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By Y. Wang

Arsenic-bearing acidic effluent from hydrometallurgical processes contains many harmful metal ions and must be appropriately treated before discharge. In the present study, arsenic, copper, zinc, aluminum, and magnesium were co-precipitated by means of the Fenton reaction. The precipitates obtained under different conditions were investigated to determine their stability. The results indicate that pH value and hydrogen peroxide (H2O2) dosage have significant effects on the removal of various elements. Arsenic, copper, zinc, and aluminum (but not magnesium) can be removed at pH 5–6 and anH2O2/As mole ratio of 2 at ambient temperature. The precipitates were mainly amorphous and granular with particle size in the micrometre range. The arsenic concentration in leachate from the toxicity characteristic leaching test was 3.6 mg/L, which proves that the precipitates are effective in fixing arsenic.

Aug 3, 2023

The industrial relations handbook, by A. Pons. Juta (P.O. Box 14373, Kenwyn 7790). 1989. "'"250 pp. Looseleaf binder. R180 + GST. Industrial laser materials processing. World Business Publications Ltd (4th Floor, Britannia House, 960 High Road, London N12 9RY, England). 1989. 180 pp. £310. Mining 1990. Longmans, Financial Times International Year Books, 1989. 592 pp. £90.00. Innovations in materials processing using aqueous, co/oid and surface chemistry, by F.M. Doyle, S. Raghavan, P. Somasundaran, and G.W. Waren (eds.). 300 pp. $125. Light metals 1989, by P.G. Camp bel (ed.). No. of pp. not available. $150. Process control and automation in extractive metalurgy, by R. Partelpoeg and D.C. Himmesoete. 225 $98. Process mineralogy VIl, by D.J. Carson and A.H. Vassiliou (eds.). 4oopp. $150. Super plasticity and super plastic forming, by C.H. Hamilton and N.E. Paton (eds.). 700 pp. $140. Supera/oys 1988, by S. Reichman, D. Duhl, G. Maurer, S. Antolovich, and C. Lund (eds.). 880pp. $99. Surface modification technologies, by T.S. Sudarshan and D.G. Bhat (eds.). 305 pp. $49. World survey of nonferous smelters, by J .C. Taylor and H.R. Traulsen (eds.). 365 pp. $90. Second Parsons International Turbine Conference. London, The Institute of Metals, 1989.270pp. £40. Mineral processing in the United Kingdom. London, Institution of Mining and Metalurgy, 1989. £25. Today's technology for the mining and metalurgical industries. London, Institution of Mining and Metalurgy, 1989. 623 pp. £60. 1989/1990 E&MJ international directory of mining. Chicago, Mining Information Services (P .0. Box 6500, Chicago, IL 60680, USA). 620 pp. US$95. Advances in project scheduling, edited by R. Stowinski and J. Weglarz. Amsterdam, Elsevier, 1989. 540 pp. Dfl. 270. Proceedings of the 3rd International Conference on Molten Slags and Fluxes. London, Institute of Metals, 1989. 335 pp. £38. Brochure on industrial screens. Obtainable from Philippe Lavernhe, Johnson Filtration Systems S.A., Z.I. Availes-en-Chatelerault, 86538 Naintre, France. 16 pp. Free. Numerical techniques, edited by P. Spiling. London, The Institute of Metals, 1989. 226 pp. £25. Phase diagrams of ternary iron aloys, Part 2, by V. Raghavan. New Delhi, Indian Institute of Metals, 1988. 360 pp. £95 (from the Institute of Metals, London). cas publications These publications are available from the Centre for Resource Studies, Queen's University, Kingston, Ontario K7L 3N6, Canada. Economic aspects of gold exploration: How much is too much, by B.W. Mackenzie and M. Dogget. 30 pp. $10.00. Mineral exploration and mine development potential in Ontario: Economic guidelines for government policy, by B.W. Mackenzie, M. Bilodeau, and M. Dogget. 180 pp. $25.00. Economic potential of base metal and gold mining in Newfoundland: Assessing the impact of regional developmentpolicy options, by B.W. Mackenzie, M. Bilodeau, and M. Dogget. 188 pp. $25.00. Publications of the AusIMM The folowing publications are available from The Australasian Institute of Mining and Metalurgy, P. O. Box 122, Parkvile, Vic 3052, Australia. Prepayment is required with al orders. The AusIMM 1989 Annual Conference 1989. $A 50. Mineral fuel alternatives and the greenhouse efect. July 1989. A$ 35. NQ gold '89. Apr. 1989. $A 50. Second Large Open Pit Mining Conference. Apr. 1989. $A 50. Explo '88. Nov. 1988. $A45. Mineral deposits of New Zealand, edited by Dr D. Kear. Monograph 13. 244 pp. $A 60. Field geologists' manual, compiled by D.A. Berkman. 3rd edition. 1989. : 350pp. $A45. The rocks speak. Essays in geology-some personal responses of a wiling listener, by Haddon F. King. 300pp. $A45.

Jan 1, 1990

By M. Weir, J. R. Cutland, L A. J. Pronk van Hoogeveen

"A computer system for the design of open pits to mine stratiform orebodies has been developed for use at Nchanga Consolidated Copper Mines, Ltd. The particular requirements of such a system, for example, the accuracy of representation of geological detail and the ability to follow footwalls, arc described in this paper, together with the methods that have been adopted to satisfy them.A modified version of the Open Pit Design Program of Rio Tinto Zinc Consultants, Ltd. is incorporated in the system and the geological data are converted into a form usable by the computer by means of a pencil follower. Some of the uses which have been made of the system are described, with reference to the long- and medium-term planning of the Nchanga Open Pit, the major producing pit at Chingola Division."

Jan 1, 2014

By T. Ellis, J. Gagnon, L. Webb, M. Burr, D. Kakengela, D. Evans, A. Mirza

Lead-based alloys are used as the primary anodes for electrowinning from sulphate-based aqueous systems. Lead anode technology has evolved over the years, migrating from pure lead and lead-antimonial alloys to the present-day lead-calcium-tin alloys for copper electrowinning and leadsilver alloys for zinc electrowinning. Anode technology has also migrated from cast to rolled microstructures in search of improved mechanical properties and higher corrosion resistance. Although great strides have been made in the development of new alloys and production processes, the industry still has unresolved issues related to untimely corrosion, which limits anode life and may lead to higher contaminant levels in the metal being produced. Lead anodes corrode because of the difference in the chemical/electrochemical potential across the microstructural features of an anode. Given a very high purity material, we find that the grain boundary areas corrode significantly faster than the rest of the grain. A balance of alloying element selection and microstructural design allows the grain boundary area to be engineered, thus minimizing grain boundary corrosion. However, operational issues can lead to unexpected corrosion behaviours that we will discuss moving forward. The comments in this work, although directed toward copper electrowinning, can be extended to similar phenomena in other metals electrowon from sulphate media (i.e., zinc, nickel, cobalt, manganese). The life cycle of electrowinning anodes depends on tankhouse operating conditions and maintenance of the anodes, including cleaning and straightening. This paper will focus on the operational aspects of maximizing the utilization of lead anodes for base metals electrowinning.

Jan 1, 2016

By D. G. Davies

Colloquium on the construction of Slimes dams The following contributions to the discussion at the above Colloquium were received for publication. D. G. DAVIES* This contribution is really a follow up on Mr H. E. Cross's paper on the conversion of a uranium plant to the recovery of zinc (published in the Journal, November 1973). Ecological aspects of slimes-dam construction by H. T. CLAUSEN C. M. VAN STADEN* Published in the Journal, December 1973 I should like to thank Mr Clausen for his paper and to congratulate the Research Laboratories and the Vegetation Unit of the Chamber of Mines on the excellent work they have done in the past, are still doing at present, and, we hope, will continue to do in future, on the testing of various methods for the covering of slimes dams and specifically on the vegetation of dams. The impact of slimes-dam formation on water quality and pollution by R. T. RUDD* C. M. VAN STADEN Published in the Journal, December 1973 I should like to congratulate Mr Rudd on the paper he presented. Congratulations are also due to the Department of Water Affairs for the practical attitude they have taken in implementing the Water Act. Slimes-dam construction in the gold mines of the Anglo American Group by W. T. RUHMER W. R. FLOOK* Published in the Journal, February 1973 Methods for the construction and operation of slimes dams in the gold-mining industry do not appear to have changed much for some considerable number of years.

Jan 3, 1974

By G. Song, X. Liu

The global coal industry has changed significantly in recent years. In this paper we analyse the coal production and consumption, imports and exports, and coal prices in China and other major coal-producing countries during the past four decades. The analysis shows that global coal production and consumption have declined over the last three years, in striking contrast to the continuous growth for most of the past 35 years. Australia, Indonesia, and Russia have become the world’s major coal providers, while China, India, and the USA, and Germany are the major coal consumers. The world’s, and China‘s, coal industry can be classified into four stages of development: the stable growth phase, stable phase, rapid growth phase, and high-quality phase. Coal prices rose in the world’s four major coal markets in 2016 after four consecutive years of falling prices. The elimination of overcapacity and production-optimizing operations in China could assist in achieving a demand and supply balance.

Aug 8, 2024

By L. Kühnel, H. Lieberwirth

Confined bed comminution in High Pressure Grinding Rollers (HPGR) and Vertical Roller Mills (VRM) is gaining substantial attention in many applications. Previously used mainly for milling coal or construction materials, HPGR and VRM have started to complement or even replace tumbling mills in ore beneficiation. Materials like coal or clinker are relatively homogenous, however, in comparison to metal ores and wall rocks. This characteristic poses a new challenge to the confined bed comminution but also an opportunity. Fuerstenau and Abouzeid have investigated the selectivity in comminution of a mixture of particles of different strength in a particle bed. The median particle size and particle size distribution (PSD) of the two constituents used were kept constant. Only the proportion of the two constituents was modified. The competence of a material is, however, also a function of particle size. Smaller particles tend to be more competent than larger ones of the same material. If selective comminution is applied on ores, this size influence has to be understood. The paper presents research results on this topic based on experimental investigations with model materials as well as with natural particles, which were stressed in a piston-die press. It appeared that the comminution result depends substantially on the material characteristics and the composition of the mixture. Conclusions will be drawn for the application in future applications of selective comminution in mineral processing. Keywords: Confined bed comminution, HPGR, VRM, piston die press, particle size

Jan 1, 2020

By G. Segaetsho

"Conventional blasting rules of thumb used to develop blast designs are based on parametric ratios, with insufficient consideration of the rock mass factors that influence the achievability of final wall designs. At a hard-rock mine in Botswana, catchment berm designs were frequently unachievable, which exposed the mining operation to safety hazards such as local wallrock failure from damaged crests, frozen toes, and rolling rockfalls from higher mining levels. Increased standoff distances from the highwall reduced the manoeuvring area on the pit floor and the extraction factor that was safely achievable. Application of rock mass classification and the Blastability Index (BI) as a means to improve wall control was investigated. Zones were defined according to rock types forming the western highwall rock mass, and distinguishing rock mass classification factors were used to establish the suitable wall control designs. The approach combined rock mass classification methodologies such as the Geological Strength Index and the Rock Mass Rating, and related them to the BI and discontinuities of the rock mass to produce a design input tool that can be used to develop objective wall control designs. The designs driven by the tool inherently take into account the rock mass characteristic factors at the centre of the rock mass classification methods mentioned above, and significantly reduce the dependence on rules of thumb. It was found that this approach produces designs with explosive energy measures that are consistent with the required rock-breaking effort and the behaviour of discontinuities, while preserving perimeter walls.IntroductionBlasting is the first step in the comminution process. Various coordinated inputs contribute to its success, and in turn to the efficient execution of processes that lie downstream from the blasting step. Primary to meeting production and operational objectives of a mine, as well as the protection of human life and the mineral resource, is the achievement of highwall design specifications and competence. To this end, this study investigated the use of existing tools and knowledge for the achievement of highwall control goals at a hard-rock mine in Botswana."

Jan 1, 2018

By J. -M. Milazzo, T. Wallmach, S. B. Blancher, A. Amalric

In a FeNi electric arc furnace, the physical properties of the slag (chemistry, viscosity, liquid/solid/gas ratio) are of crucial importance in controlling the efficiency of the process. In this paper, we studied the slag crystallised on the walls of a semi-industrial furnace (freeze-lining), the slag rising through the burden during foaming phenomena, and the casted slag. The freeze-lining is the layer of oxides that crystallises on the refractory wall of a furnace, protecting it from chemical and mechanical aggression. It records changes in furnace conditions (slag chemistry, temperature, oxygen fugacity), which makes it possible to observe the impact of these elements. In the high reduction test, the freezing lining is composed of magnesian olivine. Switching to a low reduction process increases the Fe content of the olivine and causes orthopyroxene to appear, making the freeze-lining mechanically and thermally weak. Thermal incidents in the furnace cause significant slag foaming. This foaming is produced by a massive crystallisation of the olivine (due to the drop in temperature), and inducing an exponential increase in viscosity, preventing the free circulation of gases. These foaming episodes are also recorded in the freeze lining and form layers rich in gas bubbles, and therefore mechanically fragile. The slag casted and cooled in a ladle allows the first steps of slag crystallisation to be studied. Olivine is the liquidus phase, with a magnesium-rich core and an iron-enriched rim, contemporaneous with the orthopyroxene phase. The habitus of these phases is very similar to that found in komatiites for the same minerals. FeNi slag is therefore an industrial analogue that is easy to study and compare to komatiites. Keywords: Pyrometallurgy, ferronickel, slag, freeze-lining, characterisation, olivine, mineralogy

Jan 1, 2020

"Chairman: Professor C. O. Frush Rapporteur: Mr A. C. SchmidtPapers:Planning of underground copper mining by J. K. Williams, L. Smith and M. P. WellsLinear programming models of copper leach and solvent extraction plants by W. P. C. Duyvesteyn, J. R. Cutland and J. R. L. RusselPlanning and forecasting stope production by D. W. Kappes and P. F. X. Moussett-JonesA proposed method of dynamic ore reserve assessment for a caving system of mining by A. F. Spinks and S. P. NicholsThe initial point made by Mr L. Smith in presenting his paper was that the planning aid outlined in the preprint was neither sophisticated nor complicated. However, it was a system which worked and was a very real way in which the computer was being used to assist miners, in particular, who at the present moment have very little experience in the use of computers.Mr Smith apologised for the fact that the editors of the paper had eliminated all reference to 'time'. This was very unfortunate because the essence of the system was that it saved time, which was one of the main points made in the paper.The operations being planned by this means cover the Rokana orebody which is a stratiform body mined by open stoping.The planner has to decide how much ore to mine from each base in each time period of his plan, that is, from three to four months hence to a year ahead. Normal procedure is for the planner to have discussions with the underground manager on some of the information he requires. The sort of information needed is (i) tramming limits for each face, (ii) extraction and grade factors, (iii) the present status of mining operations so that the planner knows where to start the new plan, and, (iv) details of any other mining consider¬ations that need to be incorporated in the plan.The objective at this point is to produce an initial plan for discussion purposes. All the information required comes from one sheet per stops and shows, inter alia, the stope identifier, the length along strike, the ore tonnage, the copper and cobalt grades and, finally, the extraction and grade factors.The program itself, among many other things, checks the data for validity, compatibility, completeness and credibility and prints error messages accordingly. Output from this system is in the form of a summary of production from each face, as well as giving the figures of ore reserve depletion. This summary indicates which slopes are to be mined in this time period, the original survey grades (copper and cobalt), the estimated production grades, how much is to be mined from each stope and the copper and cobalt production accordingly."

Jan 1, 2014

By J. Hadjigeorgiou, G. Knox

Since their introduction in 2010, paddled energy-absorbing rockbolts have been widely used in seismically active hard rock mines. This paper provides new data and reviews previous work to quantify the performance of paddled energy-absorbing rockbolts under controlled laboratory conditions. Of significance is the realization that the typical split location in impact tests, at the centre between two paddle anchor points can at best provide an upper limit value. This inherent variability in performance under different testing configurations should be acknowledged and taken into consideration in the design of ground support in seismic conditions. This paper discusses the reduction in capacity of paddled rockbolts as a function of loading angle from a maximum value during axial tests (0° loading angle) to the lowest value during pure shear (loading angle of 90°). A significant reduction in displacement capacity is observed as the loading angle changes between axial (0°) and 40°. Beyond a 40° loading angle up to shear (90°) loading the reduction in displacement capacity is less significant. Due to the variances in the capacity observed through the variance of the testing configuration: loading mechanism, direction of loading, location / presence of a discontinuity, it must be recognized that results from laboratory-based testing are not independent of the testing configuration. This should be acknowledged when extrapolating anticipated performance in the field.

Oct 9, 2024

By M. -A. de Ville d’Avray, J. Bosman, S. Brochot

Dense Medium Separation (DMS) technologies are used for light (coal, lithium) or heavy (chromite, iron ore, diamonds) minerals concentration, but also for ore pre-concentration (Pb/Zn) or waste (plastics). Dense media are mainly formed from a suspension of magnetite or ferrosilicon in water. Such DMS circuit design or optimisation requires a full and detailed material balance which can be obtained by the aid of modelling and simulation tools. This balance is not limited to ore and its valuable minerals, but also the recovery of the dense medium itself. If the density is the main property used for separation, the particle size plays a non-negligible role, and, more precisely, the liberation classes which can be associated to the washability curve. The paper presents how the modelling and simulation platform USIM PAC can answer this challenge with the set of models for DMS operating units such as drums or cyclones, and their associated screens (drainage, rinsing) and magnetic separators for medium recovery. Some examples for mineral concentration will illustrate this approach. Keywords: Process simulation, process modelling, dense medium separation, process optimisation

Jan 1, 2020

By F. Yang, S. S. Long

Mixed fatty acids, such as oxidised paraffin soap, are frequently used as a substitute for oleic acid in flotation of scheelite in China. Not only because it is cheaper than oleic acid, but also because it is superior in flotation performance to oleic acid. This superiority is generally attributed to the mixed fatty acids' synergistic effect. In this paper, the synergistic effect of oxidised paraffin soap was investigated. We found it mainly consists of a series of saturated fatty acid salts, with six to nineteen carbon atoms. All the contained fatty acids were classified into four groups based on their chain length to make the research work practical. Also, the groups were labelled as 1, 2, 3, and 4 in order. The research was simplified into studying the synergistic effect of four equivalent collectors, instead of fourteen fatty acids. It is justified by the fact that neighbouring fatty acids are expected to have a similar flotation performance. The synergistic effect of the four groups of fatty acids was studied by single-mineral flotation with single groups, binary mixtures, ternary mixtures, and the full component, as collector respectively. The flotation performance index and synergy value were introduced to evaluate flotation performance and synergistic effect of groups, respectively. The results show that the mixture 1+2+3 has the strongest synergy of all followed by the mixtures 1+3 and 2+3. The mixture 3+4 and 1+2, on the other hand, have negative synergy. The synergistic effect of mixtures of groups indicate that being consecutive in length and a broad range of lengths are vital for fatty acids to enhance synergy. Group 3 is fundamental for the collecting action of 733 oxidised paraffin soap in the flotation of scheelite. The fatty acid soap in group 4 is not suitable for flotation due to its low solubility. Keywords: Mixed collectors, synergistic effect, scheelite

Jan 1, 2020

By J. Pelders, F. Magweregwede, S. M. Rupprecht

Increased depths of conventional gold and platinum mines, longer travelling times as working places move further from the shaft, and ancillary activities taking place in the mining cycle reduce the useable time spent at them workface. Current shift lengths of 8 hours 20 minutes may no longer be adequate ton complete required mining activities.The impact of mineworker commuting times on shift work is also not well understood. The aim of this research was to draft a framework to optimize shift cycles in order to maximize productivity, health, safety, and wellness in the South African mining sector. The framework was informed by a review of the literature, case studies at a local gold mine and platinum mine, and a workshop with industry experts. The findings indicate potential advantages of extended shift lengths and continuous operations, such as improved productivity, asset utilization, and employee morale. However, concerns included fatigue and the associated safety hazards, particularly when working longer shifts, night shifts, and numerous consecutive shifts. Job demands, personal factors, and commuting times are further considerations when scheduling shifts. The ideal shift system for the mining sector should holistically consider and balance operational requirements, health and safety, and employees’ and their families’ requirements, and suit the unique needs of each operation. Changes in shift cycles will require a structured change management process, which involves all stakeholders, and could help to enhance the viability of the South African mining sector.

Aug 1, 2021

By J. A. L. Napier

It has been established that significant time-dependent stope convergence may occur over time periods of hours and days in certain hard-rock gold and platinum mines. The source of this time-dependent behaviour appears to be associated with both pre-existing discontinuities and with mining-induced fractures that form near the stope face. These induced fractures may be associated with blasting processes and may also be formed in response to high stress concentrations in the unmined regions immediately ahead of the stope face. In shallower platinum mining operations, time-dependent behaviour is, however, observed to be much less marked unless some form of specific mining-induced fracturing occurs. One particular case of considerable interest is the time-dependent behaviour that is found to be associated with the formation and deployment of crush pillars. The purpose of the paper is to present a simple limit-equilibrium computational model of this behaviour that is sensitive to both the formation sequence and the size of planned crush pillars in a mine layout. This model provides a useful means to optimize the sizing of crush pillars, and at the same time may be used to identify potentially hazardous circumstances in which pillars may not crush in a stable manner.

Jan 1, 2012

By J. Hadjigeorgiou, G. Knox

There is a considerable wealth of information on the behaviour of rockbolts under axial loading conditions both in situ and under controlled laboratory conditions. However, there is comparably less data on the behaviour of rockbolts in shear. Several authors have contributed to the understanding of the behaviour of conventional rockbolts’ performance under shear loading. Much of this data have been gathered through experimental programmes conducted on sections of the rockbolt. Considering the continuous coupling between the rockbolt and borehole interface, the approach is justified. Due to the design premise of energy-absorbing rockbolts with discrete couplings, full scale testing is required to quantify the behaviour of the rockbolts. This paper reviews published results obtained from two testing facilities, which are the SINTEF rockbolt pull test rig in Trondheim, Norway and the Epiroc Combinations Shear and Tensile test rig in Johannesburg, South Africa, both capable of conducting full scale testing of rockbolts. Based on this high-quality database it was possible to identify three distinct responses of rockbolts in shear. The behaviour under load is controlled by the presence or absence of an encapsulation medium (resin/cement grout), the reinforcement mechanism, and whether the rockbolt is continuously or discretely captured. As a reference the results are compared to the performance in shear of conventional grouted rockbolts.

Nov 24, 2025

By E. Y. Baafi, H. Fan, W. Zeng

We present a discrete event simulator, TSJSim (Truck-Shovel JaamSim Simulator), for evaluating the stochastic and dynamic operational variables in a truck-shovel system. TSJSim offers four truck allocation strategies: Fixed truck assignment (FTA), Minimizing shovel production requirement (MSPR), Minimizing truck waiting time (MTWT), and Minimizing truck semi-cycle time (MTSCT) including the genetic algorithm (GA) optimization and the frozen dispatching algorithm (FDA) optimization rules. Multiple decision points along the haul routes for all the trucks close to the decision points were included in the model. The simulation results indicate that the trends associated with production tons and queuing time utilizing the four truck allocation strategies (MSPR, MTWT, FDA, and GA) all demonstrated similar patterns as the fleet size varied. As the system fleet size increased, the system production tons under these strategies at first increased significantly and then remained relatively constant; the queuing time relating to these strategies showed a positive relationship with the system fleet size. The bunching time decreased when the truck allocation strategies were applied in the model. In the simulated truck-shovel network system with multiple traffic intersections, by assigning the trucks at the intersections, both productivity and fleet utilization increased.

Dec 13, 2022

By Y. -L. Chiang

Paper written on project work carried out in partial fulfilment of BSc (Eng) (Chemical) The generation and control of manganese sulphide particle size distribution using various mixing configurations were investigated. Specifically, this paper discusses how varying mixing intensities on a macro and micro scale affect the resultant manganese sulphide particle size distribution (PSD) at a constant concentration. The mixing variations were achieved using various Y- and T-mixers as premixing devices into a jacketed, agitated vessel. The reagents used to generate the seeds were aqueous manganese sulphate and sodium sulphide solutions. The results showed that the absence of micromixing resulted in very poor control of the particle size distribution, the particle size and the number of particles produced. This was due to the fact that the macromixing time is much greater than the corresponding precipitation time, resulting in different mixing regions existing within the reactor. From the micromixing experiments, the T?mixer was found to be the most effective mixing device at lower concentrations due to the T-mixer providing a faster mixing time than the other mixing configurations, thereby effectively localizing the supersaturation and hence controlling the precipitation. The results obtained from the direct addition without the extension pipe (i.e. short mixing time) indicated a general increase in mean particle size and decrease in total particle number at reagent concentration of 0.007 mol.dm-3as compared to the corresponding micromixing experiments. The phenomenon may be due to incomplete crystallization at the immediate exit of the mixing device. Further experiments need to be conducted before any conclusions can be drawn about the precipitation mechanisms.

Jan 1, 2007

By M. Royle, A. Bloem, R. Uken

Rock mass damage induced by mining increases the fracture frequency and joint aperture width in the pit walls and rock mass behind open pit mine slopes. The depth and intensity of this mechanical damage relative to the pre-mining state is not well understood and yet is a major factor in the development of slope stability models and operational guidelines. The induced damage can be partitioned into domains or zones. The blast damage zone is essentially a ‘free flow’ rock mass volume, which transitions quite rapidly into the excavation damage zone, which extends beyond that. In both zones, transient high in situ water pressures are often linked to unstable slope conditions. Whereas rock damage can enhance passive depressurisation in the rock mass, high infiltration rates on the other hand, as one could expect during rainstorm events, will decrease slope stability within the dilated pit rock mass, especially in the blast damage zone-excavation damage zone, by increasing pore pressures for short periods of time. Ice jacking and freshet are additional factors to consider in (sub) arctic environments and can be exacerbated by unfavorable rock fabric orientation. On a local scale, brittle deformation damage zones, in the form of faults, can contribute to slope instability, or enhanced stability because of slope depressurisation, depending on their location and orientation relative to the pit shape and the water sources. In this study, the shapes of the damage zones and their anticipated impact on infiltration and/or passive depressurisation are considered for different pit morphologies, rock mass conditions, in situ stress, and hydrogeological settings. Some unusual hydrological situations, like mining towards rivers and lakes and the potential effects on pore pressures, are also considered. This investigation has resulted in the development of a method to adjust initial hydraulic conductivity values used to estimate transient pore pressure conditions found in rock masses exposed in different pit morphologies and stress regimes as well as discontinuities’ orientation relative to open faces within the open pit mine. The changes in K values and pore pressures can then be used to determine hydrogeological influence more accurately on future pit slope stability.

Sep 1, 2025

By J. W. van der Merwe, K. G. Moloko

Furnace wall tubes from 600 MW subcritical boilers at three coal-fired power stations were sampled and the fireside deposits examined to determine the mechanism of fireside corrosion. This involved an indepth investigation into the morphology and composition of the fireside deposits and the conditions of the furnace that enable this type of attack. SEM-EDS analysis revealed high concentrations of oxygen, iron, and sulphur, QEMSCAN and XRD analyses identified the presence of Fe3O4, Fe2O3, FeS, and FeS2. Differential thermal analysis showed thermal activities at temperatures of 500–600°C, 900–1100°C, and 1100–1250°C, which are associated, respectively, with FeS2 oxidation to FeS and Fe2O3, at 475–525°C, formation of aluminosilicates at 925–1100°C, and melting of FeS around 1190°C. The absence of sodium and potassium eliminates the contribution of molten alkali sulphates to the corrosion. The consistent coexistence of iron sulphide and iron oxide is indicative of the substoichiometric conditions in the furnace, while the detection of pyrite suggests that the coal is not completely combusted, which points to a poor combustion process. These observations were affirmed by gas analysis at one of the stations, where very high levels of carbon monoxide were measured at the furnace wall (≥ 14 000 ppm) and furnace exit (≥ 3500 ppm). The high CO concentrations are indicative of limited combustion caused by limited O2. These reducing conditions promote the formation of FeS-rich deposit, which is the corrosive species responsible for degradation.

Jun 1, 2021