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By Floyd R. Hertweck

This Bureau of Mines publication contains analyses and related source data for 349 natural gas samples from 26 States and 2 foreign countries. The 3 samples from foreign countries and 339 of the U.S. samples were collected during calendar year 1983. The remaining seven samples were collected earlier, but releases granting permission to publish were not received until 1983. All samples were obtained and analyzed as part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by the mass spectrometer and chromatograph. The results of these investigations are published annually to make the information available to the petroleum industry and the general public. Twenty-seven publications have presented the results of 13,332 gas analyses made prior to 1983. The first three bulletins (1-3)3 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1960; these bulletins have been supplemented annually by information circulars (4-17, 19-24, 26-27) containing 8,104 analyses of sam¬ples collected since 1960.

Jan 1, 1984

By E. G. Davis

The flash reduction of fine iron ore in a dilute-phase system was investigated at 500° to 900° C within a heated stainless steel tubular coil. Alabama brown iron ore and Mesabi semitaconite ore were fed into the coil concurrently with reducing gases of hydrogen and reformed natural gas, so that the velocity of the gas at the reaction temperature was sufficient to entrain and pneumatically transport the solids through the coil. Reduction is very rapid with retention time of the ore in the coil varying from 4 to 15 seconds. Variables affecting reduction are temperature, ore feed rate, and gas flow or velocity. Results of the studies show that a partially reduced product (10-to 25-percent reduction) can be made which, on subsequent magnetic concentration, yields a concentrate containing 64 to 70 percent iron with a 90-to 94-percent iron recovery. Maximum reduction of 77 percent was obtained when hydrogen was used in a four-stage reduction test to yield a product containing 61 percent metallic iron.

Jan 1, 1972

By Thomas Varley

[For a year or more, statements have appeared in the technical press, and Especially in various trade journals, indicating that valuable metals such as gold, silver, platinum, and other rare metals, have been found and also have been successfully extracted from oil shales. These reports stated tat decarbonization and special methods of chlorination treatment, leaching and subsequent Precipitation, also cyanidation followed by table concentration of the residues after cyanidation, all indicated that told ad silver and other metals could be, and were, successfully recovered. Such articles have caused much misunderstanding, and as the correctness of some re of the statements made in them were questioned by some of the technical journals and by various chemists and metallurgists, an investigation of the subject. was begun by the metallurgical division of the Bureau of Mines, in order, if possible, to determine to what extent, if any, metals of value do occur in oil shales, and if so, the feasibility of attempting their recovery by tie processes said to have been used for teat Purpose. Inasmuch as the Bureau's station at Salt Lake City is investigating the recovery of oil from oil shales, the investigation of too recovery of metals from oil shales was assigned to my direction as superintendent 'of that station. An agreement had been entered into with the owner of m extensive oil shale deposit in Wyoming whereby I would personally collect the samples' of shales for use in the investigation.]

Jan 1, 1922

By K. K. Kelley, L. B. Pankratz

The heat contents of four silicate minerals -- akermanite , cordierite , gehlenite , and merwinite --were measured from 298 ° to around 1,700 ° K by the dropping method . The results were compiled into tabular and equation forms suitable for thermodynamic calculations . The heat contents of these compounds are nearly additive with respect to their constituent oxides .

Jan 1, 1964

By Stephen C. Tadolini

The anchorage capacity of four types of bolting systems was investigated in two mines with thick coal roofs. In conjunction with the in-mine tests, a simple axisymmetric finite element computer program was developed. Both the field and computer results indicated that thick coal roofs can be effectively supported entirely by the coal member.

Jan 1, 1986

By R. R. Sayers

The effect of comparatively low concentrations of carbon monoxide for short periods and under normal air conditions.of temperature and humidity , with the subject at rest , was studied by Dr. Yandell Henderson and his co -workers . In making recommendations to the New York and New Jersey tunnel commissions * he advised that , if the New York New Jersey vehicular tunnel be so ventilated that persons passing through the tunnel would be exposed to not more than 4 parts of carbon monoxide in 10,000 parts of air for not longer than 45 minutes , they would experience no ill effects . supplementary experiments , carried out by us in connection with our studies at the Bureau of Mines experiment station at Pittsburgh, substantiated this advice . ** In continuing our studies on low concentrations of carbon monoxide , we made a few experiments in a gas chamber where the conditions could be accurately controlled . The factors investigatel were : ( 1 ) The effect of long exposure in low concentrations of carbon monoxide ; ( 2 ) The effect of strenuous exercise ; ( 3 ) The effect of high temperature and humidity in low concentrations of ccarbon Lonoxide .

Mar 1, 1922

By B. J. Scheiner

Extraction of silver from silver mill tailings by an electrolytic oxidation procedure was investigated by the Bureau of Mines. Various parameters affecting silver extraction, such as electrolysis time, particle size, and dissolution of the silver as the tetrachloro or cyanide complex, were studied at 30° C with an electrolyte concentration of 20 weight-percent sodium chloride. Resulting silver extractions ranged from 77 to 90 percent, depending on the tailings being treated. Concomitant extraction of mercury ranged between 90 and 95 percent. Power consumption was 52 to 90 kilowatt-hours per ton for the tailings investigated. Comparative experiments using direct cyanidation resulted in extraction of 46 to 82 percent of the silver and 20 percent of the mercury. Cyanide consumption ranged from 3.3 to 9.4 pounds per ton of tailings, depending on the tailings being treated. Silver and mercury were recovered from leach solutions by precipitation on iron powder, followed by conventional distillation and fire refining steps.

Jan 1, 1972

By F. E. Armstrong

Tritiated water has been used as a tracer to follow the path of leach liquids as they flow through a copper-mine dump. Semipermeable layers, produced within the dump by compaction and "stratification" of deposized dump material, restrict the vertical movement of water. Knowledge of this restriction would aid in the optimization of the leaching process. The portion of the dump of particular interest was approximately 2,000 feet long, 800 feet wide, and 200 feet high. A total of 94 curies of tritiated water was injected into the dump at the rate of 650 gpm over a period of 39 hours. The leach liquid was sampled at natural surface outflows and through a series of wells, some drilled to the bottom of the dump and others to intermediate levels. More than 3,300 samples were analyzed, most by liquid scintillation counting, but a few hundred by gas counting. Data obtained permitted calculation of flow paths, recycle times, total fluid volume, and estimates of retention times in various portions of the dump.

Jan 1, 1971

By R. V. Ramani, S. Shankar

"Available literature on the effect of re-entrainment on overall airborne dust concentration in mine airways or the fundamental mechanisms of coal dust re-entrainment in mine atmosphere is scant (Shankar and Ramani, 1991 ). Therefore, as part of the Respirable Dust Center's ongoing research, the following three-part study was undertaken:• a study of the re-entrainment phenomena of anthracite and bituminous coal dust particles in a wind tunnel under the influence of varying air velocities;• a study of the same in the Lake Lynn Laboratory Mine of the USBM with both air flow and walking by personnel causing re-entrainment; and• the mathematical modeling and computer simulation of the re-entrainment phenomenon.In this paper, results from the re-entrainment studies in the wind tunnel and the Lake Lynn Laboratory mine are presented. Comparing the results from the two studies,it was observed that increasing the air velocity increased the rate of re-entrainment ( Shankar and Ramani, I 994a) and the rate of re-entrainment decreased with the time of exposure of the source dust to the flowing air. In addition, when the source dust was composed of particles of different sizes, the airborne dust concentrations due to re-entrainment were higher than when the source dust was composed of particles of the same size. The contribution of airborne dust concentration due to air flow was negligible compared to the contribution due to walking. IntroductionIn underground coal mines, dust is produced primarily during the process of mining and during such activities as pillar spall, loading, belt transfer and roof fall. The generated dust is entrained and then collects on surfaces through dispersion, diffusion and eventual deposition. Removal forces, such as flowing ventilation air or turbulence caused by walking and moving vehicles, can re-entrain the deposited dust (Hall, 1955). A portion of the re-entrained dust remains airborne and increases the concentration of airborne dust in mine airways.The presence of airborne coal dust in mine airways in large concentrations can be hazardous. Health effects include coal workers' pneumoconiosis (CWP) and silicosis, and it can be a nuisance affecting visibility. In addition, as is common during methane explosions, if the concentration of airborne coal dust becomes significant, there could be a coal-dust explosion (Singer, Cook and Grumer, 1972; Singer, Harris and Grumer, 1974; Edwards and Ford, 1988). Through concerned research efforts over the last decade, significantprogress has been made in reducing the airborne dust concentration in mine atmospheres. However, secondary sources, such as re-entrainment, have not been studied in-depth. It is important to understand the phenomenon of re-entrainment and its potential contribution to the airborne dust concentration in mine airways for further decreasing airborne dust hazards in mines."

Dec 1, 1996

By C. P. Hood

"The amount of ash in anthracite coal interests every buyer, and occasionally produces caustic comment, but there is a lack of authentic figures that will take the subject out of the realm of opinion and agitated fancy and. give a true picture of the quality of coal actually delivered. What per cent ash is to be expected when the coal is good, and when have we a right to make serious complaint?During the past summer the Bureau of Mines took 127 samples of 1000 pounds each, representing nearly 30,000 tons of anthracite is dealers' yards in seventeen cities in the State of Massachusetts. There were three objects in view, to discover the average and the variation in amount of ash in anthracite in some easily described area; to demonstrate standard sampling methods, and to learn something about the feasibility of itinerant coal sampling. Massachusetts was selected because its principal cities could be visited in a single season. There also appeared need for demonstration of standard sampling of coal, since a coal quality law had been passed in the State, to be administered by those unfamiliar with coal sampling."

Feb 1, 1924

By Larry D. Nichols

Poroplastic membranes containing ion exchange liquids were studied for separating cobalt from nickel-containing solutions similar to ammoniacal laterite leaches. The driving force for cobalt transport was differences in pH and composition between the leach and extraction streams. Using a diketone ion exchange liquid, a leach pH of 6.5 to 7.0, and a strip pH of 2.3, cobalt was extracted from a 750 ppm solution containing 2500 ppm of nickel at rates ranging from 1 to 10 µg/cm2 .min in single membrane cells, and from 10 to 100 in more closely spaced multiple membrane cells. Rates were variable, with evidence that cross -membrane flow pasterns were a key factor; a reproducible rate of 30 pg/cm .min would be economically viable. Loss of transport observed after several days of continuous operation was restored by flushing membranes with fresh ion exchange liquid. A major effort was devoted to preparation of thin, leak-free membranes; the resulting membranes endured operating conditions without mechanical failure.

Jan 1, 1982

By F. M. Goodwin, Campbell. John, W. J. Hiffs, G. W. Jones

"INTRODUCTION In cooperation with The Edison Electric Illuminating Co. of Boston, Mass., and the Boston Consolidated Gas Co. a survey has been conducted continuously since 1929 by the United States Bureau of Mines to determine the general hazards of combustible gases and vapors in manholes of the Edison Electric Illuminating Co. The New England Telephone & Telegraph Co. also has cooperated in the investigation, and tests have been made in its manholes since May 1, 1933.Yearly reports 6 giving the results obtained since the start of the survey have been published.The method and procedure of conductin, the survey in 1935 were the same as heretofore.ACKNOWLEDGMENTSThe cooperative investigation was arranged through the interest and effort of F. D. Comerford, president of the Edison Electric Illuminating Co. of Boston; E. N. Farnesworth, Jr., vice president and general manager of the Boston Consolidated Gas Co.; and A. C. Fieldner chief engineer, Experiment Stations Division, U. S. Bureau of Mines. Thomas H. Haines, superintendent, Distribution Department, of the Edison Electric Illuminating Co., cooperated in furnishing men and information for the work,"

Oct 1, 1936

By Allen D. Look, Stanley M. Walker, Van Fleet. Leonard A.

"INTRODUCTION The hazards to be encountered in temporarily or permanently abandoned underground mines, quarries, and open pits are numerous, and hardly a year goes by without several reported cases of fatal or serious injuries occurring to unwary people who enter these old mines. Persons visiting mining areas for the first time, tourists, and young people, especially, proceeding in the spirit of adventure common to youth or to the venturesome have suffered many such accidents during exploration trips. The possibility of salvaging salable or usable equipment prompts men and boys to go into old mines, some through ignorance of the attendant hazards, but some jeopardize their lives hopeful of gain (in some cases pitifully small), thinking the hazards are not dangerous and that they can ""get away with it.""Persons fall into unprotected holes, some seek shelter from storms under high banks, and quarries and open pits are often chosen as places for recreation, picnics, swimming, etc; all such uses of these places are likely to be hazardous and to lead to accidents, frequently fatal.These hazards are known to men in the mining profession, and the danger to the public is realized by most of them. A solution to the problem has been sought at many mining meetings, and it is recognized that complete prevention of entry into old mine workings and surface mining areas is the ideal solution, but this, unfortunately, is not always practical; better education of the public, particularly children, should help to reduce the number of such accidents and will be effective in direct proportion to the extent and vividness of such education."

Aug 1, 1948

By R. W. Stahl

Increasing use of continuous miners, especially the boring type, has focused attention on the inadequacy of face ventilation in coal mines. The bulk of the machine, the rapid advance of working faces, and the increased liberation of methane from the larger expanse of freshly exposed coal surfaces have created ventilation problems that were unknown with conventional mining equipment. Ignition of gas, especially that caused by machine bits striking hard rock or pyritic inclusions, have increased at an alarming rate. As the mines penetrate beds under thicker cover at an ever-increasing rate of face advance, this problem will probably increase unless face ventilation is improved. A previous survey, described in Bureau of Mines Report of Investigations 5414, Auxiliary Ventilation of Continuous Miner Places, disclosed that auxiliary fans with tubing generally improved circulation of air and removal of gas at the face. The study here reported attempts to examine, face ventilation at various mines and to note any plan or innovation of. air coursing that industry might adopt to reduce the danger of gas ignition. ACKNOWLEDGMENT The mines visited were very cooperative in the study-and-generously supplied any data requested.

Jan 1, 1960

By M. M. Wong

A brief investigation was made to determine the feasibility of electro-refining beryllium in a KCI-LiCI-BeC12 bath. Thin, platelike crystals of beryllium metal were produced by electrolyzing technical-grade beryllium metal beads (about 94-percent purity) as the soluble anode. Operating cell conditions were: Temperatures of 450° to 600° C.; an inert atmosphere; bath compositions of (1) 38.1 mol. percent KC1, 54.8 mol. percent LiCl, and 7.1 mol. percent BeC12 and (2) 36.7 mol. percent KC1, 52.7 mol. percent LiCl, and 10.6 mol. percent BeC12; cell voltages of 0.30 to 0.80; and initial cathode current densities of 50 to 435 a./sq, ft. Current efficiencies ranging from 87 to 96 percent were obtained. Qualitative spectrographic analyses of the metal products indicated that impurities were reduced. This technique offers the possibility of producing a grade of beryllium purer than that now generally available, which may have better mechanical properties.

Jan 1, 1960

By J. M. Kuchta

Experimental data are presented on the autoignition temperature (AIT) characteristics of the hydrocarbon jet fuel, JP-6, in various oxygen-nitrogen atmospheres under conditions of constant volume and constant pressure. AIT's of this fuel in air varied little with fuel injection pressure but increased greatly with decreasing fuel content at low fuel-air-ratios. They also increased with decreasing oxygen content of the fuel vapor-oxidant atmosphere. Consistent with thermal ignition theory, the ignition temperatures increased with decreasing initial pressure, ignition delay, and vessel radius; expressions are given which define the observed variation of AIT with these variables for JP-6 fuel vapor-air mixtures. The significance of autoignition temperature data obtained using various ignition criteria is discussed to show the usefulness of such data in evaluating fire and explosion hazards. In addition, data are presented on the extent of oxidation that occurs prior to autoignition of this fuel in air at various temperatures.

Jan 1, 1965

By D. W. Bridges, S. R. Borrowman

Thorium and yttrium oxides were recovered from siliceous ores of the Powderhorn , Colo . , area . Processing comprised ( 1 ) acid curing and subsequent ( 2 ) acid baking , ( 3 ) leaching , and ( 4) solvent extraction of thorium , using a primary alkylamine , and yttrium , using di - 2 - ethylhexyl phosphoric acid . About 95 pct of the contained thorium and yttrium was recovered from ore containing 1.2 pct Th02 and 0.5 pct Y₂ 03. The thoria product was 99 pct Tho ; the yttria product was 77 pct Y₂ 03. A 150 - to - 1 concentration ratio was effected on the latter , but some contaminating lanthanon - group oxides remained .

Jan 1, 1964

By R. D. Leitch, W. P. Yant

"In the course of another investigation4 during 1926 and 1927, samples of water collected from a few abandoned coal mines indicated that their drainage was usually lower in acidity than water from active mines in the same locality. In order to determine whether this condition might have a bearing on the advisability of sealing abandoned mines, a number of such mines were visited, samples of drainage were collected, and as much information- as possible was obtained from officials of the mining companies and older residents of the district. The results of this work are the basis of the present report.The authors are indebted to E. W. Robertson, F. F. Spowart, J. H. Nagle, and W. D. Adams of the Northwest Mining & Exchange Co.; E. M. Fasset, Fred Lane, Wm. Humphreys, and Dr. T. A. Hutchison of Brockway, Pa.; C. W. .Faulk of the Shawmut Mining Co.; James Hau of Kersey, Pa., and to others for information received; and to Dr. R. R. Sayers of the Bureau of Mines, under whose direction the work was conducted.The Lower Kittanning is the most important bed in the locality studied. A great many of the abandoned mines examined are in this bed, and nearly all of the present active ones are. The Upper Freeport bed is also mined to some extent, and a number of the abandoned mines formerly worked this bed. As only three active mines are now (1927) working the Upper Freeport, the comparison of acidities is necessarily limited. Of these three, one had been idle since 1922 until shortly before it was sampled.The location of most of the mines was already known from previous work, but some of them had to be located by following up streams known to contain acid waters. A sample of the- outflow was collected in self-sealing bottles known as ""citrate bottles"" for the determination of dissolved oxygen by the Winkler method.5 Another sample was taken for the determination of acidity according to standard methods of water analysis.6 Ferrous iron was determined at the mine or very soon after taking the sample by titrating with a standard solution of potassium permanganate in acid solution. The hydrogen-ion value was determined by a standard double-wedge comparator.7From the total acidity values in each sample, which are the most important values, the total iron was calculated on the assumption that acidity as sulphuric acid was due to dissolved ferrous sulphate. This assumption is commonly made for mine waters, but is inaccurate to the extent that free acid is already present, and some of the iron is present as ferric, rather than ferrous, sulphate. The amount of ferrous sulphate may be a rough measure of the extent to which oxygen is lacking within the mine. The permanganate titrations just mentioned showed what part of this total iron was in combination as ferrous sulphate, and the difference .was assumed to be that in combination as ferric sulphate, after correcting for the amount of free acid already formed as shown by the titration values."

Oct 1, 1928

By K. A. Johnson, H. F. Yancey

"INTRODUCTION Coals vary so widely in their burning characteristics that all coals prepared for domestic stoker use cannot be burned efficiently on every type of stoker. The overfeed stoker, a large number of which are in use in the Pacific Northwest, operates satisfactorily when burning low- to high-ash, noncaking bituminous or subbituminous coals, whereas on the clinkering-type, underfeed, bituminous stoker both caking and noncaking bituminous and subbituminous coals are burned, generally with ash contents below 12 percent and ash-softening temperatures between 1,800º and about 2,600º F. Because fly ash continues to be one of the most troublesome factors in domestic underfeed stokers, noncaking coals especially must be chosen carefully with respect to size composition, particularly as regards the exclusion of excessive fines. Their formation as a result of degradation in storage handling or because of crushing in .the stoker worm will increase the fly-ash nuisence.Bituminous and subbituminous coals with higher ash-softening temperatures and, often, higher ash contents have not been able to enter the domestic stoker-coal market in the Pacific northwest because clinkers are not formed readily during clinker-type underfeed-stoker burning, especially in mild weather, and because of the labor and attendant inconvenience required in handling larger volumes of ash. The work described in this report was undertaken to enable mines producing coals of the kind described to enter the stoker-coal markets. The anthracite stoker selected was one that conveys the refuse from the ash pit of the furnace and deposits it into one of two covered, dust-tight disposal cans."

Dec 1, 1945

By S. L. Windes

For a number of years, the Bureau of Mines conducted tests on various types of structures to determine the effect of seismic vibrations emanating from quarry blasting in an effort to determine an index of damage . Associated with these tests , occasional records were made of the characteristics of. the air blast or concussion from the explosions . Although the importance of the air - blast problem was recognized , the equipment was not designed for air -blast measurements , nor was the early research program concerned with the problem . After the ground - vibration tests had been completed , attention was turned to study of the air blast and its effect . The air - blast problem in reference to quarry and mine blasting may be divided conveniently into three phases : (1 ) Determination of the fundamental characteristics of the air blast , such as the pressure - time relationship , speed of propagation, attenuation , and the like ; ( 2) effect of blasting conditions on these air -blast characteristics ; and ( 3) determination of the conditions necessary for damage to structures . The initial step was the development of microphones suitable for recording the anticipated blast pressures. Such microphones were designed and built during 1940 , and described in technical detail for publication ( 2)3/. Briefly, the microphone adopted was a small, plate - diaphragm condenser type . The recording was through special transducer amplifiers with low -frequency response to zero cycles per second and a Duddell - type oscillograph of special design .

Feb 1, 1942