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By Sanggono Adisasmito

"The quality of the higher education in Indonesia is being improved by implementing a program financed by the World Bank under a project named QUE (Quality for Undergraduate Education). The investments are provided to selected study programs through a competitive selection process. The grant finances staff development, the purchase of equipments, textbooks, consumables, technical assistance, and incentives for outstanding faculties such as teaching grants, project grants, lecture note awards, and educational policy studies. These additional investments are provided to produce chemical engineering graduates that will compete beyond the national market.Chemical Engineering Department of Institut Teknologi Bandung in Indonesia has been selected to receive the QUE grant beginning the year 2000 and ending the year 2004. The department is actively involved in the mineral processing issues, particularly in the aspects of energy supply and the environmental protection. The activities are distributed in different laboratories and areas of expertise, such as: thermodynamics and utility systems, process equipment, chemical reaction and catalysis, microbiology and bioprocess engineering, process control, ceramics, as well as polymer and membrane technology. The main objectives of the QUE project are to improve the undergraduate program in the following aspects: Relevance, Academic atmosphere, Institutional management and commitment, Sustainability, as well as Efficiency and productivity, or abbreviated as RAISE. At the end of every fiscal year, the progress of the program is evaluated to measure the effectiveness of the project.The achievement of the QUE project objectives were assessed using performance indicators developed during the program design. There are six indicators to measure the performance of the individual program of study, such as: (1) Admission Test score, (2) average students' Grade Point Average (GPA), (3) average graduates' length of study, (4) graduates' waiting time before getting first job, (5) Test of English as Foreign Language (TOEFL) score, (6) Graduate Record Examination (GRE) score. Essentially, the RAISE evaluation criteria will be used to perform three main functions, such as (1) to measure the achievement through the six quantitative performance indicators, (2) to support the progress of evaluation and reporting throughout the implementation of the program, (3) to provide a universal framework for qualitative evaluation."

Jan 1, 2003

By Tatyana A. Ivanova, Tamara N. Matveyeva, Anatoliy A. Fedorov, Tatyana V. Nedosekina, Valentin A. Chanturiya

"As native gold resources are depleted, gold-sulfide ores consisting essentially of pyrite, arsenopyrite, chalcopyrite and pyrrhotite become one of the major precious metal sources, being presently estimated to account for more than 40 % of total world gold reserves.The prime objective of flotation of gold-bearing sulfide minerals is to increase precious metal recovery and to reduce the product cost through achieving maximum selectivity of the separation process. Separation of Fe and As sulfides in selective flotation of gold-bearing ore products helps reduce the amount of ore mass being sent to hydrometallurgical processing, and permits of recovering gold from As-free gold-containing pyrite concentrate by using a lower-cost pyrometallurgical procedure.An ingenious methodology purposively developed by the authors for comprehensive assessment of flotation properties, electrophysical characteristics and crystal chemistry features of natural gold-bearing sulfide minerals of different origin has been used in this study.Comparison of the elemental composition, non-stoichiometry and flotation activity of different monomineralic pyrite varieties revealed that samples with negligible impurity content are nearly stoichiometric, and show similar flotation properties. Samples with high Cu, As and Au contents are highly non-stoichiometric and readily floatable, even in a highly alkaline environment. Samples with high surface sulfur content and the most defective crystal lattices, with iron atoms substituting for sulfide vacancies, are most sensitive to depressive action of the alkali.A correlation between the type of conductivity, impurity content and amount of xanthate compounds on the surface and in the liquid phase of monomineralic pyrite and arsenopyrite suspensions detected by the extractive spectrophotometric analysis has been identified and analyzed. Experiments showed that the proportion of cuprous xanthate in sorptive collector layers on sample surfaces increases with increasing Cu content of the samples. In general, pH for pH, overall xanthate sorption on pyrite is greater than on arsenopyrite, with the difference increasing in passing from an acid environment to an alkaline one. A significant decrease in xanthate sorption on arsenopyrite is observed at pH greater than 9, whereas sorption on pyrite markedly decreases at pH greater than 11."

Jan 1, 2003

By K. A. Natarajan

Involvement of various indigenous microorganisms in extracellular and intracellular iron oxide formation is a convincing index for iron ore biogenesis. Biomineralization of various iron oxides such as hematite, magnetite, goethite and limonite with the participation of aerobic and anaerobic microorganisms is well established. Various aerobic and anaerobic bacteria such as Gallionella, Leptothrix, Acidithiobacillus, Thermoplasmales, Pseudomonas, Bacillus spp and Shewanella putrefaciens, which are implicated in the formation of higher and lower oxides of iron have been isolated from different iron ore deposits. Diversity of microbial life in iron ore deposits can be put to beneficial use such as selective removal of undesirable constituents such as silica, alumina, clays, phosphorous and calcite and also to bring about environmental detoxification. Role of microorganisms such as Paenibacillus polymyxa, Bacillus subtilis, Yeasts and a sulfate reducing anaerobe in the biobeneficiation of hematite is illustrated. Surface chemical changes brought about by bacteria - iron ore mineral interactions are discussed with respect to hydrophobcity, adsorption isotherms, zeta potential data and bioreagents generation. Bacterial adaptation to minerals such as hematite, quartz, alumina, calcite, apatite and clays results in secretion of mineral ? specific biosurfactants such as proteins and polysaccharides. Such bioreagents can be used as selective collectors, dispersants and flocculants in iron ore beneficiation. Research results are highlighted to demonstrate silica, alumina, phosphate, calcite and clay removal from hematite. Environmental friendliness of such biobeneficiation processes is demonstrated with respect to biodegradation of toxic amine collectors, utility of ?in situ? organisms in enhancing settlement of fines in tailing dams and water harvesting. Keywords: bio-mineralization, bio-beneficiation, bio-remediation, Gallionella, Leptothrix

Sep 1, 2012

By Jussi Liipo, Pertti Lamberg

Image analysis of process samples gives precise data on particles and their composition. The results presented as liberation tables and maximum grade-recovery curves are informative and good for comparing different feed materials, but basing on them it is impossible to predict the results of the mineral separation process (flotation, magnetic separation, gravity separation) in details. The exact and extensive particle data has remained large unused, because there has not been a model nor a modeling program to include particle information in mineral separation processes. This study introduces a method, which incorporates the particle data in the kinetic model of flotation. Similar approach can be used in modeling other separation processes, too.

Jan 1, 2003

By Johan Nell, Paul den Hoed

"Carbochlorination tests were conducted with matched particle-size fractions of rutile, ilmenite and hightitania slag in a small bubbling fluidized-bed reactor. The effects of temperature, the type and proportion of solid reductant in the charge, and the fraction of Cl2 in the fluidizing gas were investigated. Tests confirm the need for solid carbon in the bed if chlorination is to run at high rates. With solid carbon in the bed, CO supplied with the fluidizing gas does not increase significantly the degree of chlorination after 75 minutes.When large proportions (30 wt%) of carbon are added to the charge, then the reactionTiO2 + 2C + 2Cl2 = TiCl4 + 2COis favoured overTiO2 + C + 2Cl2 = TiCl4 + CO2Ilmenite is chlorinated more quickly than titania slag, which in turn is chlorinated more quickly than rutile. Rates of chlorination at 1100°C and 1000°C are much the same and significantly higher than at 900°C. Chlorination is associated with significant increases in particle porosity (even for rutile), which is brought about by the rapid initial chlorination of FeO and MnO (in ilmenite and slag) and (it is argued) by the chlorination of Ti2O3 which forms at high-energy surface sites."

Jan 1, 2003

By Markus A. Reuter, Antoinette van Schaik

"INTRODUCTIONGoods and products, such as passenger vehicles, are manufactured by using a wide spectrum of different raw materials to meet highest consumer requirements during use. Due to the time-varying composition and complexity of multi-component products such as cars, recycling is complicated. It involves a network of interconnected processes and material and energy flows. Improving the efficiency of the material cycle of the car to comply with the recycling targets as imposed by EU legislation, requires insight into all aspects influencing the closing of the material cycle (dynamics, technology, economy, legislation, etc.) and their mutual relation. In order to define the link between recycling end-of-life products, their changing composition and design a dynamic model was developed for the resource cycle of cars. The model integrates the optimisation of the material cycle with the dynamic behaviour of recycling systems."

Jan 1, 2003

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisinger

"INTRODUCTIONThe objective of this work was to deport silver into a residue suitable for subsequent extraction without compromising the high base metal extraction during the pressure oxidation.RESULTS AND DISCUSSIONThe complex sulphide from the tailing pond of Cannington mine, Australia, was re-grounded and a bulk concentrate was recovered by flotation. The major economic sulphides are galena and sphalerite. The chemical analyses revealed 17.22% Fe; 4.88% Zn; 8.22% Pb; 9.49% S2- and 422 g/t Ag. The baseline cyanidation yielded 36.60% of silver at high cyanide consumption (24.17 kg/t NaCN). Pressure oxidation at 150°C (in the absence of iodide), followed by cyanidation of the residue yielded 8% silver extraction. Pressure oxidation was carried out at 110-150°C in sulphate media with additions of potassium iodide and the resulting residue was subjected to cyanidation. High recovery of silver was achieved because its incorporation into lead-hydronium jarosite during the pressure oxidation was minimised, while its deportment into the cyanide-soluble silver iodide was favoured (Figure 1). Silver recovery decreased slightly at high temperatures (140° and 150°C) because of the enhanced stability and kinetics of leadhydronium jarosite, but this could be overcome by increasing acidity and iodide concentration of the slurry."

Jan 1, 2003

By N. Ahmed

This paper is concerned with the drainage behaviour of gangue mineral in the froth phase. Experiments were carried out in a continuous laboratory flotation cell in which froth depth and bubble size could be changed independently. The fraction of solids returning from the froth to the pulp zone was expressed using a rate constant. A mixture of hydrophilic solids (silica) and floatable particles (glass ballotini) was used as a flotation feed. Samples of glass ballotini of different hydrophobicities were obtained, using controlled silanation. Three samples, with contact angles of 50, 66, 82 degrees, were used. The effect of the initial bubble size (pulp bubble size), concentration of gangue mineral in the froth zone, and froth depth on the drainage of silica, were investigated. The drainage rate of the entrained solids increases with an increase in the degree of hydrophobicity of the floatable particles. Concerning the effect of pulp bubble size on the drainage rate of entrained solids, larger bubbles always give higher drainage rates due to formation of relatively loose froth structures which allow gangue particles to easily move down to the pulp zone. Conversely, smaller bubbles exhibit lower drainage rate constants, in particular at shallow froth depths.

Jan 1, 2003

By Georg Unland, Thomas Wegner

"Impact crushers are widely used in different industries to crush materials which can vary from soft to hard and from ductile to brittle. However, the sizing of impact crushers is still based rather on empirical than on scientific approaches. Therefore, a test rotor was developed in order to investigate the principles of comminution by impact. Rocks of diabase with different diameters were used to gain the crushing properties with the following results:RESISTANCE AGAINST CRUSHINGLikelihood of BreakageThe likelihood of breakage is a function of the impact velocity and the particle diameter. The likelihood increases with higher velocities and larger diameters. Maximum Crushing ForceThe crushing force is related to the area of projection of the rock. The smaller the particles and the higher the velocities the larger are the maximum related contact forces.Contact TimeThe contact time increases with the rock diameter whereas the influence of the impact velocity is neglectable.Mass Specific Crushing WorkThe mass specific crushing work decreases with the particle diameter and increases with the impact velocity."

Jan 1, 2003

By Y. E. Brylyakov, M. A. Kostrova

"The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. In this connection, the magnitude of cation exchange, along with the content of P2O5 and CO2, is an important property of apatite staffelite ore, which largely determines the performance of concentration processes. In the examined ASO samples, the magnitude of cation exchange measured in terms of Ca2+ is 2546-4790 g/ton. The conducted laboratory studies of apatite staffelite ores with various mineral composition showed that adding calcined soda improves the recovery of P2O5 into the flotation concentrate. Full-scale tests were conducted at the apatite staffelite ore processing plant at Kovdor Mining and Concentration Operation and demonstrated the high performance of the proposed agent treatment. The test results showed that in the flotation of apatite staffelite ores, the optimum calcined soda feed rates range from 3,500 to 5,000 g/ton of the flotation feed. With close flotation feed and concentrate grade parameters, the P2O5 recovery gain is 17%. The effect of adding soda is associated with the desorption of the hardness cations from the minerals, precipitation in the pulp and, accordingly, improvement in the ionic composition of the liquid phase of the flotation feed due to a reduced content of calcium ions. Based on the test results, the proposed agent treatment with an elevated feed rate of calcined soda was implemented at Kovdor Mining and Concentration Operation in the flotation of apatite staffelite ore. The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. These minerals have certain properties requiring a more detailed examination for a better understanding of the flotation properties of apatite staffelite ores."

Jan 1, 2018

By Sashnee Raja, Mehdi Nemati, Ashley Sissing, Susan T. L. Harrison

"Extreme thermophiles, operating at 65 - 90°C, are finding increasing application in biohydrometallurgy. These micro-organisms have the advantage of exhibiting better oxidation kinetics in terms of reaction rate and extent of mineral solubilisation (Duarte et al., 1993; Norris and Barr, 1988; Konishi et al., 1995). These extreme thermophilic Archae, characterised by a different cell envelope structure (König and Stetter 1986, König 1988, Michel et al. 1980) perceived to provide reduced structural strength in comparison to bacterial envelopes, and customised metabolic pathwaysThe active tank bioleaching process, used for high rate leaching, is conducted in a slurry bioreactor. Here sufficient energy dissipation is required to ensure suspension of the mineral phase as well as to sustain high rates of gas liquid mass transfer. It is well known that subjection to hydrodynamic stress of sufficient magnitude may alter the physiological state of a range of micro-organisms through changed viability (ability of the microbes to grow), metabolic activity and integrity. While limited study on the influence of the solids phase on thermophilic leaching performance is reported, initial reports suggest that the thermophiles used for bio-oxidation appear to be sensitive to hydrodynamic conditions (Jordan et al 1993, Clark and Norris, 1996) and the presence of solids (Norris and Bar 1988, Le Roux and Wakerley, 1988, Escobar et al. 1993, Torres et al. 1995, Nemati and Harrison, 2000)."

Jan 1, 2003

By Paul W. Cleary

"Particle scale simulation of industrial particle flows using DEM (Discrete Element Method) offers the opportunity for better understanding the flow dynamics leading to improvements in equipment design and operation that can potentially lead to large increases in efficiency, throughput or product quality. DEM has been used for modelling many industrial applications, particularly milling. This includes ball and rock motions and power consumption in ball mills, AG and SAG mills, vibrational segregation, flows in rotating drums, operation of dragline excavators and hopper flows. In mineral processing, DEM has been concentrated on mills because of their critical importance. However DEM also offers the opportunity to improve many other parts of mineral processing operations. These areas often do not receive the attention that the key comminution equipment commands, but can become critical when they fail or under-perform. Importantly their assessment/improvement using DEM is often much more feasible because of smaller problem sizes and the absence of poorly understood physics such as breakage. In this paper we describe DEM simulations of four important pieces of non-comminution equipment that are commonly found in or near mineral processing plants (these are shown in Figure 1):"

Jan 1, 2003

By Olgac Kangal, Ali Guney, Gulay Bulut, Guven Onal, Ayhan A. Sirkeci

"This paper presents the results of pilot scale column flotation applications in the two different copper concentrators in Turkey. The Kure Copper Plant is located in the Black Sea Region of Turkey. There are four types of copper ore formations in the Küre region. The so called disseminated ore contains 60-70% siliceous minerals of which Cu content is around 0.5%. The remaining three ore types in the region are generally named “massive ores”. The massive ores may assay up to 15% Cu and the major gangue mineral is pyrite associated with relatively little amount of silica. The main copper mineral in all formations is chalcopyrite that is generally finely disseminated in pyrite therefore satisfactory liberation requires ultrafine grinding especially in the case of the massive ores.A blend of these ores, containing 1.7% Cu on average, is fed to the Küre Copper Concentrator whose capacity is 1.2 million tons of ore annually. Unfortunately, today the plant operates below its designed capacity treating around 550,000 tons of ore per year. The design of Küre Copper Plant was undertaken by the Outokumpu Company of Finland. The operation of the plant is almost automatically controlled and the feed, the concentrate and the tailings are assayed for copper by on-line XRF analysers. The particle size analysers are also connected to the grinding circuit. The feed material is ground almost below 50 µm and the flotation is conducted around pH 11.2 using Hostaflot X-231 (a trade mark of Hoechst) as the collector. Apart from the rougher cells, there are four cleaning stages after which the final concentrate is produced. A very fine grinding requirement for an adequate level of liberation makes successful flotation difficult and consequently the final concentrate can hardly assay above 16% Cu leading to copper losses around 20% in the tailings that contains 0.3% copper."

Jan 1, 2003

By W. P. Roux

With depletion of higher grade iron ore reserves, and the need to process finer, lower grade material; there is a need to better understand the recovery efficiency of jigging process. The use of Positron Emission Particle Tracking (PEPT) was examined as a technique, to study the motion of particles inside a laboratory batch jig. PEPT is a noninvasive method that can provide three dimensional kinetic data of a particle during jigging. Particles with different densities and sizes were traced under the same jigging parameters, to obtain a data set that can be used for the development and verification of jigging models. From the results, detailed information on the stratification rate of a particle was obtained, with adequate resolution to see particle movement through an individual pulse. Detailed data of this nature is critical for the validation of CFD and DEM models. Keywords: positron emission particle tracking, jigging, jig models

Sep 1, 2012

By Arkady Senchenko

The application of centrifugal separation methods with the use of gravity concentrators has been assigned high priority while gold-containing minerals processing. The separation proceeds under centrifugal force resulted from the rotor spinning and wash water flow in the concentrators. The high specific gravity particles are retained at the trapping surface of the cone, and the low specific gravity particles are brought in the tailings. The centrifugal field in such concentrators (Knelson, Falcon) is generated by the rotating cone provoking the swirling of the free fed slurry flow. The author investigated the regularities of the separation process in the centrifugal gravity concentrator where a two-phase flow of the separated mineral media is under the pulsed pressure of the fluidization water and air. As a result of the study the possibility of the deeper penetration of the fine heavy fraction into the cone rings, providing the fluctuation of the fluidization water or air flow, was theoretically argued and experimentally proved. This allows the increase of the separation performance at low pulsation costs. The developed mathematical models are in close conformity with the actual process of interest and they enable the prediction of the heavy phase behavior at the isolated process stages in the concentrator. Keywords: gold, centrifugal gravity concentrator, containing, specific gravity, cone ring, pulsation, cost, fluidization water, Knelson centrifugal separator

Sep 1, 2012

By Vishal Shukla, Ashok Kumar, Manas Ranjan, D. Chakraborty, Narayan Sharma

Jigging has a very important role in mineral processing Industry. Upgrading of Iron Ore by jigging has been an emerging trend. A detailed investigation is carried out to understand the influence of Jig feed granulometry and bed height during jigging operation. Noamundi jig plant data shows that variation in jig feed granulometry, feed quality and bed height are major contributors to fluctuation in jigging performance. At Noamundi the feed size (-10.0+0.5mm) fraction is used for fines jigging operation. To understand the effect of granulometrey on jig plant performance such as yield, separation efficiency and Fe recovery. In this context The performance of jigging was evaluated by daily average data from jig operation was used to study the influence of feed distribution on jigging performance .Coarser fraction (+6mm) has a positive influence , whereas fines fraction (-0.5mm) tends to lower performance . During Jigging rearrangements of Particles takes place due to an alternate expansion and compaction of Jig Bed .These particles are arranged by increasing density from top to bottom. During the particle stratification, Jig bed physically cut at desired horizontal particle density plant to separate the desired product. Investigation shows that optimum bed height is required at different Jig feed quality to achieve desired product quality, maximum separation efficiency and Fe recovery. This Paper will illustrate role of granulometry and Bed height control on Jigging plant performance.

Jan 1, 2014

By A. J. Lynch, L. Ergun, M. Oner

"A research program on modelling cement grinding circuits has been in operation at Hacettepe University, Ankara, for four years. It has concentrated so far on tube mill and air separator grinding circuits for cement clinker, with emphasis on plant sampling surveys, including axial sampling inside the tube mills. The methodology is to use plant data to build the models and to supplement this by laboratory data where necessary, for example the determination of breakage functions. The plant data come from comprehensive sampling surveys and so far 33 surveys of clinker grinding circuits have been carried out in 9 plants. The operating conditions have been• mill sizes – 3.2 to 4.8 metres diameter and 8.5 to 15 metres long,• mill feed rates – 46 to 158 tonnes per hour,• air flow through mills – 25000 to 125000 cubic metres per hour,• cement clinker work indexes – 10.3 to 18,• separator sizes – 2. to 3.1 metres diameter,• separator feed rates – 132 to 689 tonnes per hour,• separator speeds – 12.3 to 21 metres per second.The ball mill model is Whiten’s perfect mixing model and the separator model is the Tromp curve with a fish-hook. This paper emphasises on the importance of calculating the breakage rates and the discharge functions with three case studies at five different circuits which were selected for discussion because they show how particular features of circuit operation can be included in the general models. Size distributiongraphs are used to illustrate every aspect of the discussion.In case I the special emphasis on calculating the breakage rates and discharge rates separately is given in a high pressure grinding roll-ball mill-separator circuit. The tonnes of each size fraction in the mill and the calculated values of R/D, D and R are determined. The values of R per mw are also given to allow comparison with mills of other sizes. The circuit allows the comparison of the static type (V Sep) and dynamic type separators (SKS). Comparing the reduced efficiencies shows that the dynamic separator is slightly more efficient than the static one.In case 2 data are given from two compartment tube mills having the same diameter and the motor power but different ball size gradation. The breakage rate particle size variation of the second chamber of two mills indicate that having finer ball size distribution causes higher breakage rate values."

Jan 1, 2003

By H. J. Liang

In this study, zeta potential and contact angle measurements of pyrite before and after interacting with Thiobacillus ferrooxidans are carried out to investigate the changes in its surface properties. The results show that, after pyrite interacting with Thiobacillus ferrooxidans and its metabolite, the surface electricity of pyrite changes obviously, resulting in a notable shifting of isoelectric point to lower pH value, but the contact angle varies little. Bacterial protein plays the most important role in the interaction. This work is helpful to disclose the mechanisms of Thiobacillus ferrooxidans de-pressing pyrite flotability.

Jan 1, 2014

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisinger

"INTRODUCTIONAcid pressure oxidation of high-grade natural acanthite was investigated in the range of 110-150°C and in the sulphate media. High acidity and low pulp density were used to prevent the precipitation of silver.RESULTS AND DISCUSSIONTwo sets of acanthite specimens were obtained from La Valenciana and Ingleterra mines, Mexico. Pressure oxidation tests were conducted on 1 litre scale in a standard 2-litre Parr titanium autoclave.EFFECT OF TEMPERATURE ON THE REACTION OF ACANTHITEThe effect of temperature on the rate of oxidation is presented in Figure 1. The rate of reaction increased with increasing temperature."

Jan 1, 2003

By V. F. Petrov

Cyanide is widely used gold lixiviant for hydrometallurgical processes. The resulting tails contain complex toxic compounds. With reference to this, the protection of the environment should be the major issue. A complete detoxification of cyanides before disposal, a partial detoxification to the allowable concentrations and a disposal of tails at a polygon followed by the detoxification of excess water into the environment are offered as an environmentally friendly way of disposal. However, a complete detoxification of the cyanidation tails does not give the required results due to the presence of toxic compounds, cyanides and thiocyanates in tailings ponds. This is due to adsorption-desorption process occurring between solid and liquid phases. A partial detoxification is used to down cyanide to the allowable concentrations, which are safe to the environment. The storage of tails without detoxification is mainly used at low concentrations of toxic compounds in the disposed tails. With reference to this, water recycling is practiced by Russian plants in order to reduce as much as possible or almost eliminate toxic effluents into the environment. Fresh water is applied if necessary and to make up for water losses, with 8-12% of total water supply. This allows for the stability of water balance and the decrease of consumption of the reagents applied. The conditioning technologies of water recycling followed by regeneration of free cyanide and metals recovery as saleable concentrates are specially developed due to adverse impact of water recycling on gold recovery processes due to high concentration of base metals (copper). These technologies are also profitable. In order to detoxify cyanide in the tails for tailings dam, effective and inexpensive technologies involving a seasonal use of detoxified reagents were developed. For example, a technology with aldehydes use which is applied by a series of operations. Effluents disposed to the environment are detoxified using chlorination followed by almost a complete destruction of toxic cyanides and thiocyanates. Before disposal, chlorinated water is settled to precipitate the resulting hydroxides of metals and complete chemical reactions such as a full decomposition of hypochlorite ions. In order to protect ground water, watertight screens from local water-resistant materials are used. The samples of these materials were previously tested and chosen according to their maximum ability to adsorb toxic compounds in the tailings pond. If local water-resistant materials are not available, whole welded impermeable polymer screens are used. The options mentioned allow the storage of cyanidation tails in accordance with national ecological standards. Keywords: cyaninides, thiocyanates, wastes, environmental safety, recycled water-supply, detoxification, storage

Sep 1, 2012