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By J. H. Holden

Operations involving the processing of coal, oxygen, and steam into synthesis gas by means of two pressure-type gasifiers have demonstrated the effect of heat loss and operating variables on carbon gasified and oxygen and coal requirements. Carbon gasified is the fraction of carbon in the coal that is converted to gas. Oxygen and coal requirement is the quantity of each that is needed to produce a unit volume (M std. c.f.) of carbon monoxide and hydrogen. Operating pressure of the gasifiers ranged from 150 to 300 p.s.i.g. and coal was fed at 200 to 500 lb./hr./cu.ft. of reaction-zone space. Oxygen-to-coal ratios were 8.5 to 10.5 std. c.f./lb. Heat loss and residence time have opposite effects on carbon gasified; increasing the heat loss decreases the carbon gasified, but increasing the residence time (by raising the operating pressure or reducing the coal-feed rate) increases the carbon gasified. The effects of these two factors are difficult to separate because they usually change simultaneously. A comparison of the results obtained from the operation of two gasifiers with different levels of heat loss, however, permitted the effect of heat loss to be separated from that of pressure and coal-feed rate. When the results were deter- mined on the basis of constant heat loss, increase of the residence time increased the carbon gasified until the reaction virtually had come to completion. For example, at 150 p.s.i.g., decreasing the coal-feed ratio from 500 lb./hr./cu.ft. to 200 lb./hr./cu.ft. substantially increased the carbon gasified. At 300 p.s.i.g., however, changing the coal-feed rate had little effect on the carbon gasified because the reaction had almost reached completion and further increase in residence time resulted only in a negligible change.

Jan 1, 1962

By Charles J. Cohen, Donald F. Reed

"INTRODUCTION AND ACKNOWLEDGMENTSThis report supplements a previous report on work done in this same area 4/ but covers only the period from November 1945 to November 1946. The project was established in 1943 to investigate magnetite deposits in the northwestern Adirondacks by geophysical surveying and diamond-drilling for the purpose of increasing iron production in the eastern United States.In its program of investigation of mineral deposits, the primary objective of the Bureau of Mines is the more effective utilization of our mineral resources, that they may make the greatest possible contribution to our national security and economy. The policy of the Bureau is to publish the facts developed by each project as soon as possible after its conclusion. Maps showing the detailed magnetic surveys of the deposits and anomalies discussed in this report are on open file at the offices of the Bureau of Mines, College Park, Md., and at the University of the State of New York in the office of the Director of the State Science Service, Educational Building, Albany, N. Y.The Mining Branch, Lowell B. Moon, chief, conducts preliminary exami¬nations, performs the actual investigations, and prepares the final report. The Metallurgical Branch, Oliver C. Ralston, chief, analyzes samples and performs beneficiation tests.The chemical analyses included in this report were made at the Eastern Experiment Station of the Bureau of Mines at College Park, Md., under, the general supervision of J. B. Zadra, chief, College Park Division, Metallurgical Branch, and the immediate direction of Dr. Alton Gabriel, in charge of the laboratory service unit."

Nov 1, 1947

By P. H. Mutschler

The Bureau of Mines studied the costs of transporting fossil fuels, coal, and residual fuel oil from areas of production to consumer regions. Transportation data were stratified by type of carrier, size of shipment, and distance to determine what general effects these variables have upon transportation costs. Economics of haul for coal exist for longer versus shorter distances, and for larger versus smaller trainload sizes. Tanker and barge transportation of residual fuel oil does not show economies of haul for longer distances. It is shown that tanker size and seasonal variation are primary factors influencing the cost of shipping. Railroad transportation data show that coal from western coalfields could be competitive with foreign residual fuel oil in selected midwestern fossil fuel markets. However, the western coal would not be competitive in the New England and the eastern seaboard energy markets.

Jan 1, 1973

By Mandeep Singh

The smelting of lead ores has been carried out in southeast Missouri for centuries, and modern smelting practices have generated a variety of waste products. Lead blast furnace slag is one such product, which typically contains 10% zinc, 25% iron and 2% lead. This slag has often been stockpiled on the producing smelter site and accumulations have now reached several million tonnes. It is possible that in the near future these slags will be classified by the federal Environmental Protection Agency as hazardous, and therefore there is considerable interest in possible treatment processes to render the slags non-hazardous by removing the offending metallic elements. To ensure that the overall slag processing costs are kept to a minimum, it is imperative that lead and zinc be recovered in a form suitable for sale or further processing. There are two generic routes for processing blast furnace slags and they involve hydro-metallurgical or pyrometallurgical techniques. With hydrometallurgy, the slags would be leached directly and the metal values recovered from purified leach solution(s) by electrowinning. One problem with processes of this type is that the zinc and lead grades of the slags are low and the iron content is high, and thus the economics of metal production are often not favorable. For pyrometallurgical processing (1), it has been shown that the slags can be fumed to produce an oxide dust containing all the lead and zinc, and representing only a fraction of the weight of the initial slag. The oxide dust may then be processed hydrometallurgical to recover zinc and lead.

Jan 1, 1992

By G. W. Jones

In a previous report,6/ results were given that showed the amount of natural ventilation in a manhole having a capacity of 74.1 cubic feet when the number of ventilation openings in the cover was varied from no openings to a maximum of 48. The result s showed that the ventilation (air changes per day) in the manhole was proportional to the area of the openings in the cover, and also that the number or area of the openings was the factor that chiefly affected the ventilation.

Jan 1, 1937

By John R. Bartels

This Bureau of Mines report describes the development of a preliminary design for a novel, protected, cab-shuttle car for use in working seam heights down to 40 in. Because of the severe restrictions imposed by low-coal operation, Mine Safety and Health Administration (MSHA) regulations only require canopy protection on shuttle cars operating in seam heights of 42 in or greater. MSHA routinely grants variances for canopy use in seams 48 in high or less. The design was generated by giving the operator needs equal priority as related to machine performance parameters. Cab-shuttle car concepts that led to the recommended design are described, along with criteria and testing used to evaluate their potential effectiveness.

Jan 1, 1988

This report presents the results of a study of Kennecott Copper Corporation?s Chino leaching dump at Santa Rita, N. Mex. The stability studies described herein were performed on only one cross section of the leach dump, utilizing data obtained from drilling, sampling, and testing, which was limited in nature. The first part of the report contains a discussion of site geology and seismicity, pertinent information on the waste material disposal system and leaching method, a discussion of the waste embankment characteristics, a summary of the engineering analyses, and a bibliography. The second part (appendices) contains basic geologic and engineering data supporting the discussions in the first part.

Jan 1, 1974

By Jeffrey S. Walker

The purpose of this U.S. Bureau of Mines effort was to determine if ground movement caused by mining-induced subsidence is directly transferred to a structure and, if so, how that transfer takes place. Four concrete block walls with foundations were constructed and monitored over an active longwall panel. Three of the walls were located perpendicular to the direction of mining in zones where maximum inclination, maximum tension, and maximum curvature were predicted to occur. The fourth wall was constructed along the centerline of the panel, parallel to the direction of mining. All of the walls and the surrounding ground surface were instrumented with conventional survey monitoring points and extensometer stations to observe the vertical and horizontal movements. The fourth wall instrumentation also included continuously recording tiltmeters. The results of this investigation indicate that these simple structures respond to subsidence in a similar manner as the ground surface. This suggests that once the transfer mechanism is more fully defined, prediction models can be developed to accurately estimate the effect of mining on surface structures.

Jan 1, 1989

By Martin Hertzberg

The early and reliable detection of the self-heating of combustible substances in mines is of considerable importance to the mining community. This Bureau of Mines report describes the results of a variety of studies of incipient combustion and its detection. Heated samples of coal, wood, and various polymers were used to evaluate the relative sensitivities of several types of detectors. The laboratory results indicate that submicrometer particulate detection is the most universal and sensitive method. Carbon monoxide detection was as sensitive as submicrometer particulate detection for pyrolyzing coal but was relatively insensitive to pyrolyzing wood or plastics. The conventional type of ionization smoke detector was the least sensitive for coal and of intermediate sensitivity for wood and plastics. Self-heating experiments with Pittsburgh seam coal piles of varying particle sizes gave ignition temperatures of 170° C for 4-to 7-µm dust, which increased monotonically with particle size. The measured heating rates were compared with data from an adiabatic calorimeter to obtain preexponential rate constants. The preexponential rate constants varied linearly with the surface area per unit mass of sample as would be expected for heterogeneous surface oxidation. The propagation behavior of ignition waves and the overall self-heating appears to depend critically on the magnitude of the convective flows induced, which counteract the depletion of oxygen in the void spaces of the pile. Classical theories of thermal ignition require substantial modification to be applied reliably to such cases.

Jan 1, 1977

By Robert Stefanko

This report, rather than attempting to replace previous annual reports, supplements, and more importantly, coordinates and summarizes the entire effort. Even with such restrictions, the report is voluminous and, therefore, a decision has been made to divide it into two parts. The first volume is basically narrative and includes tabular results and analyses. The second volume is in appendix form giving detailed information. Together, they permit a logical discussion of all aspects of the project (Volume I) without cumbersome distractions but, at the same time, provide all the details to permit others to evaluate and explain the results or develop similar research programs (Volume II). The aim of the original proposal was basically to develop instruments and techniques and then make measurements of suitable power parameters, ground fault currents and ground resistance beds. With such information available, it was possible to develop a meaningful simulator which would permit investigating electrical systems and components on paper without costly trial and error procedures in the third year, a cable splice testing program was added to the project. While there were the usual delays attendant in such original research, these objectives were achieved.

Jan 1, 1973

By Fred Leonard

This report is principally concerned with the engineering and economic feasibility of area surface coal mining systems other than draglines. This analysis evaluates shovel/ trucks, shovel/crusher/conveyors, and shovel/rail excavation and haulage systems for an assortment of geologic environments and production rates in the Powder River Basin (PRB). Shovel/trucks, front-end loaders trucks, and shovel/crusher/conveyors were studied in a multi-seam, dipping geologic area of the Four Corners Region. The Texas lignite engineering and economic research involved bucket-wheel excavators (BWE), BWE/backhoes, and scraper/backhoe combinations for overburden and coal excavation. The PRB truck/shovel study utilized the most recent computer simulation available in both the design and cost analyses. Detailed engineering analysis, followed by in-depth operating costs (operating and depreciation), result in a complete evaluation of each mining system. Cost comparisons of the different mining systems under similar geologic and production constraints are presented in the report to illustrate the estimated capital investment and production costs per ton of coal and bank cubic yard of overburden.

Jan 1, 1980

By Robert Stefanko

The growing demand for energy during the post World War I and World War II periods has prompted underground coal production to increase rapidly. This has been met primarily by mine mechanization, resulting in the development and application of new mining machine types. Correspondingly, the total connected horsepower of each machine as well as the number employed has enlarged rapidly since 1950. (2,3,9,14,16,17) Electrical consumption for each mine has also grown. In the early years of mining electrical applications, only d-c power was utilized underground. Yet, d-c machine limitations were soon realized, and many a-c systems were substituted to permit economic and efficient utilization of a-c distribution and motors. Due to the attractive torque characteristics, ease of distribution and speed control, several traction applications have continued to be powered by d-c motors. The result has been the now prevalent use of mixed a-c/d-c mine power. However, augmented electrical power employment seems to have added to underground coal mining electrical accidents.

Jan 1, 1974

By R. G. Knickerbocker, David Schlain, F. K. Shelton, J. H. Jacobs

"Many manganese ores contain from 0.1 to several percent cobalt. If such ores arc used for the production of ferromanganese, the cobalt is lost; on the other hand, if they are used for the production of electrolytic manganese, the cobalt can be recovered during the purification of the electrolyte.The production of cobalt in the United States is insignificant compared to the amount consumed, most of which is imported from the Belgian Congo. Cobalt-bearing manganese ores may therefore constitute an important reserve of cobalt in times of emergency. Moreover, the combined value of manganese and cobalt in some ores may be sufficient to warrant the recovery of both metals by the electrolytic manganese process, whereas the recovery of either manganese or cobalt alone might not be economically feasible.In view of the potential importance of manganese ores as a source of cobalt, a survey has boon made of the cobalt content of manganese ores. Most of the data have been obtained from analyses made in the Bureau of Mines, but valuable data have also been obtained from publications of the Geological Survey, various State publications, and other sources. Unfortunately, most published analyses of manganese ores do not include cobalt determinations; when such analyses were fairly detailed, but did not include cobalt, it was presumed that cobalt was not present in significant quantity.Information on the cobalt content of domestic manganese ores is given in table 1. Ores containing 0.1 percent or more cobalt are listed in table 2, and the districts in which such ores occur are shown in figure 1. Most of the known cobalt-bearing manganese ores occur in the southeastern part of the United States. A group of deposits in central Arizona and a few scattered deposits in other States also' contain cobalt."

Apr 1, 1946

By Philip C. Good

Red mud residue from Bayer process treatment of Jamaican bauxite was dewatered in batch and in continuous centrifuges. Solids content of the residue was increased from its original value of 20 to 25 percent to about 40 percent by centrifuging. Clear effluent amounting to approximately 40 percent of the slurry liquid was recovered containing dissolved alumina and soda values for potential recycle to the alumina plant" Addition of a chemical flocculant to the centrifuge increased capacity by about 35 percent. Manufacturer's estimate of large-scale equipment requirements, based on data collected in this investigation, was that a proposed installation for dewatering 16,000 tons per day of Jamaican red mud would require twenty-two 24-by 60-inch solid-bowl-type centrifuges. Cost analysis of a proposed installation, based on a Jamaican red mud tonnage of 16,000 per day, is included also.

Jan 1, 1968

By Donald R. Corson

The effects of adding varying amounts of type I portland cement to hydraulic backfill are described. Six different fill materials, each with three cement contents, were tested to determine which fill properties have the most significant effect on cemented strength. Two strength prediction equations, based on the physical and mineralogical properties of the fills, were formulated, and these accounted for 96 and 99 percent of the variability of the data. Results of both unconfined compression and triaxial tests of cemented fills are given, and the effects of moist curing and fill densification on the 7-day strength are discussed. Permeability test data are given, and the decreased permeability due to cement content and curing time is shown graphically. A discussion of the limited evaluation of other potential stabilization additives (expansive cement, fly ash, sodium silicate, gypsum, and asphalt) is included in an appendix.

Jan 1, 1970

By David R. Jessey

Water pollution problems associated with surface metal/nonmetal mines throughout the United States were assessed. Three major problems were identified: acid mine drainage (AMD), toxic concentrations of heavy metals and excessive sedimentation. Several factors affect the type and amount of pollutants generated at a mine site. Among these are hydrologic regime, geology, mineralogy, topography, climate, size of the mineralized area and mining method. Nine surface mines situated in distinctly different settings were visited and their pollution problems studied. These mines were located in Morenci, Arizona; Hayden, Arizona; Sauharita, Arizona; Cobalt, Idaho; Spruce Pine, North Carolina; Iron Mountain, California; Butte, Montana; Fernwood, Idaho; and DeLamar, Idaho-Oregon. A detailed evaluation of the pollution problems at the Morenci mine indicated that a diversion system and treatment pint would be the most effective means of abatement for the existing water quality problems. Based on the study of the Morenci mine and three other porphyry copper mines with differing problems a water management plan was conceived for a new source copper mine. A companion Appendix Volume containing detailed reports on the mine site visits is on file at the US Bureau of Mines Spokane Research Center.

Jan 1, 1981

By Daniel L. Ng

This Bureau of Mines report describes the results of scanning electron microscopic (SEM) studies of the combustion residues of carbonaceous dust particles resulting from explosions and thermal ignitions in laboratory and full-scale mine tests. The dusts studied varied widely in rank and volatility: Pittsburgh seam bituminous coal (35% volatility), Pocahontas seam bituminous coal (16% volatility), anthracite (7% volatility), graphite, and diamond. The most systematic explosion studies were performed in an 8-L chamber with narrow size distributions of Pittsburgh coal dust with surface mean diameters of 2, 22, and 84 pm. Experiments were conducted mainly in air, with some data obtained in 50% 02. Observations of the bituminous coal explosion residues showed particles with rounded edges, particles with blowholes, and some cenospheres. The lower volatility dust residues showed fewer changes from the original, unburned dust. In addition to the experimental studies, results of SEM observations of residues from a mine explosion disaster are reported. Comparison of such residues with those from the laboratory and experimental mine explosions can help investigators determine the extent of dust participation in the disaster and in identifying the possible ignition sources.

Jan 1, 1983

By V. E. Edlund

As part of a research program for recovering alumina from domestic nonbauxitic resources, the Bureau of Mines investigated a lime-sinter, caustic leach technology for anorthosite. This report discusses the unit operations--feed preparation, sintering, and leaching. Acceptable pellets for the bench-scale sintering studies were prepared from mixtures of minus 200-mesh anorthosite and limestone using water alone as the pelletizing agent. Heating pellets at 1,270° to 1,360° C for periods of 0.5 to 2 hr, followed by a 15-min soaking period at 700° C and cooling to room temperature, produced a sinter that dusted to more than 90 pct minus 65 mesh. The weight ratio of limestone to anorthnsite was critical in producing sinter exhibiting good dusting and leaching characteristics. A ratio of 2.0 was optimum for the bulk samples of anorthosite and limestone used in this research. Leach solutions from lower ratio sinters were unstable; gelation became progressively more severe with higher ratio sinters. Leaching the dusted sinter with 10-pct Na2CO3 at 60° C extracted 85 to 90 pct of the alumina in a product solution containing about 50 g/l A1203. Leach residue in contact with pregnant solution tended to set up as a rigid gel as a result of cementation, comp action, and gelation. The presence of a calcium-sodium zeolite [(Cn,Na2)6?(Al2Si04)12?27-3OH20] in the ungelled residues seemed to be the main difference between gelled and ungelled residues.

Jan 1, 1982

By M. A. Trevits, M. R. Thibou, A. Ozment, A. C. Smith, J. B. Walsh

The Excel No. 3 Mine is a room-and-pillar mining operation owned by MC Mining, LLC, a subsidiary of Alliance Resource Partners, LP, which produces coal from the Pond Creek Coalbed in Pike County, Kentucky. Late on December 25, 2004, a fire was discovered near the bottom of the slope and, after an unsuccessful attempt to fight the fire underground, it was decided to address the fire remotely from the surface. The mine operator developed a plan to fight the fire that called for the installation of temporary seals at the slope and mine shafts to eliminate the inflow of oxygen. In addition, the plan called for drilling and completion of vertical boreholes into select areas of the mine workings to monitor the mine atmosphere and inject nitrogen gas and gas-enhanced foam. Over the next 9 days, nitrogen gas was injected almost continuously and gas-enhanced foam was injected periodically as deemed necessary. On January 7, 2005 it was determined that the fire was successfully suppressed. This paper presents a discussion of the fire-fighting approach and an analysis of the results of the application of gas-enhanced foam technology.

By Lester J. Crow

This study advances the use of elemental sulfur in structural materials by demonstrating its value in bonding high-strength, well-graded basalt aggregates to form sulfur-basalt concretes. Sulfur is an excellent bonding agent, and the strength of a thermoplastic sulfur-aggregate mixture depends, to a large degree, on the strength and grain-size distribution of the aggregate used. A 3-cubic-foot, electrically powered mixer with heat applied to the barrel was used to mix the sulfur and aggregate. Sulfur content of several mixtures was varied to obtain the best workability with a minimum of sulfur in excess of that necessary to fill the voids. The average grain sizes and grain-size distributions were also varied to determine their effects on strength. Unconfined compression tests of forty-five 6-by l2-inch cylinders yielded average strendths of 3,348 psi to 10,398 psi. The highest strength single cylinder was 10,717 psi. The cylinders were tested from 24 hours to 6 days after pouring; after 24 hours the rise in strength was very slight. From the results obtained it appears that sulfur can be a useful construction material. An evaluation was made of a high-vacuum application for sulfur concrete. Sulfur has a high vapor pressure at elevated temperatures, 50° to 100° C; consequently, significant losses by sublimation can be expected. At lower temperatures the losses are not significant; however, this factor will limit its use at a higher temperature.

Jan 1, 1970