Search Documents

By William L. Crentz

1. SALES PUBLICATIONS

Nov 1, 1949

By A. S. Prokopovitsh

A spectrophotometric method for the determination of small amounts of copper in tungsten metal powder using the principle of solvent extraction has been developed by the Federal Bureau of Mines. The metallic sample is dissolved in hydrogen peroxide, tartaric acid added, the pH adjusted, and the excess peroxide destroyed by boiling. Copper is reduced to the cuprous state, and the reagent neocuproine (2,9-dimethy1-1,10-phenanthroline) is added to form a colored complex with the copper. This colored complex is then extracted into chloroform and the absorbance of the separated chloroform layer measured on a spectrophotometer. Copper contents as low as 1 p.p.m. (parts per million) can be determined. The method is limited to finely divided tungsten powder. The interest of the Bureau of Mines in developing more sensitive methods for the determination of trace impurities in high-purity tungsten prompted an investigation of the possibility of using solvent extraction-colorimetric methods. The organic reagents now commercially available make possible many extremely sensitive colorimetric methods for the determination of metallic ions. Extraction of the colored complex into a small volume of organic phase can be used to further increase sensitivity (4) .4/ This general approach has the added advantage that no special equipment beyond that normally found in an analytical laboratory is required.

Jan 1, 1961

By J. G. Stuart, A. W. Cipkins, R. H. Thompson

Preliminary safe distances for blasting wiring from typical electromagnetic sources are presented. The distances are for underground coal mines and electromagnetic sources in the frequency range below 10 MHz. The distances are based on measurements performed at 3 locations in each of 3 coal mines. The measurement apparatus, measurement procedure, measurement results and the rationale used in the calculation of the safe distances are all described. The safe distances presented are dependent on the measurement results and their interpretation. More measurements are clearly necessary to establish the validity of the suggested distances.

Jan 1, 1985

By S. P. Kinney

[The blast-furnace operator is often confronted with the problem of determining the size of the materials which are used in the furnace burden. The statement is heard that the coke is larger or smaller or that certain ore is finer than that previously used. A screen analysis of the materials used gives a measure of the different sizes of materials in an aggregate. When one is fine and the other is coarse, the difference is obvious; but when the materials are of similar sire, it is more difficult to estimate the degree of finances or coarseness. In considering raw materials it would be desirable to be able to judge the size of the radio ideal materials entering the furnace and the burden as a whole, by one representative value, such as the average size of particle. Previous work by Perrott and Kinney3 developed a method for measuring the average size of particle in a mass of finely ground materials, and an attempt will be made to apply this method to the materials included in the blast-furnace charge and to the entire burden.]

Jan 1, 1930

By T. L. Joseph

The purpose of this article is to describe briefly the operation of a 6-ton blast furnace on a charge of bauxite, limestone, iron ore, and cast-iron turnings and to point out the bearing which smelting such a charge has upon the production of alumina cement. One object of the experiment, conducted by the Bureau of Mines in cooperation with the Aluminum Co. of America, was to determine whether tae so-called Pedersen process3 can be applied to the blast furnace. This process consists of smelting a charge of bauxite, iron ore, and. limestone, and results in to products. One is a slag containing about 50 per cent of A1203 and is intended for use in manufacturing aluminum, and the other is iron low in sulphur. Complete details of the test are published in other reports4. Blast-furnace slag is now recognized as a satisfactory and economical raw material for making Portland cement, Wm. A. Forbes5 has recently reported that in 1926 an important steel interest used well over 1 million tons of slag in producing about 24 million long, tons of cement. This is equivalent to about ½ ton of slag for each ton of cement. Alumina cement can be made direct in the blast furnace. Its physical character would have to be changed by grinding, but no change in its chemical composition would be necessary.

Jan 1, 1928

By John A. Johnson

Tests ere conducted at the Mount Weather testing adit of the 57 Bureau of Mines on the effectiveness of spraying water along the outside of the drill steel as compared with standard wet-drilling practice. The spray equipment used in the tests was designed primarily for the control, in quarries, of dust from dry drilling with solid type drill steel. Equipment Spray equipment is made in sizes to fit different drill steel but is alike in design, the only difference being in the diameter of the ring and the number of spray holes. The device is mace of cast steel and has a coating of Stellite on the inside edge that comes in contact with the drill steel. It looks like a garden spray, except that the spray holes point in only one direction.

Jan 1, 1939

The Ringelmann Smoke Chart fulfills an important need in smoke abatement work and in certain problems in the combustion of fuels. A knowledge of its history and method of preparation is, therefore, of interest to many. Since instructions on its use are not shown on the recent edition of the chart, those included in this revision of the previous Bureau of Mines publication now are a necessary complement to the chart, More detail regarding the use of the chart is included than was given in the earlier version.

Jan 1, 1967

By D. E. Hirsch

The Bureau of Mines has developed a systematic procedure for separation, characterization, and semiquantitative analysis of high-boiling (350° to 550° C) distillates of crude oils. Isothermal and molecular distillation were used to prepare the 370° to 530° C distillate of Recluse, Wyo., crude oil. The distillate was separated into fractions by chemical treatment, silica-alumina gel adsorption, and gel permeation chromatography (GPC). The fractions were analyzed by use of GPC correlations and mass and nuclear magnetic resonance (NMR) spectrometry. The increased knowledge of petroleum composition obtained from the data will contribute to improved petroleum processing and utilization and energy conservation.

Jan 1, 1974

Control the release of ground-water into active underground coal workings by short-term pumping from dewatering wells sited on fractures. Approach The sudden release of fracture-stored groundwater into underground coal workings often occurs when mine workings are developed beneath fracture valleys, Pumping from fracture trace-sited dewatering wells, prior to development of the underlying workings, can be an efficient means of intercepting fracture-stored groundwater before it is released into the mine. Dewatering operations are discontinued once the underlying mine workings have been fully developed, and the maximum possible reduction in fracture storage has been achieved through pumping. How It Works An aerial photographic technique known as fracture trace analysis is used to site dewatering wells on rock fractures in a valley bottom. Downhole caliper and temperature logs are used to assess the fracture flow potential of each dewatering well drilled.

Jan 1, 1987

Develop a more efficient method of testing the integrity of in-situ leach mining operations. The Problems For economic and environ-mental reasons, in-situ leaching operations must be sure that wells do not leak. Loss of solution in large quantities can be expensive in itself, and if such losses result in pollution the costs can be even higher. Wells are usually tested for leaks by sealing them with packers, pressurizing them and monitoring the pressure drop. However, many commercially-available packers are designed to be used in steel-cased wells rather than the fiberglass-or plastic-cased wells used for in-situ mining. These packers are heavy, cumbersome, expensive, and often leak. In addition, commonly used well-integrity-test systems require lengthy test periods and drill rigs or hoist trucks with rigid pipes must be used to run the packers in and out of the well. The Bureau of Mines has developed a mobile, self-contained leak-testing system that is faster, uses trailer-mounted equipment that can be operated by one person, and features a new inflatable packer.

Jan 1, 1985

By G. St John Perrott

"The United States Bureau of Mines is cooperating with the State of Utah and the City of Salt Lake in an investigation of methods of abating the smoke nuisance in Salt Lake City. In the course of this work samples of the atmosphere have been collected and analyzed in an attempt to determine the part played by sulphur dioxide or smelter gases in polluting the air at Salt Lake City.A fairly wide-spread opinion exists in Salt Lake City that the smelters contribute appreciably to the smoke nuisance. The gases discharged from the smelter stacks are believed (1) to float over the city in a heavy blanket which prevents the smoke from rising, and (2) to unite with the water vapor in the air to form corrosive fogs injurious to health and property.The first of these theories seems untenable. If the gas did not mix with air it would sink, owing to its heavier specific gravity, and form a blanket an the earth. Actually, the gas diffuses rapidly in air and any part reaching Salt Take must he thoroughly diluted. Perhaps sulphur dioxide in sufficient concentration might aid in fog formation. The more obvious nuisance, however, would be the injury to health and vegetation.The Garfield smelter is 16 miles west of the city, The Murray smelter 8 miles south, and the Midvale smelter 12 miles south. Under normal operating conditions, a relatively small amount of solid matter is discharged from these stacks. The toxic gaseous constituent of the discharge is sulphur dioxide, it is being discharged from the smelters the year round. If they are a factor in the city's smoke problem, the concentration of this gas in the air of the city should be appreciable and should increase toward the smelters, the con centration being highest with a south or a west wind."

May 1, 1920

By Ronald A. Vary

This paper is one of a series prepared by the United States Bureau of Mines dealing with milling methods and costs. In view of the current revival of interest in gold mining, information dealing with practices and costs in the development of gold properties is apropos. Milling practice at a small gold property in the prospect stage is described where, with a small outlay for plant and equipment, development has been carried on for about 20 months on the proceeds of the mill operation with little additional expenditure. The paper shows about what may be expected as to costs at a small property operated under northern climatic conditions and with rigid economy throughout the plant.

Jan 1, 1931

By James A. Powell

The theory of electromagnetic fields indicates such fields could be used to detect and locate trapped miners. To be useful, the hardware of the system must meet a number of requirements, including small size, intrinsic safety, and rugged construction. Such hardware has been built, and the system has been tested by the Bureau of Mines and its contractors. These tests indicate that the electromagnetic method provides a practical means to locate miners in emergencies.

Jan 1, 1976

Provide a means of recovering precious metal values from finely ground tailing materials. Approach Determine the procedures needed for agglomerating the finely ground material for subsequent heap-leach cyanidation of the precious-metal-bearing tailings. Applying Agglomeration/Heap-Leaching to Fine Tailings Agglomeration technology was developed by the Bureau of Mines to provide cost-effective recovery of precious metal values though better heap leaching of clayey or low-grade ores. While many precious metal producers have adopted this technology to reclaim precious metals from crushed ores and wastes, other operations have experienced problems in using the heap leaching technique effectively on piles of fine tailings. In contrast to the coarser ore and waste material, most tailings piles contain more than 50 percent minus 200 mesh materials with no coarse material. Fine particles and clays present in the pile can impede 8 uniform flow of the leaching solution through the heap, thus preventing efficient and cost-effective precious metals recovery.

Jan 1, 1986

By John A. Johnson

[Tests were conducted at the Mount Weather testing adit of the Bureau of Mines4/ on the effectiveness of spraying water along the outside of the drill steel as compared with standard wet-drilling practice. The spray equipment used in the tests was designed primarily for the control, in quarries, of dust from dry drilling with solid type drill steel. EQUIPMENT Spray equipment is made in sizes to fit different drill steel but is alike in design, the only difference being in the diameter of the ring and the number of spray holes. The device is made of cast steel and has a coating of Stellite on the inside edge that comes in contact with the drill steel. It looks like a garden spray, except that the spray holes point in only one direction.]

Jan 1, 1939

By N. A. Eilertsen

This report describes field investigations conducted in 1953 of two occurrences of manganese and a separate magnetic anomaly in the Southern manganese district of Aroostook County, vicinity of Houlton, Maine -the Pierce deposits, in Hammond Plantation Township; the Burnham anomaly, also in Hammond Plantation; and the Nickerson-Farm prospect in Hodgdon Township. The manganese occurs in a thinly laminated sedimentary rock containing manganiferous carbonate interlayered with fine-grained metamorphosed sediment, rich in chlorite or hematite. The surrounding rocks are mostly dark gray-green slates. Samples composited for metallurgical testing from the Pierce deposits and the Nickerson-Farm prospect assayed 9.0 to 12.3 percent of manganese. More than 90 percent of the manganese could be extracted with sulfuric acid, but in most instances 30 to 40 percent of the iron was also extracted. Leaching tests indicated that, after being reduced in a hydrogen stmosphere at 600° C., about 85 percent of the manganese could be selectively extracted by a solution of ammonia-ammonium carbonate with iron extraction of only 14 percent.

Jan 1, 1958

By Richard C. Repsher

Intermittent mining in the slope section at Dutch Creek No. 1 mine, Carbondale, Colo., of the Mid-Continent Coal and Coke Co. has resulted in erratic and minimal rock noise data, which, in turn, has necessitated a change in the method used to plot daily mine noise in order to be useful to the researchers at the mine. Daily and weekly cumulative plots of rock noise under these conditions have not shown significant stress changes as clearly as bimonthly or longer noise rate plots. Hence, longer term cumulative rock noise plots, as described in this Bureau of Mines report, have been added to the data analysis at Dutch Creek No. 1 mine, and have been shown to delineate unique areas of rock noise activity more clearly than shorter term plots. The longer term plots should aid in the detection and delineation of potential failure areas, when used in conjunction with other proven forms of data analysis.

Jan 1, 1979

By B. J. Dalton

Several relationships between coexisting phases for analytical binary solutions near the critical point are given. These relationships were developed from a consideration of a (G u, P) surface at constant temperature and a (G u, T) surface at constant pressure, where G is the molal Gibbs free energy, u is the concentration of component 1 expressed as a mole fraction, G is the pressure, and T is the temperature. These formulas should facilitate the calculation of some of the quantities useful in making thermodynamic consistency checks on phase equilibria data about the critical point.

Jan 1, 1970

By G. A. Apell

The presence of considerable mineralization at the surface together with other favorable conditions suggested inclusion of the Nigger Jim diggings area in a comprehensive study of shallow lead deposits in southwestern Wisconsin. The area, which was the site of considerable shallow development some 60 to 70 years ago, offered the possibility of substantial quantities of lead at near-surface horizons. The investigation included completion of 30 churn-drill holes totaling 1,808 feet of drilling, 2 diamond-drill holes totaling 164.5 feet of drilling, and 25 feet of test pitting in two excavations. The degree of mineralization was determined in an area l,500 feet long and 150 to 300 feet wide along a mineralized trend that has not been investigated beyond the limits of the zone drilled by the Bureau of Mines.

Jan 1, 1948

By Jack R. Woodyard

Bonding angles, promotion energies, and relative atomic sizes can be estimated through the solution of a set of algebraic equations generated from simple atomic models, and quantum mechanical parameters such as bond strength can be estimated from simple, hydrogenic form-wave functions. The precepts of The Engel-Brewer Theory are melded with the "Crystal Approximation Model" to produce atomic-structure models making these predictions, The two-valence-electron case is presented in this report. For the candidate atoms Be, Mg, Ca, Sr, and Ba the calculated promotion energies agreed within a few percent of their experimental values. These atomic parameters determine the possible crystal structure of the candidate atoms when alloyed. This is part of the effort at the U.S. Bureau of Mines to develop methods for alloy design in response to requirements for new high-performance alloys that conserve critical or rare materials.

Jan 1, 2010