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By S. McCarthy, K. E. Waters, A. Jordens

The beneficiation of rare earth (RE) element bearing minerals has become an active area of research as applications for these elements grow while the supply to non-Chinese consumers is restricted by export quotas. One of the most interesting beneficiation techniques for RE minerals is froth flotation as their unique chemistry suggests that collectors with a specific affinity for RE cations should be able to selectively recover these minerals. Existing literature, focusing mainly on bastnäsite flotation, identifies hydroxamic acids as excellent collectors for RE minerals. The high stability of hydroxamate-RE cation complexes is the explanation most often offered for the observed selectivity of these reagents in bastnäsite flotation however some research has also suggested that mineral solubility plays a crucial role in the success of hydroxamic acid flotation of RE minerals. This work investigates the interaction of allanite, a relatively insoluble RE-silicate mineral, with benzohydroxamic acid using zeta potential measurements and microflotation. The effects of Fe(III) and Fe(II) ions as potential activating ions (cations that form stable hydroxamate complexes) on benzohydroxamic adsorption to the allanite surface are investigated as a potential solution to promote hydroxamic acid adsorption. The results indicate that the optimum conditions for separation of allanite from quartz occur at pH 4 using FeCl2 as an activator for benzohydroxamic acid adsorption.

Jan 1, 2014

By Gerhard Kircbner, Boen Tan

"IntroductionThe Key Lake uranium-nickel ore deposits are located in the Athabasca Basin of northern Saskatchewan, Canada (Fig. 1). Many papers have been published on Key Lake in the past (Dahlkarnp and Tan, 1977; Kirchner and Tan, 1977; Kirchner et al., 1980). Immediately after its incorporation in 1968, Uranerzbergbau GmbH, a German holding company, set up exploration subsidiaries in Australia, the United States and Canada. This account reviews those exciting years starting with the concept to explore the rim of the Athabasca Basin in Saskatchewan, and leading up to the discovery of the deposits in 1975 and 1976.A few summary statements can be made:• The discovery of Key Lake resulted from a very systematic exploration approach and the persistence of Uranerz, the operator. • Cluff Lake and Rabbit Lake had been discovered some seven years before, but it was the discovery of the Key Lake deposits which brought Saskatchewan to the forefront to become Canada's foremost uranium producing province.• The experiences gained at Key Lake, which were subsequently published, triggered the discovery of many other deposits of similar, or even larger, size than Key Lake. The spatial relationship of those deposits to graphitic conductors and hydrothermal alteration zones are presently the most effective indicators for locating new deposits - indicators which were first recognized at Key Lake.• Key Lake is, and will remain for some years to come, the largest producing high-grade uranium mine in the world."

Jan 1, 1994

By G. E. Agar, R. Stratton-Crawley

"The applicability of a hydrocyclone model to simulation of the cyclone banks in a multi-stage sandplant circuit producing mine back fill has been demonstrated. The model ha~; been used in conjunction with a modular computer program for circuit simulation in order to study the effect of changes in the operating conditions. It has been shown that weight recovery to sand fill increases as feed percent solids decreases, and, to a lesser extent as pressure drop across the banks increases. An increase in apex diameter also causes an increase in weight recovery. Increased weight recovery must, however, be balanced against sump an1l cyclone capacity and dilution of sand fill by fines. The predicted results from circuit simulation were in good agreement with plant data.The model has been found to be applicable to widely different ores."

Jan 1, 1979

By A. Putz, F. Vincent, A. R. Laplante

"This paper briefly reviews some of the gravity research done at McGill University and current Canadian operating practices, with emphasis on results of interest for operators. The following topics are addressed: security, economics, predicting recovery, circuit optimization, unit selection and final upgrading. Emphasis is placed on the Knelson Concentrator.The topic of security and economics are addressed jointly, in terms of the place of the gravity circuit in the mill flowsheet. Actual plant experience is drawn upon to identify potential problems and actual solutions.Predicting primary recovery is linked with a characterization of the ore, the choice of a circuit, and the fraction of the bleed used. Factors such as feed preparation, preliminary upgrading, fraction of recycle treated, ability to recover fines and location of the bleed are discussed.Final upgrading is achieved almost only by tabling and smelting. This can lead to fine gold recovery problems when more effective units are used upstream. Alternatives are discussed.IntroductionResearch on gold recovery by gravity over the past eight years has associated McGill University with a number of gold producers. This paper attempts to review the information gathered from a practical perspective. Some of the information was generated in McGill University's labs, some gathered at plant site, and some was shared by operators."

Jan 1, 1994

By Antonio Laguna

During the past few years, synthetic efforts have been addressed to the synthesis of polymeric materials with optical or semiconducting properties or even with capabilities to act as sensors for volatile organic compounds (1). The most recent studies have been concerned with the synthesis of heterometallic systems with short metal-metal interactions and the determination of their optical properties. These complexes are undoubtly interesting from a theoretical viewpoint and include an emerging class of luminescent materials, in which the observed luminescence results mainly from the interactions among the different metal centers, as well as the environments of these atoms. The understanding of the photophysics and photochemistry of these products could permit the design of complexes with appropriate metals and ligands chosen for individual applications. Following a synthetic strategy consisting on reactions between acid heterometal complexes and basic gold precursors we have succeded in synthesizing supramolecular assemblies formed via acid-base stacking, which display tunable luminescence or selective and reversible sensitivity to Vapour Organic Compounds (VOC?s) (2-5). In this sense, in accord with previous Mössbauer studies carried out in the gold precursor complex [AuR2]- (R = C6F5), the basic properties of this and related materials have been employed as building blocks of supramolecular assemblies in their reactions with complexes in wich the metallic centers act as lewis acids as, for instance, Tl(I) or Ag(I) (6). For instance, in the case of silver, by reacting equimolecular quantities of [NBu4][Au(C6F5)2] with AgClO4, in acetone, a solid of stoichiometry [Au2Ag2(C6F5)4(OCMe2)2]n is obtained. The polymeric nature of this material in solid state is confirmed through X-ray analyses (figure 1). It consists of polymeric chains formed by repetition of Au2Ag2 moieties linked through short gold-gold interactions. Nevertheless, in solution, the nature of this polymeric materials was still a matter of controversy and, in this case, the optical properties have been shown as useful tools in order to obtain information. Thus, while dilute acetone solutions of this complex give a emission coming from pentafluorphenyl localized ??* excited states, in accord with the presence of isolated tetranuclear Au2Ag2 units, when the measurements are done at different and higher concentrations, a band that does not obey the Lambert-Beer law appears. This deviation is consistent with molecular aggregation in solution of these units through gold-gold interactions, and a clear correlation between the emssion wavelength and the structure in the solid state and in solution is shown (figure 2). DFT calculations accord with the observed experimental behaviour and show the nature of the orbitals involved in each transition.

Oct 1, 2003

By James A. Deeks

"Motor failures and equipment bearing failures are responsible for reduced productivity.With the introduction of computers and data acquisition systems, users are now able to monitor, report and trend deteriorating conditions and take corrective action before a critical shutdown occurs.This paper discusses the monitoring and trend analysis of' motors, and motor and equipment bearings. With today's digital electronics technology users are now able to monitor their equipment, detect deteriorating or abnormal conditions quickly, alarm the condition locally and or remotely, and decide if immediate corrective action is necessary or if it can be delayed until the end of a work Shift. All of this can be done long before any damage is done to the equipment.Monitoring Trend AnalysisIt is no longer necessary to compromise in selecting products, since state-of-the-art designs allow the adjustment in such small increments that the users are able to detect minute changes in a system's performance.Monitoring and trending of motors and equipment bearings is now available in economical packages which can be expanded as a system grows. Simply select the information you need, set the parameters, choose the scan time, and decide on the degree of reporting.Buffer storage of short-term monitoring of a number of analogue channels permit the user to view the recent history of motor data such as: motor average load, unbalance, motor current, ground fault, reserve thermal capacity, plus all of the settings of the protective device.A decision can be made to freeze the stored information after the motor stops or after the motor starts. Then the user is able to recall the conditions and diagnose the performance and the cause of the abnormal condition. Typical scan times range from ¼ second to 5 seconds ."

Jan 1, 1992

By J. A. Eisele, D. L. Pool

"The Bureau of Mines has developed a particle agglomeration technique to improve the flow of leaching solution through heaps of low-grade gold-silver ores which contain clays. Benchscale experiments and industrial practice have shown that the percolation rate of cyanide leaching solution is greatly enhanced by mixing the ore with Portland cement as a binder, moistening the mixture, mechanically tumbling to form agglomerates, and aging before heap building and leaching. A slight modification ofthe technique allows its application to precious-metal-bearing tailings, which cannot normally be treated by heap leaching because they are too fine. IntroductionMany low-grade gold and silver deposits and tailing materials from former mining operations in the western United States are potential sources for precious metals. These sources are too low grade or too small to support the capital cost of a conventional cyanidation plant but have stimulated the development of lowcost procedures, such as extraction of the precious metals by heap leaching with cyanide. The Bureau of Mines has investigated methods to improve the recovery ofgold and silver by heap leaching these low-grade materials.For heap leaching to be successful, the crushed and stacked ore must have good permeability so that uniform distribution of the cyanide leaching solution through the heaps can be achieved. Some of the most difficult gold and silver ores to treat by heap leaching are those containing excessive amounts of clays, or fines generated during crushing. Excessive amounts of slimes, generally minus 50-micrometre or 270-mesh Tyler sieve size particles, in the heap feed will slow the percolation of the leaching solution, cause channelling, or produce dormant or unleached areas within the heap, resulting in long leaching periods and low extractions. In extreme cases, the clays or slimes can seal the heap and cause the leaching solution to run off the sides of the heap rather than through it."

Jan 1, 1987

By David L. Sprott

This paper presents an evaluation of underground-to-surface haulage options for a relatively large deposit. Specifically, it presents a recommended haulage option to provide the greatest value to the Project. Options considered included conventional truck, trolley-truck, conveying and shaft hoisting. The work was done at the level of a preliminary assessment as input to an internal pre-feasibility study. The Base Case for the analysis in this study was a Long Hole Open Stoping option (LHOS) using conventional truck haulage. Two scenarios were considered for the evaluation and included: 1. The current resource to ~700 m depth. 2. An expanded resource to ~825 m depth. The haulage options evaluated included three trucking options, three conveyor options and two shaft options. The paper presents the results from evaluating these options within the two mining scenarios using a Discounted Project Cost (DPC) comparison. Recommendations are made for the options that will provide the greatest overall value to the project.

May 1, 2008

By William E. Stanley

The paper examines the problems that arise in undertaking socio-economic impact studies to meet the requirements of environmental-impact legislation governing new mine development or expansion. An approach to undertaking socioeconomic impact studies is outlined, responses to specific problems are discussed and ways in which the mining company can use these studies to meet its general objectives are explored. The paper concludes by examining how a socio-economic study, as required by legislation, can be used to assist the mining company in achieving some general objectives it will have in developing a mine.

Jan 1, 1979

By L. Nutter, J. Clancy

"Barite is used extensively by the oil and gas well-drilling industry as a weighting agent. It is particularly well suited for drilling mud because of its qualities; it is non-abrasive, heavy, virtually inert chemically, easy to handle and inexpensive compared to other available heavy materials. Increased deep well drilling in Western Canada, and especially in the Arctic regions, could dramatically affect the demand for barite through this decade. Known deposits in northeast British Columbia are possible sources of incremental barite supplies, should the situation develop.IntroductionThe purpose of this report is to examine the opportunities for expanding barite production in British Columbia. Of primary interest will be the relationship between the projected future levels of production and consumption of barite in Western Canada and the extent to which increased domestic production could replace the need for imports in filling any expected supply shortages.After a brief overview of the nature and uses of barite and some of the relevant features of the barite supply industry, the discussion will turn to the supply gap in the Canadian market and the possibilities for import substitution.OverviewBarite is an industrial mineral which is used in large quantities by the oil and gas well-drilling industry. It is often an important component of drilling mud, a fluid circulated continuously in the well during the drilling process to lubricate and cool the drilling apparatus and to contain the high oil and gas pressures found at depth. Barite (BaSO4) is particularly well suited as a weighting agent for drilling mud because it is a heavy (specific gravity to 4.5) inert mineral which is inexpensive in relation to other materials having a high specific gravity. In the on-site use of drilling mud, ground barite is combined with numerous other solid ingredients and chemicals in the form of a slurry. Other advantages of barite include cleanliness, ease in handling and its non-abrasive character (hardness of 3-3.5)."

Jan 1, 1982

By Lee Nichols

The Oil Sand Industry in northern Alberta, Canada, disposes of the by-products of bitumen extraction into tailings ponds. The mix of tailings sand and mature fines, with gypsum added as a flocculent, constitute a waste stream called Consolidated Tailings or Composite Tails (CT). The two main challenges of the tailings disposal process are a chronic shortage of economical containment and the potential mobility of CT deposits in the event of breaching by, for example, long term erosion, which makes abandonment of tailings ponds more complicated. Thick deposits of CT do not consolidate in adequate time to provide reassurance for abandonment of the CT containment facilities and that is why the containment must be adequately robust or the properties of CT improved for long term stability. This paper addresses potential solutions to these problems by applying the gravity drainage of CT and quasi-homogeneous construction for containment facilities. Gravity drainage is suggested as a mechanism to facilitate the consolidation of CT in critical areas of the ponds by inserting internal sand layers within the body of the deposit. Critical CT areas are defined as areas around the perimeter of containment. The advantages of this solution are long-term stability of the disposal area by creation of stiff deposits around its perimeter and facilitation of reclamation efforts on its surface. The present solution for containment of CT deposits is not favourable from a materials balance point of view. In general, sand has become a valuable resource as it both forms the primary component of the CT matrix and becomes the containment building material. If sand is required for CT, less is available for dyke construction. This puts additional pressure on the industry as a whole to maximize the use of overburden and interburden for construction of tailings containment structures. Typically, only 50 percent of dry mine waste (overburden + interburden) is incorporated into dyke construction. The remainder of dry waste is stored either in waste dumps or in tailings ponds, consuming valuable in-pond space originally allocated to CT material. Quasi-homogeneous dykes are proposed to contain CT deposits rather than traditional minimum cross-section dykes built of overburden and/or cell sand. The quasi-homogeneous dyke may change the unfavourable material balance and lessen the construction constraints that are presently imposed on the mine/waste disposal process.

May 1, 2004

By A. L. Williamson

Bio-mining is a cost-effective, energy efficient and potentially environmentally protective method of exploiting a variety of ore deposits, from high-grade base metal deposits of nickel to lower-grade uranium and rare earth deposits such as are found in the uraniferous quartz-pebble conglomerate beds of the Quirke Syncline, Elliot Lake, Ontario. The effectiveness of bio-mining in Elliot Lake depends on the success of bacterially-influenced dissolution of metals of economic importance. The determination of both the dissolution efficiency and rate controls for uranium and rare earth elements from bio-extraction processes is critical to assess the potential for success of bio-mining along the Quirke Syncline. This poster provides an overview of proton-mediated biogeochemical dissolution of more than 50 elements, including uranium and rare earth elements from samples of the low grade uraniferous ore collected as drill core from the Elliot Lake area. The elemental data is quantified using advanced spectroscopic tools (ICP-MS and ICP-AES) to analyze solutions obtained from a series of environmentally controlled biologically-mediated uranium ore extraction experiments. The findings are being to guide design of larger scale bio-leaching experiments to further assess the potential for success of bio-mining along the Quirke Syncline.

Aug 1, 2010

By J. W. Merks

"The accuracy of a measurement on minerals and ores can be assured by applying suitable and unbiased procedures but its precision is a function of the number of primary increments and their mass, the number of lots per consignment or samples per shift, and the number of measurements on analysis fine samples.Experimental data will be used to show how the variance components for sampling, sample preparation and analysis contribute to the total variance on which precision statements for the final measurement are based. This type of experiment should not only form part of quality control programs at mines and smelters, but also underly the criteria on which the design of manual sampling regimes and mechanical sampling systems for bulk solids and slurries should be based.Sampling systems and regimes can only be adjusted and optimized if the variance component for each step in a quality evaluation process is measured. Knowledge of precision characteristics lies at the core of effective loss prevention and control programs."

Jan 1, 1985

By Weimin Fu

Chondrite-normalized rare earth elements (REEs) profiles and high field strength elements (HFSEs) in rocks and minerals represent important tracers of geological processes. Of these the birdwing-shaped profile with negatively-sloped light REE ((La/Sm)N >1), positively-sloped heavy REE ((Tb/Yb)N <1), and strong negative Eu anomalies is commonly associated with large-scale hydrothermal systems or granitic intrusions. In a different way, severe deviation of Nb/Ta, Hf/Sm ratios from those of chondrite may also indicate hydrothermal signatures in the rocks involved as these ratios are generally stable and chondritic in normal magmatism as a result of their nearly identical ionic radii and charge. In this study, we present a typical setting where birdwing-shaped REE profiles together with Nb/Ta, Hf/Sm ratios unusually higher than those of chondrite, are systematically developed in a series of garnetite, quartzofeldspathic gneiss, Fe- or Mg-rich aluminous gneiss, and sulfides and magnetite. These units and associated Cu-Au mineralization form a VHMS-style hydrothermal system in the granulite-facies 1.4 Ga -1.35 Ga volcano-plutonic, arc-related Bondy gneiss complex (BGC), western Grenville Province, Canada. Outside the recognized hydrothermal system of the BGC, such REE profiles are not observed. Instead the surrounding felsic and mafic gneisses display primary trace element characteristics of island-arc magmas, suggesting that granulitefacies metamorphism did not modify significantly the trace element signatures of the protoliths. Although magmatic fractionation of accessory minerals can produce birdwing-shaped profiles, it cannot explain the extreme fractionation of isovalent trace elements (Nb-Ta) and the high Zr content of the hydrothermal rocks. Neither is it compatible with the lack of significant Nd depletion that would normally incur during this process. Following our study, we demonstrate that F-rich fluid and mineral phases enriched in LREEs and HREEs respectively must have been involved in the main hydrothermal alteration and REE fractionation process in the BGC. Preferential removal of REEs from the interstitial glass of the volcanic protoliths together with dissolution of plagioclase and subsequent external influx of HREEs and HFSEs can produce birdwing-shaped REE profiles. In turn, such profiles and/or unusual Nb/Ta, Hf/Sm ratios can be used as a sensitive marker of hydrothermally altered rocks in targeting mineral exploration.

May 1, 2003

By BARRY BANNATYNE

Non-swelling bentonite has been quarried in Manitoba by Pembina Mountain Clays Limited since 1941. It occurs in several thin layers near the base of the Pembina Member of the Upper Cretaceous Vermilion River Formation, and is quarried from the narrow outcrop belt along the slope of the Manitoba Escarpment. It is marketed both as natural and activated bentonite for a variety of specialized uses. Percolation of acidic water through bentonite has produced a naturally activated bentonite with good absorbent properties; these properties are enhanced by treatment with sulphuric acid to produce an activated bentonitefor decolourizing petroleum and vegetable oil.

Jan 1, 1984

By W. E. Johnston

At last year&apos;s Annual Meeting a paper by Haultain and Johnston was presented entitled Is the Gold in Tellttrides Soluble in Cyanide? Since then the writer has continued the study of various phases of this problem. Samples and specimens of ore from some of the Kirkland Lake mines have been studied and non gold-bearing tellurides have been found in these that are not soluble in ordinary mill solutions. Samples of tailings, both old and recent, from this district have been examined with apparatus and methods that have proved very successful in detecting the presence of extremely minute quantities of tellurides. Tellurides, both base-metal and gold-bearing, have been discovered in these tailings, but only in such minute quantities that their presence would not affect the ordinary assay results. More free gold particles have been found in the tailings than gold-bearing tellurides. Much experimental work has been done on tellurides, concentrated from high-grade material and from ordinary run-of-mine ore. The gold-bearing tellurides behave very much as does gold itself. Finely divided particles are dissolved fairly rapidly, coarser particles more slowly. All the tellurides are soft and brittle and also have a high specific gravity, with the result that they are extremely finely divided in ordinary mill practice. The ordinary high-lime solution of Kirkland Lake practice is suitable for the dissolving of the gold tellurides. Oxygen is necessary, but apparently not more so than in dissolving gold. Some particles have been found that appear under the microscope to be ordinary metallic gold particles, but on heating they show a small telluride content. These appear to dissolve more slowly than gold. There is considerable variation in the ratio of tellurides to gold from different points in the mines. So far the writer has failed to find any connection between this ratio and the richness of the ore. Generally speaking, the base-metal tellurides predominate. Some of these contain gold but this may be due to a mixture of tellurides in the one particle.

Jan 1, 1933

By Frank Wright

"The Icon Sullivan Joint Venture ore deposit was discovered in June, 1965 by Messrs. Paul Benard, Bob Galipeau and Mac Watson working under the direction of Mr. Andrew J. Troop, as employees of the Icon syndicate. The deposit is located on the Waconichici River as the south end of Baie du Poste of Lake Mistassini, approximately 45 miles north of Chibougamau. Property acquisition and Winkie drilling was followed by a diamond drilling program to evaluate the deposit. Stripping of the open pit area connnenced in the late fall of 1966 and the first test sample of ore was shipped to Chibougamau in December of that year.Regular ore shipments to the mill of Merrill Island Mining Corporation Limited for concentration commenced May 25, 1967. Production to December 31, 1970 amounts to 42,960,000 pounds of pay copper.The ore is chalcopyrite in white quartz dolomite, and it contains a very small amount of precious metals. The quartz dolomite assumes a flat to gently dipping attitude and is associated with a graphitic argillite contact zone on both hanging and footwall sides, in dolomitic limestone rocks. There is practically no other sulphide present in the ore.During the summer of 1969 a series of pre-concentration tests were completed and a Wemco heavy media sink float plant was installed in late 1969 and early 1970. This pre-concentrator eliminates at least one third of the ore mined in the form of barren quartz dolomite prior to ore shipment by truck to the concentrator in Chibougamau."

Jan 1, 1971

By D. T. Smith, S. J. Strohmayr

Originally developed as a step change in ultrafine grinding efficiency, the IsaMill™ has made inroads into conventional ball mill and tower mill mainstream grinding duties during the last 5 years - beginning with the Anglo Platinum mainstream grinding projects in South Africa. At the 2006 SAG Conference, plant testwork on the incorporation of IsaMill™ technology into the McArthur River (Northern Territory, Australia) Pb/Zn primary grinding circuit was reported. The IsaMill™ has now become an integral component of that circuit, treating up to 1mm top size feed and directly producing P80 45 µm rougher flotation feed. Two 1.1 MW IsaMills™ are now used in this duty contributing to a 27% increase in overall plant throughput and a reduction in rougher feed size distribution. In this paper, we report on the current state of development and performance of the IsaMill™ in the primary grinding duty at McArthur River and also consider future directions.

Jan 1, 2012

By Arne Renström

A fleet management system such as Minestar with CAES and Aquila could basically be defined as a tool for production control and distribution of drill and load maps, but should also be considered as continuous improvements and a never ending production study. The objective of production studies is to establish facts to be used for production improvements. In a mine operation there are many issues to improve and they spread from achieving productions plans, drilling precision, improved spotting while loading to equipment utilisation. This gives that there is not one single key value to present; we need to manage information presented on maps, as trends, graphs, tables and pre-calculated data for ?free-use? normally in spread-sheets to be able to turn data into useful information.

May 1, 2003

By Edgar L. Horner

"The objectives of the Wabush Mines tailings stabilization program are to control dust Ii/t-off and to rehabilitate the disposal area. The evolution of the program started with test plots in 1970, these being continued and expanded upon through 1974. In 1976, a 35-acre vegetation field trial was attempted and failed, part of the failure being attributed to lack of adequate equipment. Subsequently, equipment was purchased and during the summer of 1979-80 extensive areas were treated. The program was also expanded to include the evaluation of chemical and water spray stabilization versus vegetation in areas where shorter-term control is required. In addition, during the summers of 1979-80, spruce bog material was spread over about 100 acres and seeded.The approach to reclamation by vegetation at Wabush is one of soil building. Work to this point indicates that iron ore tailings can be converted to a soil capable of supporting plants. Plans for the Wabush tailings disposal area should make dust lift-off from inactive tailings areas negligible within the next few years."

Jan 1, 1981