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The mineralogical composition of the ore was determined and the mineral phases with which nickel is associated were identified. The ore was prepared by grinding to -420 micrometres and classification into granulometric fractions. Prior to the main series of experiments the effect of agitation rate on nickel recovery was investigated. The influence of sulphuric acid concentration, temperature and particle size on the kinetics of nickel extraction was then studied, both quantitatively and qualitatively, over fixed value intervals. Application of the initial rate method enabled determination both of the order of reaction with respect to sulphuric acid concentration and the activation energy for the dissolution of nickel. The results indicate that a physical mechanism can be ruled out as the rate-determining step in the extraction of nickel from the ore and that a chemical mechanism is more likely

Dec 1, 1991

By G. E. Pearse, comp.

Questions from the conference delegates and replies by the papers' authors are summarised for sessions on hydropower, metro/rail and water/waste tunnels, tunnel-boring machines, environmental issues, research and case histories, design, and tunnel machinery, with reference to papers on tunnels in Lesotho, Nova Scotia, Italy, UK, Sweden, Kenya, Massachusetts, Germany, Norway, Taiwan, Switzerland, Greece, Malaysia, Australia and Texas.

Dec 1, 1994

By J. J. Mackay

The Parliamentary Under-Secretary of State at the UK's Department of Transport introduced the symposium, approved its emphasis on environmental planning and the mitigation of environmental impact, discussed the publicity resulting from the recent opening of the Channel Tunnel as well as the role of private financing, and pointed out the leading role played by the Department of Transport in the introduction of the New Austrian Tunnelling Method to projects such as the Jubilee Line extension and the Heathrow Express (an editor's footnote, however, mentions with regret the Heathrow subsidence that occurred just before the journal went to print)

Jun 16, 1905

By V. E. Ross

A comparison was made of three methods for determining the contributions of true flotation and entrainment during batch flotation tests. In the first method size-by-size recoveries are measured in both the presence and the absence of a collector, a frother being present in both tests. In the second method the mass of solids and water recovered after a chosen time of flotation is varied by changing the rate of froth removal and the depth of the froth. The third method uses a transfer factor to describe the classification of solids and water, and hence the changes in the composition of the pulp, during a single flotation test. Batch flotation tests were carried out with artificial mixtures of pyrite and gangue, the amount of floated material recovered being calculated according to each of the three methods. The discrepancies betweeen the calculated amounts are analysed in terms of the assumptions that are made for the various methods and the most suitable conditions for the application of each method are identified

Dec 1, 1991

By R. Trueman, D. B. Tyler

Numerical modelling was used to determine the magnitude and direction of stresses around drives both adjacent to and distant from open stopes in the South Crofty tin mine. Modelling predicted that drives near the stopes are situated in a stress-relaxed zone. The peripheries of drives that are sited in solid rock away from the influence of stoping are in compression. Key-block modelling was used to determine the typical geometries of critical blocks and distinct element modelling was used to determine block stability. The conclusions derived from modelling fitted the observational data. This indicated that key-block theory is a valid tool for analysing the stability of roadways in the South Crofty mine. The support requirements for drives located next to stoped-out areas were formulated using a risk analysis approach to key-block formation. The results were compared with support guidelines derived using empirical design methods. Good agreement was obtained for the roofs of the drives but not for the sidewalls. The concept of a critical excavation width was formulated: once an excavation is larger than the critical size the length of rockbolts need not be increased as the excavtion dimensions increase. This may be the case in all rock mases.

Jan 4, 1993

By A. Paulin, A. W. D. Hills

The work has shown that packed-bed behaviour can be predicted from the results of single-particle experiments, total reaction times being predicted somewhat more accurately than gas and solid temperatures and gas compositions. A small laboratory packed-bed reactor was built and used to study the decomposition of beds of specially prepared CaCO3 spheres, steps being taken to minimise the effects exerted by the walls of the bed on processes occurring within the bed. Gas and solid temperatures and gas compositions were measured at various points in the bed and compared with theoretical predictions based on kinetic data determined in previous single-particle experiments. The measured solid temperatures and total reaction times agreed remarkably well with the values predicted theoretically. Gas and solid temperatures measured after the reaction had finished at any point in the bed did not agree with the theory. This was because solid temperatures in the bed rose very rapidly once the reaction was completed and the walls of the bed could not be heated at a sufficient rate for their temperatures to rise as rapidly; thus some loss of heat from the bed to the walls was inevitable, and this could not be accounted for in the theory. In addition, the theory did not allow for the conduction of heat within the bed, and this resulted in some further slight discrepancy between the measured and predicted values, particularly after the reaction was completed. Gas compositions measured in the bed were rather scattered, but, even so, they agreed moderately well with the predictions of the theory.

Dec 1, 1971

By Winmill T. F.

Paper presented at the at the Institution of Mining Engineers' general meeting held in London on 8th June 1916: In a previous paper it has been shown that the rate of absorption of oxygen by coal is neither directly proportional to the surface area of the coal exposed nor to the percentage of oxygen in the air. Further experiments are now described supporting this conclusion

Dec 1, 1916

By M. D. Pritzker

Shrinking-core models are used to describe the physico-chemical processes that are associated with many metallurgical gas-solid and liquid-solid reactions. The models can be used to evaluate rate constants and effective diffusion coefficients from experimental data. This work generalises the model for diffusion through a product layer to cases where the transport of more than one species is rate-controlling

Jul 1, 1991

By A. G. Royle

Sampling formulae for in-situ material, hard rock sampling and alluvial sampling are briefly discussed

May 1, 1991

By C. A. Pickles, S. J. Splinter, J. Cameron

The addition of copper oxide to a borosilicate slag resulted in the breakdown of the silicate network and a dramatic decrease in viscosity. With increasing borax to silica ratio the viscosity was reduced by two mechanisms. First, rising sodium oxide content promoted cleavage of the Si-O bonds. Second, increasing boric oxide (B2O3) content increased the number of trigonal borate units that were converted to tetrahedral borate units by sodium oxide and copper oxide. The BO4(4-) tetrahedra decreased the local silicate symmetry, thus disrupting the silicate network and lowering the viscosity. The activation energy decreased with increasing temperature and increasing copper oxide content

Jun 13, 1905

By N. T. Moxon, D. Mead, S. B. Richardson

A laboratory and theoretical study of air decks was carried out to assess the effects of the size and location of air-decks on fragmentation. The degree of fragmentation was found to depend on both factors. As the size of the air-deck increases the degree of fragmentation is reduced relative to a full column charge. However, the reduction is relatively small until a critical size is exceeded. The critical size depends on the strength and structure of the surrounding material. A critical air-deck length of 30-35% of the original explosive column was determined for the model materials used in the study. A theoretical explanation of the results was derived based on pressure decay rate relationships. The location of the air-deck also influences fragmentation. The interaction and oscillation of the two shock fronts from the top and bottom charges mean that mid-column air-decks produce better fragmentation for the same air-deck length and explosive loading as top-column or bottom-column air-decks.

Jan 4, 1993

By W. J. Whiten, D. W. Grinsberg

Most cluster analysis techniques are not well suited to the analysis of engineering data as they have been designed for more qualitative data that tend to produce compact clusters. A clustering technique is described which develops and uses local cluster shapes to build clusters that are suitable for use in engineering applications. The technique is finding application in the analysis of many types of data, particularly where multiple trends and outlying points occur in multiple dimensions. Applications of particular interest are the calibration of on-stream analytical equipment and the analysis of data on plant performance. In both cases the multidimensional nature of the data renders manual analysis very difficult

Dec 1, 1991

By R. Patel, J. Ephraim

The production of titanium dioxide (TiO2) from its minerals such as ilmenite is challenging, and subsequent isolation of titanium from TiO2 is even more difficult because of the metal-oxygen bond strength. Currently, titanium sponge is mainly produced via the Kroll process, which is energy intensive and generates large quantities of waste. A number of international research groups have come up with technologies for the production of titanium metal. However, none of them have been commercialised, because of engineering or economic issues. The team at Bradford have confirmed that ultra-pure titanium powders can be separated from TiO2 powder through metallothermic reduction and are working to scale up the process.

May 1, 2015

By T. Sharma, T. C. Rao

Laboratory studies have been carried out on acid leaching as a possible route for the extraction of potassium from glauconitic sandstone. Leaching efficiencies with sulphuric, hydrochloric and nitric acids were investigated. The effects on potassium dissolution of temperature, concentration and type of acid, stirring speed and leaching time were also studied. The results show that it is possible to recover 87.5, 93 and 85% potassium with 5 M H2SO4, HCl and HNO3, respectively. During the initial stages of the sulphuric acid leaching process the chemical reaction at the mineral surface is the rate determining step, whereas during the later stages diffusion through the product layer is rate-controlling. Overall, the process follows a mixed-control model that includes both chemical reaction and diffusion. The activation energy for the dissolution of K was found to be in the range 25.79-106 kJ/mol.

Jan 12, 1992

By H. L. Shergold, O. Mellgren

The conditions of amine concentration and pH necessary for the concentration of fine haematite particles at the iso-octane-water interface have been determined. Results obtained from the related studies on the effect of pH and dodecylamine concentration on the adsorption density, electrokinetic potential, contact angle and concentration of various amine species in the system are included. A good correlation was obtained between these different variables. Maximum concentration of haematite at the oil-water interface was obtained when the haematite zeta-potential was small or equal to zero

Dec 1, 1971

By A. W. Fletcher

Report of discussion at February, 1971, IMM general meeting (Chairman: M. J, Cahalan President) of a paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, December, 1970, pp. C247-52, and contributed remarks. Contributions are included from: Cahalan M.J., giving figures related to leaching Cu from pyrite at Rio Tinto 1880-1910; Noakes F.D.L.; Embling P.M.K.; Bradshaw A.V.; Le Roux N.W.; Kelly D.P.; and Tuovinen O.H. Questions were raised regarding impurity removal, effects of light and ultraviolet light on the bacteria, the economics of solvent extraction and the possibilities for other organisms or other metals

Dec 1, 1971

By R. N. Pryor, S. H. Shaw, D. L. Dowie, S. H. U. Bowie, M. J. Cahalan, S. F. Gandar

It is concluded that land-based mineral resources will be adequate for most minerals in the immediate future, but in the long term more minerals will come from offshore locations. Because the oceans are international and can transport pollution, international control of offshore workings will be necessary. In the UK and similarly highly developed areas, the working of low-value bulk minerals will create increasing problems in urban development and countryside preservation. Much more information should be published on standards to be adopted and their costs, if emotional social pressures founded on ignorance are to be avoided. The Town and Country Planning Acts have greatly improved the environmental quality in Britain in relation to mineral working. In the long term conservation of some minerals in short supply may be necessary on a national or international basis. Much research is required for the determination of adequate criteria and standards for the preservation of environmental quality in the mineral industry. New local, national and international legislation will be required and the adoption of voluntary standards by trade associations should be encouraged wherever appropriate

Dec 1, 1971

Summary of the morning's events with a Written Contribution to Paper No. 4 and author responses

Jan 1, 1947

By R. G. Jones

Chris Hinde talks us through his career from BSc in Mining Engineering to roles with Golder Associates, Schroder Securities, Mining Journal and SNL. He discusses the issues facing the mining industry.

May 1, 2015

By D G. Jefferies

This paper covers National Grid's role in the electricity market, the growth of competition in both generation and supply in that market, and the resulting impact on fuel usage, prices and the environment. It also considers other, external influencing factors on the electricity supply industry, as well as the growing trend towards globalization.

Jan 12, 1997