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By A. Adams

The Bureau of Mines determined the composition of the vapors liberated during thermal decomposition of aluminium nitrate nonahydrate. Small samples were heated from room temperature to 5500 C with initial heating rates from 500 to 2000 C/min. Gases were rapidly swept away from the heated chamber with Ar and subjected to immediate analysis in order to minimize reaction between the components. In addition to H20, four N-containing compounds were identified: HN03, N02, NO, and N20. Nz could not be determined in the presence of the nitrogen oxides, and at-tempted separation from the oxides led to the formation of more nitrogen. Relative amounts of each component were found to vary over a period of time; however, total amounts measured with different heating rates were reasonably constant and were typically as follows: 84.2 pct HN03, 7.1 pct N02, 4.3 pct NO, and 4.2 pct N20. HN03 and NO were determined from chemical reactions with a permanganate solution, N20 was measured with a mass spectrometer, and NO2 was measured with a spectro-photometer. Details of the methods used are described. Since NO2 and NO can readily be converted to HN03, about 96 pct of the N from the decomposition can be recovered as HN03

Jan 1, 1987

By George S. Rice

"It is well known that the lost coal left in the ground in mining, under such conditions that recovery is practically impossible, constitutes a large proportion of the coal in the beds worked. A recent estimate, in a paper on ""The World's Fuel Supply"" presented by Prof. L. P. Breckinridge, of Yale University, before the Annual Meeting of the. American Society of Mechanical Engineers, places the average loss in bituminous coal mining as one-third left in the ground.The bald statement that there is a loss of one ton of coal for every two recovered may seem to those not familiar with coal mining to imply inexcusable and wanton waste. Perhaps a better way of expression is in terms of total recovery rather than in terms of losses. Many mine superintendents and mine owners will readily concede that their total recovery may be only 60 to 75 per cent, but to state that they are wasting 25 to 40 per cent arouses antagonism. The suggestion is of willful waste, whereas the majority of the operators try to the best of their ability to get a high recovery under the adverse and complex conditions that confront them. These involve natural, commercial, and labor conditions, and the requirement in many cases of boundary pillars under railroads and buildings, which may be called for in the deed or lease, or in the absence of specific exemption in the deed or lease, the common law requirement that a surface owner is entitled to the support of the surface."

Apr 1, 1921

By Elton L. Litchfield

The techniques for direct initiation of detonation, developed by the Bureau of Mines, have been applied to gaseous mixtures of oxygen with methane, 'thane, propane, butane, or hexane. An exploding wire was used as the initiation source to determine minimum stored electrical energies required to effect detonation of mixtures between one-half and two times the stoichiometric fuel ratios. Detonations were obtained in the most easily initiated mixtures of ethane, propane, butane, and hexane for initiation energies between 24 and 33 joules at 1 atm and 28-43 joules at 0.5 atm initial pressure. Methane mixtures, at 1 atm, were not observed to detonate when initiated with up to 484 joules.

Jan 1, 1966

Treat contaminated coal mine drainage to meet EPA and State water quality requirements. Approach A model (fig. 1) is presented for selecting, designing, and sizing one or several passive mine drainage treatment systems that can be used in remediation of abandoned mine lands (AML). The three principal types of passive mine drainage technologies for the treatment of coal mine drainage are an aerobic system, a compost wetland, and an anoxic limestone drain. The multistep approach presented here provides a simplified method to characterize the type and magnitude of the water quality problem and then to select either a single treatment system or a combination of treatment systems to address the specific site situation. How It Works Step 1. Discharge Characterization. Characterization of the discharge consists of measuring the discharge flow rate and collecting water samples at the point of discharge for chemical analysis. Both the flow rate and chemistry of a discharge can vary seasonally and in response to storm events. It is important to account for this variability by determining flow rates and water chemistry under various conditions.

Jan 1, 1992

By Ann Hubbs, Vincent Castranova, Jane Y. C. Ma, De-Hwa Chao, Joseph K. H. Ma

AN OVERVIEW OF THE ACTION OF TETRANDRINE ON SILICOSISBecause of the persistent presence of silica dust in the lungs silicosis is a progressive and irreversible disease. At present, there is no proven effective therapy for silicosis. Limited choices of therapeutic intervention with corticosteroids and other immunosuppressive regimens 1,2 have been accepted for some forms of pulmonary fibrosis. These treatments are only minimally effective, and the results provide little understanding of the disease state due to the lack of correlation between drug activity and the mechanism of fibrosis. Thus, continuing effort must be made in the search for effective antifibrotic agents, which may be used to provide a sequential analysis of the fibrotic process and to open the door for further research and clinical development. Tetrandrine is one of hundreds of drugs screened for antifibrotic activity by Chinese scientists. It has been used in China as a treatment for silicosis in open clinical trials3 and in laboratory animals. The action of tetrandrine on pulmonary fibrosis has been attributed to its ability to inhibit particle stimulation of alveolar macrophages, a key cell type central to the fibrotic process, to release oxygen radicals and inflammatory cytokines. Alveolar macrophages (AM) residing on the alveolar wall, are the predominant phagocytic cells of the lungs responsible for pulmonary defense against inhaled microorganisms and other particles and thus play an important role in maintaining the homeostasis of the lungs. 7 Ample evidence suggests that cells of the monocyte-macrophage series play an important role in the immunopathogenesis of pulmonary fibrosis. When upregulated by silica, alveolar macrophages generate reactive oxygen metabolites8·9 which can damage lung parenchyma and release fibrogenic growth factors and cytokines, 10,11 such as interleukin 1 (IL-1), which can induce fibroblast proliferation and collagen synthesis. The cytokine-mediated fibroblast proliferation and collagen synthesis are key steps in the development and progression of pulmonary fibrosis .11 Previous studies by our group have shown that tetrandrine exhibits strong binding affinity to AM and inhibits particle-stimulated respiratory burst activity (oxygen consumption, superoxide anion release, and hydrogen peroxide secretion) in these cells. 13 In addition, studies by Kang et al. 14 have reported that tetrandrine inhibits silica-induced release of fibrogenic factors such as IL-1 which are capable of inducing fibroblast proliferation and collagen synthesis. Reist et al. 15 further suggested that the antifibrotic action of tetrandrine may be mediated in part by the direct effect of this drug on the ability of fibroblasts to respond to proliferative agents. These results indicate that the mechanism of silicosis involves activation of AM and fibroblasts by silica, resulting in abnormal collagen production due to miscommunications between the cell types. Tetrandrine may interrupt this process by direct interaction with the lung cells.

Jan 1, 1998

By D. J. Parker

Ability to signal the hoisting engineer in shaft mines is of utmost importance from the standpoint of safety and economy. The problem of signalling from the cages and especially from the moving cages has received too little attention from mine operators; however, this problem has been given considerable thought and attention by at least one large metal-mining company in Utah which has devised successful, economical, and safe systems of signalling from the cage whether it is moving or at rest. A Report of Investigations on "Methods used in Utah for signalling mine hoists from moving cages," by C. A. Allen, then a metal-mining engineer in the Bureau of Mines, was issued in June, 1920. As this report contains interesting history of systems of signalling from moving mine hoists, and describes several systems then in use, it is here quoted in full.

Jan 1, 1929

By M. E. Kundick, W. E. Dieter, L. Cohen

The major details of design and maintenance of a seamless stainless steel fume hood system , developed by the Bureau of Mines , are described and illustrated . Operating and housekeeping routines are outlined .

Jan 1, 1964

By A. D. Garman

This paper presents one of a series of digests of foreign mining legislation and court decisions which is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in various foreign countries . This interpretation of the laws of El Salvador has been prepared from the best available information in Washington , but is released subject to correction and amplification , if necessary , by the proper American diplomatic and consular officers to whom it is being referred through the courtesy of the Department of State . Under the terms of the Code of Commerce ( arts . 12ff . ) , foreigners living in El Salvador can engage in business on the same terms as nationals . This involves ( = $434.00 ) - except for those with a working capital , of less than a thousand pesos inscription in the merchants ' register , which can be refused only in case of manifest disability of a permanent nature .

Sep 1, 1930

By F. R. Cattoir, T. A. Sullivan

Commercial uranium metal was electrore fined to a high- purity product using molten- salt electrolytes in an inert atmosphere cell . Electrorefined uranium that contained , after consolidation , less than 30 ppm of metallic impurities was prepared . A method of leaching the electrolyte crystals to remove the salts was developed . Cathode current efficiencies from 90 to 100 percent were obtained . Two molten- salt electrolytes were prepared and evaluated : (1 ) lithium chloride - potassium chloride - uranium trichloride and ( 2 ) sodium chloridepotassium chloride - uranium trichloride . Very little difference was found in the purity of the uranium metal produced in either system . The lithium chloride - potassium chloride - uranium tri - chloride electrolyte was preferable from an operational standpoint .

Jan 1, 1964

By Edward W. Parsons

Conventional rock-bolt anchors often fail when installed in weak formations. The purpose of this work was to develop an anchor that would utilize an explosive charge to secure anchorage in any type of rock. Laboratory work to develop a rock-bolt anchored by explosive forming was initiated using rock-bolt models which had a drilled explosive chamber and were composed of various metals. This was followed by the use of several types of seamless tubing which were expanded with a water-coupled explosive capsule. By attaching a length of solid bolt to the anchor tube, a prototype explosive-anchored rock bolt was made. More than 150 laboratory models were expanded during this phase of development, During two field tests in underground mines (A and B) and one in an open- cut mine (C), 87 explosive-anchored bolts, 9 slot-and-wedge bolts, 2 bolts anchored with expanding grout, and 28 expansion-shell bolts consisting of three types of shells were installed and subjected to pull tests. The field tests were run to determine the effects of variables such as the amount and placement of the explosive charge, design changes in the bolt, and the effect on anchorage of different pull-test techniques. The field tests revealed the following: Mine A. The explosive-anchored rock bolt was feasible, but changes were necessary in bolt materials and in some details of bolt design. Mine B. The design and materials of the bolt gave excellent results in hard fractured rock, but no information was obtained concerning variations in the dimensions of the anchor unit or in the explosive charge. Nine C. Varying the explosive charge to produce a beaded surface on the bolt tube and tightening of the anchored bolt before pull-testing were found to increase significantly the anchorage obtained in soft ground.

Jan 1, 1963

By A. C. Rice

Aminopolyacetic acid chelating agents were added to separatory-funnel-scale solvent-extraction systems to determine the effect on separating rare-earth elements. Average values for separation factors between adjacent elements obtained with Primene JM-T2 increase 36 percent when EDTA is added to the aqueous phase. Adding HEDTA or DCTA also improves separation factors for certain rare-earth elements. Percentage of extraction and the separation factors exhibit marked sensitivity to concentrations of amine, chelating agent, and hydrogen ion. The chelating agents improved separation in Primene JM-T, BHDA, and Primene 81-R extraction systems.

Jan 1, 1963

By Oliver W. Keener

This paper describing the methods and costs of mining at the Hartley-Grantham mine of the Century Zinc Co. in the Tri-State Lead and Zinc district is one of a series being prepared by the United States Bureau of Mines can mining practices, methods, and costs in the various mining districts of the United States. LOCATION, HISTORY, AND GEOLOGY The Hartley-Grantham Mine is located just outside the city limits of Baxter Springs, Kans., as shown in Figure 1. A plan of the mine is given in Figure 2, and Figure is a cross section through A - A of Figure 2.

Jan 1, 1930

By D. J. Stoops

The object of the research described in this paper was to investigate the effect of metallurgical and surface treatments on the corrosion behavior of arc-melted reactor-grade zirconium in cupric or ferric chloride solutions. An apparatus was constructed and specimens of various metallurgical conditions and surface treatments were tested for 6 days at 35° C., with aeration. Some correlations were observed between corrosion rate and the metal's condition and treatment, Specifically, the unattacked or least attacked specimens were those that had been etched as a final treatment before testing. The most severely attacked specimens were those that had been vacuum-annealed as a final treatment before testing. The moderately attacked specimens were those neither vacuum-annealed nor etched, but having a final surface treatment which left a cold-worked surface. Attack by cupric and ferric chloride was by pit- ting with no preference for grain boundaries, The corrosion scale was cow posed predominately of very fine zirconim particles, Particles from the FeC1,-corroded specimens were more pyrophoric than those from CuCl2-corroded specimens, and appeared to have a higher surface area to volume ratio. Comparison of results to those of previous investigators showed that at certain salt concentrations the more pure, reactor-grade zirconium was quite resistant to attack while the less pure, graphite-melted zirconium was severely attacked.

Jan 1, 1962

By O. P. Hood

The spontaneous combustion of coal lies at the bottom of the subject of storage. It is useless to store coal that is to be lost by fire from spontaneous combustion. Every engineer is familiar with the phenomena of the self-heating of coal, yet, for all that, spontaneous combustion is relatively rare. If we counted the times a portion of cod was stored where it would be undisturbed for a few weeks, the number of such storage operations in any one year would mount into the millions. Of these, a relatively small number show the phenomena of spontaneous combustion and time risk per ton is very small. It is extremely rare that in the smaller operations involving; only a few tons there is any heating. There is no spontaneous combustion of anthracite, and very rarely does the domestic consumer of bituminous coal find troublesome heating. The main interest in the subject lies in the large piles needed as reserves for public-service utilities, and the industries. Everyone desires to have directions for storage that are perfectly simple and yet will insure against loss. Unfortunately, the problem is too complicated for a simple solution. Many of the factors involved are difficult to determine, as we have no practical means of quantitative measurement. The factors involve chemistry, physics, and engineering, and the man who is

Jan 1, 1939

By Murray Jacobson

The Federal Coal Mine Health and Safety Act of 1969 established mandatory dust sampling of coal mines according to procedures prescribed in the Mandatory Health Standards, title 30, Code of Federal Regulations, part 70, published in the Federal Register on April 3, 1970. A laboratory was established in the Pittsburgh Field Health Group of the Bureau of Mines to process the coal mine dust samples collected by the mine operators. This paper describes the laboratory and presents the equipment and procedures used in processing these samples.

Jan 1, 1971

By E. J. Schneider

In view of the current interest in the constituents of low-temperature tar, the Synthesis of three known xylenols and their hydroxyacetic acid derivatives has been undertaken by the U. S. Bureau of Mines. One of these xylenols, the 1,3,2 derivative first reported by Steinkopf and Höpner,4 has been described by Brown and Branting.5 The other two derivatives, the 1,3,5 first reported by Schütz6 and the 1,2,3 reported by Steinkopf and Höpner, have now been studied in greater detail. In the present work the synthesis of 1,2,3-xylenol and 1,3,5-xylenol was repeated, with some improvements in the former. The hydroxyacetic acid derivatives were also prepared, and it was found that while the melting point of the 1,2,3 derivative agreed with that of Steinkopf and Höpner. that of the 1,3,5 derivative was found to be 111° instead of 85 to 86° as reported by Schütz, by Steinkopf, and later by Bruckner. The discrepancy between the melting-point figures is doubtless due to differences in the purity of the xylenols used in the synthesis of the acids. Schütz obtained his 1,3,5 acid by recrystallizing an impure sample obtained from a mixture of xylenols. The difficulty of obtaining a pure acid by starting with a mixture is demonstrated by Bruckner, who despite painstaking efforts was unable to obtain the pure 162.5° melting 1,2,4 isomer from a mixture that persistently melted at 138° C. Steinkopf did not repeat Schütz's work but merely used the latter's figures in compiling a table. Bruckner, on the other hand. apparently also made the acid (by an improved method), and it is difficult to explain his checking Schütz's figure, unless it is that he, too used a symmetrical xylenol obtained from a tar and not prepared synthetically, as was the one reported in this paper.

Jan 1, 1929

By F. M. Boler

The U.S. Bureau of Mines has configured a flexible data acquisition and analysis workstation, which incorporates control and analysis software written in-house for use in mining research experiments conducted in the laboratory and in operating underground mines. This data acquisition system combines computer-automated-measurement-and-control (CAMAC) modular instrumentation with a Unix-based graphics workstation. The data acquisition front-end hardware can be interfaced to almost any computer. CAMAC instrumentation modules adhere to mechanical, electrical, and digital interface standards and can be custom designed or purchased off the shelf. Communications along the CAMAC bus are regulated by the crate-controller module, which contains the only hardware link to the computer interface. Software support for the data acquisition and analysis workstation consists of a series of functions and programs written in the "C" programming language designed to provide flexible and fast data acquisition, processing, and analysis. The user can interactively control the digitizers and other CAMAC modules by sending standard CAMAC read, write, and command function codes from a menu-driven program. Automated data collection is achieved through software that responds to hardware interrupts triggered by acoustic emission or microseismic events. Graphics display routines are used to plot part or all of the data and provide the ability to process and store signal information selectively.

Jan 1, 1990

By E. D. Gardner

This paper is one of a series on mining methods and costs being published by the United States Bureau of Mines. In April 19.74 the St. Joseph Lead Co., at Atlanta, Elmore County, Idaho, was mining and milling about 225 tons of gold ore daily with a total force of 150 men. The mine, which comprises the old Boise-Rochester and Monarch properties, is at an elevation of about 6,000 feet. Snow lies on the ground about 5 months each year but does net interfere greatly with local operations. However, the road to Mountain Home, the shipping point 80 miles distant, passes over a high range and usually is closed by snow from about November 15 to June 15. Heavy supplies are brought in and concentrates trucked out during the summer. In winter the district is served by a biweekly mail plane and a passenger and express plane making 4 to 6 trips weekly. Mine timber is cut locally. A plentiful supply of water is obtained from a stream brought to the property through 7,500 feet of plume.

Jan 1, 1935

By McHenry Mosier

Diamond -drilling blast holes at Eastern Magnetite Mine C is proving economical in boundary shrinks , in removing pillars not readily accessible for percussion drilling , and in driving scraper drifts . The cost per foot drilled is greater than for percussion drilling , but savings in associated factors outweigh this handicap . The rocks drilled include trap rock and magnetite ore . The mining method is the panel , block- caving system utilizing scraper sublevel drifts instead of branch raises to convey the ore to the haulage level . Diamond -drilling blast holes was begun early in 1945. Three rigs equipped with noncoring bits are now in active operation two shifts per day . They are owned by the company , and the drill operators are paid by the day . In shrinkage stopes the drill is mounted on a horizontal bar set against opposite walls of the stope . Stoping holes are horizontal , which gives better results in blasting and requires fewer set ups . In scraper drifts the drill is mounted on a horizontal bar clamped to two columns about feet apart . Trim holes around the periphery of the drift and reliever holes are drilled 50 to 80 feet in length . A 10 - foot wedge cut drilled with a stoper is blasted in conjunction with a corresponding length of the trim holes to effect a 10 -foot advance of the full- sized drift . Recent drilling averages 97 feet per machine shift , excluding time utilized in setting up and moving the machine , hand mucking , and barring down . The feet drilled per bit at present is 417. These data represent the average for drilling in both rock (waste) and ore . Percussion drilling utilizes three types of wet drills . Detachable bits are standard . Gage changes for new bits is 1/8 inch and for reconditioned bits 1/16 inch . The life of a bit is five uses . Resharpening is on contract . A drill carriage is used in haulage headings .

Feb 1, 1948

By Robert M. Doerr

The oxidation kinetics of Ni-Y alloys in the range 0.04 to 8 weight-percent Y, and of high-purity Ni, were compared by the use of a sensitive volumetric apparatus. The reactions followed approximately the parabolic rate law; for oxidations in 02 at 0.5 atm and 1,200° C, the parabolic rate constant was about 0.37 + (0.064) (Y-2.11) mg cm-2 min-1/2, where Y represents the weight-percent Y in the alloy. Internal oxidation of Y occurred in the alloy specimens and the resultant Y203 particles, which were in patterns related to the eutectic structure of the alloys, served as markers showing that the subsequent oxidation of the surrounding Ni was by inward diffusion of O. The scale consisted in each case of NiO, but the inner parts of the scale on the alloy specimens included the patterned Y203 particles. The thicknesses of the inner parts of the scale depended directly on the Y concentration, and the thicknesses of the Y2O3-free outer parts of the scale were inversely related to the Y content of the alloys. There is thus a relationship between the thickness of the outer part of the scale and the protectivity of the scale. Outward diffusion of Ni and inward movement of 0, from the inner boundary of the Y2O3-free part of the scale, is proposed as a mechanism for these results.

Jan 1, 1966