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By G. C. Weatherly, D. S. Wilkinson, A. M. Limarga

Competition between stress generation and relaxation mechanisms during the oxidation process has been observed. However, the nature of the intrinsic growth stress in thermally grown scales is not well understood. In this talk, we will propose a conceptual model to calculate the intrinsic growth stress based on the analysis of stress-driven diffusional process of oxygen ions along the oxide grain boundary. The calculated stress, which is considered to originate from the constrained lateral expansion of the oxide, is in agreement with a range of experimental observations.

Jan 1, 2004

By F. Habashi

In the period 1970-1995, a number of hydro metallurgical processes to treat copper concentrates to overcome the pollution problem due to S02 emission in smelters were developed. Pilot and commercial scale plants were built and operated for some time, but eventually all were abandoned a few years later. It is constructive to examine why these processes were abandoned after so much expenditure of funds and effort, so that errors should not be repeated in the future and lessons from the past are learned.

Jan 1, 2007

By R. M. Kalanchey

The application of pressure oxidation processes to copper feed materials has gained increased exposure in recent years and some of these processes have made commercial inroads, although rather limited to date. Among the hydrometallurgical processes with significant commercial potential, Dynatec's copper pressure leaching process has been applied to arsenic-bearing copper materials and has shown, through a number of batch and continuous test programs, that pressure oxidation is a technically feasible option for the recovery of copper with coincident sequestration of arsenic in an environmentally benign residue.

Jan 1, 2007

By F G. Cooke

"This paper describes a medium-sized copper mine's results in making innovations and changing operational practices to combat increasing expenditures due to higher labour and supply costs, extended workings, scarcity of experienced manpower and problems created by deteriorating ground conditions.OPEMISKA COPPER MINES (QUEBEC) LIMITED is located at Chapais in the Chibougamau area, in central eastern Quebec, approximately 300 miles north of Montreal and 150 miles north west of Lake St. John. The latter area, developed by lumbering and farming, has supplied the majority of the employees, who, with training and experience and a desire to work and improve themselves, have become the backbone of the Company's 600 personnel.Opemiska began production in 1954 at a rate of 400 tons per day, using diesel power and road transportation. The rate was progressively increased and, by 1959, with hydro-electric power and rail transportation, the mine had reached its present production rate of 2,000 tons per day. It has produced concentrates containing over 430 million lbs of copper."

Jan 1, 1968

By Donald J. MacNeil

The commercial carbonate industry of Cape Breton Island, Nova Scotia, began about eighty years ago with the opening of the Sydney steel plant. Significant carbonate deposits are confined to the Precambrian George River Grav" and the Mississippian Windsor Group. George River Group carbonates are thought to have formed as part of a stable platformal sequence. They are crystalline and lie within a dominantly quartzitic sequence. Of the four major sites for George River carbonates on the island, the most commercially promising are the dolomite at Kelly Cove and the limestone and dolomite at Glencoe. Kelly Cove dolomite has good potential for metallurgical, agricultural and fettling purposes; reserves approach 13.6 million tonnes. Windsor Group carbonates were deposited as marine sediments in basins formed by pre-Carboniferous fault blocks. Windsor dolomite reserves at Stoney Creek are only fractionally retrievable and hence are of little economic value. The Windsor Group's Irish Cove limestone has been quarried on a large scale since 1964; no undeveloped commercial deposits, however, remain in the group.

Jan 1, 1984

By G. Barbery, P. Dauphin

"In order to obtain reproducible and reproducible results in batch flotation, researchers have tried various approaches, from normalized testing, to modifying existing cells, and even designing new machines. The paper reviews the basic concepts that must be fulfilled in a laboratory flotation machine, and present the FLOTOMATEC design, which results from five years of testing and development. In addition to providing accurate measurements of air flowrate, power consumption, agitation speed, the cell eliminates most operator induced errors. Results of experiments comparing FLOTOMATEC to a conventional cell, as well as reproducibility tests are given. Introduction The use of batch flotation machines in mineral processing research and development is very common. These machines have been used for many years without almost any change in their design, instrumentation or automation. Various authors since Raffinot (1960) have criticized the available designs, especially with respect to the large errors that are introduced by the manual mode of operation. Barbery et al. (1986) have presented a review of the problems involved in laboratory testing in flotation research.Batch laboratory machines should have the following characteristics:"

Jan 1, 1989

By N. Schmitt, E. Blond, F. Hild

Working linings of steel ladles progressively damage during the steel manufacturing process due to both severe thermomechanical and chemical stresses. In the framework of the coupling scheme proposed by Blond et al. (1), this study examines the effects of the thermomechanical loading on the onset of microcracking by considering that the complex microstructure of the slag-impregnated brick is fixed during the steelmaking process. The behaviour of the refractory is identified by using thermoelastic-(asymmetric)viscoplastic constitutive equations. Numerical simulations of a simplified geometry of the lining subjected to cyclic thermal loadings at the inner side are shown. Two cases are analysed, namely, i) the material is a homogeneous continuum with a thermoelastic-(asymmetric)viscoplastic behaviour, ii) the material is porous and saturated by liquid slag, and the skeleton has the previous non-linear behaviour. The stress and strain fields are shown, and for the porous medium the interstitial pressure of slag as well. Comparisons between these assumptions are made to assess the role of slag on the degradation of the working lining.

Jan 1, 2004

By Christopher W. N. Anderson

Induced hyperaccumulation of gold by plants was first reported in 1998 by researchers from Massey University in New Zealand who proposed the idea of mining gold using plants (phytomining). Since that time research has been conducted to understand the conditions under which plants can be made to take up economic amounts of the metal. One key focus has been on the geochemistry of gold-rich soils, leading to a diagnostic test that can predict how suitable a particular soil might be to gold phytomining. Field trials have been conducted at several locations around the world in collaboration with industry partners. A Decision Support System has been developed to assist in the design and management of phytomining operations, and economic modeling has been carried out to set targets levels for phytomining technology. Novel studies are now examining the form of gold in plants. Research suggests that plants may store gold as discrete metallic nanoparticles in leaf and stem tissues, an observation that may lead to new ways to recover the metal from harvested biomass.

Oct 1, 2003

By R. von Gal

Hazelett Strip-Casting Corporation has been producing the Hazelett® twin-belt casting machines for copper casting since the mid-1960s. The first commercial casters were developed for copper alloy strip and anode plate. In 1968, development work was started to adapt the twin-belt caster for copper bar casting to be rolled in-line into wire rod. Since then, 36 casters have been sold as part of the CONTIROD® system for the production of a substantial portion of the world's copper rod supply. A unique feature of the twin-belt caster is the mold's ability to comply with the size and shape of the cast bar as it shrinks during solidification. Maintaining contact between the mold and the bar provides a high rate of heat transfer as well as other benefits, including the prevention of surface imperfections caused by remelting in the mold. This paper will give an overview of the continuous evolution of the twin-belt caster technology with an emphasis on recent developments in compliant mold technology for copper casting.

Jan 1, 2007

By William A. Price

The objective of this paper is to outline the approaches used in British Columbia to address the challenges posed by metal leaching and acid rock drainage (ML/ARD). Challenges include the large financial costs, the need for site-specific assessments, the large information requirements, the need for mitigation measures to be designed and financed in a manner that permits long-term performance, the lack of long-term operating experience, the ongoing changes in many important processes, the need for pro-active detection and resolution of concerns, difficulties in predicting the potential for ARD or significant metal leaching, the need for new tools, and the multidisciplinary, highly specialized nature of the work. Consequently, mines must be planned, operated and closed in a manner that permits regular review, detailed monitoring and adaptive management. Proper consideration of the challenges involved, including a plan of how all outstanding concerns will be addressed, studies to address areas of significant uncertainty and caution in the absence of the required understanding, should ensure environmentally safe practices in the future.

Nov 1, 2002

By V. Ramachandran

The successful advent of solvent extraction (SX) reagents for copper recovery and improvements in electrowinning of copper to produce LME grade A copper cathode have paved the way for the hydrometallurgical treatment of copper oxide and low grade sulfide ores. This has resulted in about 25-30% of the world's copper being produced today by the Leach-SX-EW process. The obvious next step was to develop processes for the hydrometallurgical treatment of copper sulfide concentrates, as an alternative to a typical smelter-refinery complex. The current paper updates the processes that have been developed to date with emphasis on processes that are being commercialized or that are seriously under consideration for commercialization. Most of the discussions relate to the hydrometallurgy of chalcopyrite concentrates, which account for about 70% of the world's known copper reserves. In summary, in the last thirty years, the hydrometallurgical treatment of copper sulfide concentrates has attained full maturity and will be a serious option to contend with while evaluating any future new copper plant.

Jan 1, 2007

By C. Phan

This paper outlines opportunities provided for enhanced management and process control by ISA PROCESSTM technology. ISA PROCESSTM technology has the core advantage of offering the potential for vastly improved electrode handling systems. This fundamental characteristic has enabled ISA PROCESSTM technology to develop management and process control systems that are modular, minimalist in their complexity and tailored to a tankhouse operating environment. A review will be presented on the current status of management and process control in ISA PROCESSTM tankhouses covering the central issue of electrode handling as well as electrolyte circulation systems, voltage monitoring, cathode plate tracking, and product tracking. Particular reference will be made of the recent development by Xstrata Technology (XT) and their technology partners, VRT Systems, of an Radio Frequency Identification (RFID) based solution for tracking ISA PROCESSTM cathode plates. The system encompasses fixed readers which identify plates passing through the stripping machines and the use of sophisticated tracking and database software enabling the development of cathode asset management and operational strategies. The performance of individual plates and batches of plates can be tracked through a full service history.

Jan 1, 2007

By Douglas E. Wolfe, Jogender Singh, Robert Miller, Dong-Ming Zhu, Jeff Eldridge

This paper discusses microstructural changes produced by two novel approaches using electron beam physical vapor deposition (EB-PVD) in which periodic strain fields/microporosity was incorporated within the large columnar grains of Zr02- 8wt.%Y2O3 (8YSZ). The traditional columnar microstructure of partially stabilized zirconia has been slightly modified to produce a lower thermal conductive thermal barrier coating (TBC) by periodically interrupting the condensing vapor resulting in microstructural modifications with diffuse or sharp interfaces and morphological changes on the sub-micron scale without changing the composition of the TBC. These microstructural modifications resulted in a 20-30% reduction in the thermal conductivity, 28-56% increase in hemispherical reflectance, improved oxidation cyclic life (over 100%), and better strain tolerance as compared to standard ZrO2-8wt.%Y2O3 deposited on platinum-nickel-aluminide and CoNiCrA1Y bond-coated MAR-M-247 test samples. The TBC with tailored microstructures were examined by various techniques including scanning electron microscopy (SEM), x-ray diffraction (XRD), steady-state laser heat flux technique, and hemispherical reflectance.

Jan 1, 2004

By J. A. Hurd

Towards the goal of a better understanding of the structure-proton conductivity relationship in PEM materials, this project concerns the design of ordered polymeric solids containing well-defined sulfonate aggregates. The approach employed involves the templation of sulfonated monomers using core principles of crystal engineering. In addition to sulfonate groups, the monomeric units contain crosslinkable functionalities to enable formation of a covalently linked network. The templation strongly directs the construction of well-defined sulfonate clusters and aggregates. Structural, sorption and conductivity data for the networks will be shown.

Jan 1, 2005

By F. Filzwieser, K. Gamweger

The process of gas purging in molten aluminium has been an industrial practice in Europe for many years. The advantages are a reduction in the hydrogen content and impurities in the melt, as well as a homogenisation of the temperature and chemical analysis in the molten metal. Formerly used lances or impellers are being replaced by porous plugs which are installed at the bottom of the furnace. This special product of RHI Refractories has proven its efficiency in primary melting as well as in die cast, sheet and extrusion plants.

Jan 1, 2004

By H. P{ops

This paper summarizes important developments that have occurred in the mining and subsequent production of copper into rod and wire from 9000 B.C. until the present time. Principles and practices associated with continuous rod production are discussed from a metallurgical perspective, and include the effects of oxygen content and impurities. A brief historical review is also given of important wire drawing events dating back thousands of years. Finally, predictions concerning the future of the wire and cable industry are presented with particular emphasis upon copper wire, technology in this market, and competitive materials.

Jan 1, 2007

By Andreea Catalina Gluhoi

The oxidation of propylene and methane has been investigated over two series of Au/MOx/Al2O3 and Au/MIOx/MIIOx/Al2O3 catalysts (M, MI, MII =Li, Rb, Mg, Mn, Ce, Zr). Whereas the effect of the presence of MOx or MOI x/MOII x on the oxidation of methane is relatively small, a large enhancement in activity is observed for propylene oxidation. Synergistic effects have been observed by combining ceria or a transition metal oxide (high oxygen storage capacity) with an (earth) alkali metal oxide.

Oct 1, 2003

By J. P. Bennett, W. E. Lee, S. Zhnag, K. S. Kwong

An EAF slag properly saturated in MgO results in increased refractory service life and steelmaking efficiency. A computer model was developed using phase equilibrium data from the MgO-CaO-SiO2-FeO, MgO-CaO-Al2O3-SiO2 and SiO2-CaO-Al2O3-FeO systems to predict MgO saturated slag chemistry. This model has been successfully applied to a commercial EAF, although disciplined plant practices are required to achieve benefits from slag chemistry control.

Jan 1, 2004

By Lawrence Devon Smith, Keith Spence, William Roscoe

"In March 2003 the CIM Council adopted and approved the document “Standards and Guidelines for Valuation of Mineral Properties” as developed by the Special Committee of the Canadian Institute of Mining, Metallurgy and Petroleum on Valuation of Mineral Properties (CIMVal). The document is referred to as the CIMVal Standards and Guidelines. The document evolved from a specific recommendation by The Mining Standards Task Force (MSTF) of the Toronto Stock Exchange and the Ontario Securities Commission in its Final Report (January 1999) that the CIM form a committee of valuation practitioners to review and advise on approaches to valuation of Mineral Properties. The CIMVal Standards and Guidelines are organized into two parts: •,Standards which are general rules in the Valuation of Mineral Properties. The use of the Standards is mandatory if the Valuation Report is stated to follow CIMVal (although not mandatory in the sense of having regulatory authority). Definitions are given at the beginning of the Standards. •,Guidelines which elaborate on the Standards and, while not mandatory, provide guidance and best practices which are highly recommended to be followed in the Valuation of Mineral Properties.CIMVal specifies requirements for the Qualified Valuator who has the responsibility for choosing the appropriate approaches and methods for the valuation of mineral properties. With regard to the specifics of the application and practice of valuation approaches and methods, CIMVal directs the Qualified Valuator to the large body of published papers, published valuations, presentations and court judgments to guide his or her choice. This is also the approach taken by VALMIN (Australia) and SAMVAL (South Africa). To facilitate the dissemination of industry practice, the CIMVal Committee organized a “Valuation Day” at the CIM Annual General Meeting in Toronto (Mining Millennium 2000), on March 8, 2000. Industry experts presented papers on valuation of Mineral Properties which were subsequently published in a proceedings volume and individually ad technical papers in the CIM Bulletin. The Management and Economics Society of CIM has continued to identify and publish papers on valuation in the CIM Bulletin and Magazine. The present document gathers in one place the CIMVal Standards and Guidelines, the papers from the 2000 Valuation Day, and a number of subsequent papers that illustrate industry practice for the valuation of mineral properties."

Jan 1, 2003

By J. Chlan

"Dryer DescriptionProctor and Schwartz Continuous Conveyor DryerThe Proctor and Schwartz Continuous Conveyor Dryer has been in operation since July 1958, and comprises six unit• - an 8• wide single conveyor with roller extruder, insulated housing, type 304 stainless steel circulating and exhaust fall system, steam heating coils, temperature controls and discharge crusher rolls. Entire dryer dimensions are 52’ x 12'0""weighing 53,000 lbs,Extruder rolls - setting is 1/8"" (Drive 3 HP 1800 RPM) clearance off the extruder screen.Conveyor - consists of 151 interlocking pans, measuring 8"" x 8' (2 HP 1200 RPM) One Exhaust Fan (5HP - 900 RPM)Steam Coils -- l"" steel pipe - with steel fins -- each coil measures 16' 2’’- 64 coils in the No, 1 Compartment- 64 coils in the No, 2 CompartmentDryer OperationThe yellowcake slurry at 28% solids is pumped to an 81 x 8' Peterson Filter. The filter media presently being used is a Neotex 4372 blanket, being 100% staple fibre nylon, 12 oz per square yard with air porosity of 9 CFM's. The cake discharge at 45 - 50% moisture falls into the roller extruder. Extrusions are formed by forcing the material by rolls through a perforated plate moving back and forth and depositing the spaghetti-like extrusion on onto the dryer-conveyor.The conveyor now carries the extruded material through the heating chamber•, The feed end of the dryer will be referred to as No. 1 Compartment, with temperature control set at 280""F. The circulating fans take the hot air off the coils and circulate the heated air through the perforated openings in the dryer conveyor pane, After passing through the set of steam coils and circulating fan in No, 1 Compartment, the material then goes through No, 2 Compartment where the temperature is set at 305'F, Final material then discharges through a set of crusher rolls set at ~"". Moisture of final dried product runs at less than 2%.The dryer conveyor load is usually run to a 3"" - 4"" depth load. Conveyor speed at approximately 90 minutes for load to pass through. Load onto the conveyor is controlled by boot level and speed of the 8' x 8' filter. The dryer steam coils are water-washed twice a month."

Jan 1, 1972