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The value creation with kaolin clays depends on removing the colored impurities which manifests in to higher brightnessone of the most sought after properties on applications such as paper coating, paint and others. The processes for removing impurities include magnetic separation, froth flotation and selective flocculation. While the flotation and selective flocculation processes exploit the physico-chemical differences between the surface properties, the magnetic separation uses the bulk magnetic susceptibility differences between the diamagnetic clay and ferro- and para-magnetic nature of the impurities. The major advantage with magnetic separation remains high yield and no or low reagent usage. However, the magnetic separation technology suffers from low separation efficacy when finer colored impurities (<1 µm) are encountered in the feed. Use of stronger magnetic intensities during magnetic separation showed limited success; nonetheless the adverse effect due to finer size range remains a dominant effect even at 5 Tesla magnetic field. Furthermore, the presence of diamagnetic colored impurities irrespective of their sizes can not be removed. Cytec Industries has recently developed a ?bolt-on? chemical enhancement technology for magnetic separation that essentially embraces the best product performance attributes of flotation and selective flocculation while keeping the chemical usage to a minimum level and using the readily available magnetic separation equipment. The paper will outline the technology and illustrate optimization work at pilot plant magnet on a wide variety of crude accommodating the process needs and plant limitations. The major advantages of chemical enhancement technology to magnetic separation include: 1) simple extension to existing magnetic separation technology, 2) ability to produce comparable product in quality with cost effectiveness compared to flotation and selective flocculation, 3) removal of impurity minerals over wide size range, 4) removing non-magnetic impurities, 5) providing robust process with high process yield and 6) operation-friendly nature. Furthermore, chemical enhancement technology for magnetic separation has also emerged as a platform for re-moving impurities at low levels in other mineral systems as well.

Jan 1, 2014

By Kaustubh Joshi, Pradip, Beena Rai, Kesri L. Menaria, Venugopal Tammishetti

"Beneficiation of alumina rich iron ore slimes is a major challenge for the Indian iron ore industry. High alumina is deleterious for the performance of both blast furnace as well as sintering plants. Slimes generally contain 5 - 10% alumina, and hence despite assaying as high as 60% Fe, those are dumped in tailing ponds. The slimes are typically less than 37 microns. Selective flocculation of iron ore slimes using highly selective reagents is thus an option worth exploring. Our research is directed at employing state-of-the-art molecular modeling techniques for the selection/design of selective reagents for this separation. We have earlier reported our results on starch as a selective flocculant for iron ore slimes. In this paper, we present our results on the selective dispersion-flocculation of natural iron ore slimes using guar gum flocculant. With careful selection of various process parameters such as flocculant dosage, dispersant dosage, pH and settling time, we were able to obtain a concentrate assaying >66% Fe and <3.5% Al2O3 with an yield of 65 to 68% (recovery of iron values more than 70%) from a natural iron ore slime sample assaying 58% Fe and 7% Al2O3."

Jan 1, 2014

By Carlos Gualdron, Elizabeth Gomez, Rafael Bolivar

The productivity index of the Coopracarcegua Ltda., a mid-size coal mining company of Norte de Santander, Colombia, was related absenteeism using accident, productivity and profit data four years. The analysis was based on type, severity and frequency of accidents, number of absentee days; price per metric ton, and other relevant parameters. The enterprise is formed by 5 different mines of thermic coal, each one with different exploitation technologies and different productivity. Each mine was analysed separately and the loss of profit due to absenteeism was calculate for each one. The study showed that the foregone earnings due to absenteeism in terms of the whole productivity of the enterprise was about of 6.6% of the total profit average the 4 years, with calculated values of 14.7%, 3.5%, 8.4% and 4% per year in the evaluated period. The study identified that the most important cause of absenteeism was "General Disease". The foregone earnings in 2009, the highest loss for the analysed period, was about US$ 0.937 million and during the whole evaluated period was US$ 2.46 million.

Jan 1, 2014

By Liang Dianyin

In this paper, the molybdenite flotation tailing of cleaner-scavenger bank which has a mass of very fine particles has been taken as raw ore to be processed by flotation with/without ultrasonic. The effect of ultrasonic frequency, intensity, processing time and uploading location on molybdenite flotation efficiency is investigated by four-factor three-level orthogonal experiment, and the effect significances of these ultrasonic variables to molybdenite flotation efficiency have also been evaluated. Single-factor analysis of variance is conducted to investigate whether the effect of ultrasonic on molybdenum ore flotation efficiency is significant or not. The samples extracted from different ore species in different time have been mixed to analyze the particle size. The results show that the particle size of +38µm in concentrate obviously increases while the particle size of -25µmobviouslydecreaseswith ultrasonic, which means that ultrasonic is good for flotation due to sludge removing effect. Keywords: ultrasonic, flotation efficiency, sulfide ore, tailing, grade, sludge removing

Sep 1, 2012

By P. Spolaore

In the frame of Bioshale FP6 project, the bioprocessing of a polymetallic and polymineral concentrate produced in an industrial operation in Lubin, Poland, was assessed. Following successful batch culture tests, processing in continuous conditions was tested to determine the main specifications for the application of the stirred-tank technology to this sulphide concentrate from black shale ores. The experimental work was carried out in a laboratory-scale unit consisting of 3 stirred tanks (50L or 20L) using an acidophilic and moderate thermophilic bacterial population. Different configurations of the unit and key operating parameters were tested (nutrient medium composition, solids concentration, rates of agitation and aeration). Scientific and technical approaches, such as bacterial community structure and mineralogical analysis were implemented in order to better understand the chemical and biochemical reactions occurring in the system. Using the data produced during the continuous operation, downstream processing assessment for both copper and silver recovery was also carried out. The best copper recovery obtained in the continuous operation was 92% and a hot brine leaching of the bioleach residue (PLINT process) allowed to recover 92% of the silver. A preliminary tech-no-economic evaluation of Lubin concentrate bioprocessing including bioleaching, copper and silver recoveries demonstrated the potential economic feasibility. Recovery of silver plays an important role in the economy of the process. This study presents promising values to further investigate this bioprocessing option.

Jan 1, 2014

By A. N. Zagorodnyaya, Ye. G. Bochevskaya, E. A. Sargelova, Z. S. Abisheva, A. S. Sharipova

"In Kazakhstan, there is a unique sulphide copper deposit, in the ores containing the natural isotope of osmium-187 (more than 90 %). In the pyrometallurgical processing of concentrates for the target metal, osmium is mainly sublimated, with wet cleaning of metallurgical gases (dust and gas mixture) 40 % of it together with rhenium passes into washing solutions (wash acid). On the basis of this acid, the production of ammonium perrhenate was organized at the enterprise of the RSE ""Zhezkazganredmet"" and for the first time in the world practice - the isotope of osmium-187. However, the degree of its recovery from solutions does not exceed 8 % of the amount supplied with the charge or 25 % of the amount that was received for extraction. But the bulk of it (~ 75 %) remains in the raffinate, discharged to sewage treatment plants (wastewater). The studies presented in this work are aimed at solving the problem of osmium isotope-187 extracting from wastewater, which are a potential source of increasing metal production in Kazakhstan. The aim of this work is the development and scientific justification of osmium deposition regimes from wastewater using such reagents as thiosulfate and sodium sulphide. The influence of various physicochemical factors on the precipitation of the osmium was studied and optimal conditions for its maximum transition to sediment were chosen. An original method for obtaining osmium concentrate in the presence of sodium thiosulfate with the addition of potassium iodide from a new type of wastewater - man-made ammonia solutions has been developed. These solutions were combined mother liquors of solid-phase stripping operations and dissolution of pulp of crude ammonium perrhenate. On the basis of the obtained results, a settling technology for extraction of the osmium from man-made ammonia rhenium-containing solutions was introduced at RSE ""Zhezkazganredmet"". It should be noted that the degree of extraction of osmium, depending on its concentration in solutions entering on the settlement, and taking into account the addition of sulfuric acid, will vary from 60 to 90 %. The recovery of osmium during the test period was 58 %."

Jan 1, 2018

By A. L. Hinde

The steady-state and dynamic behaviour of semi-autogenous grinding (SAG) mills are arguably best described using a population model that caters for the breakage kinetics and the material trans-port of rock and pulp inside the mill. Breakage kinetics are usually expressed in terms of a specific breakage rate function and a separate primary breakage distribution function. Material transport usually invokes the concept of a specific discharge rate function. Unfortunately, the breakage rate and breakage distribution functions for SAG mills are very difficult to estimate uniquely from plant data alone. Simplifying assumptions must be made to over-come this problem, which leads to many unresolved dilemmas with regard to whether or not the de-rived functions are accurate, precise, and reflect reality. For example, it is sometimes assumed that the breakage distribution function for a SAG mill treating run-of-mine ore can be derived from laboratory dropweight and tumbling tests on small rocks in narrow size ranges. Such tests hardly reflect the environmental conditions likely to be encountered in a pilot or production SAG mill where there is a wide spectrum of particle sizes. It is shown that the dilemmas associated with standard population balance models (models that utilise separate breakage rate and breakage distribution functions) can be overcome by expressing breakage behaviour inside a SAG mill in terms of a single function. This function is an energy-based cumulative breakage rate function defined as the fractional rate at which particles and rocks coarser than a given size break to below that size per unit specific energy input. A model for SAG milling is formulated, which invokes the concept of a cumulative breakage rate function. Comparisons are made between the mathematical structure of this ?simple model? and standard population balance models. Perhaps the most attractive feature of the ?simple model? is that the cumulative breakage rate function can be uniquely estimated from measurements of size distributions and mass flows of the feed and discharge streams together with the size distribution and holdup mass of the mill charge. Such measurement can easily be made at pilot scale. It is concluded that this simplified approach to SAG milling may turn out to be the quickest way to fully describe and quantify the performance of these very complex mills.

Jan 1, 2014

By V. K. Chandaliya

N-Methyl-2-pyrollidone (NMP) has already been proven a good solvent for extraction of coal. It is believed that organic components of coal are likely to be dissolved with the solvolytic power of NMP. During dissolution process, original coal also gets disintegrated and thus helps in further extraction. Coal extraction highly depends on temperature, coal to solvent ratio, N-Methyl-2-pyrollidone (NMP) to Ethylenediamine (EDA) ratio and the size of coal particles. The process has been established in the laboratory. There is no reference available beyond lab scale. In present study, we are running a bench scale plant with 40 kg/batch capacity. Design of experiment was done in such a way that the optimum zone of the process gets evaluated for clean coal having low ash with high yield. Bench scale plant trial was conducted based on optimum zone developed during design of experiments (DOE). From the DOE analysis it was observed that feed size and coal to solvent ratio are important parameters for this process. Total 27 experiments (four factors with 3 level of variation) were designed through Box-Behnken model. It was observed that -0.5 mm feed size of coal, 150 °C extraction temperature, 17:1 NMP to EDA ratio, 1:9 coal to solvent ratio was optimum conditions. The results obtained at optimum conditions are 50% clean coal yield with 5% ash.

Sep 1, 2012

By U. S. Chattopadhyay

The estimated requirement of the nation by the year 2020 is approx. 80 Mt of steel and more than 0.2 million MW installed capacity of the electricity, thereby increasing the consumption of the coking and non-coking coal, which is expected to be in tune of about 75 Mt & 500 Mt respectively. One of the major deleterious factors in achieving the goal is the deteriorating quality of the feed coal used in both steel and power industries. Indian coking coals, in general, are typified by high ash, high inert (both organic and inorganic), low rank, low reactive macerals content, heterogeneous petrographic make-up, inferior coking properties and poor amenability to washing, thereby necessitating suitable washing measure. Coke-based steel industries in India require washed coking coal containing ash % varying between 17-19. The situation demands taking on immediate challenges to fill up the gap between the requirements and supply of coking coal. This paper reviews the R&D attempts in this laboratory and throws light on the key measures as long-term solution to the problem. Search for alternative source of coking coal, like LVC coal and their judicious preparation technology. The low volatile coking coal (LVCC) constitutes about 50% of the total coking coal reserves in India. These coals are characterized by high raw coal ash content (37 to 40%) and very difficult washability potential. If these coals are treated in the existing washeries, which are generally 2 or 3-product systems, the cost of clean coal is high as the byproduct sale value is low. It has been proposed to produce a new type of by product, which enjoys high demand and good coking properties.

Sep 1, 2012

By S. Groudev

Acid drainage waters generated in the uranium deposit Curilo, Bulgaria, were treated by means of a pilot-scale passive system consisting of a permeable reactive multibarrier and a constructed wetland connected in a series. The multibarrier had a total volume of 23 m3 and consisted of an alkalizing limestone drain and an anoxic section for microbial dissimilatory sulphate reduction, bio-sorption and additional chemical neutralization. The waters had a pH in the range of about 2.5 ~ 4.0 and contained radionuclides (uranium, radium), heavy metals (copper, zinc, cadmium, lead, nickel, cobalt, iron, manganese), arsenic and sulphates in concentrations usually much higher than the relevant permissible levels for waters intended for use in agriculture and/or industry. The water flow rate through the multibarrier varied in the range of about 1 ~ 17 m3/24 h, reflecting water residence times of about 300 ~ 18 hours. An efficient removal of pollutants was achieved by the multibarrier during different climatic seasons, even during cold winter days at external air and water temperatures close to 0oC. The multibarrier effluents were enriched in dissolved organic compounds and in some cases still contained manganese and iron in concentrations higher than the relevant permissible levels. These pollutants were removed in the constructed wetland as a result of the activity of different heterotrophic microorganisms, including some bacteria able to oxidize the bivalent manganese and iron ions to Mn4+ and Fe3+, respectively.

Jan 1, 2014

By Olga D. Khmelnitskaya

The paper presents the results of research on the development of gold recovery technology from oxidized gold-copper ore of one of deposits in Russian Federation. Gold and copper grades in the ore are 9.5 g/t and 0.4%, respectively. Various options of flowsheets, such as direct cyanidation, thiourea leaching, flotation and gravity concentration followed by subsequent cyanidation of con-centration products, were tested. It was established that gravity-cyanidation technology with filtra-tion leaching tails and the use of solutions in the recirculation is the optimal option for ore treatment. The proposed flowsheet provides gold recovery for 91.0% at NaCN consumption 2.5 kg/t ac-cording to the results of pilot testing. Ammonia-cyanide gold leaching was also examined. In comparison with cyanidation, gold leaching solution in system NaCN-NH4OH-(NH4)2CO3 allows NaCN consumption to be reduced three times from 4.5 kg to 1.5 kg per 1 ton of the ore and provides the same gold recovery. Based on the laboratory and pilot plant tests results of gravity-cyanidation technology of gold dissolution, process design criteria were developed.

Jan 1, 2014

By Jacob Masliyah, Zhenghe Xu, Lujie Yan

"Understanding adsorption mechanism of polymeric organic process modifierssuch as carboxymethyl cellulose (CMC) on talc hasbeen a major challenge due to anisotropic nature of talc basal planes and edge surfaces. The main objective of this study is to investigate the adsorption of CMC on the basal planes and edge surfaces of talc.Smooth basal plane and edge surfaces of talc were prepared successfully by simple cleavage and sophisticated ultramicrotome cutting method, respectively. The prepared surfaces were characterized by atomic force microscope (AFM) imaging to be sufficiently smooth for colloidal probe force measurements using AFM. Anisotropic surface charge characteristics were determined,with the basal planes to carry a permanent negative surface charge and edge surfaces featuring a pH-dependent charge characteristic. The adsorption of CMC on talc basal plane and edge surfaces at pH 9 in KClaqueous solutions of various ionic strengths wasinvestigated by in situ AFM imaging technique. Themorphology of adsorbed CMC on talc basal planes and edge surfaces was found to be significantly different, due to different binding mechanisms involved. Interaction of CMC with the talc basal plane was found to bedominated by hydrophobic interactions while its binding with the talc edge surface was mainly through chemical complexation and hydrogen bond. The amount of CMC adsorbed on both talc basal planes and edge surfaces increased with increasing ionic strengthof solutions. The methodology developed in our study opens the door to probe polymer adsorption on anisotropic phyllosilicate surfaces, which can help us better understand the mechanism of polymer adsorption on specific mineral faces."

Jan 1, 2014

By X. Y. Zeng

Most Chinese titanium bearing minerals are the composition of magnetite vanadium and ilmenite. All of such mineral processing plants use low intensity magnetic separators to recover magnetite and vanadium goes with magnetite. In the past years most of the plant tails containing about 10% TiO2 were abandoned. Now many of these plants use SLon magnetic separators to recover ilmenite in the roughing stage, which can throw away most of the gangs and slimes with very low cost. The new development of applications of SLon magnetic separators in Chinese ilmenite processing industry is introduced in the paper.

Jan 1, 2014

Anglo American Platinum practices fine grinding in its processing plants to enhance the liberation of valuable minerals. If the fine particles of valuable minerals generated during fine grinding are not recovered during the flotation process, this could significantly contribute to the overall losses. This study examines the flotability of fine moncheite (PGE mineral) particles in a controlled environment (moncheite size distribution, concentration and liberation). A barren Norite ore ground to 40% and 80% passing 53µm was spiked, with four different size fractions of moncheite (-5, -10+5, -25+10 and -53+25µm) in order to evaluate the effect of particle size on flotation. The investigation also included the effect of energy input and collector dosage on the flotation of two moncheite size fractions, namely -5µm and -10+5µm. The results showed that the moncheite particle size has a significant impact on flotation. Coarse particles (-53+25µm) showed the highest Pt flotation kinetics and overall recoveries. The -5µm size fraction of moncheite could also be recovered by flotation, however, at a lower rate compared to the other size classes investigated. The increased collector dosage of 300g/t at the finer Norite grind of 80% passing 53µm enhanced the flotation rate of the -5µm size fraction of moncheite when compared to the lower collector dosage of 150g/t. The higher energy input during laboratory flotation, at an impeller speed of 1000rpm also increased the flotation rate of the -5µm size range, however, at a lower concentrate grade, when compared to the lower impeller speed of 700rpm. More favourable Pt flotation kinetics data was obtained for the -53 +25µm size fraction of moncheite at the fine Norite grind when compared to the coarse Norite grind. Keywords: flotation, moncheite, particle size, energy input and SIBX

Sep 1, 2012

By Eduard Stefanescu, James M. Mwase, Egon Sehner, Stoyan Gaydardzhiev

"The study is focused on investigating the production of synthetic rutile of 95% purity or higher from a Norwegian ilmenite ore concentrate. This was to be achieved using a sequential process involving oxidative-reductive roasting at 975°C, followed by magnetic separation to further concentrate the sample and finally leaching with 20% HCl to remove mostly Fe-based impurities leaving behind synthetic rutile. The key process parameters considered were roasting time (1 and 2 hrs), leaching temperature (100, 125 and 145°C), pulp density (15 and 25wt%) and leaching time (3 and 6 hrs). The option of directly leaching the concentrate without pre-treatment was also evaluated. Test work was conducted using samples screened to a size fraction of 105-212 µm. Samples were leached in a 1 L glass autoclave. The reactor was hermetically sealed and thus the resulting pressure was not controlled but was dependent on the process temperature. The product from leaching was calcined and analysed via XRD and SEM to determine the purity of the product. The magnetic separation step was found to be ineffective and discontinued early in the study. Thus far a product with 97% synthetic rutile purity as analysed by SEM has been produced by directly leaching the concentrate at a temperature of 145°C, pulp density of 25wt% and leaching time of 6 hrs.INTRODUCTION The study investigates the use of a process route comprising oxidative-reductive roasting, followed by magnetic separation and then hydrochloric acid leaching and calcination to produce synthetic rutile from ilmenite concentrate. The grade of synthetic rutile produced should be suitable for chlorination to produce pigment grade TiO2. Hence the proposed process should produce a product consisting of no less than 95% synthetic rutile. Additionally, the product should have no more than 1.5wt% combined content of CaO and MgO (Zhang et al., 2011) as they tend to form high-boiling-point chloride leading to the malfunctioning of fluidized bed chlorinator (Cardarelli, 2008). Finally the product should have no more than 2.1wt% of Fe2O3."

Jan 1, 2018

By A. I. Arol

Bentonite is an important industrial mineral with very wide application areas. Its unique colloidal, swelling, thickening and adsorption properties make it a useful agent in drilling, metal casting, and iron ore pelletizing, environmental, food, cosmetics, pharmaceuticals and many more industries. Because of its swelling property, bentonite suspensions can only be prepared at rather low solid coentrations, i.e. 8-10%. In order to process bentonite in slurries with high solid content, it was thought that a non-polar organic solvent, instead of water, can be used. Not only large amounts of bentonite can be dispersed in organic solvents but also the solvents may be regenerated. The bentonite obtained through such a process must either equal or better properties than those of untreated bentonite. In this study, the effect of organic solvents such as acetone, methyl-ethyl ketone and n-haxane on the main properties of bentonite, such as water adsorption and rheology, was investigated. It was found that bentonite can be dispersed in the mentioned organics in large quantities with no loss of quality. Keywords: bentonite, montmorillonite, water adsorption, industrial minerals

Sep 1, 2012

By Sudarshan Martins, Peter Radziszewski

"Tumbling mills are machine, operating in non-equilibrium, capable of applying forces on the ore contained within, causing the ore to break down. The action of the mill on the ore is very inefficient, producing a large quantity of heat. The inefficiencies of the mill drive the desire for improvement, spawning research and development activities. Given the non-equilibrium nature of the mill, the theory of Large Deviations is proposed as the framework that captures the state of the mill. The theory of Large Deviations allows for the determination of the rate function and the scaled cumulant generating function (SCGF), for systems in either equilibrium or non-equilibrium. Powerful connections can been made between familiar concepts of statistical physics and the concepts introduced by the theory of Large Deviations: entropy can be associated with the rate function; the scaled cumulant generating function with the free energy. It is shown that observables, compatible with Large Deviation theory, can be identified for the tumbling mill. Here, the time series of the energy associated with an element of the charge is such an observable. Furthermore, using some experimental data, it is shown that the time series of the energy can define a rate function, thereby describing the system within the Large Deviation framework. Finally, a discussion of the results is given, particularly how this theory can be further developed for tumbling mills."

Jan 1, 2014

By Pejman Oghazi

During the last decade the output of mining companies has increased rapidly. The key driver is the increase in demand for raw materials in the developing world, and thus this demand has driven up ore prices. From the time when the Raw material group (year 2000) started to introduced their index, it was set to 100 points. Today, year 2011, the index is over 400, which means that ore prices have quadrupled since then. Mine companies have to go deeper in the mines to access the ore bodies to increase the mine capacity and to be able to respond to the market. By going deeper in the mine, there will be new challenges that have to be considered. One of these challenges is how to handle the mine water that is produced in the mine. The water has to be moved to the surface in order to keep the mine from flooding, and this causes more challenges. One solution is to pump the mine water up to the surface without treatment; however, this causes considerable pump wear and the water will still require treatment on the mine?s surface. Another solution is to treat this water in the mine before pumping it to the surface. Metso Minerals has a system solution to treat the mine water, by separating the solids from the mine water. This system reduces the erosion in the pumps and will save many maintenance hours in the long term. One other option is to use the treated water in a closed circuit and reuse it in the process. This system can be divided into three steps: Firstly, a spiral dewaterer to remove the coarse solid particles. For the next step, lamella thickener is used to remove most of the solids, and lastly tube press to handle the sludge from the underflow lamella thickeners. Keywords: mine water, mineral processing, dewatering, separating

Sep 1, 2012

By Ghislain Bournival, Cagri Emer, Seher Ata

"It is well known among flotation practitioners that the contact angle can be correlated with the amount of material recovered from feed by flotation. The contact angle of solids can easily be modified by the addition of a collector. However, some collectors also have frothing properties thus altering the solid and bubble surface properties simultaneously. To avoid this problem, a technique has previously been used in which silanol groups are attached to the surfaces of the particles, but this method has its own problems. In this work, silica particles with various surface hydrophobicities were prepared using an esterification process. By using alcohols with different hydrocarbon chain lengths, from 4 to 12 carbon atoms, surfaces with a wide range of contact angles could be prepared. The technique was used in the modification of silica particles that were tested in a fluidized bed flotation column, and a laboratory mechanical flotation cell. In parallel experiments, dodecylamine (DDA) was used as a collector. It was found that irrespective of the type of flotation machine and surface preparation method, there was a close correspondence between flotation recovery and the contact angle of the particles. The silanation process has known drawbacks relating to the presence of moisture during the reaction, and the stability of the silane coating after it is been prepared. Esterification does not suffer from these disadvantages. This work has shown that the esterification technique is a robust alternative method for preparing hydrophobic quartz surfaces."

Jan 1, 2014

By J. Seo, W. Kim, I. Bae

"Microcrystalline silica impurities such as quartz and opal-CT commonly associated in bentonite should be controlled and removed as far as possible when bentonite is used as biocompatible raw material because they show sufficient evidence of carcinogenicity. Since opal-CT contained in bentonite in trace amounts cannot be well separated by conventional sedimentation method, in this work, the ultrasound-assisted removal of the impurity was attempted. Irradiating ultrasound into bentonite-water suspension promoted the production of fine montmorillonite particles in the suspension and the production markedly increased when montmorillonite was activated by Na2CO3. Subsequent centrifugation of the suspension made it possible to recover pure montmorillonite particles as an overflow product. Only 16.2 mass % of total solids was recovered as an overflow from the non-activated suspension, whereas 63.5 mass % was recovered from the activated suspension at centrifuging speed of 10000 rpm. Increasing sonicating time enhanced the yield of overflow, however, excessive sonication up to 10 min hindered the purification of montmorillonite. It was observed that the peak reflection of (101) plane of opal-CT in overflow increased as sonicating time increased during prolonged sonication. INTRODUCTION Bentonite consisting predominantly of mineral montmorillonite is clay-rich soft rock generated frequently from the alteration of volcanic ash. Depending on the nature of its genesis, bentonite contains a variety of accessory minerals, which may include mainly quartz, feldspar, opal cristobalite/tridymite (opal-CT), calcite, illite and mica. The presence of these accessory minerals can impact the industrial value of the deposit, reducing its commercial value depending on its applications. Therefore, bentonite is often purified by removing these impurity minerals for special applications where specific properties and characteristics are required (Murray, 1999). Among the special applications, bentonite is often used in the cosmetic and pharmaceutical industry as both excipient and active ingredient in the forms of liquid (suspensions, emulsions), semi-solid (creams, ointments) and solid (powder, capsules and tablets). The basic requirements for bentonite to be used as raw material are pure, microbiological and mineralogical inertness. Physical properties such as swelling volume and gel formation are also important. Particularly, microcrystalline silica polymorphs such as quartz, cristobalite and opal-CT should be controlled and removed as far as possible because they show sufficient evidence of carcinogenicity in humans."

Jan 1, 2018