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By L. Cornish, P. A. Olubambi, J. H. Potgieter

Four 22%Cr series duplex stainless steels alloys containing varying nickel contents of approximately 5, 7, 9 and 13% were melted in a vacuum induction furnace, hot rolled, solution annealed and water quenched. Their corrosion behaviour was investigated in sulphuric acid and sodium chloride solutions using a potentiodynamic polarization technique. Increasing nickel contents have appreciable influence on their corrosion behaviour. Polarization curves show similarities in the uniform corrosion behaviour of the alloys in the solutions and a significant difference in their pitting behaviour in chloride environments. Alloy 2209 generally exhibited highest resistance to uniform corrosion while 2213 displayed distinct and best pitting corrosion resistance. Their corrosion behaviour were attributed to the influence of nickel on phase modification, microstructural refinement, and the probably types of films formed in different environments. Keywords: Duplex stainless steel; Nickel; Microstructure; Phase modification; Corrosion

Jan 1, 2006

By G. R. Marchant, B. K. Loveday

A mathematical model has been developed for flotation circuit simulation. This model was designed to investigate the effect of varying the circulating loads and to determine whether an improvement in overall efficiency could be gained by a size separation prior to flotation. Model parameters were obtained by regression to plant data. Highly correlated parameters in the model were combined to reduce the number of parameters so that the need for excessive data gathering was eliminated. Mass balance smoothing was used to obtain a consistent data set for regression. The results of the simulation indicate that for the same grade of concentrate, an increase in copper recovery of 0.6 per cent may be possible by increasing the circulating loads. The results of the simulation also indicated that recleaning of the plus 200-mesh material may be beneficial.

By N. Brown

Australian mining companies are actively exploring for and developing mineral deposits throughout the world with interests in emerging markets such as Africa, Asia and South America. It is important to understand emerging market risk as this will affect the willingness of mining companies and financial institutions to invest in a country, especially with reference to their key asset, the mining licence or operating/concession agreement. Mining companies looking to develop new projects in emerging markets have different risk profiles than projects in countries such as Australia and Canada. Examples of key risks faced in emerging markets include: 1. political - expropriation, nationalisation, contract frustration, currency inconvertibility, war, terrorism, strikes, riots and civil commotion; and 2. legal - mining legislation, arbitration and dispute resolution, trade agreements. There is a problem in the difference in risk perceptions between mining companies, financial institutions and insurers. This can cause different stakeholders to carry out different evaluations of the risks faced by a project, resulting in confusion about the risk margin attached to any project. In a time where resource nationalisation and energy security are prompting governments to become more involved in the mining sector we run through some recent examples of mining companies that have had problems due to the key risks highlighted earlier. Importance of carrying out the right due diligence to replace perceptions with reality: ? early identification of risks - detailed due diligence on emerging market risks that may arise will help with their identification and mitigation, ? make use of companies that can help identify risks and suggest solutions, ? control the cost of financing - risk margin applied to a project ? finance loan will be influenced by the risks faced, and ? risk management and using political risk insurance. There are plenty of opportunities in emerging markets but it is important to recognise the associated risks. Detailed due diligence at an early stage will provide long-term benefits.

Jan 1, 2007

By C. J. Van Niekerk, D. R. Allen

The electrolytic extraction of zinc at the Zinc Corporation of South Africa Limited by C. J. VAN NIEKERK, B.Se. (Hons.)(Poteh.), M.Se. (Unisa)(Fellow) and D. R. ALLEN, A. Met. (Sheffield) (Member) This paper gives a brief account of some modifications that were made to the process of zinc electrowinning practised by the Zinc Corporation of South Africa Limited. Some changes in the materials of construction are also described.

Jan 2, 1977

By E. H. van Niekerk

The production of high-strength Iow-alloy (HSLA) steels containing either niobium or vanadium as the principal micro-alloying element is discussed, including recent developments in steelmaking practice that have had a great effect on the development of HSLA steels; strengthening mechanisms, as well as the principles of thermomechanical treatment during controlled rolling on a hot-strip mill; and the results of production heats with various amounts of micro-alloying elements.

Jan 1, 1984

By L. A. Vermeulen, D. D. Howat

New distribution functions are derived to describe the size distribution of grinding elements in ball mils. The formulations are based on the assumption that abrasive as well as impactive interactions occur during bal milling-an assumption that is supported by a large body of experimental evidence. It is shown that the functions can be used in the estimation of the magnitudes of abrasive and impactive components in the total rate of bal wear. The relative magnitudes of the wear components provide a basis for optimization of the chemical and metallurgical properties of the balls in a given milling situation. However, it is contended that these quantities are also useful indicators of the relative intensities of the abrasive and impactive interactions that are operative in the size reduction of mineral particles within ball mils. These quantities can be determined for any industrial ball mil, and their magnitudes provide practical guidelines for mil operation. The theory is used in an analysis of samples of ball charges from two industrial ball mils, and it is also applied to al the data on bal-size distributions found in the literature. The qualitative correlation between the calculated values of the wear components and the reported operating conditions is good for a variety of industrial ball mils, in conformity with the hypothesis that the relative magnitudes of the wear components are related to the milling conditions.

Jan 1, 1986

By H. J. R. Way

Dr H. J. R. Way: In his reply to my queries Mr Bath still adheres to his statement that it may be possible to replace the estimated R200 million reduction in gold revenue in 1980 by exports of ferro-chromium, and apparently based his conclusion on a growth rate in demand for corrosion resistant steels of 10 per cent per annum in the next few years. As I pointed out at the previous discussion at Middelburg this would entail a production of about one million tons of ferro-chromium in 1980. Exact statistics of South African ferro-chromium production are not available, a fact which is very much to be regretted. But statistics of exports of ferro-chromium are available from "Foreign Trade Statistics" of the Customs and Excise. These show that South Africa exported 99,580 short tons in 1967. The quantity of ferro-chromium consumed in South Africa in 1967 was fairly small and we can therefore assume that the production was 99,580 tons. For this amount to grow to 1,000,000 tons in 1980 would require a growth rate of 19.4 per cent per annum. At 10 per cent this would grow to 344,000 tons and at 7 per cent 240,000 tons. The following growth rates in the form of average trends are pertinent: STEEL - Per annum World steel ingot production - 1957-67 – 6.8 per cent Free-world ingot production - 1957-67 – 6.0 per cent Consumptions of crude steel by four major Free-world Consumers - 1957-67 - 5.6 per cent CHROMITE World production - 1952-67 - 2.5 per cent South African total sales - 1948-67 – 5.4 per cent South African exports - 1948-67 – 3.9 per cent United States consumption, very irregular, but - 1962-67 – 6.5 per cent FERRO-CHROMIUM - Per annum United States consumption - 1952-67 - 6.5 per cent South African exports - 1957-62 - 25.2 per cent South African exports - 1962-66 - 41.9 per cent South African exports - 1966-68 - 21.2 per cent These figures show that exports of ferro-chromium have been growing at a very high rate varying from 21.2 per cent to 41.9 per cent since 1957, but in view of the market situation it seems somewhat doubtful if that high rate can be maintained up to 1980. Of our 1966 exports U.S.A. took 63 per cent which was 53 per cent of their total imports. Their average consumption is trending at a growth rate of 6.5 per cent per annum from 1952-67, but the growth from 1964-66 was 5- 2 per cent and 1966-67, -12 per cent!

Mar 1, 1968

Knelson concentrators are commonly used to recover fine liberated gold in gold processing plants. The decision to employ a gravity gold circuit consisting of centrifugal devices such as Knelsons is primarily taken on the results of GRG tests, among other considerations. While the GRG test is considered a material characterisation test, which is useful in the design stages, its use in evaluating the performance of an existing unit is questionable. The problem is exacerbated by the fact that it is time consuming and costly. This paper examines the validity of the GRG test for performance evaluation and discusses alternative test work that can be performed to evaluate the performance characteristics of an operating machine. Principles that are useful in selecting optimal operating parameters, such as optimal fluidising water flow rate for a given ore/machine combination, are also discussed and illustrated with laboratory and plant data.

Jan 1, 2007

By J. Keyser

The realization of an Integrated Technical Resource Asset Management System (ITRAMS) has so far evaded all software developers in the mining industry. The major factors that have prevented the development of such a system are limitations on software, hardware and network systems. Several factors have come together at Venetia Mine, which has made the undertaking of such a project both possible and desirable. This has led to the formation of a strategic partnership between Venetia Mine and Gemcom Software International Inc. This partnership is dedicated to develop and provide an Integrated Technical Resource Asset Management System based on Microsoft Back Office architecture, Gemcom for Windows™ and the MinRas system. This paper will elaborate on the phased approach of the integration of systems into the core repository, mechanisms of integration, the functionality of the system, final results, techno-economic benefits and general project management issues.

Sep 1, 2001

By Marthie Kotze, Jacolien Wyethe, Bert Van Hege, Richard Bell

Base metal refinery effluent streams may contain low metal concentrations that cannot be recovered by precipitation. Although the concentration is low, the total mass of unrecovered metal can have significant value because of the volumes of effluent generated. This metal may be recovered with high efficiency using selective ion exchange resins. Three process schemes are considered, viz., fixed bed column ion exchange, continuous countercurrent resin-in pulp, and continuous carousel resin-in-pulp. Each of these has different requirements in terms of equipment, resin inventory, capital and operating costs, and different limitations on feed conditions. Bateman and Mintek recently developed a model which allows an upfront economical evaluation of ion exchange options. The model evaluates the capital and operating costs for each process scheme for various base metals. This provides a general guideline for selecting the appropriate process arrangement for a given process stream.

Jan 1, 2005

By P. A. J. Cabassi, B. K. Loveday, M. J. Wilkinson, P. H. Radcliffe

The recovery of gold, uranium, and pyrite from accumulated residues at mines in the Orange Free State is adversely affected by the presence of pyrophyllite, which is naturally floatable and must be prevented from floating with the desired constituents by the use of a mica depressant, and of thucholite (uraniferous kerogen), which contains significant quantities of uranium and gold but does not float readily in the presence of a mica depressant. In laboratory tests on these residues, the use of a mixture of MIBC (methyl isobutyl carbinol) and paraffin in addition to the suite of reagents normally used was found to increase the gold recovery substantially, but the sulphur grade was lower. The recovery of thucholite also increased considerably, but the proportion of uranium associated with this mineral was small. Plant trials, which are continuing, have been encouraging, indicating an increase in the gold recovery of 4,6 per cent.

Jan 1, 1983

By G. J. Wright, M. J. Neale

As machines become more complex and vital to our way of life, any disturbance or failure of their proper functioning tends to have serious consequences. To prevent such failures, increasing attention is being paid to techniques for the monitoring of machinery condition or 'health'. Of the many methods available, examination of the lubricant and any particles it contains forms a basis for interpretation of the conditions of operation, and the rate and severity of degradation of the moving parts, in a machine. Many techniques of wear-debris analysis, such as spectrographic oil analysis and ferography, are available indicate the composition, shape, size, and concentration of contaminants in a lubricant. This paper reviews the important aspects of wear-debris analysis as an integral component of machinery condition monitoring, and gives an insight into the selection of appropriate techniques and the information that can be obtained from each.

Jan 1, 1987

Dr H. J. van Eck (Honorary Life Member): "Mr President, I regard it as a signal honour that I was invited to address the South African Institute of Mining and Metallurgy on its 75th Anniversary. I also wish to add my congratulations and good wishes to the many you have already received on this memorable occasion. Seventy-five years is indeed a good age and the achievements of your Institute certainly justify this special celebration. South Africa owes her present prosperity largely to the technological ability and determination of her own people. Members of the Institute contributed in large measure to this great development of our country and through the years have upheld their high reputation for scientific integrity, dynamic enterprise and dedicated service. It was their knowledge which provided the key to unlocking the mineral wealth which lay dormant for countless ages. The history of world mining dates back many centuries. We know of the mercury mines of Spain, the tin mines of Cornwall and the zinc mines of Poland, but it was not until colonization of the western hemisphere started in about 1500 that mining of any consequence began in North America. It is true that the peoples of South America and Mexico had accumulated wealth out of gold and silver, but industrialized mining was not a feature of these agrarian cultures. The mining wealth that eventually developed in North America was based on advances in the technology of processing minerals and served as an incentive to people in other new countries. Big mines were opened elsewhere in the world. From Canada, Mexico, Venezuela, Brazil, Peru, Chile, Bolivia, Rhodesia, Australia, Burma and India, to name but a few, there has been a steadily increasing production of an expanding range of minerals and metals. By the middle of the 20th century the trend was to increase the production and use of such comparatively uncommon metals as cobalt, nickel, titanium, and others, and a great mining rush started to search for, and develop, the deposits of uranium, and related radio-active minerals. It is worth pausing a few minutes to reflect that most of early mining was based on the recovery of virgin metals like gold and silver or easily treated high grade ores of copper, tin and zinc. Today, much of this type of mining would be regarded as picking the eyes out of the mine. With the development of improved ore separating, ore concentration and recovery processes, we developed into bulk mining and bulk treatment and in South Africa we have some very big mines, also outside the gold mining industry at Phalaborwa, for instance. Mining techniques are applied which compare with the best in the world. These large mines could only develop because of the perfection of new concentrating techniques and, of course, because of the development of markets. We have mentioned nickel and cobalt. These names were given to those mischievous mining sprites called nickels and kobolds to whom the suspicious miners ascribed their inability to smelt copper from copper nickel or arsenious copper ores. In South Africa, the presence of minerals was known to the modern Western world as far back as 1497 when Vasco da Gama found the native 'strandlopers' at the St. Helena Bay wearing copper rings. In 1669, after the British East India Company had formed their settlement, they employed miners and assayers in prospecting for minerals and in 1685 found traces of copper in the copper mountain of Namaqualand where some 170 years later a rich deposit of copper was to be opened up. This deposit also had a chequered

By P. R. Jochens, D. D. Howat, R. B. Atmore

INTRODUCTION The Miller chlorination process has assumed a preeminent position in the refining of gold bullion, a position it has maintained for over half a century. In the early sixties considerable interest was aroused by the idea of producing a consistently high grade bullion at the mine smelthouses themselves. However, as the use of chlorine in industrial plants is associated with considerable hazards, oxygen was considered a natural alternative, apart from bing less expensive than chlorine. Partial refining at the mine smelthouses would considerably decrease the requirements made on Rand Refinery Limited as well as indicating the possibility of reducing final refining costs. An added factor would be the purer silver chloride obtainable, after prior removal of the base metals by oxygen injection, which would facilitate the production of high-purity silver. The free energies of formation of the oxides of the metals;- silver, copper, lead, zinc, iron and bismuth indicate that, with the exception of silver, these metals should be capable of removal as oxides by oxygen injection. Rose1 had shown that during injection of gold bullion, considerable loss of silver to the boraxsilver slag occurred and, furthermore, that copper removal was not efficient and oxide attack on the refractories was severe. Plant test work2 had confirmed the difficulty of copper removal, but had shown that zinc and lead were almost completely removed. The difficulty of copper removal by oxygen injection warranted further investigation. Also, the high decomposition pressure of silver oxide suggested that by suitable control of the slag composition it might be possible to reduce to very small proportions the silver carried into the slag as oxide. The oxidation of copper by oxygen injection and subsequent dissolution of the oxide in a slag may occur according to the following reactions; Reactions 4 and 5 were considered because of the relatively high solubility of oxygen in molten silver and silver alloys. Thermodynamic data indicate that there is little possibility of any reaction involving the formation of CuO occurring at temperatures above 1 000 °C. To ensure that the operative reactions 1 and 4 take place to the maximum extent, the following factors He significant. (a) an increase in the activity of the copper in the bullion, (b) an increase in the partial pressure of oxygen in the system, (c) an increase in the activity of the oxygen in solution in the metal, (d) a decrease in the activity of cuprous oxide in the slag. From practical considerations, the operative variable most easily susceptible to control is the composition of the slag. SOLUBILITY OF COPPER OXIDES IN BOROSILICATE SLAGS Very scanty information exists on systems containing copper oxides but the indications are that slags containing considerable amounts of boric oxide would possibly prove to be the best solvents for cuprous and cupric oxides. This is attributed to the fact that the activities of copper oxides are much lower in boric oxide slags than in slags in which silica is the main network former. The number of possible slags containing boric oxide was limited by consideration of liquidus temperature, viscosity, corrosive action on refractories, volatilization, and ultimately cost (for industrial application). Slags in the systems soda-boric oxide-silica and lime-boric oxide-silica were selected paying due attention to the above limitations. Additions of 5, 10 and 15 per cent cupric oxide were made to the finely ground, premelted slags. These mixtures were then reground and 2g quantities held in re crystallized alumina crucibles at temperatures of 1150°C and 1 250°C respectively for 30 minutes. The crucibles were removed from the furnace, rapidly cooled, cut in half longitudinally, and a thin section taken from one half was subjected to microscopic examination.

By F. van Heerden

The paper sketches the. management of the various phases in a cost-reimbursable, plus-fee contract. which is claimed to be the most flexible of all contracts. In this type of contract, the contractor is reimbursed for all the direct costs Incurred, plus a percentage fee to cover his profit (or overheads and profit). The client usually reserves the right to approve all drawings, equipment purchases. contract awards, technical specifications. project cheques and change orders.

Jan 1, 1982

By J. J. Geldenhuys

The Institute revived a valuable tradition when, on the 19th of March, 1983, it held its first 'annual' banquet in some fifteen years. It was such a sparkling success that it is sure to be held more frequently in future. The success of the occasion was borne out by the fact that the main banqueting hall at the Wanderers Club was filled to capacity, with over four hundred members and guests.

Jan 1, 1983

By B. H. Sandelowsky

Prehistoric metal-working in South West Africa by B. H. SANDELOWSKY*, Ph.D. (Visitor) This paper describes a three-hundred year old metal-working site at Rehoboth, and makes a plea for information on such sites elsewhere in South West Africa so that they can be investigated. The technique of ore smelting that was used at Rehoboth appears to be different from that practised elsewhere by Bantu peoples before the modern era.

Jan 5, 1974

By P. C. van Aswegen

Owing to the strategic value of organic solvents, an investigation was conducted on the reduction of solvent losses at the Buffelsfontein solvent-extraction plant. It was established that the major cause of the high solvent losses was the high content of suspended solids in the uranium pregnant solution. To improve the clarification of the pregnant solution, it was decided to replace the conventional sand clarifiers that were being used at that stage. After pilot-plant tests had been conducted, a circulatorclarifier 16 m in diameter was installed to treat 9000 m3 per day of pregnant solution containing approximately 500p.p.m. of suspended solids. The clarifier was commissioned successfully, and yielded an overflow containing approximately 80 p.p.m. of suspended solids compared to the previous value of 250 p.p.m. This reduction in suspended solids immediately resulted in a decreasing trend In losses of organic solvent, finally yielding a reduction in these losses of approximately 50 per cent.

Jan 1, 1983

By C. Musingwini, M. Woodhall

An often overlooked factor in the analysis of mine layouts and schedules is technical operating flexibility, mainly due to its nebulous nature. If one glosses over technical operating flexibility the resultant mine layouts and schedules tend to be sub-optimal. The need to incorporate technical operating flexibility into the analysis and comparison of mine layouts and schedules is increasing in importance. This paper illustrates the nature of technical operating flexibility, reviews previous work on valuing operating flexibility and proposes how technical operating flexibility can be quantified for tabular reef mines by using a platinum reef deposit as a case study. Once technical operating flexibility is quantified it becomes possible to explore its incorporation into the analysis of mine layouts and schedules and subsequent optimization processes. The work described in this paper is part of a current PhD study at the University of the Witwatersrand. Keywords: mine plans, layouts, schedules, technical operating flexibility, ore availability.

The Water Year Office for South Africa has supplied a provisional list of scientific congresses and meetings due to be held during 1970 with "Water" as the main or secondary theme, as follows: February: SARCCUS conference on "Water for Progress," Lourenco Marques. March 16-20: Annual Congress, Institute for Water Pollution Control, Cape Town. May: Possible S.A. Akademie conference on Cooling Tower Experiments, Pretoria. May: Annual Meeting of Association of Municipal Electricity Undertakings, Potchefstroom. May 27-29: Congress on "Water Resources of Natal", Durban. June 29/July 4: Annual Congress, South African Association for the Advancement of Science, Cape Town. July 2: Joint meeting of South African Association for the Advancement of Science and S.A. Akademie, Stellenbosch. July: Winter School, Federation of University Engineering Students. July: Youth Science Week. Foundation for Education, Science and Technology. July 21-24: The South African Tunneling Conference. September: Proposed SARCCUS conference on water in Nature Conservation, Skukuza. November 16-20: International Convention on "Water for the Future", Pretoria.