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By H. F. Broicher

Introduction In April 1998, AIS Sommer GmbH of Germany delivered the first laser-induced fluorescence (LIF) analyzer to the mining industry. LKAB's Kiruna iron ore mine in Sweden shared the costs and the risk of building the prototype. This marks the beginning of LIF analysis as a technique for quality control in mining and mineral processing. Photoluminescence analysis is well established. In most laboratories, fluorescence spectrometers are standard equipment for quality or pollution control. LIF is being used in several applications, including combustion studies and particle image velocimetry. However, it has mostly been used in laboratory environments. The availability of rugged lasers for industrial use brings this powerful tool to the forefront of production, even in the rough conditions found in mining and minerals processing. Laser-induced fluorescence Basics. Fluorescence of naturally occurring minerals has fascinated man since scientific investigation of this phenomenon commenced about 200 years ago. However, importance in industrial application and peripheral activities. Hand sorting of ore under ultraviolet (UV) lamps is seen as an archaic method. Long gone are the days when geologists set out at night with UV hand lamps to find valuable ore deposits, especially those of tungsten. Today, fluorescent minerals are considered collectors' items and museum exhibits. In the late 1960s (Hemphill, 1968) and during the 1970s, attempts to use lasers for excitation of fluorescence in minerals led to the development of an airborne fluorosensor (Seigel and Robbins, 1980). However, this prospecting technology did not gain industry acceptance and vanished from the market. During the past seven years, ongoing research of the LIF of minerals resulted in new findings that give good reason to revive the interest in fluorescence and its use in the mineral industries (Broicher and Zydek, 1995; Broicher, 1998). Fluorescence is defined as the short-lived form of photoluminescence, in which matter emits visible radiation during and after irradiation with light – the fluorescence generally being of a longer wavelength than the irradiation. Fluorescence of matter is described by: • the absorption spectrum, • the emission spectrum, • the decay curve and • the quantum efficiency. The absorption spectrum shows the fluorescence intensity in a fixed spectral band as a function of the excitation wavelength, while the emission spectrum shows the fluorescence intensity at varying emission wave- lengths for a fixed excitation wavelength (Fig. 1). The decay curves describe the exponential decrease of the fluorescence intensity with time. The quantum efficiency is the ratio of irradiating energy to emitted energy. Re- cent research has found that: the quantum efficiency of minerals can be measured and evaluated,

Jan 1, 2000

By A. K. Haines, M. W. Godfrey, D. M. Miller, P. C. van Aswegen

The Bacterial Oxidation [(BIOX)] process for the pre-treatment of refractory ores for gold recovery developed by Genmin, the mining division of Gencor, has been operating successfully at the Fairvew Mine since October 1986. The continuous operation of a pilot plant at Genmin Process Research has resulted in further process developmenst to improve plant operating efficiencies. These new developments, which include a higher solids content of the pulp feed to [BIOX], lower retention times, higher operating temperatures, lower power utilizaton for oxygen dispersion and reduced nutrient addition, have all been successfully implemented on the Fairvew plant. It has furthermore been confirmed that the arsenic precipitate formed in the neutralization of effluent solutions complies to the United States of America EPA standards. Contineous cyanidation pilot plant work conducted on [BIOX] product has indicated that cyanide consumption can be drastically decreased if a continuons flowsheet is implemented in preference to a batch leaching system.

Jan 1, 1992

By George M. Potter

During the late 1960s the mining industry became interested in USBM's efforts to develop the gold-silver heap leaching process. In the last 10 years, successful commercial heap leaching applications increased. The process provides a relatively low-capital means of processing treatable ores with reasonable operating costs. Present gold and silver prices compared to capital and operating costs favor the continued growth of the heap leaching method. The heap leaching process is defined as the percolation leaching of relatively coarse gold-silver ore piled on an impervious surface. To date, dilute alkaline cyanide solution is the lixiviant of choice. Other leaching reagents such as thiourea and hypo have been suggested, although they are not currently used in heap leaching practice. Ores may he run-of-mine in size or crushed as fine as about 10 mm. Gold and silver-bearing so¬lutions draining from the heaps may be processed in activated carbon columns to recover the metals, followed by stripping and metal recovery, or treated by the Merrill-Crowe zinc dust precipitation method. All solutions are generally recycled to the leaching step, and the heap leaching system is relatively easy to control from an environmental viewpoint. One advantage of the heap leaching process is its flexibility. Plants may be very simple, comprising leaching of uncrushed ore on a locally-obtained clay-lined pad and shipment of gold and silver recovered in the form of loaded carbon or zinc precipitates; such a plant would have a relatively low capital investment. More elaborate plants for larger ore bodies may be planned to include crushing, cyclic pad use, and done gold-silver recovery. General planning is similar in each case. This article outlines some key factors in designing heap leaching operations and discusses how these factors are applied to develop a working operation. Since individual design requirements and local costs vary so much, only a few general comments on costs are included.

Jan 3, 1981

By M. Cambridge

The design process must anticipate all construction and operational conditions and make an allowance for all eventualities. Prevention of failure during operational life, and in some cases post abandonment, requires that a risk assessment is undertaken during the design stage which defines not only the factors of safety to be used but the criteria for the structure during its operating life. These operating criteria should clearly identify the at-risk structures and the inspection and monitoring routines required to ensure compliance with the design objectives. On a mine site, it is the role of mine management to ensure that the operating rules be applied throughout the mine life and that a system of inspection and monitoring procedures be instigated. Where the risks are significant, high-level auditing by an independent engineer will also be required. Within the inspection and auditing framework, the designer needs to incorporate instrumentation to enable the operators and management to confirm that the facility meets the requirements of safety, stability and environmental compliance whilst continuing to meet its operational function. This paper reviews the use of inspection and monitoring to prevent failure and provides, in summary, examples of where monitoring has been undertaken and prevented failure. A tabulated review of legislation, regulations and technical guidance generated as a result of previous failures or untoward events is provided.

Jan 1, 2005

The application of Kirchoff's laws to two adjoining mine ventilation network meshes containing fans results in the construction of two general quadratic equations. These equations may be solved to give the resultant airflows and hence fan duties within the system for given network parameters and fan characteristics. This technique has a wide application for calculating the duties of fans in various combinations within a mine ventilation system. Recent difficulties in economically maintaining environ- mentally safe conditions in underground working areas distant from main ventilation fans has led to increasing interest in the use of controlled partial recirculation of ventilation. This paper develops a recirculation model which can be solved directly using mathematical techniques obviating the need for iterative techniques such as the Hardy-Cross method. The advantage of a direct mathematical analysis is that mathematical algorithms may be constructed to completely describe the ventilation system under a wide range of operating conditions. This technique is applied to controlled partial recirculation ventilation systems to demonstrate its advantages for mine ventilation planning.

Jan 1, 1989

By I. R. McGowan, J. Tilk, J. I. Hershman, R. L. Lewis

The White Pine Mine is a large underground copper mine located in the Upper Peninsula of Michigan. A numerical ground water flow model of the White Pine Mine was constructed to evaluate potential engineering controls that would reduce the rate of mine-water discharge after closure. Of the passive controls evaluated, the placement of bulkheads within the mine workings was predicted to offer the greatest benefit, reducing the rate of discharge by as much as 35%.

Jan 1, 1998

By Robert Semrad, J. Colin Anderson

INTRODUCTION Sulphur is a mineral which accounts for 0.05% of the earth's crust and may be found either in its elemental state or as a compound. References to sulphur production and consumption are found in early antiquity and international trade of sulphur from volcanic deposits in Sicily began in the 1880's. The supply of sulphur consists of two components: the first is production, and the second is inventory. HISTORICAL SUPPLY Production World sulphur production in 1984 was approximately 53.5 million metric tons, compared to the 1970 level of 42 million metric tons. Of this 11.5 million metric tons production increase, brimstone accounted for close to 90%. Production distribution in 1984 was 62% brimstone, 21% pyrites and 17% other forms, while in 1970 it was 55%, 28% and 17%, respectively. Brimstone Production is derived either from mining operations (Frasch, underground melting and native refined) or as a by-product from hydrocarbons. World production in 1984 exceeded 33 million metric tons, up approximately 10 million metric tons from the 1970 level. This increase was uniformly distributed throughout the world as shown in Table A.

Jan 1, 1986

By M. J. Rex, K. L. Wiley, D. S. Ramey

In situ leaching, initiated in 1986 at the San Manuel Mine, was economically developed in 1989. The primary reason for this lag time between startup and viable production was the time required for technical development. The technical development pursued comprised detailed design, development and implementation of in situ well construction methods, formulation of suitable well pattern arrays and the development of extensive hydrogeologic and geochemical knowledge of the mineral deposit. Since 1989, the in situ leaching program has become a viable and cost-effective method to extract copper from the supergene mineralized zone of the San Manuel deposit. The in situ leaching methods that are currently used have been progressively expanded and continually developed. They will become the cornerstone of copper production from the San Manuel oxide mineral deposit. This paper presents an overview of the supergene hydrogeology, current design techniques, drilling methods and well completion, pump determination and setting, solution management and future plans for the increased extraction of copper by in situ leaching methods at the San Manuel Mine.

Jan 1, 1995

By Norman Haber

The Haber Gold Process (HGP) is a proprietary. hydrometallurgical extraction methodology that was developed in 1983-1984 by Norman Haber and Dr. John Lee of Haber, Inc., a small public company in Towaco, New Jersey specializing in hydrochemical process development for precious metals. It was pilot tested repeatedly in 1985 at our pilot plant in Tombstone, Arizona, with different types of gold bearing mineralization. Both Pincock, Allen and Holt (USA), and PA Technology (Australia) were involved with some of these pilot tests. The ores tested included easily cyanide-extractable oxide type gold ore from Australia, marginal heap-leach type ore from Cripple Creek, USA, and a hematite bearing ore from California. In all cases, extraction time was 6 hours or less yielding 90-99% recoveries of assayed gold values. The HGP operates as a lixivient which parts the gold from the rock matrix, yielding gold in solution in a fully recoverable form. Both precipitation methods, such as zinc participation or Carbon in Leach systems ( or Carbon in Pulp) have been shown to be feasible with this technology for the recovery of gold from the pregnant solution. Both batch vat leaching as well as continuous processing are realistic for use with the HGP. It has also been considered that the HGP might also benefit heap leaching due to several advantageous factors over cyanide. One such consideration is that the HGP can operate effectively with acidic ore types. The use of cyanide with such ores often requires attention to pH and neutralization with lime. This tends to reduce and even clog the permeability of the leach bed.

Jan 1, 1998

By Fred D. Wright

In this paper the principal theories used to design roof bolting systems are presented and discussed. Then the characteristics of various types of roof bolts are presented and finally the interaction between rock and roof bolt characteristics on choice of roof bolts is discussed. Theories can be considered design tools which may or may not be appropriate for a specific situation. It is good for a design engineer to have a number of such tools available and also important that he understand their good features as well as their limitations. Hence, some of the principal theories and classification systems used for design of roof bolting systems are discussed first.

Jan 1, 1982

By B. M. Ghadiali, J. B. Putnam, T. P. Smirnoff, M. A. Elioff, P. F. Ryan

Geotechnical investigations for the Mid-City Extension of the Los Angeles Metro revealed high concentrations of toxic hydrogen sulfide (H2S) gas as well as methane. Testing techniques employed to determine the extent of gasses, and to identify potential treatment measures, included gas sampling with cone penetrometers and soil-gas extraction with air injection testing. A gas reservoir model was developed to predict inflows into excavations. Other studies included a hazard evaluation and a general data search for other H2S occurrences and geologic conditions that could facilitate the accumulation of H2S. The paper describes the investigations and proposed design and construction alternatives.

Jan 1, 1995

By Ralph D. Daley, Kevin E. Redinger

The production of coal/water fuel (CWF), a highly loaded mixture of finely ground coal, water, and chemical additives, presents a unique opportunity for significant ash and sulfur reduction through physical coal cleaning. Froth flotation can be integrated with the staged, wet, fine grinding inherent in the CWF production process. A laboratory scale research program was conducted to demonstrate the feasibility of a flexible, integrated coal cleaning/CWF process flowsheet. Performance of the conceptual flowsheet was examined for two coals of CWF commercial interest, Upper Freeport and Pittsburgh seam coals, from central and southwestern Pennsylvania, respectively. Several multi-stage coal flotation and reverse flotation circuits were evaluated. CWF was produced from the cleaned coal in each case at similar solids loadings and viscosities as observed for the raw coal. However, the ash loading and SO2 emission potential for each CWF had been significantly reduced.

Jan 1, 1988

By John Brett

BHP Australia Coal Pty. Ltd. (BHPAC) manages and, through its parent company BHP, partly owns seven large opencut mines in the Bowen Basin of Central Queensland, Australia. In terms of developments in surface mining in Australia, the operations of BHPAC are as representative as any. The seven mines managed by BHPAC produce a combined total of about 40 Mt/a (44 million stpy) of mostly high quality coking coal. They also produce small but increasing amounts of thermal and PCI coal. Virtually all of the coal produced is sold on the export market. In 1993, Australia exported 133 Mt (146 million st) of coal. Salable production was 172 Mt (189 million st) in New South Wales and Queensland and 180 Mt (198 million st) nationwide. Mining systems Surface coal mines in Queensland can be typified as large, long-strike-length, shallow-dipping and sometimes multi-seam dragline operations. There are exceptions. Blair Athol, for instance, works a 30- to 40-m (100- to 130-ft) seam beneath shallow cover but is still a dragline operation. Moura is truly multi-seam and steeper dipping but also is still a dragline operation. Mines in the Ipswich area are small shovel-truck operations.

Jan 1, 1995

By John Ralston, Rossen Sedev, Nicola Richards, Quinn Anthony, Geoffrey Reynolds

Derivatised 2,4-diketopyrimidine groups have been anchored to planar gold surfaces as self¬-assembled monolayers (SAMs) for chemical and photochemical studies. Three derivatives, 5-methyluracil (thymine), 5-trifluoromethyluracil and 5-nitrouracil, were chosen for the specific moiety present at position C-5, which can exert strong or weak inductive effects on the adjacent aromatic ring. The measured acidity constants decrease from 5-methyluracil to 5-nitrouracil as the inductive properties of the group at C-5 position increase. When grafted to the surface the acidity constants increase, albeit still adhering to the expected inductive trend. The functionality also exerts an influence on the surface wetting properties. Surface wettabilities indicate that the orientation of the pyrimidine groups at the surface occurs so that the C-5 position has a direct effect upon the surface chemistry. Upon dimerisation the surface contact angles increase signifi¬cantly. At pH 11 the contact angle changes reflect that the dimer has a higher pKa than the monomer. The monomer surface is deprotonated at this pH while the dimer surface is partially deprotonated, leading to changes in contact angle of up to 22 degrees. Large changes in contact angle were observed for 5-nitrouracil which were independent of surface charge and were appar¬ently due to conformational changes alone. Electrowetting of three fluoropolymer surfaces by electrolyte solutions was studied with the sessile drop method. The electrowetting curve (contact angle/potential) is analogous to the elec¬trocapillary curve (surface tension/potential) and may be described by a combination of the Young and Lippmann equations. We demonstrate that for some specific surfaces a systematic deviation occurs at positive potentials. This departure is attributed to double layer effects, namely the adsorption of hydroxide and halide anions. pH, ionic strength and polymer composi¬tion can all influence electrowetting behaviour.

Jan 1, 2003

By S. Shrivastava, R. G. Reddy

Spent potliner is generated in the electrolytic process of reducing alumina to make aluminum metal using molten fluoride electrolytes. Spent potliner(SPL) is obtained at the end of the pot's life. The SPL contains small amounts of cyanide and fluoride, which present environmental problems. Spent potliner could possibly be used as a fluidizer to replace calcium fluoride (CaF2) in the iron- and steelmaking industry and in the glass industry. A low viscosity and a low melting point are prime requirements for such an application. In the present study, viscosity measurements were performed. The effects of various additives, such as sand, limestone, dicalcium silicate dust and MgO baghouse dust, on the viscosity of SPL were studied. The results showed that the addition of sand and limestone can produce a very high fluidity SPL melt at significantly lower temperatures. The results suggest that spent potliner mixed with additives could potentially be used as a substitute fluidizer.

Jan 1, 2002

By James R. Tompkins

This paper details the successful progression of a promising exploration property into a producing gold mine in only 35 weeks on schedule and on budget. While under construction, an extensive exploration program continued to add to the mine life through the increase in reserves, resulting in a decision to increase the mill capacity from 500 tonnes per day to 1000 tons per day while maintaining the original construction schedule. Details are provided on the unique geology at the Puffy Lake Gold Mine, development from the exploration stage through construction and ultimately to production, with a detailed flow sheet. In addition, of note is the successful change over from contract mining to the hiring of Pioneer personnel who are successfully carrying on both stope mining and development. Operating costs per ounce of gold production are projected at $185 U.S. and alternate methods of mining are currently being examined which could further reduce operating costs.

Jan 1, 1988

By Donald Lau, Adrian Crawford

In the field of grouting, practitioners fre¬quently advocate procedures that are often unique and contradictory. As a result there has been considerable debate as to what constitutes optimum grouting practice. A knowledge of both the rheological properties and the flow characteristics of grouts is essential to the development of a rational understanding of the grouting process. Flow models and viscosity experiments have been conducted using cement grouts comprising High Early Strength Portland and Microfine cements. The addition of superplasticizers was found to enhance the flowability of the grouts as well as to reduce the effective groutability ratio. Steady state flow equations and design charts for predicting the radial penetration of cement grouts have been developed.

Jan 1, 1986

By L. A. Puchkov

The creation of automatic methane concentration control systems presupposes the use, as a control factor, of the air rates in workings and in mine as a whole. These systems present a complicated set of computers and software, including as major components the following - systems for detecting methane concentration and air rate; - telemechanics systems; - programs and means of data processing; - programs and means of air rate control in workings and main fan capacity control. The paper analyses the experience of development and exploitation of automatic methane control system in gassy mines of the USSR Donetz coal basin. Much attention is given to the study of technological factors influence upon aerogasdynamic process using automatic methane control system.

Jan 1, 1989

By Michael Rieber

Capable of establishing a net present value of zero over a short period of time small mines, though not simply scalers of large operations, minimize market risks and reduce investment capital. Particularly now they are relevant to LDC development. Small mine concepts are reviewed with emphasis on sizing, speed, and LDC problems. The special problem of gold and the precious metals is examined with respect to mine evaluation. Small mine analysis is introduced with emphasis on the financial model including gold price forecast considerations.

Jan 1, 1987

By Thomas G. Johnston, Garston H. Blackwell

The development of a block model for a copper molybdenum ore deposit is described. The early use of the inverse distance power estimator, and later transition to geostatistics and kr iging, produced block models suitable for global reserve estimates. Because the global reserve was inadequate for routine mine planning, the production blast hole assays were incorporated into the block model, resulting in excellent local grade prediction. The on site use of small mini, and more powerful personal computers for estimating grades is described. The development of a computer aided, interactive graphic, mine planning system utilizing the grade block model is detailed.

Jan 1, 1987