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By L. J. Barnes

The process for bio-remediation of sulphidic slag (BROSS) operates at 45 degrees C in a neutral (pH 7), aerobic aqueous environment in which sulphide in the slag is converted to sulphate. A two-stage version has been developed that involves quantitative chemical pre-oxidation of total sulphide to thiosulphate, followed by complete biooxidation of thiosulphate to sulphate. Ferric hydroxide, also produced, acts as a flocculant in the bioreactor effluent, concentrating heavy metal precipitates in the thickener as a sludge which can be returned to the smelter. The process has a high sulphate production rate and low acid and nutrient consumptions. Microorganism growth is the rate-limiting stage, requiring a minimum liquid residence time in the bioreactor of about 7 h. Although large quantities of oxygen are needed, sufficient gas mass transfer can be attained in an air-lift reactor. Products are an aqueous stream containing sodium sulphate with only trace levels of toxic heavy metals and a benign, toxic metal-containing sludge

Jun 18, 1905

By Fearnsides W. G.

The second part of the paper, presented at the Midland Institute of Mining, Civil and Mechanical Engineers' general meeting held in Doncaster on 27th May 1916, addresses the post-Carboniferous and pre-Permian movements which brought about the partition of the area and gave to the North Midland district its individuality as a separate coalfield. As earth-movements of several ages subsequent to the Carboniferous have played a part in the formation of this particular coalfield, the aim is to elucidate the effects which belong to the post-Carboniferous and pre-Permian Period and to disentangle them from those of later date. This is done by comparing the geometry of the folded surface of one of the more important horizons in the Coal-Measures with that of the surface of unconformity which divides the Permian from the Carboniferous rocks in South Yorkshire, Derbyshire, and Nottinghamshire

Dec 1, 1916

By D. M. Milne, P. J. Lunder, R. C. Pakalnis

During the mining of an open stope, deformation of the hanging-wall and the potential for dilution generally increase with the size of the exposed hanging-wall. Excluding discrete structures that may delineate unstable blocks, the mechanisms that drive hanging-wall deformation and possible dilution comprise several factors which can include elastic, plastic and discontinuum deformation. These stages of deformation are not mutually exclusive and at any point during mining all three of these mechanisms may be acting on the hanging-wall rock mass. Computer modelling techniques are available to analyse the three stages of deformation, but the difficulty lies in trying to obtain realistic rock mass properties for input and in determining when each stage of deformation is acting. Instrumentation data can be used to predict the effect of continued mining. However, it is often difficult to calibrate numerical models against field data owing to the large number of input parameters required. An empirical approach is recommended that uses two new parameters, the radius factor and the effective radius factor. A method is proposed for predicting the effect of continued mining from existing deformation and dilution data for a given hanging-wall

Apr 1, 1996

By R. Poulin, C. F. Gleeson

The Birimian rocks of the region are gold-bearing and show many similarities to those of Burkina Faso. All three greenstone belts (Goroual, Tera and Sirba) host gold-bearing quartz veins. It appears that, contrary to previous misconceptions, lateritic terrain is not an unfavourable environment for exploration geochemistry. This is demonstrated by the results for the Koma Bangou area, where soil and termite-mound geochemistry have been successfully used in the search for gold. Soil provides an effective sampling medium where it is shallower than about 2 m; there is evidence that some soil anomalies are enhanced by the presence of secondary (botryoidal) gold. In areas of thicker, allochthonous soil cover, termite-mound sampling is more effective. At Koma Bangou an identified resource of some 11 100 000 tonnes with an average gold grade of 2.44 g/t has been reported. The gold mineralisation occurs in quartz veins and stockworks aand in the wallrocks of shear and fault zones that trend N, NW and NE. The host rocks are a granodiorite-syenite porphyry and intermediate metavolcanic rocks and tuffs

Apr 1, 1996

By G. D. Schena, M Zanin

A numerical approach is presented for predicting the liberation of phases during comminution, with direct calculation of a liberation spectrum giving the fraction of the particulate system in each narrow size-composition class. The numerical model uses a Poisson flat process for stochastic generation of the non-convex three-dimensional Poisson polyhedral textures and the system of fractures that give rise to convex fragments. With this numerical approach, there is no need to assume random uniform isotopic fracture (lack of selective liberation); only computational geometry primitives are exploited for the derivation. The agreement with relationships obtained previously under the random uniform isotopic fracture hypothesis demonstrates that the approach is capable of deriving full liberation spectra directly. Both volumetric and superficial composition can be calculated

Jun 21, 1905

By B. S. Terry, C. L. Harris

After measuring the kinetics of Ni reduction from a SiO2-saturated fayalite slag into a Cu-based metallic phase on a laboratory scale, a general model was developed that is capable of simulating mass transfer to and from metal-slag, slag-gas and metal-gas interfaces for multiple species. The model was used to simulate the reactions that occur when Cu and Ni are reduced from fayalite-based slags into a Cu-based metallic phase. Good agreement was achieved between model predictions and experimental data

Aug 1, 1995

By D. C. Bailey, D. I. Hodson

Paper presented at the annual joint meeting of the IMM and IMinE held in Harrogate, 31 January 1991. The Neves-Corvo copper-tin mine is the highest-grade large-tonnage copper operation in the world and is now arguably the most significant producing base-metal mine in Europe, rating in the top ten world producers of both copper and tin. A description is given of the initial exploration work and the development of the project from the orebody discovery in the Iberian Pyrite Belt of southern Portugal in 1977 to full operating capacity in 1990. The chronological account includes discussion of the main organisational, financial, technical and environmental decisions and of the various difficulties encountered, and the challenges of the future are identified. The project was brought in on schedule and within budget

Jan 1, 1991

By H. Forster, F. H. Koenemann, U. Knittel

The greenstone belt developed along the Sandawana line, an anastomosing, transcrustal shear zone. The lode gold is concentrated in veins and along brittle-ductile shear zones and other faults. Gold contents of 200 rock samples were found to be well below economically significant levels, excluding purely syngenetic deposit formation. Average gold content of unmineralised banded iron formation decreases from 7.3 ppb in the east (Manica) to 1.6 ppb in the west (Odzi), where depletion reflects hydrothermal leaching. The mineralising fluids may have been generated during deep crustal deformation, metamorphism and magmatism. Gold was hydrothermally deposited during carbonatisation and sericitisation of ultramafic and mafic rocks and during hydrothermal overprinting of banded iron formation and felsic rocks. It is present in native form and as microscopic to submicroscopic inclusions in pyrite, arsenopyrite and pyrrhotite. Argentiferous galena and other sulphides are commonly observed. Rezende, which produced over 38 t Au, is hosted by a granodiorite stock. By-product gold was produced from Cu-Ni sulphides at Mundonguara. The deposits are related to the older, but not the younger, of the granitoids intruding the belt's supracrustal sequences; the estimated age of mineralisation is 2700-2600 Ma. Odzi district, with 61 mines, has produced only 3.5 t Au as its higher-level host rocks have apparently been eroded. Mutare (formerly Umtali) district, with 133 mines and 9 placers, has produced 68 t Au (65 t from Rezende and adjacent deposits), and Manica district, with 23 mines and 8 placers, 12 t Au. Estimated reserves for the Rezende area are 20 t Au and for Manica district 4 t lode Au and 19 t placer Au

Apr 1, 1996

By M. Lombardero, J. Garcia-Guinea, J. Taboada, B. W. Roberts

The structural, textural and mineralogical properties of the slate formations of NW Spain make it the most important district in the world for quarrying roofing slates. Over the past 10 years the introduction of new methods has increased yields from 2 to 13%. The main factors affecting quality are quartz grain size less than 75 micrometres, homogeneity of slaty cleavage and S0-S1 intersection angle, very low metamorphic grade, absence of secondary foliation, beds 10-12 m thick and low content of oxidisable Fe sulphides. The two main controls on fissility are lithology and deformation accompanied by metamorphism. The minimum natural block size should be 0.6 m3 but this volume can be reduced for modern cutting tools such as diamond wire, chain and circular saws. Structural analysis is crucial in exploration and quarrying, as shown by the prospecting methodology applied at Dominio de Truchas in central Spain and the computer analysis of rock mass discontinuities at Casaio quarry

Jun 19, 1905

By P. H. Morris

The exponential delta profile equation matches the profiles of a wide range of coal and metalliferous subaerial tailings deltas well, but the original model implies unrepresentatively low solids concentrations. A revision, based on analysis of the governing equations of mobile bed flows with high concentration values, has shown that for exponential delta profiles to form there must be quasi-steady, slowly varying flow and slow deposition as well as tailings with a log-uniform sorting-parameter distribution. Deposition on tailings deltas is slow and the flow in many natural streams and, by analogy, tailings deltas is quasi-steady and slowly varying; the assumption of such flow is justified by the strong congruence of the revised model and the available data. The predictions of the theoretical model are essentially unchanged but concentration and flow Froude number are now not explicitly limited

Jun 19, 1905

By E. O. Afreh, R. J. Bowell, E. Hanssen, D. Pohl, S. Abe, R. K. Yao, N. d'A. Laffoley

In the largely preserved laterite profiles at Syama mine, in the savanna region of southern Mali, element geochemistry in the mottled-clay horizon and below can be related directly back to the protolith, but above this, in the ferricrete and cuirasse horizons, the hypogene signature is much modified by pedogenic processes. In tropical rainforest terrains extensive remobilisation can result in wide but weak geochemical targets for gold and pathfinder elements. At the Hire concession in central Ivory Coast, intense recent alteration of the largely intact laterite sequences has modified soil-geochemical dispersion patterns extensively, producing Fe-rich nodular stone lines and obliterating previous patterns and features. Where the upper horizons of the laterite profile have been removed or reworked, as at the Senoufo concession in northern Ivory Coast (savanna) or the Kubi prospect in Ghana (rainforest), all soil horizons can be related directly to hypogene geochemistry. In these truncated profiles, gold and base metal anomalies are essentially those of the lower weathering profile and form narrow but strong dispersion haloes. A good understanding of the geochemical processes active in deeply weathered profiles is required if targets are to be recognised effectively

Apr 1, 1996

By W. R. Paterson, W. Morton, D. B. Cameron

The Massbal II computer simulation program has been used to develop a general framework for the building of thermochemical models of metallurgical processes. The framework allows the rapid, simple construction of complex models of process equipment for use in flowsheet design, planning and plant operation. Application of the program to model the iron-making blast furnace and a flash smelting process is described

Apr 1, 1991

By R. A. Halatchev

A risk model for assessment of the uncertainty in the forecasts of the planned profit is developed. It is based on the selling price of the metal recovered from the ore and the production per shift of the excavators. These two critical variables characterise the economic and technical aspects of the mining venture. Time-series methodology is used to describe the behaviour of the economic variable, which improves the adequacy of the modelling. A hypothetical open-pit gold mine is used to illustrate the application of the model. Results obtained show that the model is a good alternative to sensitivity analysis in taking account of the stochastic character of the price of the metal recovered from the excavated ore and the production per shift of the excavators used. The model can be extended by the inclusion of new variables that have a probabilistic nature

Dec 1, 1996

By K. C. Misra, W. Wrightson Jr.

The Lick Fork prospect shows appreciable nickel sulphide mineralization in a narrow, steeply dipping, layered sequence of metamorphosed hornblende peridotite, gahhro and hornblende gahhro, intrusive into the Pedlar Formation (charnockitic pyroxene granulite) of the Virginia Blue Ridge Complex (Precambrian). Rocks of the intrusion have equilibrated to granulite- facies metamorphism, as indicated by pervasive polygonal texture of silicate aggregates, development of biotite- and hornblende-preferred orientation, compositional equilibration of the silicate minerals, the Mg-Fe2+ (orthopyroxene-dino- pvroxene) distribution coefficients (average 0.57), (MgO + FeO + Fe20 3)/Al20 3ratios in orthopyroxenes, and Ti contents and AI(i\)/A I(\i) ratios of hornblendes. The sulphides, consisting of pyrrhotite-pentlandite (with up to 4 wt% Co)-chalcopyrite-pyrite-marcasite-violarite- bornite—mackinawite, are virtually restricted to the ultramafic unit of the intrusion and constitute 20-30% of the samples of hornblende peridotite studied. Although the basal accumulation of the sulphides may suggest magmatic segregation, sulphide- silicate textures typical of sulphide liquid immiscibilitv are not present, even in the sparsely mineralized gahbro units. On the other hand, the transgressive and relict textures are strongly suggestive of replacement of the silicate minerals by sulphides. These include chaleopyrite ± pyrrhotite ± pentlandite (violarite) ± pyrite ±magnetite veins crosscutting silicates, sulphide penetration into silicates at silicate-sulphide contact zones, rounding of silicate grains against sulphide matrix, and islands of silicate minerals (olivine, hornblende, pyroxene, biotite) in sulphide masses. Metamorphic mobilization of pre-existing sul­ phides is a possibility, but involvement of post-metamorphic, hydrothermal fluids is suggested by the following features: paucity of annealing and deformation textures in the sulphides, replacement of metamorphic and deformed silicates, lack of differential sulphide mobilization and the common occurrence of sulphides along grain boundaries and triple junctions of poly gonal silicate aggregates. The consistent association between sulphides and hydrothermal alteration products of silicates suggests that they are cogenetic. The hydrothermal fluids may have merely mobilized and concentrated the pre-existing, disseminated, magmatic sulphides, or there may have been significant addition of sulphides during this process. This question cannot be resolved unequivocally with the existing data.

Jan 1, 1984

By J. A. Every-Brown

Case studies are presented of three derelict sites in Kent and Essex that provide a good cross-section of opportunities for second-generation commercial uses of former chalk, limestone, clay and gravel workings. A 240 ha abandoned chalk quarry at Grays in Essex, now known as Chafford Hundred, is undergoing mixed development to include leisure facilities, a range of housing and commercial areas and an enhanced environment. The 120 ha of Stone Marshes now comprises the Crossways business park and the Dartford international ferry terminal. Reclamation and servicing required more work than had been anticipated and the fact that the area was within the green belt added to the delays, but Blue Circle was eventually able to provide a comprehensive development of the entire area to a high environmental standard. Stone Pit 1 landfill, at Dartford in Kent, is a former chalk quarry 40 ha in area and with an original average depth of 35 m. Landfilling commenced in 1976 and during the period 1979-1984 the site operator designed, developed and installed a gas collection and flaring system. From 1986 a gas plant supplied up to 5 000 000 therm/yr of landfill gas to a local cement works and in 1989 a 1 MW power generation scheme, later expanded to 3 MW, was commissioned. Gas is currently also supplied to a metal refining company for use in internal combustion engines

Aug 1, 1994

By J. A. Hudson, X. D. Pan

A rock mass responds to excavation according to the properties of the intact rock, the network of contained discontinuities and the susceptibility of the rock mass to weathering. Large deformation often occurs when one of these components causes the rock mass to have a low strength relative to the stress conditions. Analysis of such large deformations forms a significant feature of current numerical modelling in rock mechanics. A practical large deformation problem of roadways in a coal mine is described, demonstrating the requirements for improving numerical techniques. The development of a numerical model is then summarised with particular attention to several concepts pertinent to large deformation analysis in geomechanics. A numerical case study is presented in which the developed finite-element model is used and the results are compared with the in-situ measurements. Conclusions are drawn for rock engineering that are also relevant to both civil engineering and mining engineering projects

Sep 1, 1991

By S. Kelebek

DETA exhibits a highly selective depressant action on pyrrhotite without adversely affecting the collectorless flotability of pentlandite and chalcopyrite in nickel-copper ores of the Sudbury region. A simplified Eh-pH diagram has been constructed to illustrate the extended stability of elemental sulphur and to explain the collectorless flotation of pentlandite and chalcopyrite. Cu and Ni ions, which are known to exist on the surface of pyrrhotite, promote the flotation of this mineral whether a collector is present or not. Thermodynamic calculations indicate that the action of DETA involves the sequestration of Cu and Ni ions from surfaces under a wide range of redox conditions; analysis of flotation test filtrate indicates as much as a 20-fold increase in the concentration of Ni and Cu ions. It appears that DETA may enhance the self-hydrophobicity of chalcopyrite and pentlandite by exposing more of the sulphur-rich surface sites for bubble contact in flotation. There are various possible explanations for its depression of pyrrhotite

Jun 18, 1905

By G. J. Hearn

between particles in the classifying region is then

Apr 1, 1995

By J. D. T. Capocchi, M. B. Mourao

The rate of reaction between iron oxides and carbonaceous materials, agglomerated as pellets, was studied experimentally by measuring the weight loss as a function of time. The effects of temperature, carbon type, inert gas flow rate, pellet size and additions (sodium. carbonate and Portland cement) were determined. It was shown that the value of the apparent activation energy can display large deviations under different experimental conditions; in the present work it was found to be 226.6 kJ/mol. The reaction with coke is slower than with charcoal, and the rate increases as the flow of inert gas in the reaction vessel decreases. Comparison of the rates for pellets of different sizes has shown that for small pellets the initial rate is faster but that it slows down at high conversions owing to the penetration of inert gas into the pellet. Additions of sodium carbonate and Portland cement increase the rate; sodium. carbonate promotes the catalysis of the Boudouard reaction, which is the slowest of the partial reactions. The increase in the rate with Portland cement is attributed to the release of water vapour

Jun 18, 1905

By B. M. England, C. Y. Yang, L. T. Matthews, J. Y. Yin

The domestic concentrate used by the Shanghai Meishan Metallurgical Corporation in Nanjing contains significant siderite, magnetite and haematite, the siderite having a substantial influence on its sintering behaviour. On the basis of experimental findings and published information it is proposed that siderite decomposition starts at c.400 degrees C and results in the formation of CO and/or H2, which then reduces the haematite to magnetite prior to the initiation of high-temperature sintering; inter-mixed particles of Australian haematite and pisolite ores also undergo significant reduction. As the gaseous reduction process is so effective, low-temperature forms of silico-ferrite of Ca and Al (SFCA) cannot form even at high sinter basicity. The bench-scale results were confirmed in a pilot-scale facility whose sinters consisted mainly of magnetite, high-temperature SFCA and glass, which is typical of sinters formed from mixes with high magnetite levels

Aug 1, 1995