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By R. del Villar, A. R. Laplante

"This article presents four grinding simulation programs, written in Applesoft BASIC. The firs t two calculate residence time distributions (RT Ds) for open and closed loops mills. The third program calculates the select ion functions from the RTD, breakage function and particle size distribution (PSD) o f the feed and discharge. Two linear regression programs are also included to calculate the breakage function. These results are used in the fourth program to simulate continuous or batch grinding kinetics.The modelling approach presented is the size discrete, time continuous matrix formulation presented by Reid (1965) from concepts originally proposed by Epstein (1948). It is at the present time the most widely accepted phenomenological model of grinding kinetics and is standard textbook material (Austin et 01., 1982; Kelly and Spottiswood, 1982, p. 152). The concepts of RTDs and tracer testing originated from chemical engineering theory and practice, and are well presented in Leven spiel (2n d Ed . 1972 , Ch. 9) .Applesoft* was chosen because it is compatible with many micro computers. It is also one of the simplest and least powerful BASIC versions. Thus it can easily be adapted to other more complex BASIC versions.Open Loop Residence Time Distributions (Program RTDOPEN)As mixing, channelling, stagnation and short-circuiting all affect slurry motion in tumbling mills, transport characteristics are very complex an d cannot be derived from fundamental principles. Fortunately , as grinding follows first order kinetics, transport characteristics for the purpose of grinding simulation ca n be represented by the RTD of the slurry phase . It is normally determined using liquid tracers, as it has been demonstrated and is commonly accepted that in industrial ball mill s, the RTD of the so lid phase is particle size independent and equal to that of the liquid phase."

Jan 1, 1985

By Jaime V. Ongpin

"The author will give a capsule history of Benguet Corporation and attempt to identify its operating environment and underlying ""strategy"" until 1974, when the company's management assumed office. The company's operating environment and ""interim strategy"" from 1975 to 1980 will be described. The discussion will cover an environmental forecast and define the company's"" strategy for survival"" for the balance of this century.IntroductionIn December last year, I was asked to deliver a pa per for the management lecture series a t the Asian Institute of Management in Manila. The paper was entitled "" The 1970's: A Decade of Disaster For New Mining Projects"" . In that paper, it was my task to review the results of new mining projects in the Philippines during the previous decade. The task was not a happy one, for the results themselves were not only unhappy, but disastrous on a scale unprecedented in Philippine history. Out of a total of 17 major mining project s involving an aggregate capital investment in excess o f US $2 billion during the 1970s, only three project s have been profitable, and all the rest have either gone "" belly up"" or are teetering on the very edge of financial disaster.It is in the context of this shocking record of widespread financial dislocation in the Philippine mining industry, (which in varying degrees appears to have been paralleled in virtually every other country in the world where mining is an important sector of the economy) that I address myself tonight to the theme of this symposium. My paper is entitled ""Risk Management Strategy in Mining"" and it is sub titled ""Can Benguet Corporation Survive to Celebrate its Centennial in 2003?"". I have inserted the word ""Strategy"" and added the subtitle, because I wish to make it clear first, that my presentation to you tonight will be focused exclusively on the strategic aspect s of risk management, and second that I will limit myself to Benguet's own ""in-house"" experience and perspectives on this subject. I would caution you therefore, to consider my views within this restricted framework, and in light of the particular and sometimes peculiar circumstances within which Benguet Corporation operates."

Jan 1, 1983

By T. H. North, A. G. Glover, R. J. Pick

"Girth welding operations represent the rate-limiting step in pipeline construction. A joint industry-university program was set up to establish the field welding characteristics of large-diameter, high-strength line pipe.Theoretical work carried out at the University of Waterloo showed that pipe wall thickness and joint misalignment prior to welding has a marked influence on the lifting stresses acting on the root pass of girth welds. Pipe diameter and pipe ovality had negligible effects. Super-position of lifting and residual stress (caused by the fusion welding operation) highlighted regions of the weld bead most susceptible to hydrogen-induced cracking.The field welding characteristics of 1219-mm-diameter, 13.72-mm-wt Grade 483 line pipe were evaluated using a specially designed test rig. The principal test variables were lift height, delay time after root pass deposition, preheat temperature, pipe composition and joint misalignment prior to welding. For any given life, preheat and joint misalignment prior to welding had the most significant effect on cracking tendency.The output of this program has industrial significance and illustrates the beneficial features of university-industry collaboration.IntroductionField welding operations comprise the rate-limiting step during pipeline construction. Crack-free girth welds must be made in a wide range of weather conditions and consequently the field weldability of line pipe compositions directly affects pipeline integrity and construction economics.Pipe-laying practice comprises root bead deposition followed by a skidding operation involving lifting (or lowering) the pipe length onto skid s so that the next pipe length can be aligned prior to welding. Consider pipeline construction using 24.4-m lengths of 1219-mm-diameter , 13.72-mm-wt Grade 483 pipe weighing approximately 10,000 kg. Skidding involves loading a 3-mm-thick root bead by moving the free end of the pipe through vertical distances of up to 700 mm . The likelihood of cracking in these circumstances depends on the inherent crack susceptibility of the pipe composition employed, on the hydrogen content of the deposited weld metal and on how well the joint handles the external stressing caused byskidding."

Jan 1, 1981

By Stephen G. Hardcastle, Michel G. Grenier

"Safety and health issues are and have been in the last decade a very high priority item with all parties involved in the Canadian mining industry. As a result of this high level of concern for workers' safety and health, Canadian mines are at the leading edge of environmental control technology. For the most part, the occurrence of pollutants in mines is unavoidable. Dust from mining operations, airborne radiation, gases and heat from the strata as well as gases and particulate from diesel engine emissions will undoubtedly be found to some level in most Canadian mines. A lot of work remains to be done, however, in order to bring all Canadian mines at the same level of proficiency when it comes to safety and health. Also, more work is needed in order to maintain our status as world leaders in this field.CANMET's Mining Research Laboratories (MRL) in Elliot Lake and Bells Corners, Ontario, with the cooperation of the mining industry, have contributed to improving environmental conditions in underground and surface mining and milling operations. The extent of collaboration and efforts vary widely from long-term, multi-million dollar projects between several interested parties to smaller projects involving one laboratory and a single mining operation. This paper gives examples of such collaborative efforts and potential future directions as they apply to: mine ventilation analysis using tracer gas techniques, optimization of mine ventilation network efficiency using real-time monitoring and controlled recirculation (heat saving), respirable dust and radiation sampling and control techniques, diesel emission control using regenerative ceramic filters and, finally, the control of sulphide dust explosions and resulting sulphur dioxide production."

Jan 1, 1990

By L. M. Ame, W. D. Harwood

"This paper outlines a management philosophy aimed at promoting employee involvement, quality and process improvement at Inco 's Thompson operations. It describes the use of statistical process control techniques, lessons learned and examples of progress.IntroductionThis paper provides an overview of the Manitoba Division's performance through the promotion of greater employee involvement, quality and process improvement. Having learned from other practitioners o f quality management, the Manitoba Division believes its experiences are applicable to all mining and other businesses.The Thompson operation consists of two underground mines, an open pit, a mill, a smelter and an electrolytic refinery. The workforce consists of 2000 members. The main products are electrolytic nickel slab and proprietary nickel rounds. Production levels are currently at capacity in response to heavy market demand.Paralleling much of the mining industry the corporation was faced with six years of decreasing nickel prices (Fig. I). Inco Limited survived by focusing on productivity and cost improvement. Manitoba Division productivity improved 32070 over three years beginning in 1982-the worst financial year in the company's history (Fig. 2). A real unit cost reduction of 20%, net of inflation, was also achieved (Fig . 3)."

Jan 1, 1990

By G. M. Ritcey, M. Silver

"The processing of uranium ores produces tailings that could constitute environmental problems. At most operations the tailings are dumped into a designated area, with the ultimate acid drainage occurring if sulphides are present, together with the release of metal constituents to the rivers and streams. If the chemical reactions occurring within the tailings could be predicted, perhaps methods could be developed to either increase or decrease 'the rates of reaction. One such study has been in progress at CANMET during the past three years. The paper describes the use of Iysimeters containing low-grade and complex uranium tailings to determine the effects and interactions of bacteria, sulphides and solvent extraction organics on the release of radionuclides and on acid production. A simulated rain cycle nine-fold the normal was used and the Iysimeters were subjected to timed intervals of light and darkness. As a result, the tests simulated a 25-year period.IntroductionAlthough Canadians derive major benefits from uranium, there are environmental and health consequences, not yet fully understood, from the associated mining and milling operations. A major project at CANMET (Canada Centre for Mineral and Energ y Technology) has the ultimate goal of ensuring that any adverse effects on man and environment, now or in the future, resulting from the processing of uranium should be acceptably low. The magnitude of the task was exacerbated by the fact that the increased demand for electrical energy and the resultant increased prices for uranium oxide during the 1970s led to a rapid expansion in the industry. Annual world demand for uranium was expected to increase 12-15 fold in the next quarter century, with annual requirements of between 200,000 and 300,000 metric tonnes anticipated by the year 2000. Currently, the demand is low and the prices for the oxide have decreased."

Jan 1, 1982

By John E. Udd

"Mining research at CANMET is delivered by the Mining Research Laboratories Division (MRL), with facilities in Sydney, Nova Scotia; Bells Comers, Elliot Lake, and Sudbury, Ontario; and Val d'Or, Quebec. This paper gives an overview of the work of the Division as of early 1993. An addendum, at the end of this paper, describes the organizational changes that will take place in April 1994. IntroductionCANMET, the acronym for the Canada Centre for Mineral and Energy Technology, is the name by which the organization founded in 1907 as the federal Mines Branch is presently known. The name was changed in 1974, in order to give recognition to the importance of both minerals and energy technologies in the activities of the Branch. Further reorganizations have taken place since 1987. As a result of these, CANMET has assumed the status of a Sector (equivalent to the Geological Survey of Canada) and has been organized into four branches.The organization as a whole functions in an environment of semi-matrix management. Some of the ""line"" Divisions report to Directors-General for the appropriate branches while other, larger divisions, report directly to the Assistant Deputy Minister.The second dimension of the organizational matrix is composed of a number of ""staff' divisions which report to the DirectorGeneral for Policy and Planning. Each of these Divisions performs a function which is common to all of the ""line"" divisions. For example, the Research Projects Office is responsible for monitoring the range of research activities of CANMET and for recommending allocations of funds for both research contracts and operating budgets. The Library and Documentation Services Division is responsible for CANMET publications and information services. Likewise, the Engineering and Technical Services Division provides support through, among other services, the construction of specialized laboratory equipment."

Jan 1, 1994

By C. Arson

We modeled mode I fracture in shale with an equivalent damage zone (CDM), a cohesive zone (CZM) and discontinuous enrichment functions (XFEM). In the Differential Stress Induced Damage model (DSID model) used in the continuum approach the total work input is equal to the sum of the energy released by crack debonding, the energy dissipated by crack opening, and the elastic strain energy stored in the bulk outside of the damage zone. In CZM and XFEM, the overall stiffness of the rock mass in the process zone drops as soon as the fracture starts propagating (unstable fracture propagation), whereas rock elastic properties in the CDM equivalent damage zone evolve smoothly with the displacement imposed at the boundary of the domain. In the CZM and XFEM, fracture propagation stabilizes after a turning point: this point coincides with damage initiation in the DSID model. As a result, the total energy of the rock mass calculated with CDM is about twice as large as in CZM and XFEM. The relative energy components of the rock mass are in the same order of magnitude and follow the same trends in the three models. This numerical study compares the evolution of dissipated energy potentials during mode I fracture propagation, and is expected to provide a basis to predict the amount of energy released by discrete fracture growth vs. damage propagation in the fracture process zone.

Jan 1, 2015

By Chris Brothen

The introduction of new technology in mine operations has provided real opportunities for increased efficiencies and production gains which translate into enhanced profits. Computing and network technology usage has become integrated into surface mining operations and on average these investments in technology have proven beneficial for efficiency and productivity improvements. Embracing new technologies however, does not guarantee positive results. The expectations or improvements derived through the technology must be confirmed and clarified well before implementation. Tire Pressure and Temperature Monitoring Systems are an excellent example of an existing technology that can provide full time automated performance measurements of tires operating under harsh conditions and environments. Prompt warnings or alarms signaling when a tire has exceeded operating capacities will provide savings through lowered maintenance costs and increased productivity. To truly quantify the projected savings in tire life, fuel consumption, and increased levels of production, all costs associated with the technology, both direct and indirect must be considered. Apart from the initial cost of the system implementation, ongoing maintenance and support costs must be considered as well as the costs of system integration into existing mine operations

May 1, 2008

By J. G. Peacey

"Canada has a special place in non-ferrous pyrometallurgy because it is the only country in the western world that is a significant producer of all the major non-ferrous metals; aluminum, copper, lead, magnesium, nickel and zinc. This large non-ferrous pyrometallurgy industry has developed because of Canada's abundant mineral wealth and energy resources. Table I summarizes the number of primary non-ferrous production facilities in Canada and their share of western world production.Production of non-ferrous metals is a mature, capital intensive business and its basic processes have been in use for many years. Nevertheless, these processes have continued to evolve in response to changing needs and external pressures; such as the energy crisis of the early seventies; historically low metal prices in the early eighties and the continuing pressure to reduce plant emissions and improve in-plant working conditions. Canada's major metallurgical companies: Alcan, Cominco, Falconbridge, Inco and Noranda have played a leading role in pioneering new process technology and continue to meet the difficult challenge of keeping their operations competitive in the global metals market. This paper will try to give an overview of the major developments in non-ferrous pyrometallurgy, largely from the Noranda and Canadian perspectives, highlighting the current status of process technology and possible future directions.AluminumCanada has the world's second largest aluminum smelting industry and its capacity has expanded rapidly in recent years with the completion of several large projects in Quebec. The location and capacity of the Canadian aluminum smelters are given in Table 2. All these plants use the Hall-Heroult process, that was invented over a century ago but over the last twenty years considerable improvements have been made to increase productivity, reduce power requirements and emissions.The developments in aluminum cell technology can be illustrated by the experience at Noranda Aluminum. In 1971, Noranda Aluminum started its first pot line using Kaiser's P69 prebake cell, which was considered, at that time, the best available technology. The P69 cell was designed primarily for high productivity, operating at 150 000 amps and high current density to produce just over tonne Al per cell-day. The P69 cell is a simple design, typically operating at about 88070 current efficiency and 15 800 kWh/tonne Al. When Noranda Aluminum decided to expand in 1980, the Alcoa 697 cell was selected as it then represented the most proven, stateof- the-art technology. This cell is similar to that installed at Alcan's new Grande Baie and Laterriere smelters and is designed to operate at 180000 amps and 93070 current efficiency, producing about 25070 more aluminum per pot-day than the P69 cell using about 15070 less power. The 697 cell has a much more sophisticated cell design, with very good balancing of the magnetic field giving a flat metal pad and allowing efficient operation at the higher amperage. Alumina is fed via point feeders that provide an almost continuous feed allowing close control of the alumina level in the bath and the use of low-ratio bath composition, giving much higher current efficiencies."

Jan 1, 1991

By S. A. Jacob

Magnesium sheet is notoriously difficult to form at low temperatures without initiating failure, In the present work cold rolling and annealing conditions are varied to produce samples of AZ3lB sheet with a range of grain sizes. The formability of these samples is investigated using tensile testing and forming limit diagrams (FLD's), The results are discussed in terms of twin types and frequencies.

Jan 1, 2005

By R. W. Luhning, S. D. Gittins, J .. A. Haston

"The Underground Test Facility (UTF) project operated by the Alberta Oil Sands Technology and Research Authority (AOSTRA) north of Fort McMurray has achieved marked success in field testing mining access and horizontal well in situ recovery of bitumen from the Athabasca oil sands.Mine access has provided for effective placing and operation of horizontal wells in the oil sands from a tunnel system in the underlying limestone. Performance of the in situ recovery process, Steam Assisted Gravity Drainage, has substantially exceeded forecasts made at the start of the project. Over-all results of the program to date show great promise for horizontal well in situ technology as a competitive source of bitumen from Alberta's vast oil sands deposits. The potential economics of a commercial expansion at the site are reviewed in this paper.IntroductionIn situ recovery o f bitumen from the Athabasca oil sands has puzzled the oil industry for many year s, but a breakthrough appears close at hand. The Underground Test Facility (UTF) project initiated by the Alberta Oil Sands Technology and Research Authority (AOSTRA) has had notable success in the piloting of horizontal well processes, which offer prospects for commercial development even under the highly competitive situation facing the Canadian industry . This paper describes the project briefly and presents the potential economics of commercial development on the UTF lease."

Jan 1, 1990

By Ting An Zhang, Chengzhi Jiang, Xiujing Zhai, Feng Xie

The extraction and concentration of nickel from aqueous solutions by emulsion liquid membranes (ELMs) using tributylphosphate (TBP) as extractant has been investigated in this research. The emulsion liquid membrane consists of a diluent (kerosene), a surfactant (Span 80), a mobile carrier (TBP), and a stripping solution (ammonia solutions). Important factors influencing the separation process including membrane composition, feed composition, and mixing speed have been examined. The results show that more than 90% of nickel in the feed solution could be extracted by ELMs under the experimental conditions, indicating the feasibility to use the designated ELMs to detoxify nickel-containing industrial waste solutions.

Jan 1, 2014

By M. L. Jeremic

"Hydraulic mining consists of coal erosion by powerful jet s of water from hydraulic monitors operated by remote control. The broken coal is crushed and mixed with water and then transported from the face to the surface using gravity whenever possible. This is a simple, safe and productive method. It will easily satisfy North American productivity standards if the structural features and coal properties are favourable for water jet cutting technology (Kaiser Resources Ltd. , hydraulic mine). General ConsiderationIn open-pit mines, placer mining (Fig. I) and hydroelectric construction projects, hydraulic earth moving techniques have been successfully applied. The stripping and transporting of the overburden has been accomplished by means of large monitor jets augmented by slurry pumps and pipes. An extension of this technique has led to the underground extraction of coal and ores. To date, the method has been most successfully used in undergrond coal mining, because the coal can be easily cut and flushed away by water jets, and the rocks of the roof strata can be left behind. Due to this favourable situation, the hydraulic mining definition only relates to the underground coal mines.At present, there are four basic types of hydraulic mining, which can be defined according to the coal breaking technique used in each case. The methods are briefly discussed below:(1) Coal excavation may be carried out by conventional techniques, but the mine is designed and equipped for the hydraulic transport of the mineral from the working place to surface. Under these circumstances, the coal breaking may not be influenced by the water jet, however it may be indirectly involved. For example, pre-loosening of the coal may be done by water infusion-hydraulic fracturing. Water may also be used to flush the broken coal, which has been excavated either by drilling and blasting or by mechanical cutting, into the transport flumes. In other cases, a mechanical loader may load the coal directly into the hydraulic transport system, without using any water for the extraction process. This hydraulic mining concept is primarily used for hard and impermeable coal, such as anthracite."

Jan 1, 1980

"Line Creek Resources Ltd. produces three million clean tonnes per year of metallurgical and thermal coals for the international market. The mining operation, which is located in the mountains of southeastern British Columbia, produces coal from four pits by conventional truck and shovel methods.The South Pit, which has been in operation since J982, has a benched highwall 490 m in height. Shallow dipping coal seams at the base of the syncline formation will be exposed in the highwall over the next four years of pit life. The first of these seams, which will measure 500 m in final highwall length, was exposed in J994. An auger, powered by a 1250 hp engine capable of cutting 2.2 m diameter holes, was brought on site in J994 and has proven to be a successful means of recovering coal from the J3 m thick seam.This paper covers the background to the selection of an auger mining method to recover highwall reserves together with the geotechnical and methane considerations for this approach.IntroductionLine Creek Resources Ltd., a wholly owned subsidiary of Manalta Coal Ltd., owns and operates the Line Creek mine. The operation which consists of four active pits, a processing plant, and rail loadout is located in the southeastern coal fields of British Columbia. Figure 1 shows the general area.The coal bearing sequence at the mine is preserved on the east and west limbs of a major syncline. Up to twelve mineable coal seams, ranging in thickness from 2 m to 15 m are contained in the formation. Within the pits the seams are stratigraphically consistent and structurally undisturbed, except for small-scale thrust faults that create multiple repeats of the seams."

Jan 1, 1995

By A. J. Basu

Air quality in underground mining operations can fluctuate significantly during the working day, but until recently the only way to ensure a mine had sufficient air quality was to over-ventilate and, with significant delay in adjusting the volume or direction of the airflow, working conditions were tolerable but rarely ideal. Underground ventilation management systems have been considered to achieve improved energy efficiency since at least 1995 in Canada. However, Mine Ventilation Optimization, (MVO) and integrating it with Ventilation on Demand (VOD) is only becoming more of a reality in the last seven (7) years. A systems approach to MVO takes into account all the elements from the point the power is distributed into the ventilation fans through to the actual quality and quantity of fresh air to the working face. Opportunities exist throughout the system for energy savings but not all of them are cost-effective. Depending on the application, these opportunities can be easily realized by properly sizing, streamlining, maintaining and operating the ventilation system using premium mine proven energy efficient components throughout. Implementation of VOD is a key step in achieving the MVO objective. However, VOD is a concept, and it requires various tools, procedures, and strategies for cost-effective and operationally viable implementations. This paper provides a historical background in the development of VOD and provides a framework for proper and cost effective implementation. In addition, an optimized ventilation system will also allow increased airflow by reducing resistances and shock losses. This turn in would allow production target improvement, which could be an attractive objective compared to energy savings. Mine ventilation is the life support system of an underground mine, and contributes to sustainable development and corporate social responsibility goals assuring health and safety aspects of strategic planning. The proposed framework addresses implementing mine ventilation optimization integrating ventilation on demand as a vehicle for energy, health and safety improvement and overall productivity gains in the mining cycle efficiency while significantly reducing carbon footprint of a mine.

Aug 1, 2013

By C J. Coveney

This paper, after a brief introduction to the mineralization and structure in the mine area, outlines the methods now being employed for grade control at Bethlehem Copper Corporation. Sampling, subgrade drilling, blasting and the actual outlining of the ore are among the topics covered. The paper concludes with a summary of the results obtained, showing a reduction in dilution and an improvement in the grade of the copper ore going to the mill. Introduction T HE Bethlehem property is located in southern British Columbia in the Highland Valley about 30 miles southeast of the town of Ashcroft. The property is located within the Guichon batholith. The rock comprising the batholith is a massive, coarse-textured diorite, which, at Bethlehem, has been intruded by a younger quartz diorite, porphyries and breccia, referred to as the "Younger Complex." Mineralization, consisting of chalcopyrite and bornite with minor pyrite and molybdenite, occurs as disseminations, fracture fillings and coarse blebs. The ore zone lies close to the Guichon -Younger Complex contact where, prior to the development of the breccia, the rocks were shattered and jointed. Subsequent mineral

Jan 1, 1965

By J. E. Marshall

"The concept of employing a project management team to coordinate all aspects of the construction of a new resource development has gained wide acceptance. This team can be formed from within the staff of large mining companies or contracted from major engineering firms and consultants. The mandate of the project managers usually terminates on successful startup of the operation. For frontier mineral developments in the Canadian Arctic or in the developing countries, startup and the initial year of operation represents the period in which the project is most vulnerable to technical, political and managerial problems. A complete change of the management team or the retention of the construction project managers and the resulting cost combined with the breakdown of organizational accountability within the operating staff .are unnecessary management problems.Independent project management services provide the commitment necessary to sustain the continuity of management through all project phases. Efficiency and the ability to make decisions quickly are characteristics of the many successful small mining companies. These qualities are necessary in the project management group, which will be responsible for up to 90% of the preproduction costs.Continuous project management in the construction and operational phases of a mineral development are common in the iron ore industry, but remain anomalous in the base metal, energy mineral and industrial mineral fields.The Nanisivik project on Baffin Island in the Canadian Arctic is used to illustrate the advantages of total project management through construction and operation.Total project management has further potential for foreign interests and financial and utility organizations desirous of participating in the Canadian mining industry, but with no direct involvement in the construction or operating management. Participation agreements in the operating phase of a project can be negotiated to have management fees related to both the production and the profits of the enterprise."

Jan 1, 1980

By D. R. Spink, G. L. Rempel, C. O. Gomez Bueno

"A morphological and chemical study of the Great Canadian Oil Sands Ltd. (GCOS) fly ash has been carried out. Extensive scanning electron microscopy, as well as light microscopy, showed that the GCOS fly ash consists of two fractions, one composed of unburnt or partially burnt irregular-shaped carbon particles and an ash fraction composed of transparent and opaque, often coloured, glassy spherical particles-some of them cenospheres (hollow spheres) and the others plerospheres (hollow spheres packed with smaller spheres). Microcrystals (0.1 to 0.3 um long) growing on the inner and outer surfaces of some of the spheres were also noted and found to contain more Fe, Ti, Ni and V than the spheres.The carbon-free GCOS fly ash particle size follows a lognormal distribution, with a geometric median particle size (by count) of3.8um and a geometric standard deviation of 1.84. IntroductionCanada's current energy situation strongly suggests that oil from the Alberta tar sands deposits will probably be recovered more extensively in the future. Today's commercially proven technology to recover oil from the Athabasca tar sands, as practised by Great Canadian Oil Sands Ltd. (GCOS), involves two major operations, namely: separation of the bitumen from the sand and upgrading of the bitumen to refinery oil; the production of significant amounts of petroleum coke and sulphur during the bitumen upgrading process. The bulk of the petroleum coke is burnt in boilers to fulfill the energy requirements of the entire operation. The boiler ash, which contains appreciable amounts of metals, such as vanadium, nickel, titanium, iron, aluminum and other elements, is collected in the boiler hoppers and cyclones of the petroleum coke-fired steam generation plants. Thus, as well as representing a petroleum resource, the tar sands represent a resource for vanadium and possibly other metals providing that metal recovery processes can be developed."

Jan 1, 1980

By K. Enns, J. J. Byerley

"While thiocyanate (SCN-) is used in a number of industrial processes (production of polyacrylonitrile filaments, synthesis of agricultural chemicals and certain metallurgical solvent extraction and flotation circuits) it is recognized more as an undesirable by-product associated with ' the metallurgical industry. Thiocyanate is present at low concentrations in some waste streams from the iron and steel industry. Of particular significance is the formation of thiocyanate during cyanidation of gold and silver ores, concentrates, tailing s and residues. The thiocyanate levels present in the resulting effluents may range from a few mg/I to several thousand mg/I.At present, thiocyanate does not appear to be as hazardous in the environment as cyanide (CN-) at the same concentration although its interaction with other species and resulting decomposition of products may be unacceptable. Of course the presence of thiocyanate in the leaching circuit and ultimately in the effluent streams may add considerably to the oxidative requirments of any non-selective treatment process for cyanidation wastes.With respect to the thiocyanate as it relates to the cyanidation process, two aspects are evident. Thiocyanate forms and persists in the cyanidation circuit resulting in a ""fouling"" condition with subsequent loss of leaching activity. In order to reduce or control this problem, it is common practice for some mills to discharge daily as much as 20% of the barren leach liquor. Besides contributing to fouling of the leach liquor the formation of thiocyanate represents an irreversible loss of reagent cyanide. It is noteworthy that in some present or proposed mill practice reagent cyanide loss through thiocyanate formation may reach 50%(1). The purpose of this paper is to discus s the application of controlled electrooxidation of thiocyanate with the view of suggesting a process for regenerating cyanide from waste thiocyanate(2). The paper describes the important theoretical aspects and presents experimental data obtained for thiocyanate electrooxidation using both small and large scale electrochemical reactors. Some economic conclusions are presented."

Jan 1, 1984