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By N. A. C. Smith, D. D. Stark

"Sulphur is apparently a normal Constituent of crude petroleum, but in most crudes is present in percentages of less than one-half of one per cent. Some crudes, however, contain more, and occurrences have been reported of heavy asphaltic oils with as much as five per cent of sulphur.Occurrences of Sulpher-bearing CrudesIn North America, the fields rest of the Mississippi River are almost entirely free from sulphur oils, the time oil from Northern Ohio and Indiana, and the Potrolia crude in Ontario, being practically the only ones which contain sulohur in amounts over 0.5. per cent. In the Mid-Continent district the production of high sulphur crude in general is small and unim¬portant. The two main excentions are the Healdton field in Oklahoma and the El Dorado field in Arkansas, both of which produce oils with considerable sulphur content. In the Wyoming field, one sand, the Ember Sandstone, pro¬duces a crude of high sulphur content, and it is probable that this crude rill be of considerable importance as production increases. At present, however, very little crude is produced from this formation. In the Gulf Coast conditions are irregular, some crudes being low in sulphur and others comparatively high. The same is largely true of California. The crudes of Mexico contain notable amounts of sulphur, and as they have been of great commercial importance in this country, a typical sample of light Mexican crude was selected for the present study. It is probable that the results obtained poly also (but to a lesser degree) to other sulphur-bearing oils. An analysis of this crude will be found in Table 3, also analyses of other typical sulphur-bearing crudes from different sections of the United States."

Mar 1, 1924

By H. J. Kelly

[This investigation of the refractory properties of seven Pacific Northwest chrome ores and concentrates has shown that five of the ores and one of the concentrates are suitable for making refractories and that all may be used in combination with high-grade chromite. The specific objectives of the investigation were to determine the inherent physic al and chemical characteristics, to shapes using each of the chrome ores and concentrates, to compare the refractory qualities of the laboratory-prepared with commercial chrome refractories. As far as possible, standard tests were used as criteria.]

Jan 1, 1952

By Albert L. Toenges

ALMOST all of the coal used for metallurgical purposes west of the Continental Divide is ruined from the Lower Sunnyside bed in Carbon County, Utah. Coke produced from Lower Sunnyside coal and used in western steel plants is weaker structurally than coke used elsewhere in this country. For this reason, western coal operators and steel manufacturers are anxious to develop new areas of coking coal of better quality than the coal produced from the Sunnyside bed. Early in the war, the Bureau of Mines undertook an intensive investigation of western coals to (a) develop additional reserves of coking coal to supplement proved reserves in the Sunnyside bed and (b) develop, if possible, reserves of coal with coking qualities superior to Lower Sunnyside coal. Results of investigations in the Kemmerer district, Wyoming,9 and in the Minnesota Creek area, Gunnison County, Colo.,10 have been published.

Jan 1, 1952

By F. D. Stevenson

Thermodynamic properties of metal halides and, in particular, vapor pressures have become of great importance in recent years owing to increased application of chemical processing to extraction of metals from their ores. Vapor pressure data serve not only as a valuable source of latent heat of vaporization and fusion values but also differences in metal-halide vapor pressures often provide the basis for their separation by conventional mass transfer operations. This literature search was made to provide a ready reference to experimental vapor-pressure data of metal halides and oxyhalides. Results are reported in two main sections: (1) A tabulation of vapor- pressure references for each of the metal halides (listed by metal) for which actual experimental data are reported (table 1), and (2) a bibliography of the citations. Metal halides and oxyhalides are listed by chemical formula and chemical name, based on the stock4 system. To facilitate location of the references, a listing of the journal titles and their abbreviations follows the bibliography.

Jan 1, 1963

By Irving Hartmann

As part of the continuing effort by the Bureau of Mines to promote mine safety, research work is being conducted at the Experimental coal mine, Bruceton, Pa., on the prevention of coal-mine explosions and on other mine-safety problems. The principal subjects studied during the past 2 years are briefly described in this paper. Although at present these problems are relevant particularly to the mine layout and to high-speed mining practices in numerous American coal mines, it is hoped that the findings will prove interesting and useful also to our European research colleagues. Some of the investigations treated here will be presented in greater detail in forthcoming Bureau of Mines reports. 1. UNDERGROUND STORAGE OF COAL CUTTINGS The seams in mist American bituminous-coal mines are undercut, shear-cut, or top-cut before blasting. The cuttings arc generally loaded out with the balance of the coal. However, in some mines it is not economical to load and remove cuttings from the mine. This applies especially if the cut section of the seam is of appreciably lower grade than the rest of the coal, or if the cut is made partly into an adjacent stratum that is high in incombustible content. In such mines the cuttings are sometimes stored in random heaps in rooms or other areas, along the ribs of mine entries, or in layers on the floor of rooms or entries.

Jan 1, 1956

By D. C. Crowell, A. G. Loomis

Both Dimensional and Inspectional Analysis are developed from fundamental concepts , and dimensionless groups are derived which represent the viscous , capillary , and gravitational forces existing in two - phase , incompressible flow in petroleum reservoirs . It is shown how properly scaled models may be devised by means of the foregoing groups . Laboratory measurements with such models faithfully duplicate the behavior of the reservoir on a miniature dimensional and compressed time scale , and when all the pertinent variables are evaluated , the model is a most effective tool for the study of complex fluid displacements in the reservoir . Applying the Principle of Similitude , it is shown how dimensionally scaled models are applied to various types of reservoir displacements : ( 1 ) Oil displaced by water , ( 2 ) gas displaced by water , and ( 3 ) miscible displacement . The special case of water displacing gas by imbibition is analyzed , and it is shown that the dimensionally scaled model must be fabricated of sandstone rather than unconsolidated sand , which is generally used in such models . This report is intended to be a review and summary of the application of Dimensional Analysis to reservoir displacement problems for those who are beginning the study of this useful and interesting method .

Jan 1, 1964

By N. F. Le] [Jaune

[ ]

Jan 1, 1923

By D. Bienstock

In connection with air-pollution studies, the Bureau of Mines is cooperating with the U.S. Public Health Service in investigating the use of solids for removing sulfur dioxide in concentrations of less than 0.5 percent from combustion and waste gases. Removal of sulfur dioxide at flue-gas tempera¬tures would no longer result in the cooling of scrubbed gas, which is inherent to liquid scrubbing processes used exclusively in industry today. Results are reported of extensive investigation, using metallic oxides as absorbents, adsorbents, and oxidation catalysts at 130° and 330° C. (temperatures at which flue gas may be treated in powerplant practice). The most active absorbents tested were the oxides of manganese, cobalt, copper, and alkalized alumina; 23 to 33 grams of sulfur dioxidn were removed by 100 grams of absorbent at 130° C., while scrubbing more than 90 percent of the sulfur dioxide from a simulated flue gas, and 19 to 61 grams of sulfur dioxide were removed at 330° C. A more detailed study is reported on absorption and regeneration, using manganese oxides and alkalized alumina. Adsorption of sulfur dioxide on activated carbons and molecular sieves at elevated temperatures is considerably less efficient than removal by absorption--a maximum of 7 to 8 grams of sulfur dioxide could be removed with 100 grams of adsorbent at 130° C. A potash-promoted vanadium pentoxide is effective in converting sulfur dioxide to trioxide; complete conversion in a simulated flue gas containing 0.35 percent sulfur dioxide was obtained at 365° C. Pilot-plant and cost studies are being made by the Bureau to determine the economic feasibility of removing on an industrial scale the sulfur dioxide present in gases in low concentrations.

Jan 1, 1961

By George R. McCormick

Because several new and unusual synthetic minerals were found in the system MgO-MgF₂ - SiO2 with Li * , or Nat a similar system with Geo₂ replacing Sio , plus Lit was investigated . In addition to the expected compounds of germanium , Ge - fluor - hectorite and a Ge - fluor- chrysotile were synthesized . Protoamphibole was not observed . Data are given for 69 compositions prepared in the system MgO- MgF₂ - Ge02 at 6.94 percent LiF .

Jan 1, 1964

By W. G. Sandell, L. C. Bauerle, K. C. Dean

"INTRODUCTION As a part of the wartime activities of the Bureau of Mines, metallurgical services were extended to other Government agncies engaged in purchasing and stock-piling some of the more critical and strategic materials. At the request of Dr. Alan M. Bateman, special representative of the Metals Reserve Company, metallurgical studies were made on three samples of oxide tin ore from, the States of Zacatecas and Guanajuato, Mexico. The samples were submitted for testing by A. Porraz of the Financiera Miners, S. A., institution Financiera, Edificio Guardiola, Despachos 500-507, Mexico, D. F.The samples as received were marked Nos. 1, 2, and 3 and described as follows:Sample 1. - Origin: Mining camp ""El Naranjo,"" municipality of Sombrerete, State of Zacatecas, Mexico. This sample was partly concentrated by washing and as received was all minus 10-mesh in size.Sample 2. - Origin: Deposits in Sierra. Fria and Juan Cherey, municipality, of Jerez,State of Zacatecas, Mexico. This sample represented run of-mine ore.Sample 3. - Origin: Mine ""La Frontere, "" Ranch of San Pedro del loya, State of Guanajuato, Mexico. This run-of-mine sample was low in tin content but came from a highly mineralized tin field."

Jun 1, 1947

By F. E. Block

The metallic reduction of vanadium chlorides was investigated by the Federal Bureau of Mines as a possible new route for preparing vanadium metal in an effort to develop a production process that would be adaptable to large-scale plant production and would yield metal of uniformly high quality. Vanadium tetrachloride was usually prepared by chlorinating vanadium pentoxide in the presence of carbon. Although oxygen-?free tetrachloride was difficult to prepare this way, it could be prepared by the direct chlorination of vanadium carbide. Lower valent vanadium trichloride was prepared by the thermal decomposition of vanadium tetrachloride. Vanadium dichloride was also prepared by the thermal disproportionation of vanadium trichloride.

Jan 1, 1961

By Jeffrey P. Schubert

The study site in northeastern Illinois underwent surface mining for coal in 1943 and was reclaimed by the state of Illinois in 1972-1973. Additional soil amendments and seed were applied to the spoil surface in 1975-1980. Previous studies in 1975-1978 had shown that the surface spoil materials and five final-cut lakes at the site were quite acidic and the lakes contained high concentrations of sulfate and dissolved metals. Surface runoff water from monitoring plots in 1976 were only moderately acidic and the mean concentrations of most dissolved metals and sulfate in the runoff waters were less than 25% of the concentrations found in Lake B. By 1980, vegetation had become well established over most of the mined area. However, the five final-cut lakes (Lakes A-E) remained acidic. The purpose of the study reported here was to determine the physical and geochemical subsurface conditions of the spoil materials, the hydrologic flow system within the spoils, and the magnitude of acidic spoil leachate migration into the lakes and into the wetland prairie north of the mine site. Lakes A, B, C, and E were still very acidic in 1980-1981 (pH range: 2.9-3.4; aridity range: 110-860 mg/L as CaCO3). Lake B had the worst water quality, with mean concentrations of dissolved aluminum, iron, manganese, and sulfate of 75, 25, 37, and 3340 mg/L, respectively. Shallow groundwaters in spoil materials around Lake B had a lower pH and about two to four times greater concentrations of aridity, aluminum, manganese, zinc, and other metals and nearly 20 times greater dissolved iron than the water in Lake B. The shallow groundwaters in undisturbed soils and bedrock 10-30 m north of the mine site spoils generally were alkaline, but did contain occasional moderately high sulfate and metal concentrations. Pumping tests and recovery tests conducted in piezometers showed hydraulic conductivities of spoil materials ranging from less than 10- to 10-5 m/s; hydraulic conductivities of natural soils and bedrock were measured between 10-10 to 10-7 m/s. Water levels in spoil materials increased rapidly in response to rainstorm events and the recession curves were relatively quick to decline, lasting only two or three days. Quick infiltration of rainfall into the spoil surface and percolation down to the water table caused a rise in groundwater levels and movement of spoil groundwater into the lakes. This groundwater component in the lake water budgets could account for most of the water quality problems occurring in the acid lakes.

Jan 1, 1984

By E. P. Carman

In this report, the Federal Bureau of Mines presents a summary of the occurrence, properties, and uses of some natural bitumens, using the layman's or dictionary definition of bitumens - that is, naturally occurring hydro-carbons. Emphasis is on the less common solid and semisolid bitumens, particularly those occurring or used to some extent in the United States. This comprises data from many sources and references to these sources for more detail than is given in this summary. This paper was prepared primarily to answer questions about some of the less known bituminous materials. The word hydrocarbons could just as well have been substituted in the title for bitumens, but bitumens was used, since an abstract of the paper was presented at a meeting where the major emphasis was on bituminous materials. The reader will realize that coals, of which only the more unusual such as the cannel coals and torbanites are discussed in this paper, are primarily mixtures of bituminous materials and carbon. The amount of bituminous material, or volatile matter, in coals is greatest in the lower rank coals and the unusual types described in this paper, and decreases as coal rank increases. However, since no method other than destruction of the original coal substance by heat is known that will separate the volatile matter from the carbon, it appears reasonable to classify the coals with other bituminous materials, particularly since bituminous coal - the most widely used coal - by its name indicates the combination of bituminous materials and carbon.

Jan 1, 1961

By Robert W. Waytulonis

The mining regulations of all 50 States were reviewed by the Bureau of Mines, and those parts pertaining to the use of internal combustion (IC) engines (particularly diesel engines) in underground mines or confined spaces were extracted. Also extracted were subjects associated with the use of IC engines; for example, storage and handling of flammable liquids, maintenance, and ventilation requirements. As the laws now stand, 29 States have specific regulations that affect the operation of diesel engines in underground coal and/or metal and nonmetal mines. The other States have no regulations because either they have no mining activities or they defer to Federal regulations. Six states have regulations expressly prohibiting the use of diesels in underground coal mines. Specific contacts (addresses and phone numbers) precede each State's regulations to facilitate inquiries about regulation revisions and interpretation.

Jan 1, 1981

By John O. Atkins

[Experiments were conducted by the Bureau of Mines on five types of simuated lunar rock (dacite, tholeiitic basalt, vesicular basalt, pumice, and uluth Gabbro) to study the effects of various simulated lunar environments n their strength and deformational properties. Specimens were tested in an ltrahigh vacuum (UHV) system at pressures ranging from atmospheric down to 0-11 torr and at temperatures of -130°, 20°, and 135° C. All tests were onducted with a servocontrolled testing machine. Rock specimens tested at 0° C in UHV exhibited significantly higher compressive strength and Young's odulus than those tested at 20° C in atmospheric pressure. The magnitudes f increase are related to the porosities and permeabilities of the rock pecimens; high porosity and permeability allow better outgassing and thus nprove surface cleanliness in UHV. The compressive strength generally ncreases but Young's modulus decreases as test environments change from 20° C i UHV to 135° C in UHV. No significant difference was observed in the iysical properties measured at 20° C in LTV and -130° C in UHV. Anisotropy i strength and Young's modulus exist both in UHV and at atmospheric condi¬'.ons with the same symmetry pattern. The orientations of the principal axes iy, however, change from the atmospheric to UHV condition. The results idicate that rock fragmentation in lunar environment will require more ergy than that at 20° C in atomospheric pressure.]

Jan 1, 1974

By D. J. Bauer

The Bureau of Mines has conducted extensive studies on the recovery of alumina from kaolinitic clay by a HCI leaching-HCI sparging process. The current study reports a modification of the process, which involves a double-leaching system. The first leach of the calcined clay is made at as high a HCI acid strength as possible so that the dissolution of aluminum chloride hexahydrate (AlCI3*6H20) is suppressed, Most of the impurities, but very little aluminum, are soluble in the strong acid. After liquid-solid separation and washing, the solids are leached with recycled weak HCI, which dissolves the AICI3'6H2O. The pregnant liquor is separated from the gangue, and AICI3'6H2O is crystallized from solu-tion by injecting HCI gas. A proposed flowsheet is presented, and the effect of bleedstream size on AlC13'6H20 purity is discussed.

Jan 1, 1984

By Frank T. Duda

A U.S. Bureau of Mines interactive FORTRAN computer program can screen explosion-proof enclosures intended for underground service. The program incorporates important information and criteria to assist enclosure manufacturers and Mine Safety and Health Administration (MSHA) personnel by providing a first-order approximation of rectangular explosion-proof enclosure characteristics prior to actual certification testing. The program uses information and data that can be retrieved automatically during program execution. The program also performs the calculations for a series solution algorithm and various equations to evaluate the enclosure for both a static internal pressure and an internal explosion. The program writes the intermediate and final calculations and information concerning the status of the screening process to a summary file on a floppy disk. One data base contains MSHA certification requirements given in the Code of Federal Regulations (30 CFR 18). A second data base contains material properties of acceptable construction materials and weld joint efficiencies. A series algorithm determines bolt and cover stresses for a simply supported rectangular cover with arbitrary bolt locations. Limit and yield line analysis is used to calculate the strength of body panels.

Jan 1, 1989

By Michael Rieber

This study is an extension of our previous work in the area of coal transportation Its subject is the comparative costing of competing transport erodes. A wide range of costs and aspects of costs are dealt with in terms of engineering - economic analyses of the cost of the components which make up the facility and operating system descriptions of each coal transport mode. The cost comparisons, though analyzed, are not meant to be statements of policy but, rather, an input to decision making. The technical material presented in the succeeding volumes, alone with the earlier work cited above, forms the basis for the analyses. This material may also broaden the general understanding of coal transportation issues and problems. The project is divided into two main sections: (1) lone distance coal transport and (2) gathering and distribution systems. Within each section economic and technological comparisons are made of the available modes. These are used as the basis for comparisons among the modes. Inter-modal compatibility is studied with respect to both mixed trunk line shipment anti with respect to feeder to trunk line and trunk line to distribution systems. The engineering and technological data form the bases for the costing and economic analyses.

Jan 1, 1977

By D. A. Reynolds, R. G. Travis, James J. Dowd, R. F. Abernethy

"1. Reserve estimates have been made for eight coal beds in Monongalia County, W.Va., but only the Pittsburgh, Sewickley, and Upper Freeport beds are important at this time. The Pittsburgh, Sewickley, Waynesburg, and Upper Freeport beds contain the largest recoverable reserves.2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 short tons per acre-foot of coal in place, are estimated at 3,526 million tons as of January 1, 1954. Of this total, 3,294 mil¬lion tons is in beds 28 inches and more thick. Areas in each bed except the Pittsburgh were omitted from the estimate because available data relative to the bed characteristics are too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.3. Recoverable reserves of coal have been estimated in beds 28 inches and more thick. This thickness is about the minimum now being mined by hand loading onto conveyors in the Appalachian region. The weighted average recovery for all beds in Monongalia County, as determined by this investigation, is 47.9 percent. This percentage is based on the total thickness of coal (less partings three-eighths inch thick or more) in the bed rather than on the thickness of the coal mined. Based on the weighted average percentage of recovery for all beds in Monongalia County, the recoverable reserves are estimated at 1,577 million tons as of January 1, 1954.4. Monongalia County coals of the major producing beds are of high-volatile a bituminous rank.5. The Pittsburgh and Lower Freeport beds in this county yield coal that can be used as metallurgical coal, especially when blended with low-volatile coals. The Lower Freeport coal is coked singly and in beehive ovens, and makes good metallurgical coke.INTRODUCTIONThe investigation to evaluate the reserves of coking coal was planned to cover three phases: (1) Estimation of known measured and indicated recoverable reserves of all coking coal; (2) study of methods of upgrading marginal coals through effective preparation; and (3) study of carbonizing properties of coals and coal blends not now widely used for metallurgical coke making."

Jun 1, 1956

By Albert E. Schreck

[THE COMPOUNDS of strontium were confused with those of barium until 1790, when A. Crawford discovered that the mineral strontianite, long believed to be a barium mineral, was a compound of a new element. This discovery was confirmed 2 years later by I. C. Hope. The mineral was named strontianite because it was found near the town of Strontian in Argyllshire, Scotland. In 1808 Sir Humphrey Davy isolated strontium metal by the electrolysis of fused chlorides. Celestite (strontium sulfate) and strontianite (strontium carbonate) are the principal strontium minerals. Because of its more widespread occurrence, celestite is more important commercially.]

Jan 1, 1959