application of this technology will likely require crushing to about -2 cm (-3/4 in.), followed by aeration in a wet stockpile for long periods, up m three years. Natural convection may he inadequate, hut forced air ventilation, at modest pressures and power consumption, is affordable.

Jan 1, 1991

By Dominigue Francois-Bongarcon

This paper presents a step by step vulgarized review of the applications of geostatistics to the estimation of the mineable, recoverable reserves of the Cinola gold deposit in British Columbia.

Jan 1, 1988

By J. Harrison Daniel

Increasing mechanization of underground mining operations throughout the years has reduced the dependency on large, concentrated working forces. Fewer workers in scattered locations, coupled with the versatility of diesel equipment to load and haul personnel, supplies, and mineral ore, has made diesel equipment attractive in mine feasibility and design studies. The use of the mobile equipment along with higher production or "bulk" mining methods provides for more efficient mineral extraction systems. These systems are expected to become more widespread until long-term research provides a further evolution to more complete automation of underground mining. The U.S. Department of the Interior, Bureau of Mines, has been conducting research to reduce the health and safety hazards posed by increasing use of diesel equipment and the higher power ratings being proposed. The goal is to provide for safe and efficient use of the equipment. The National Institute for Occupational Safety and Health has recommended that diesel exhaust be regarded as a potential occupational carcinogen adding importance to the Bureau's research program. The paper describes advances in engine design, the use of diesels in mining operations, and significant health and safety research accomplishments of the Bureau of Mines. These accomplishments will help assure that diesel equipment remains an option for determining the most efficient system to mine an ore body.

Jan 1, 1989

By Robert G. Beverly

INTRODUCTION Standards limiting the annual exposure of United States uranium miners to radon daughters were established in 1967 at 12 Working-Level-Months (WLM). The standard was reduced by a factor of three, to 4 WLM, in 1971. Currently, the standard is again being examined to determine if it should be changed. Since 1967, Union Carbide has calculated individual monthly exposures in company and contract-operated mines located on the Colorado Plateau. Although it has been possible, by extensive ventilation control measures and accurate routine sampling, to meet the current exposure standard, there are many miners whose exposures closely approach the 4 WLM standard for any given year. However, it was noted that for miners who work for any extended period of years the [average] exposure was much less than the standard. The primary purpose of this paper is to show that, in effect, any annual exposure standard to radon daughters results in a long-term exposure considerably below that standard. Further, most miners, due to their job assignments and/or employment habits, only receive a small fraction of the standard. HISTORY OF EXPOSURE STANDARDS Prior to 1967, radiation protection in uranium mines was fundamentally based on a radon daughter concentration guide. In 1960, the American Standards Association published mine and mill radiation protection standards (ASA-1960). The Colorado Department of Mines, in 1961, adoped a standard which followed the ASA Standard and provided that if concentrations exceeded 10 Working Levels (WL), the area was to be shut down until corrective action was taken; if between 3 and 10 WL, corrective action was to be initiated; between 1 and 3, additional samples were to be taken and individual exposures evaluated; and if below 1 WL, conditions were considered to be controlled. In 1967, the U.S. Department of Labor issued the first exposure standard which called originally for limiting annual exposures to 3.6 WLM but which was later changed to 12 WLM. The complicated regulatory developments leading to this standard have been described elsewhere (Beverly-1969, Rock & Walker-1970). Effective July 1, 1971, this exposure standard was lowered to 4 WLM per year, which is the current standard. Over the past year, there has been speculation about the potential risk to uranium miners working at the present standard. A recent NIOSH Study Group Report (NIOSH-1980) concluded: "There is also strong evidence that a substantial risk extends to and below 120 WLM of exposure." The 120 WLM corresponds to a miner working in uranium mines for 30 years, a rare occurrence, at an exposure rate of 4 WLM per year, an even rarer occurrence. On the other hand, the General Accounting Office, in a recent Report to the Congress (GAO-1981), was very critical of reports by NIOSH on general low-level radiation risks. The GAO recognized that”...important questions remain unanswered about the cancer risks of low-level ionizing radiation exposure;" and recommended that Congress enact legislation giving statutory authority to an interagency committee to coordinate Federal research on health effects of ionizing radiation exposure. The International Commission on Radiation Protection at its March, 1980 meeting recommended limiting the inhalation of radon daughters to 0.02 J per year, equivalent to 0.4 WL, which on an annual basis would be 4.8 WLM and noted it is common to reduce this figure by 20% for allowance in the case of uranium miners for external and/or dust exposure(Sowby-1980). This is essentially equal to the present standard of 4 WLM. As earlier uranium miner exposure studies are reevaluated, and as new studies are conducted, it is important that the relationship between regulatory standards and the resulting actual exposures be recognized. UNION CARBIDE URANIUM MINING EXPERIENCE Union Carbide started mining Colorado Plateau uranium-vanadium ores in the late 1920s for the contained vanadium values. In the early 1950s, the Atomic Energy Commission contracted Union Carbide to produce uranium at mills located in Uravan and Rifle, Colorado. The company now has over fifty years of mining experience in the area. Some mines are operated as company mines and others are operated by private mining companies under a contractual arrangement. Ventilation, sampling, and exposure calculations are carried out the same in contract mines as in company-operated mines. Data presented in this report do not differentiate between company or contract employees and include all employees who worked underground any portion of a year in Union Carbide mines from 1967 through 1980. At the peak of uranium mining activities in 1970, there were 577 miners employed at year end (285 company employees and 292 contract) and 52 mines in operation (8 company-operated and 44 contract mines). Contract mines varied from two-man operations up to 15 employees. Company mines were generally the larger operations and employed from 20 to 100 miners.

Jan 1, 1981

By R. J. Pugh

The surface chemical sites on several fillers (quartz, feldspar, calcite and granite) were studied by the adsorption of well defined acid and basic probe molecules (benzoic acid, benzyl alcohol, ethyl benzoate, pyridine and benzyl amine) from cyclohexane. The results provided a wide variation of adsorption data, emphasizing the extensive range of site heterogeneity on the filler surfaces. In addition, it was shown that the acidic probes were strongly adsorbed on all of the minerals, thus indicating that the basic surface sites dominate the acidic ones. Also, through FTIR studies with vapor-phase probes adsorbed on orthoclase, it was possible to identify the nature of specific sites and the type of bonding occurring between the filler surface and the probe molecule. These types of surface analytical techniques could give useful information for predicting the adsorption functional groups on dispersants, dyes, thickeners, etc. and could lead to enhanced interfacial bonding between the filler and the matrix.

Jan 1, 1993

By J. D. Miller, D. M. Catarious, F. L. Stanley

The quality of cleaned products from coal preparation plants is often variable due to natural fluctuations in the washability characteristics of the plant feed. To combat this problem, many modern plants have installed on-line analyzers that provide feedback for the real-time control of product quality via the adjustment of circuit cutpoints. Unfortunately, optimization studies show that this approach may actually lead to increased losses of saleable coal. This paper discusses the problems associated with the real-time manipulation of circuit cutpoints and suggests alternative modes of operation that are better suited for plant optimization. A case study involving an eastern U.S. coal plant has been used to compare the economic impacts of these different approaches for plantwide control.

Jan 1, 2000

By S. Constantinescu

The alloys mainly used for short (or segmented) chip material cutting (cast iron, porcelain, etc) are alloys of the WC-Co type; in some cases with small additions of other carbons. The same alloys but of different granulometric classes are also used for pieces exposed to wear (wire drawing, moulds) The higher performance of the WC-Co alloys in chip machining applications is accounted for by their very good heat conductivity, which is 2-3 times higher than that of fast steels. The hard-alloys producers can resort to a wide range of possibilities to achieve variation of properties of a WC-Co composition and thus they can adapt their products to the particular type of tools they may choose to manufacture. The present metallography technique allows for a correct identification and evaluation of hard sintered carbons structures. The metallography approach is an indispensable method of investigation and control in the industry.

Jan 1, 2008

By D. O. Shah, K. C. Adiga

Flotation of coal after multistage addition of frother was found to yield coal fractions with significantly lower ash content as compared to the feed. Ignition and combustion characteristics of different coal fractions were evaluated using a differential thermal analyzer (DTA). A correlation between low ash content, low specific gravity, and high reactivity of coal was observed. It is suggested that in the ignition stage, removal of mineral matter enhances reactivity through the physical changes brought about by ash removal. A detailed analysis of pre-ignition kinetics indicated the possible effect of bulk density of coal in terms of resistance to volatile release and effective (available) surface area of coal. In the char combustion stage, mineral matter seems to influence reactivity through catalytic activity of surface concentrations of metal ions, ratio of combustible/non- combustible material, internal pore structure, and surface roughness.

Jan 1, 1988

By John A. Herbst, K. Rajamani

Process improvement is probably the most widespread objective of mineral process plant operators in the late 1980's. An important part of such improvements is dynamic optimization which involves reacting to inevitable plant disturbances in such a way that productivity is maximized at every instant of time. This paper describes the way in which mathematical models can be and have been used in dynamic optimization. Both off-line and on-line model applications are described.

Jan 1, 1989

By J. A. Brierley, S. R. Hutchins, C. L. Brierley

Introduction Many gold and silver ores are refractory to conventional processing technologies. Thus, precious metals recovery is uneconomic. These resources can consist of ores, flotation concentrates, mill tailings, and other reserves. The refractory nature of these materials can be ascribed to such components as iron sulfide minerals, silica minerals, tellurides, organic compounds, and sulfosalts. Precious metals locked within iron sulfide minerals account for a large number of refractory gold ores. These minerals consist principally of pyrite or arsenopyrite. They must be oxidized to liberate the encapsulated precious metal and allow its contact with the leaching agent. Carbonaceous gold ores represent a unique class of refractory precious metal ores in general. Not only does gold encapsulation by iron sulfide minerals occur (Hausen, 1985), but these ores also contain organic matter that interferes with gold recovery by cyanidation. Direct interference can be attributed to either occlusion of gold within organic matter or formation of a stable gold-carbon complex. The magnitude of this problem is debatable. Wells and Mullens (1973) examined two carbonaceous gold ores and found no association between the gold and carbonaceous material. A more common problem is indirect interference, whereby the aurocyanide complex formed during cyanidation is sorbed by the native organic matter and is not available for recovery. This phenomenon is referred to as "preg robbing" (Osseo-Asare et al., 1984; Hausen and Bucknam, 1984). Guay (1981) summarized various methods that can reduce preg robbing during processing of carbonaceous gold ores. However, some are not applicable to carbonaceous ores that have significant amounts of gold locked in iron sulfide minerals. Several methods exist for oxidizing iron sulfide minerals and rendering refractory precious metal ore amenable to conventional recovery processes. These include various embodiments of roasting (Jha and Kramer, 1984; Brown, 1984; Arriagada and Os-seo-Asare, 1984; Smith, 1986), pressure oxidation (Muir et al., 1984; Beattie et al., 1985; Thompson, 1986; Weir et al., 1986; Argall, 1986), and chemical oxidation (Scheiner, 1971; Jackson, 1983; Van Weert et al., 1986). Each process has been successfully used for refractory precious metal ores. In many instances, however, their use is precluded by capital and operating costs relative to the value of the ore. An alternative to these methods is microbial pretreatment - a biological process whereby iron sulfide minerals are degraded and the liberated precious metal values can be recovered by conventional technologies. Bioleaching refractory precious metal ores is a relatively new concept compared to roasting and chemical oxidation. It is rapidly becoming established as a viable pretreatment alternative. Numerous studies have been conducted in the laboratory and on a pilot scale (Yudina et al., 1979; Lawrence and Bruynesteyn, 1983; Pol 'kin et al., 1985; Marchant, 1985; Livesey-Goldblatt, 1985; Gibbs et al., 1986). Comparative tests have demonstrated that bioleaching can be equal to or better than roasting or pressure oxidation in terms of product recovery and process economics (Fridman and Savari, 1983; Livesy-Goldblatt et al., 1983; Karavaiko et al., 1985; Gilbert et al., 1986; Hackl et al., 1986). Bioleaching's main drawback is that pretreatment requires days rather than hours. This can lead to excessive operating costs for difficult-to-treat ores. In all of the tests reported thus far, the leaching microorganism used has been thiobacillus ferro-

Jan 4, 1988