Search Documents

By Sophia Katsouri

Hydrothermal circulation that produces sulfide deposits in the marine environment can also produce sulfide deposits in lakes. The major differences in terms of process are (1) in lakes the hydrothermal fluid is meteoric water of low salinity whereas in the marine setting it is saline and (2) the rocks that are leached of metals to produce the deposits are continental crust in one case and oceanic crust in the other. We have examined sulfides that are presently forming in two lakes ? Lake Tanganyika in east Africa and Lake Oyunuma in Hokkaido, Japan. Tanganyika is the second largest lake in the world and the second deepest rift lake, after Lake Baikal in southeastern Siberia. Two hydrothermal fields are known in its northern basin at Pemba and Cape Banza (Tiercelin et al., 1993). At Pemba, CO2 and CH4-rich, low temperature (53-88°C) hydrothermal fluids are forming decimeter-tall chimneys at 2-46 m water depth. Our microscopic and x-ray diffraction study of samples from the Pemba site reveal marcasite and pyrite to be the most common sulfides. Minor minerals include barite, hematite, bornite and chalcopyrite. Quartz and feldspar are also identified and were probably incorporated from the surrounding lake sediments. At Cape Banza, aragonite chimneys, up to 70 cm high, are venting fluids at 66-103°C.

Jan 1, 2001

By Bjørn Eske Sørensen, Kristian Drivenes, Przemyslaw Kowalczuk, Kurt Aasly, Gavyn Rollinson, Ben Snook

Efficient and successful mineral processing is dependent on detailed knowledge of the materials and minerals that are to be separated and concentrated. Common bulk methodologies such as XRD and XRF are fast and easy, and can provide an overview of the mineralogy and bulk chemistry of the material. However, they will not provide any textural information. Knowledge of the often intricate interaction between minerals in seafloor massive sulfide deposits is crucial in plant design for mineral processing. Samples from the Loki’s Castle hydrothermal vent have been characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), optical microscopy, Scanning Electron Microscopy (SEM), QEMSCAN, Electron probe microanalyzer (EPMA), and Electron Backscatter Diffraction (EBSD). Processing experiments used froth flotation and leaching techniques. The typical line of operation in ore characterization is shown in Figure 1. Mineral processing may be commenced after any stage of ore characterization. However, it is ideal to have completed as many steps in the ore characterization as possible in order to have the most information of the initial feed material. The main economic minerals in the samples are isocubanite (CuFe2S3), chalcopyrite (CuFeS2), and sphalerite (ZnS), with minor galena (PbS) and trace amounts of Au and Ag. The minerals show complex intergrowth textures down to the nanometer scale. These samples exemplify the need for advanced microtextural analyses to adequately characterize ore material prior to processing. The complex textures hamper the use of flotation as an efficient technique, due to the inability to sufficiently liberate the different minerals and problems with selectively floating isocubanite. Thus, leaching was the preferred method for extracting metals.

Jan 1, 2018

By Michael W. Milner

Cold Ocean Placers: Polar storms, interstadial littorals and crustal adjustments. Polar storms with consistent strong winds in the Southern, Antarctic Ocean are responsible for placer deposits on both the east and west coasts of Australia, on the west coast of New Zealand, as well as on the coasts of South America and Africa. Arctic winds, confined by both land and ice, generate similar placers in Labrador and Greenland as well as on the coasts of Scotland, Norway, Hudson's Bay, Nome, Goodnews Bay, Kamchatka and the north coast of Siberia. Tasman and Labrador seas have several parallels to Newfoundland, including north-south polar waterways, young spreading ocean floors, and youthful coastal escarpments with glaciated coasts. Black sand beds in beach deposits on the modern and Pleistocene transgression strandlines, skewed to the distal ends of beaches, and set into either bedrock or sediment fill, are the locus of the light-heavy mineral placers with titanium, zirconium and rare earth elements; chromium; iron; and tin. Gold and platinum group elements are the ultra heavy minerals at one end of the spectrum and tend occur in proximal placers generated, either directly from bedrock sources, or as minor by-products in distal light-heavy mineral placers. Diamonds are unusual in that the value is only in the larger stones, despite the formation of beach sand and aeolian placers in the littoral zone, and the sites of concentration are in very high energy bedrock traps, on terraces that are mined to depths of 100 metres below sealevel.

Jan 1, 1995

By Valery M. Yubko

During the last ten years seven applications for nodule-bearing areas of the World Ocean Floor International Region (IR) have been made by national companies of Russia (Yuzhmorgeologiya), France (IFREMER/AFERNOD), Japan (DORD), India (The State Department of Sea Resources Development), China (COMRA), Korea (KORDI) and the Interokeanmetal Joint Organization (IOM) of some East European countries and have been registered by the Preparatory Commission of the United Nations International Seabed Authority (ISA). Besides these groups registered within Resolution 11 of the Final Act of the III United Nations Conference on the Law of the Sea there are four international consortia registered in the USA [Kennecott (KCON), Ocean Mining Associates (DMA), Ocean Management Incorporated (OMI), and Ocean Minerals Company (OMCO)], which have interest in areas in the IR and can be considered as potential applicants. All registered areas (with the exception of the Indian Ocean) including the areas of potential applicants and also 6 areas, reserved for the ISA are located in the Clarion-Clipperton Zone of the Pacific Ocean. If within each area not less than one deposit of polymetallic nodule-bearing ores can be discovered, then, the total number of such deposits, for the present moment, is 20.

Jan 1, 1994

By Amy Gartman

The interactions between hydrothermal fluids and seawater result in minerals that range in size from nano- to macro-scale and constrain mineral emplacement, whether in hydrothermal chimneys or metalliferous sediments. Although broad similarities exist, and sulfides are the most important component of seafloor massive sulfide deposits, the specific mineralogy, size and therefore reactivity of particles emitted varies between hydrothermal sites in the global ocean, and even at different sites within the same vent field. The oxidation of sulfide minerals results in one of the major impacts of terrestrial mining of volcanogenic massive sulfides as it creates acid mine drainage. At marine hydrothermal vents, the chimneys themselves, as well as the ‘black smoke’ begin to oxidize as soon as they are in contact with ocean water; the breaking of sulfide minerals during marine mining will expose further surface area to seawater and oxidation. Although the cold temperatures and circum- neutral pH result in oxidation proceeding less rapidly than in many terrestrial systems, there is limited data on the kinetics of sulfide oxidation in seawater. Here, the oxidation of sulfide minerals in seawater and the implications for marine mining will be discussed, with an emphasis on nano-ZnS and sphalerite, including reaction kinetics, processes, and oxidation products.

Jan 1, 2018

By Guillaume Blanc

The development of marine mining in the offshore areas adjacent to most of the insular and continental European States is limited by the complex and evolving nature of its legal regime on the basis of the relevant applicable international, European and domestic rules. As the development of marine mining requires investments in capital-intensive technologies, the bankable feasibility of marine mining projects is very much dependent on the legal security of mining rights, assets and operations in offshore areas. This is quite difficult to assess due to the constant accumulation of applicable and potentially conflicting international and domestic laws in these areas, in particular the coastal zone, the territorial sea, and the Exclusive Economic Zone (EEZ). The often conflicting interaction of international treaties, laws and regulations in offshore areas raises specific and major issues in terms of permitting processes, access rights, ownership rights over the mineral resources explored and mined, flag vs. coastal State jurisdiction over mining vessels and marine mining equipment, international environmental liabilities, and unitisation and multi-forum disputes. In addition, the determination of jurisdiction and the legal regime under which marine mining could take place is becoming even more complex with the development of EU Law and the recent revision of the International Law of the Sea, particularly the new extension regime of the EEZ and jurisdiction over the continental shelf.

Jan 1, 2004

By Georgy A. Cherkashov

Two principal types of the hydrothermal fields in Atlantic - axial and off-axis - could be established based on their structural setting in the rift zone of the Mid-Atlantic Ridge (MAR) (Figure1). The first (axial) type is represented by five high- and three low-temperature hydrothermal sites (Table 1). All of these fields are connected with young axial effusive volcanism and related to large linear volcanic ridges or central volcanoes at the inner floor of the rift valley. The hydrothermal activity here is controlled by the intersection between longitudinal magma feeding faults and transverse weakened zones characterized by high permeability. [ ] The hydrothermal sites of the second (off-axis) type (such as Rainbow, TAG, 24°30?N, Logatchev, newly discovered 13°N (Figure 2) and possibly 16°48?N sites) are related to large tectonic dislocations forming marginal scarps of the rift valley as well as transverse discontinuities.

Jan 1, 2003

By V. Zaykov

The Urals massive sulfide deposits are concentrated in Silurian -Devonian fold belt extending for 1500 km with length from 50 to 150 km. By paleodynamic reconstmction it is established that they were formed in submarine parts of island arcs, in inter arc and back arc basins, marginal seas. When "black smokers" were found in rift zones of present oceans, problem searching their analogues in the Urals Paleozoic complexes was arisen. For solving this problem and demonstration of seafloor origin of massive sulfide many quarries and drill cores were carefully sketched and studied. Particular attention was given to correlation between ores and synchronous sedimentary rocks and fossils. Various laboratory methods were used for comparing sulfides from ore hills with ore-clastic sulfides.

Jan 1, 1993

By Jan Magne Markussen

The aim of the paper is to analyze the viability of commercial exploitation of polymetallic nodules, the time aspect for exploitation and the probable organization of commercial projects. METHOD My methodological point of departure is to view the various factors in context, and to differentiate between the various groups of actors. This involves taking as my starting point the interaction that exists between economics, technology, politics, law, the environment, and even psychology and ideology, and acknowledge that the various actors may well have differing motives for their engagement.

Jan 1, 1992

By Hunsoo Choi

Internal textures of manganese nodules from Clarion-Clipperton zone of northeastern Pacific Ocean are classified into five textural zones: columnar-textured layered zone, cuspate-textured layered zone, cuspate-textured massive zone, cuspate-textured porous zone and massive- textured massive zone. Vernadite is the main constituent mineral in the columnar- and cuspate-textured layered zone. Buserite sometimes occurs in the cuspate-textured layered zone. The cuspate-textured massive zone is mainly composed of buserite. Todorokite is also associated with buserite in the massive-textured porous zone, where cuspates and globes are partially replaced by massive texture. In the massive-textured massive zone, todorokite, buserite and birnessite occur together. The analyzed elements of all zones are also classified into four elemental groups by the cluster analysis of correlation coefficients: Mn group, Cu-Ni-Mg group, Fe group and Si group. Mn group consists of Mn and K. Cu-Ni-Mg group consists of Cu, Ni, Zn, Mg and/or Ca, Na. Fe group consists of Fe, Co, Ti and/or Ca, P. Si group consists of Si and Al. Each textural zone is composed of three or four elemental groups. These four elemental groups are correlated with mineral composition, such as, Mn group with todorokite, Cu-Ni-Mg group with buserite, Fe group with Co-bearing iron-oxyhydroxide minerals, and Si group with silicates.

Jan 1, 2002

By Allan Spencer

In March 2007, Nautilus Minerals Inc. announced that they had commenced their 2007 exploration and development program with the mobilization of the Research Vessel Wave Mercury and the Survey Vessel Aquila onsite Papua New Guinea.

By Simon McDonald

The Neptune Group was established in 1999 to apply for exploration permits within New Zealand’s 200nm EEZ. These applications were to investigate and commercialise hydrothermal Seafloor Massive Sulphide (SMS) deposits identified by international researchers and to locate others. SMS are volcanically related seafloor accumulations of copper, lead and zinc with high levels of gold and silver. Neptune has three granted exploration licenses within the New Zealand EEZ and has application in other jurisdictions. Neptune undertook the world’s first commercial drilling exploration work of SMS in December of 2005.

Aug 24, 2006

By Anthony T. Jones

Deep seabed mining requires technology to collect materials and transport them to the surface. An international patent search was conducted to define the state of the art in seabed mining technology. Over 350 patents were identified from 12 patent systems. The majority was from the United States, Japan, and the former USSR. Patent activity in this field peaked in 1983 when 34 patents were issued. Since 1984, on average 6 patents have been issued annually. The technology represents ten major classifications. With the exception of Deepsea Ventures, Kawasaki and International Nickel, it appears that much of the technology developed and tested in the 1970s by consortia active in seabed mining was never patented. Over the past two decades, identifiable trends in marine technology could influence seabed mining application such as more sophisticated communication systems, advances in hydraulic manipulators, improved computational technology in navigation, modeling of vessel ? ocean interactions, and improved materials. The most significant recent activity has been in European applications, which disclose remotely controlled subsea vehicles for mining diamonds.

Jan 1, 2001

By Jonguk Kim

Hydrothermal exploration aboard the R/V Onnuri was performed along the northern Central Indian Ridge (CIR) between 8°S and 12°S in January 2010. The main objectives of this first Korean research cruise on mid ocean ridge system was 1) to understand the nature of spreading segments of the northern CIR area, where no systematic survey have been operated before, by mapping and sampling of volcanic rocks and 2) to discover new hydrothermal venting along the spreading center of northern CIR. During the first leg (IR09 Leg1) bathymetric data, in ~50 km width, were collected by multibeam echo sounding system (EM120), which reveals the exact location and structure of axial rift valley of northern CIR between ~ 8°S and 17°S. Then, rock sampling and CTD casts and tows were performed in northern half of the multibeam survey area in the second leg (IR09 Leg2). The results of bathymetric survey clearly display ocean core complex between 10°S and 11°S. The ocean core complex is featured by topographic-high area with corrugated surface. Lineament of corrugations of the ocean core complex are clearly perpendicular to abyssal hill direction which are triggered by symmetric-normal faults. Symmetrical and asymmetrical segments are characterized by parallel abyssal hills and ocean core complex and/or subparallel abyssal hills, respectively. Geochemical analyses of basaltic glasses from spreading axis show geographic trend of increasing of incompatible elements north to south along the spreading axis, which might be influenced by Reunion hotspot plume. However, local but clear enrichment of incompatible elements is observed in volcanic lava from segment 2, which suggests possible local mantle heterogeneity of uncertain source. Lots of serpentinite and gabbroic rocks with coarse-grained feldspar was recovered in the ocean core complex. Ultramafic and/or mafic rocks indicate the gentle-domed block was traveled from upper mantle. Along the spreading axis of the northern CIR, significant hydrothermal plume signatures were detected by CTD castings and tows. Plume signatures were observed at all 5 surveyed segments, suggesting vigorous hydrothermal activities along the northern CIR. However, the optical signals (light transparency and backscattering) of the nearly every cast along the axial valley of the CIR showed increased background level, which might be due to higher level of suspended particles within the axial valley not only by widespread hydrothermal plumes but also by other processes like resuspension. Onboard dissolved methane analysis indicates that the greater part of the plume signals are originated from hydrothermal venting, not by resuspension. However, more detailed examination, including analyzing additional hydrothermal tracers, need to distinguish actual hydrothermal plume signature.

Jan 1, 2010

By Eric J. Foell, Hjalmar Thiel, Gerd Schriever

Environmental studies for the mining of polymetallic nodules (PN) from the deep sea may be traced back for some 35 years.

By Cheng Xiangzhou

The China's Pioneer area includes two parts. The topography in the western part is very different from that in the eastern one. The distribution of the manganese nodules in these two regions differs correspondingly China Ocean Mineral Resources Research and Development Association (COMRA) will take appropriate measures so that the next development will be adapted to the features of its potential minable area.

Jan 1, 1996

By Akira Usui

Occurrence of hydrogenetic ferromanganese crusts has been well documented over inactive seamounts in the central and southern Pacific Ocean. It has been thus believed that the hydrogenetic crusts develop preferentially at water depths between about 800 to 2500 meters. In fact, according to the Manganese Crust Database (F. Manheim, 1988), only two occurrences are known at water depths below 5000 m out of 819 occurrences cited in the database. Unexpectedly, we found typical hydrogenetic ferromanganese crusts from deep-sea floors; 1) outcropping old volcanic basement over the Philippine Sea Plate (abandoned spreading centers and subducting old oceanic crusts) and 2) one from the slope of an abyssal hill in the Central Pacific Basin (Cretaceous deep-sea basin) at water depths ranging between 5200 to 6100 meters. We report their occurrences with submersible observations from Shinkai 6K, physical parameters (such as thickness of crusts about 2-4 cm in maximum), chemical composition, petrology of substrate, and results of Be-10 dating for some samples in comparison with typical Co-rich manganese crusts from the Central Pacific seamounts. The preliminary chemical and mineralogical analyses reveal that they are of typical hydrogenetic origin, and typical of iron-manganese oxide mineral, vernadite, slow and probably continuous growth, and lower content of Co than the Central Pacific seamount crusts. The occurrences and nature of the crusts indicate that deep-sea floors are also optimal for the growth of hydrogenetic crust even at 5000 m water depth or deeper, only if oxygenated deep waters are supplied and the sea-floor morphology keeps stable enough for significant geological time period. Additional details of chemical analyses will be prepared by November and to be shown in the conference.

Jan 1, 2001