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By J. J. deBarbadillo

This Bureau of Mines report describes a process for recovering chromium and other metals from superalloy scrap. Laboratory-scale experiments were conducted to test a complex flowsheet utilizing a wide range of extractive metallurgical operations. The novel basis for the process is the fonnation of a sulfide matte in which chromium is concentrated in a discrete chromium sulfide phase. Mineral processing and hydrometallurgical procedures are used to separate chromium sulfide from the other matte constituents. The products of the process are a chromium-nickel alloy suitable for reuse in the superalloy industry, electrolytic nickel, electrolytic cobalt, and iron-molybdenum residue. Recovery of the principal elements contained in the scrap is chromium--93 percent, nickel--99 percent, cobalt--96 percent, and molybdenum--92 percent.

Jan 1, 1981

By L. B. Pankratz

Thermodynamic data on the elements, oxides, sulfides, halides, and selected hydrides, carbides, nitrides, carbonates, sulfates, silicates, and miscellaneous compounds were reviewed, evaluated, and compiled at the Bureau of Mines. Values for CP°, S°, H° -H°298, ?Hf°, and ?Gf° are given in tabular form. A brief thermodynamic background and a number of examples and applications are presented.

Jan 1, 1984

By M. E. Tyrrell, C. W. Houck

Mixtures of zirconium diboride and refractory metals of group VI were resistance sintered to high - density compacts using modified electric welding equipment . To evaluate the use of chromium , molybdenum , or tungsten as binders for zirconium diboride the sintered compacts were examined in polished sections and tested for crushing strength , hardness , microhardness , oxidation rate , and resistance to mechanical shock . Chromium yielded the highest compressive strength , the greatest resistance to mechanical shock and oxidation , and a satisfactory Rockwell hardness . Molybdenum did not yield a satisfactory cermet . Tungsten yielded compacts having high microhardness but very low mechanical strength .

Jan 1, 1964

By J. W. Thompson

ESTATE IN MINERALS. Minerals beneath the surface may be made the subject of separate ownership either by a grant of the minerals by the owner of the land or by a grant of the land excepting the minerals, and thereby an estate in fee simple is created in the minerals, as corporeal things real. Colby, In re, Iowa, 169 Northwestern 443, p. 444. DEEDS EXCHANGING DIFFERENT MINERALS-RIGHTS OF PARTIES. The lands of two adjoining owners were underlaid with cement rock and clay at a depth of about 100 feet from the surface and with coal veins some 600 feet below the surface. By an exchange of deeds one of the land owners conveyed to the other the cement rock and clay with the right to mine and remove the same without entering upon the surface, but the deed contained no covenant not to injure the surface. The other deed conveyed the coal seam and so much of the rock and other minerals just above and below the coal as might be required in connection with the mining and removing of the coal, together with the right to mine and remove the same, and the adja- cent rock, clay, and other minerals, without entering upon or injuring the surface, with one immaterial exception. The deeds do not define the word "surface" and neither expressly nor by implication did they secure to the coal owner the right to subside the overlying cement rock; but the implication is to the contrary, as the deed gives the right to mine and remove coal without entering upon or injuring the surface. The provision that the coal owner should not enter upon or injure the surface amounts to a clause that the coal mine. shall not be worked so as to let down the surface and this does not create any inconsistency with the provision giving the right to mine and carry away the coal.

Jan 1, 1919

By K. E. Stanfield

The oil yields of sections of Green River oil shale in Colorado, Utah, and Wyoming are presented as part of a continuing project to determine oil-shale reserves in the United States. Oil-yield logs, based upon analyses obtained from 1945 through 1952, are presented to show the thickness and richness of 202 sections of Green River oil shale. The logs are based on analyses of approximately 20,500 samples, representing 179,000 feet of shale, which were made by the Bureau of Mines, and upon analyses, representing approximately 26,000 feet of shale, which were made by other agencies. The samples consisted of cores from a Bureau of Mines coring program in U. S. Naval Oil-Shale Reserve 1, Garfield County, Colo., and cores, drill cuttings, and channel samples provided by other agencies, chiefly oil companies. Most of the samples of oil shale from Utah and Wyoming were derived from oil-well drilling operations. As a result, the oil-shale sections were widely scattered and were not extensive or reliable enough to be representative of the significant deposits of Green River oil shale in these States. The oil-shale sections for Colorado, however, were more comprehensive, and a number of the sections were used in a previous report as a basis for estimating oil-shale reserves in Colorado. The present report does not give estimates of oil-shale reserves but is limited to presentation of oil-shale analyses that may be used for future reserve estimates. Other sections of Green River oil shale are being analyzed, and the results will be published in subsequent reports.

Jan 1, 1954

By M. P. Board

The U.S. Bureau of Mines, under a cooperative agreement with Hecla Mining Co., conducted a rock mechanics study at four widely spaced horizons in a deep mine shaft in northern Idaho. The objective of the project was to measure and analyze rock deformation and lining behavior during construction of a deep shaft in a high in situ stress field within an isotropic rock mass. Rock mass displacements were monitored with multiple-position borehole extensometers. Liner stress and strain were measured with concrete pressure cells and embedment strain gauges. This report discusses the general trends and magnitudes of data from the four test sites, and relates the data to a proposed anisotropic constitutive model for the rock mass. A design procedure is then outlined for specifications of liner thickness and support installation sequences for future shaft sinking.

Jan 1, 1989

By K. O. Bennington

The thermodynamic properties of two manganese silicates, pyroxmangite and fowlerite (zincian rhodonite), were experimentally determined by the Bureau of Mines. The standard enthalpies of formation were determined by hydrofluoric acid (HF) solution calorimetry, the low-temperature heat capacities by adiabatic calorimetry, and the high-temperature heat capacities by differential scanning calorimetry over the range 322 to 1,372 K. Data for the standard enthalpy of formation (AH298), the derived standard entropy (S298), and the standard Gibbs energy of formation (AGf 298) are as follows: Pyroxmangite [(Mn0.9554Cao,0446)(Si03)J- AHf298 319.668±0.46 kcal/mol AH298 (from oxides)... -7.215±0.11 kcal/mol 5295 23.785±0.048 cal/(mol'K) AGf298 -301.190±7.96 kcal/mol Fowlerite [(Mno.7o3Zno.0884Ca0.2086)(Sio3)]--AHf298 ?... -329.914±0.419 kcal/mol AH298 (from oxides)... -8.400±0.104 kcal/mol 5598 21.949±0.059 cal/(mol-K) AGf298 -310.716±7.99 kcal/mol These experimentally determined values were combined with data from the literature to calculate the Gibbs energies and equilibrium constants of formation over the temperature range of the measurements. Standard enthalpies, Gibbs energies, and equilibrium constants of formation are given as a function of temperature from both the elements and the constituent oxides.

Jan 1, 1987

By G. B. Shea

"INTRODUCTION Much of the recent progress in increasing the efficiency of oil-well performance can be attributed to advancements in the art of cleaning wells. Through research and development by operators and service companies during the past decade, significant improvements in the application of engineering and chemical principles to well-cleaning technology have widened greatly the scope of ""clean-out"" methods to the end that greater ultimate recovery of oil will be attained.This report reviews recent improvements and developments on this important problem in California; it describes also the use of various methods and tools for cleaning wells to stimulate or revive their productivity. Developments in preventing and removing mud sheaths in well-completion operations also are described. The report is based on a field survey, supplemented by data from the technical and patent literature and from manufacturers' catalogs, which contain much valuable information.In preparing the material for publication as a Bureau of Mines report, the author has been fully aware of certain limiting conditions that attend the discussion of a subject such as that treated in this report. The following are examples:1. To a considerable extent, well cleaning in California is done with tools rented from service companies, and their representatives and employees are specialists in jobs of this type. They usually have working experience with their own equipment and methods which greatly exceeds that of persons whose interest has been casual or who have had no opportunity to study the subject in detail in actual practice. Many of the tools and methods are covered by letters patent for the protection that may be in developing and successfully applying these mechanical and chemical means of increasing the production of wells. Frequently several years have been required to perfect a given tool or technique, requiring relatively large investments to establish a service that is remunerative to those who have primary interest in a certain development and at the same time attractive enough to the operators of producing properties (because of greater quantities of oil delivered into the flow tanks) to warrant employment of or contractual agreements with a particular service group."

May 1, 1943

By Dean H. Ambrose

[Mining and processing earth's materials form the basic building blocks from which many technology advancements and products are made. Virtually all metallic and non- metallic products are derived from a substance found in our earth that we blend, mold, extrude, or pulverize into something useful, the mining industry is responsible for the first step of this process: extraction from the ground. Mining particularly coal mining. poses significant risks to both humans and machines. As raw materials are]

Jan 1, 2009

By Thomas P. Dolley

Building stone, cassiterite, kaolin, gold, lime, and peat were the only commodities mined, The country's main economy was in agriculture, primarily in coffee exports. Tribal violence occurred again, between the Hutu and Tutsi tribes, causing an estimated 50,000 deaths, mainly in rural and mining areas. The inflation and a large deficit continued. The country continued to import cement, fertilizers, oil, and petroleum products. Burundi possessed numerous small gold deposits. The northwest and north-east were the country's two most important gold-bearing regions. A large kaolin deposit was found at Ngozi, and its mining was specified in the fifth 5-year development plan for 1988-1992. In the area of Rugombo, limestone was being explored with the intention of opening a cement plant.

Jan 1, 1990

By James F. O'Neill

Brown iron ore resources in Barbour , Butler , Crenshaw , and Pike Counties were investigated in a drilling program and geological study by the Federal Bureau of Mines in cooperation with the Alabama Geological Survey and the University of Alabama . The aggregate footage drilled was 18,010 linear feet . When developed , reserves of 12,664,000 long tons of crude ore were indicated , containing from 26.9 to 29.0 percent iron and 0.2 to 1.6 percent manganese under a maximum overburden of 40 feet . Total inferred crude ore for the four counties was calculated to be 827,700,000 long tons . Beneficiation of samples by simulated log washing and use of a 1 / 8 - inch screen yielded from 46.8 to 51.7 percent iron and 0.2 to 2.6 percent manganese . Screen- test studies indicated no appreciable interlocking between the iron and manganese minerals and the waste particles of materials retained on a 200 - mesh screen . Clay was prominent in micron - size slimes . Silica was deleterious in the minus 20 - mesh size . While an indicated 2,198,000 dry long tons of usable iron ore can be recovered , sink - and - float tests show that it may be possible for 4,654,000 dry long tons to be recovered by other than log washing . However , applicable commercial processes have not been demonstrated .

Jan 1, 1965

By R. S. Dean

"INTRODUCTION The idea of direct steel is by no means new. Although the work of Bessemer and Siemens provided simple and effective moans for converting pig iron into steel and established the ""blast-furnace route"" as the almost universal method of producing steel, metallurgists have not ceased to dream of direct steel. By direct steel is meant any process by which iron oxide in ore is reduced to Iron of the same or greater purity than the final steel or wrought iron. That is, carbon or alloying elements would be added as needed, not reduced in unwanted quantities into the iron and then removed more or completely by refining (Bessemer or open hearth) only to be readded in desired quantities.In general, direct-steel processes are ""sponge-iron"" processes, because reducing iron oxide without simultaneously alloying the iron with carbon, phcophorus, sulfur, and silicon present in ore and fuel succeeds only if the temperature is below the melting point of the iron. Such solid iron formed by reduction of iron oxide at relatively low temperature is sponge iron, which is butlery and porous. When the reduction proceeds at the higher temperature at which the particles of metal can weld together or finally even melt to yield pellets or balls that do not have the porosity and low-density characteristic of sponge iron, the product might preferably be called simply ""direct iron."""

Jan 1, 1945

By Arcy R., D&apos George

A process for removing sulfate from Great Salt Lake brines and other natural brines, including sea water, has been developed. Sulfate is quantitatively removed by precipitation as barium sulfate in a cyclic process employing ion-exchange techniques. Barium is continously recovered and recycled, and sodium carbonate and sulfur or sulfuric acid are produced as byproducts in quantities sufficient to more than defray the cost of desulfation.

Jan 1, 1967

By R. F. Waters

Laboratory-scale selective volatilization methods developed by the Bureau of Mines to recover germanium and gallium concentrates from coal fly ash and phosphorus furnace flue dust are summarized. In the better experiments between 85 and 98 percent of the germanium was recovered as the lower oxide and as sulfides, and between 75 and 97 percent of the gallium was recovered as the lower oxide and as the trichloride. Grades of the condensates were inconsistent and varied between a few tenths of a percent and 8 percent, depending on the method used. In the primary extractions of germanium alone the degree of enrichment surpassed 100 to 1, and for gallium the best ratio was 30 to 1. Upgrading of condensates by vaporization retreatment and by leaching and precipitation is discussed. An appreciable degree of mechanical preconcentration by attrition scrubbing and elutriation was possible on two fly ash samples.

Jan 1, 1967

By G. B. Gait

This report is the third in a series concerning the Bureau of Mines program for microfilming maps of abandoned mines in the Pennsylvania anthracite region; a catalog of the microfilmed maps of mines in the Lackawanna Basin of tile Northern anthracite field is presented. Previous reports IC 8274, published in 1965, and IC 8379, published in 1968, were catalogs of microfilmed maps of mines in the Eastern Middle anthracite field and Wyoming Basin, Northern anthracite field, respectively , Additional catalogs will be published as the microfilming of significant mining areas is completed.

Jan 1, 1970

By J. Kruttschnitt

This paper, describing the mining operations at Mount Isa Mines, is one of a series covering mining methods and costs being published by the United States Bureau of Mines. The Mount Isa property has been in operation since June 1931; during this period operations have changed from the production and treatment of carbonate ores to the mining, milling, and smelting of sulphide ores. This change involved revision of ore-extraction methods. Stoping methods have been designed to apply to parallel lodes ranging from 10 to over 100 feet in width and dipping at 50° to 60°. The hardness and strength of the ore and enclosing wall rocks, together with the strength and thickness of the country rock between lodes, have permitted the selection of a sublevel stoping method for mining the sulphide ores.

Jan 1, 1937

By A. J. Kraemer

The twenty-fourth of a series of semiannual surveys pertaining to motor gasoline marketed in the United States was made by the Bureau of Mines in August, 1931. The first part of a report giving the results of that survey as they pertain to specification data is given in this paper. A companion report, Part II, is in preparation and will discuss the results of other determinations made on the samples, including octane number ratings on the individual samples (to be made by the Bureau of Standards) and results of the determination of gravity, color, doctor test, and "gum" content by the copper dish method and the Bureau of Mines steam-oven method. The retail price and the tax at the time each sample was taken will also be reported.

Jan 1, 1932

Objective: On-the-job training (OJT) is a common means of training workers. By definition, it seems relatively simple. However, to be effective, training must go beyond the simple process of following an experienced worker around the workplace— sometimes called the "follow Joe" method. NIOSH researchers spoke with human resources personnel, safety and health specialists, supervisors, experienced miners, and new miners and found that OJT was of high interest, but was rarely part of a formal or standardized program. Various training methods have evolved to ensure that a trainee will absorb the information presented rather than simply emulate what the instructor is teaching. These methods have been brought together into a published guide for developing an effective formalized OJT program. The guide (Information Circular (IC) 9479) is called "Coaching Skills for On-the-Job Trainers." It contains materials and suggestions for your company or mine to conduct a 1-day workshop for teaching OJT trainers how to be better coaches to less experienced workers. The guide was created by the NIOSH Pittsburgh Research Laboratory and a safety professional from a private mining company.

Feb 1, 2006

By A. J. Kraemer

This paper is the second and concluding report of the results of the twenty-fourth semiannual survey made by the Bureau of Mines of motor gasoline marketed in the United States. The first report7 on this 1931 survey gave the results of the examination of the gasoline samples in accordance with the new Federal specification for United States Government Motor Gasoline.8 The present paper reports results of the examination of the gasolines for color, doctor test, gravity, end point, per cent recovered, copper-dish gum, and steam-oven gum. The retail price and the tax at the time each sample was taken are also reported.

Jan 1, 1932

By Seth T. Reese

THE INJURY DATA and experience at coke ovens in the United States for 1952 are presented in this bulletin under the following general sections: (A) General injury experience: Tables 1 to 9: Contain current and comparable data on operating statistics, number and classification of injuries, frequency rates, and accident agencies involved in causing injuries. Data are given for the industry as a whole, for each type of oven, and for the States in which coke is manufactured. (B) Selected injury experience: Tables 10 to 15: Contain comparable injury data in the coking industry covering 5- and 10-year periods on the number of injuries, accident agencies, and severity of injuries. (C) Historic injury experience: Tables 16 to 19: Contain data on the number of injuries, frequency rates, and employment at coke ovens from the earliest records through 1952, Operating statistics from 1929 through 1952 are given in table 19.

Jan 1, 1955