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By Paul D. Young, Michael J. Allan

"The Con Mine has been producing gold continuously since 1938. In 1990 laboratory and pilot plant investigations began into the use of pressure oxidation for treatment of an arsenic trioxide waste product from two previous roaster operations on the property. This led to the construction in 1992 of a 96 ton/day plant to treat a mixture of arsenic waste and flotation concentrate from the existing mill. The plant was commissioned in the fall of 1992.This paper describes experience gained in the commissioning and initial operation of the plant. The unique aspects of treating a hazardous waste product are described including special operating procedures to satisfy environmental and employee safety concerns. The paper further describes modifications made to the process flowsheet, to operating procedures and to materials of construction in the early months of operation."

Jan 1, 1994

By S. K. Sadrnezhaad, B. Hashemi, Z. A. Nemati, Z. Moghimi

Based on the kinetics relationships of a solid - gas model, a software was developed for the prediction of oxidation. Preliminary prediction of oxidation by the software and experimental results of MgO-C refractories were studied and compared. By using the obtained data from this approach, the effective diffusion coefficient, intermolecular diffusion coefficient and diffusion activation energy in the MgO-C refractories, containing various amount of graphite were obtained at different temperatures. First of all, the prediction by the software was very compatible with experimental results, for different oxidation mechanisms in the MgO-C refractories. The results showed that pore diffusion is the predominant oxidation mechanism in this system. The results indicated that when graphite content was above 10wt%, the intermolecular diffusion coefficient was independent from graphite content, and it was closed to a constant value at each temperature.

Jan 1, 2004

By T. H. Etsell, P. C. Holloway

The fly ash produced by oil sands operations in northern Alberta represents a large, high-grade, potential resource for vanadium production in Canada. After extensive batch testing at the University of Alberta, a conceptual process flowsheet for the recovery of vanadium from oil sands fly ash has been developed. The various unit operations for this process, including decarbonization, roasting, leaching, desilication, precipitation, salt recovery and byproduct recovery, are described. Processes for the recovery of molybdenum and ammonium chloride from waste streams from this process, are proposed, as are potential uses for the ash residue; these byproducts represent significant potential sources of secondary revenue while reducing the environmental impact from the process. A preliminary economic analysis for vanadium recovery from oil sands fly ash using this process is also included and several major economic factors influencing its commercialization are discussed.

Jan 1, 2004

By Wei Wei

Mining induced ground movement and/or stress redistribution could cause ground instability issues. This is particularly true when the extraction of large stopes is done with one or two large production blasts. Often enough, it is the nearby mine development like haulage drifts and cross cuts that are influenced the most by production blasts. Proper and timely mitigation of ground control issues due to stress redistribution is required. This is usually done by drift rehabilitation involving the installation of secondary support system in the affected areas of the mine development which include; slashing, wire mesh, and in some cases the use of shotcrete liners. It is imperative that such rehabilitation be implemented to the mine infrastructure in a timely manner in order to avoid aggravated ground control problems and production delays. If the real time performance of the support system is captured, it would be possible to determine the timing for rehabilitation job. Birchtree Mine in Thompson, at the Vale Manitoba Operation, has begun mining the 84 Deep Orebody. One of the identified risks is the stability of the crusher room under mining induced stress redistribution. It is proposed to use the U-Cell technology to monitor the primary support system performance (rebar bolts and extension bolts) and monitor the real time performances of the bolt axial loads. The U-Cell technology is a 7-inch long, coupler load cell that is screwed onto the threaded portion of a rock bolt prior to installation. Rehabilitation in the vicinity of the crusher area where U-Cells are installed is recommended when the bolts have reached 70% of their yielding capacity. Catastrophic ground failure can be avoided by adding secondary support in a timely fashion. This paper presents a case study at Birchtree Mine in Thompson Manitoba, where the performance of primary ground support system is monitored and recorded during production.

Jun 1, 2012

By R. T. Seaman

There are several hydrometallurgical alternative processing options under development for high enargite and arsenic containing copper concentrates ranging from biological, atmospheric, medium temperature oxidation to total oxidative leaching. The most developed of these options is the CESL process boasting pilot campaigns totaling more than 8760 hours of fully integrated continuous operation, as well as, over two thousand batch scale oxidation tests performed on dozens of concentrates for flowsheet development. This paper reports the observed deportment of arsenic under varying arsenic, iron and acid oxidation conditions; it also describes the impact of iron to arsenic ratios and residue recycle on overall arsenic behavior and its stability in residue. INTRODUCTION The CESL Hydrometallurgical Process (CESL) was originally developed to compete with smelting of clean chalcopyrite concentrates. High Treatment Charges and Refining Charges (TC/RCs) combined with premiums on London Metal Exchange (LME) grade copper from onsite refining made treatment of copper concentrates using CESL a viable option at the time. As world demand for copper increased and a subsidized Chinese refining market developed, smelting contracts became more favourable for the miner and focus was placed on modifying the CESL Hydrometallurgical Process to handle concentrates with elevated deleterious elements. Dozens of pilot campaigns processing concentrates containing elevated concentrations of uranium, fluoride, mercury and nickel all led to further developments of the CESL Hydrometallurgical Process. In 2016 a United States patent was granted for a novel modification of the CESL Hydrometallurgical Process for recovery of copper from arsenic-bearing and/or antimony-bearing copper sulphide concentrates, Henry Salomon de Friedberg (2016). To date, over 2000 bench scale tests along with five fully integrated closed loop pilot campaigns, totaling over a year of online operation time, have been conducted processing arsenic bearing copper concentrates. This paper summarizes the observed behavior of arsenic under varying autoclave and process conditions.

Jan 1, 2019

By Ayako Iwakoshi

Highly concentrated pastes of gold nanoparticles were successfully produced by use of a special kind of protective polymer and a mild reductant. Solid part of the pastes consists of up to 85wt% of gold nanoparticles, 10~30 nm in diameter, and residual protective polymer. This component can be diluted by any kinds of solvent at arbitrary rates. Electronics, optics, catalysts, colorants and surface metal coatings are possible application fields. 1. Introduction Noble metal nanoparticles are of interest in a variety of fields ? such as colorants, metal coatings, electronics(1), optics(2), and chemical catalysis(3). Especially, in the color field, the gold nanoparticle has been known as an aesthetic red colorant for stained glass and fine glassware, such as Venetian glass. The mechanism of coloring is attributed to surface plasmon absorption of gold nanoparticles(4,5). The gold nanoparticle in stained glass shows very clear red color, which is very durable for hundreds years. On the other hand, the red color of organic pigment in paint films often fades away within several years. We intended to reproduce the elegant and stable coloring of stained glass in paint films. In order to color a very thin, 20~50?m, paint film like stained glass, production of highly concentrated dispersion of gold nanoparticle is necessary. To achieve this, there were two issues to be overcome. One is how to prevent the coagulation of gold nanoparticles in highly concentrated solution. So far, several methods to prepare gold nanoparticles(6,7) were reported. But only a few methods succeeded to stabilize the gold nanoparticle dispersion at higher concentration than ppm order. The other is controlling of the particle size, this is because the color of gold nanoparticles is very sensitive to the particle size. Only when the particle size lies around 10 nm, the suspension exhibits red color like stained glass.

Oct 1, 2003

By M. C. Bétournay

? Prioritization of this research area identified through a CANMET-MMSL industry survey ? Possible technological breakthrough ? Prioritization of this research area identified through a CANMET-MMSL industry survey ? Possible technological breakthrough Disadvantages ? High cost and long time for equipment development ? Hard rock mining condition limitations ? Size of equipment ? Equipment set-up time, down time ? Performance does not meet financial return targets ? Ground control issues ? Drill and blast retains overall advantage

Feb 1, 2008

By David Morley

This paper considers the ideal truck-excavator combination, defined as the combination resulting in the lowest direct unit cost, in consideration of multiple haul scenarios characterized by different haul distances, material and equipment availability. Through the application of Monte Carlo simulation, selected for its unique ability to handle the uncertainty of activity durations, the ?four to six passes? loading rule is shown to not correlate with the selection of the minimum cost fleet. Additionally, through the results of the simulation it is determined that the haul truck capacity has a greater effect on the overall efficiency of the system than does the excavator capacity. As a result, in order to arrive at efficient operations, the entire earthmoving system must be viewed as whole, namely, considering haulers together with excavators, as opposed to the popular method of first selecting a loading unit and then selecting a hauler obeying the ?four to six passes? loading rule. Furthermore, truck utilization and excavator utilization exhibit an inverse relationship and neither directly correlates with the overall efficiency of the earthmoving operation. The following conclusions are drawn: first, with limited financial resources, it is more valuable to increase hauling unit size before increasing loading unit size and second, predefined rules or generalizations, not based on evidence, potentially eliminate optimal truck excavator combinations from being considered.

Aug 1, 2013

By Rebecca L. Jones

The paper addresses the application of XPAC AutoScheduler at the Fort Hills Energy Oil Sands Project to complete fast turn around ?what if? scenario testing of different mine schedules. Traditional scheduling approaches involve engineers making a ?best guess? at the required mining sequence, loading this sequence into a scheduling package and testing the results to determine if the schedule meets corporate objectives. This process is iterative and can be very time consuming. Autoscheduling techniques, on the other hand, are based on the engineer pre defining the mining rules and constraints of the deposit. The software then automatically selects a sequence of mining which the schedule should try and achieve, based off specified corporate objectives. Under this system the engineer is able to adjust the objectives and rules to evaluate numerous scheduling scenarios quickly and easily. An XPAC AutoScheduler model was built, documented, and implemented by Runge and Petro-Canada Oil Sands Inc. personnel in a month. It is currently being used by Petro-Canada Oil Sands Inc. to run multiple schedule scenarios, most taking less than ten minutes configure and ten minutes to schedule. The results of each schedule are tabulated with supporting graphs on; the bitumen grade profile, strip ratio, ore inventories and mined tonnage. In addition to this, the block model may be animated to show the progression of the resources mining the schedules.

May 1, 2008

By M. D. Evans

"Note: The views expressed herein are those of the author, not of the Government of CanadaThe mining industry has a significant opportunity to capitalize on past learnings to build better social relationships. The industry’s relationship with society is critical and under pressure. Rising levels of public opposition and social conflict are already having material impacts on operations around the world. The industry has an opportunity to shape the future direction of this social engagement, build public trust, and proactively respond to a material risk to operations, but first it needs to better understand the nature of the challenges and the urgency of addressing them.RÉSUMÉ L’industrie minière a actuellement une excellente occasion de tirer profit de ses expériences antérieures pour établir de meilleures relations sociales. Les relations entre l’industrie et la société sont critiques et elles subissent de grandes pressions. L’escalade de l’opposition par le public et les conflits sociaux ont déjà des impacts physiques sur les opérations partout à travers le monde. L’industrie a l’occasion de façonner la future direction de son engagement social, d’accroître la confiance du public et de répondre de manière proactive à un risque matériel aux exploitations, mais elle doit tout d’abord mieux comprendre la nature des défis et l’urgence de les traiter."

Jan 1, 2015

By Chris Yellowega

The construction and startup of a new mine is a daunting task. To successfully locate, design, build and startup an immense human endeavour like a new mine, takes perseverance, planning, dedication and significant capital. The application of capital requires a thorough evaluation of risk and where that risk is most properly limited to create the risk/return profile. One area of significant capital and thus, significant risk is the selection and maintenance of the very machinery needed to deliver the creation of investor wealth. Albian Sands Energy is the operator of the new Muskeg River Mine located north of Fort McMurray in Alberta?s oilsands. The Muskeg River Mine is owned by a joint venture of three companies: Shell Canada, Chevron Canada Ltd.and Western Oil Sands. The mine is designed to run 400,000 tons per day, 365 days per year. The mine conditions vary from material as hard and of similar consistency to pavement to underfoot conditions as soft as saturated sands. Water cannot be drained below surface conditions, shovel teeth can disappear in less than 24 hours and the primary business is often constructing large civil structures that have little to do with the delivery of ore. The mine starts with the deposit (if it doesn?t exist, nothing else matters), moves into the design, the feasibility study and the approval. The evaluation of risk and the strategies surrounding the control of that risk truly lie after these stages are complete. The strategy and execution stage is where risk is eliminated or accommodated. The point at which the investors money is being spent is the point at which the decisions made cannot be reversed. It is of absolute importance that the execution of the decisions are consistent with the strategy agreed to, lest the investors need to be asked for more money. The key sources of risk identified for the Muskeg River Mine were recruitment of trained and experienced personnel and the delivery of ore to maximize early (<2yr) cash flow. The Muskeg River Mine personnel determined that to minimize risk, personnel would be recruited to operate the mine equipment yet, the requirements for maintaining the equipment would best be held by the manufacturer. The strategy was to obtain the correct equipment for the operation of the mine and leverage the supplier?s expertise to ensure the mine wasn?t training a maintenance organization at the same time as a mining organization. In essence the key strategy for the mine start up and early operation was to leverage the equipment suppliers to maintain and repair the equipment. Albian Sands would maximize the utilization of Maintain And Repair Contract?s.

May 1, 2003

By Peter J. Barnard

Mitochondria play a key role in the regulation of apoptosis (cell death) and in diseases characterised by abnormal apoptotic responses such as cancer. Mitochondrial membrane permeabilisation (MMP), regulated by the mitochondrial permeability transition pore complex, is widely accepted as being central to the process of cell death. As a result there has been considerable recent interest in targeting mitochondrial cell death pathways in the development of new chemotherapeutic agents.(1) There is potential to overcome the two overriding problems in cancer chemotherapy?the common occurrence of drug-resistant tumour cells and the lack of selectivity of cancer drugs in differentiating between tumour cells and normal tissues. Significantly, carcinoma cells have an elevated mitochondrial membrane potential relative to normal cells and lipophilic cations are concentrated within mitochondria in response to mitochondrial membrane potentials. There is potential for the selective targeting to tumour cells with compounds having optimal lipophilic-hydrophilic character. Research stemming from the early 1980?s points to two distinct classes of Au(I) phosphine antitumour agents where an antimitochondrial mode of action has been implicated: (i) neutral linear two-coordinate Au(I) complexes such as triethylphosphinegold(I) chloride and the tetraacetylthioglucose gold(I) phosphine complex, Auranofin; (ii) cationic tetrahedral bis-chelated Au(I) phosphine complexes related to [Au(dppe)2]+.(2) Recently it has been reported that Auranofin, at submicromolar concentrations, induces MMP observed as mitochondrial swelling and dissipation of membrane potential.(3, 4) Both events are completely inhibited by cyclosporin-A, the specific inhibitor of MMP. The permeability changes were shown to occur at concentrations associated with the selective inhibition of mitochondrial thioredoxin reductase.(3) Auranofin is a potent and specific inhibitor of this enzyme due to Au(I) binding to the active-site selenol group.(5) The redox state of mitochondrial thiols may be critical in the control of MMP.(3) In general, swelling is stimulated by thiol blocking or oxidising agents and is prevented by thiol reducing agents.(1) Mitochondrial thioredoxin reductase may play an import role in the redox control of the permeability of mitochondrial membranes.(3) Our interest is in investigating the antitumour potential of Au(I) phosphine compounds using a number of different approaches. In recent work we have evaluated a series of hydrophilic analogs of [Au(dppe)2]+ containing pyridylphosphine ligands which have demonstrated greater tumour selectivity than the parent compound. To investigate the possible antimitochondrial mode of action we are studying the effect of [Au(dppe)2]+ and related compounds on isolated rat liver mitochondria. To assess whether the lipophiliccationic nature of the compounds determines the antitumour activity, we have synthesized a series of novel Au(I) complexes based on heterocyclic carbene rather than phosphine ligands. The similar chemistry and structural features of the two classes of complexes allow us to assess whether the phosphine ligands are essential for the antitumour properties.

Oct 1, 2003

By Jeremy D. Glennon

A number of exciting challenges, opportunities and unanswered questions remain concerning the chemistry, geochemistry, medical, industrial and analytical applications of gold and its compounds.1 Among the challenges presented is the need for extraction methods for gold, at process and indeed analytical scales, that avoid the use of organic solvents or hazardous reagents. Extensive environmental contamination has occurred in the Brazilian Amazon from the mercury-gold amalgamation process. Major problems with the cyanidation process are the relatively slow dissolution kinetics and the health and environmental problems associated with it. With innovation and technical changes, a cleaner way for solubilising and extracting this versatile precious metal can be found. This cleaner future may lie in supercritical fluid science. Interestingly, geochemical studies of gold solubility and speciation in hydrothermal solutions have highlighted the importance of supercritical conditions and sulphur species in the deposition of gold in natural environments. Gold solubility in supercritical brines is far higher than previously supposed while interest in the high content of carbon dioxide in the mineralizing fluids is growing. 2,3 In recent years, also, there has been a tremendous amount of attention paid in analytical chemistry and in industry, to the area of supercritical fluid extraction (SFE) of organic and metallic species. 4 This interest has been fuelled by the introduction of more stringent environmental control and the subsequent need for cleaner solvents and processes to replace established ones. Carbon dioxide is the substance of choice for SFE because of its moderate critical parameters (Tc = 31oC, Pc = 73atm), inertness and availability in pure form. It is an excellent extraction medium for non-polar and moderately polar species, and with careful ligand design, it can be used for analytical and process scale metal extraction from solution and solid phases. In general, the dissolution of a metal in supercritical CO2 (sc-CO2) requires that the charge on the metal ion be neutralised on complexation by the ligand or through a form of ion pairing (analogous to the situation where metal ions are extracted into organic solvents, such as methyl isobutyl ketone or toluene). In this way, then, many chelating agents such as dithiocarbamates and hydroxamic acids have been utilised to extract metal ions such as Cu and Fe into sc- CO2, the process greatly enhanced by the use of fluorinated ligand derivatives. 5-7 In this review paper, we show that supercritical conditions and complexation with sulphur donor atoms, important in the natural deposition of gold, can form the basis of a clean, eco-friendly chemistry for gold extraction. Analytical scale extractions of gold from a variety of matrices can be conveniently used to assess the efficiency of any new proposed ligand.

Oct 1, 2003

By W. R. Middagh, R. M. Garvey

"Phosphate rock is shipped by boat from Florida to Vancouver, B.C., where it is unloaded and stored in a 50,000-ton silo. It is shipped from Vancouver in 100-ton hopper cars in 80-car trains to Fort Saskatchewan. Both the ship and the hopper cars are on a back-haul with potash. The rock cars are unloaded at Fort Saskatchewan at a rate of approximately 4 cars per hour. The rock is stored in three concrete silos, 40 ft in diameter by 110 ft high, which hold 18,000 tons of recoverable rock with 2,000 tons dead space. The rock is reclaimed from the silos by gravity and fed to the phosphoric acid plant by remotely operated conveying equipment.Problems encountered in the operation include scheduling the rock shipments, contamination of the rock with potash, and handling the 80-car trains both in Vancouver and Fort Saskatchewan."

Jan 1, 1968

By C. Bissue, G. M. Castillo

Newmont’s Phoenix mine started production in March of 2006. Due to the extreme hardness of the ore, the mill has struggled to meet throughput projections. Grinding studies showed that optimizing the existing circuit would not achieve budgeted throughput. These studies also showed that the pebble crusher was being underutilized due to the inability of the SAG mill to break the rock. The concept was developed to supplement the feed to the existing pebble crusher with a secondary crusher. Models of this process looked favorable so a portable crusher was installed to test the process. The temporary crusher was successful at increasing the throughput by 7% and based on the operating data, plans are currently being developed to install a permanent secondary crushing system in front of the SAG mill. This paper will review the results from the test crusher and the flow sheet for the permanent secondary crusher.

Jan 1, 2012

By T. Cutard, E. Cailleux, F. Nazaret, G. Bernhart

This paper deals with the study of the mechanical behavior in the 20°C-900°C temperature range of refractory concretes reinforced with metallic fibers. Fibers are introduced to improve the damage resistance and to minimize the quasi-brittle behavior of refractory concretes. In some cases, a plastic or ductile like behavior can be obtained. Two approaches are considered in these studies. The first one is based on the micromechanical scale. Main objectives are to understand, quantify and predict the thermomechanical behavior of monofiber microcomposites. Such considerations are helpful to optimize the composite formulation for a better behavior. The second one is based on the macromechanical scale. Main objectives are to characterize and to model the macroscopic thermomechanical behavior of randomly reinforced refractory concretes. A particular attention is firstly paid to the relationships between the microstructural changes and the mechanical properties and secondly to the structural size effects.

Jan 1, 2004

By S. R. Izatt

The use of MRT, a highly selective separations technology, has long been demonstrated to be a cost effective, efficient, and environmentally sound process for extraction of a wide range of anions and cations that are commonly found in copper electro - refining and electro - winning circuits, as well as in environmental treatment operations. This paper provides an update of commercial MRT applications in the copper industry. Several recent installations and test programs are reviewed including recovery of bismuth from tank house electrolyte, and from chloride matrix selenium reduction solution which is generated in the anode slimes treatment process. Recovery and refining of platinum group metals originating in the anode slimes is also discussed. Various other base metal and other target separations of interest to the copper producer are also reviewed. The recovery products are high purity metal salts which can be marketed directly or readily reduced to metal.

Jan 1, 2007

By D. MacGREGOR, VERA TUREK

The Badgeley Island quartzite deposir in Georgian Bay is worked by lndusmin Limired and was developed in 1969 to produce a high-qualiry silica for use in rhe ferrosilicon and glass industries. The quartzire is part of the Precambrian Bar River Formarion, and is a generally whire, fine-grained rock containing rhin sericire seams. Primary sedimenrary features wirhin the deposit are bedding and ripple marks. Amphibolite and diabase dykes cur the quarr zire body.

Jan 1, 1984

By M. Rigaud, N. Zhou, K. Sankaranarayanane, X. Zhou

The effect of amount and type of dispersants on the rheological behaviour of bauxite-based low-cement castables has been studied in detail. The rheological properties: flow resistance and torque viscosity, as measured by a rheometer, are found to be strongly influenced by the amount and type of dispersants. In the present investigation, a mix containing sodium hexametaphosphate, at an optimal level, is observed to be theologically superior at the given experimental conditions.

Jan 1, 2004

By D. W. Heard

Electrospark Deposition (ESD) is a low heat-input, high energy density, micro-welding process. The short pulse duration and high-pulse frequency, in combination with the small amount of material transferred during each pulse, results in the evolution of extremely rapid cooling rates, believed to approach 105-106 °C/s [1]. This rapid solidification event results in the refinement of the microstructure to the nanostructured or amorphous level [2, 3]. Figure 1 displays the resultant microstructure of an Al-17%Si alloy deposited by the ESD process. Furthermore, it was determined that the microstructure of the deposit remained unchanged after subsequent layers were welded onto the presented layer. Freeforming of materials is a rapid prototyping process in which the deposited feedstock is built-up to the desired geometry in a near-net shape manner. Figure 2 displays the automated set-up employed produce three dimensional freeformed objects via multiple deposition trials of the ESD process. The automated XYZ table is equipped with CNC software to transform CAD renderings into three dimensional tool paths. Figure 3 displays an Al-12Si freeformed gear (2" diameter, 12 teeth) produced by the ESD process, prior to removal from the substrate. An SEM analysis of the freeformed component showed that the microstructure did not coarsen during the deposition of subsequent layers during the freeforming process, as depicted in Figure 4, resulting in the production of a bulk nanostructured component. This paper represents a summary of the capabilities of ESD to fabricate advanced materials possessing refined microstructure. In particular, results on the microstructural evolution obtainable for various wear-related systems will be presented. In addition, the feasibility of using the ESD process to freeform three-dimensional objects via multiple deposition passes will be presented and accompanied by a characterization of the properties of the freeformed component. [1] R. N. Johnson, "ElectroSpark Deposition: Principles and Applications," in Society of Vacuum Coaters, 2002, pp. 87-92. [2] J. Milligan, D. W. Heard, and M. Brochu, "Formation of nanostructured weldments in the Al-Si system using electrospark welding," Applied Surface Science, vol. 256, pp. 4009-4016. [3] S. Cadney and M. Brochu, "Formation of amorphous Zr41.2Ti13.8NilOCul2.5Be22.5 coatings via the ElectroSpark Deposition process," Intermetallics, vol. 16, pp. 518-523, 2008.

Jan 1, 2010